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Trapping of the Dichlorocarbene Intermediate in the Reaction of α-Cyanobenzyl carbanion with Carbon Tetrachloride 被引量:1
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作者 Jin Pei CHENG Zi Rong ZHENG(Department of Chemistry, Nankai University, Tianjin 300071) 《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第10期895-896,共2页
In Me2SO, an X-philic reaction took place between α-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1, 1-dichloro... In Me2SO, an X-philic reaction took place between α-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1, 1-dichloro - 2, 3 -dicyano -2, 3 -diphenylcyclopropane. 展开更多
关键词 DICHLOROCARBENE S_N2vs. et mechanism CCl_4
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