Key factors controlling shale oil enrichment in saline lacustrine rift basin:implications from two shale oil wells in Dongpu Depression,Bohai Bay Basin

Comparative analyses of petroleum generation potential,reservoir volume,frackability,and oil mobility were conducted on 102 shale cores from the Dongpu Depression.Results show the shale has high organic matter contents composed of oil-prone type I and type II kerogens within the oil window.Various types of pores and fractures exist in the shale,with a porosity of up to 14.9%.The shale has high brittle mineral contents,extensive fractures,and high potential for oil mobility due to high seepage capacity and overpressure.Although the petroleum generation potential of the shale at Well PS18-8 is relatively greater than that at Well PS18-1,oil content of the latter is greater due to the greater TOC.The porosity and fracture density observed in Well PS18-1 are greater and more conducive to shale oil enrichment.Although the shales in Wells PS18-1 and PS18-8 have similar brittle mineral contents,the former is more favorable for anthropogenic fracturing due to a higher preexisting fracture density.Besides,the shale at Well PS18-1 has a higher seepage capacity and overpressure and therefore a higher oil mobility.The fracture density and overpressure play key roles in shale oil enrichment.

Mixed carbonate rocks lithofacies features and reservoirs controlling mechanisms in a saline lacustrine basin in Yingxi area,Qaidam Basin,NW China

Taking the mixed pre-salt carbonate rocks in the upper member of Eocene Xiaganchaigou Formation(E_(3)^(2))of Yingxi area in the Qaidam Basin as an example,the lithofacies and controlling mechanisms of reservoir formation are analyzed based on a large dataset of cores,thin sections and geochemical analysis.The reservoirs in E_(3)^(2)pre-salt layers have five types of lithofacies,of them,mixed granular calcareous dolostone,massive calcareous dolostone,plaque calcareous dolostone,and laminated dolomtic limestone are of sedimentary origin,and breccia calcareous dolostone is of tectonic origin.The four types of sedimentary lithofacies are divided into two types of saline sedimentary sequence lithofacies combinations,low-energy type in the sag area and low to high-energy type in the slope and paleo-uplift zone in the depression.Affected by high-frequency supply of continental clastic material,the two types of salty sedimentary sequences are mostly incomplete subtypes of lithofacies.Lithofacies have strong impacts on pre-salt reservoirs in E_(3)^(2):(1)Lithofacies type and sedimentary sequence controlled the formation and distribution of dolomite intercrystalline pores and dissolved pores during the pene-sedimentary period.(2)The structure of laminated dolomitic limestone controlled the formation of large-scale laminated fractures and high permeability channels during the diagenetic period.(3)Granular,massive,plaque calcareous dolostones have low mud content and strong brittleness,in the late tectonic reactivation period,the distribution of the three types of lithofacies,together with their distance from the top large slip faults and secondary faults,controlled the formation and distribution of high-efficiency fracture-cave brecciaed calcareous dolostone reservoirs.The above research led to the composite lithofacies-tectonic formation model of pre-salt reservoir in E_(3)^(2)of Yingxi area.The tempo-spatial distribution of tectonic breccia calcareous dolostone reservoirs,laminated dolomitic limestone shale oil reservoirs and granular,massive calcareous dolostone dissolved-intercrystalline pore tight reservoirs in various structural belts of the studied area have been figured out.These findings gave new insights into tight-shale oil accumulation theory in mixed carbonate successions from saline lacustrine basins,aiding in high efficient exploration and development of petroleum in the studied area.

Effects of deep alkaline and acidic fluids on reservoir developed in fault belt of saline lacustrine basin

Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.

Vertical properties of nutrients and oxygen under temperature-salinity structure of the Bering Basin in July 1999

The China R/V Xuelong went on the first Arctic scientific cruise, and we obtained 271 hydro-chemical samples from 22 deep-sea stations in the Bering Basin in late July, 1999. Here we describe vertical properties of silicate [Si] , dissolved inorganic nitrogen [DIN] or [N] (nitrate plus ammonium plus nitrite) , phosphate [P] and oxygen [ O2 ] in seawater under potential temperature-salinity structure. The seasonal stratification in the summer and the water exchanges of the North Pacific Ocean over the Bering Basin resulted in that the four layers of vertical structure with two thermoclines may be found. Vertical [Si] and [N] and [P] profiles show that the nutrients are consumed mainly in ≤50 m and the order of deficient nutrients is [Si] the first, [N] the second and [P] the third. The [N] and [P] increase with depth downward to about 500 m and then both decrease, but the [Si] increases from 150 m to 2000 m or the bottom. In ≥ 150 m the [ O2 ] decreases, which is related with both [P] and [N] increasing closely. Seawater [N] :[P] ratios are 6 - 12 in =≤50 m, 10.5 - 14.3 in 100 - 150 m and 11.7 - 15.8 from 300 m to the bottom.

Geochemical characteristics of aromatic hydrocarbons in saline lacustrine crude oils and their significance as exemplified by the south area of western Qaidam Basin

Based on quantitative GC-MS analysis of 40 crude oil samples collected from the south area of western Qaidam Basin,one of the largest saline lacustrine basins in China,the geochemical characteristics of aromatic hydrocarbons in oils were studied systematically in this paper.Among those constitutes,naphthalene(43% 59%),phenanthrene(12% 21%) and taromatic-sterane series(6% 28%) were the main ones of aromatic hydrocarbons.The ratio of aromatic hydrocarbon maturity parameter vs.saturated hydrocarbon maturity parameter C 29 20S/(20S+20R) shows that some aromatic hydrocarbon maturity parameters are not suitable for low-mature oils,including MPI,MNR,DNR,etc.Meanwhile,maturity parameters for dibenzothiophene and taromatic-sterane series are more appropriate for low maturity saline lacustrine crude oils.Based on the ratio of 4,6-DMDBT/1,4-DMDBT,the R c values are within the range of 0.59% 0.72%.However,the abundance of dibenzothiophene(DBT) is low,and the dibenzofuran(DBF) content is even lower,suggesting that the crude oils were formed in a saline lacustrine anaerobic environment.The high abundance of C 26 triaromatic steroid also indicates that the source material is brackish water-saline water with strong reducibility.

Development,sand control mechanism and hydrocarbon accumulation of beach-bar sandstone in a saline lake basin:A case from the Neogene of southwestern Qaidam Basin,NW China

Based on the data of field outcrops,drilling cores,casting thin sections,well logging interpretation,oil/gas shows during drilling,and oil/gas testing results,and combined with modern salt-lake sediments in the Qinghai Lake,the Neogene saline lake beach-bars in southwestern Qaidam Basin are studied from the perspective of sedimentary characteristics,development patterns,sand control factors,and hydrocarbon accumulation characteristics.Beach-bar sand bodies are widely developed in the Neogene saline lake basin,and they are lithologically fine sandstone and siltstone,with wavy bedding,low-angle cross bedding,and lenticular-vein bedding.In view of spatial-temporal distribution,the beach-bar sand bodies are stacked in multiple stages vertically,migratory laterally,and extensive and continuous in NW-SE trending pattern in the plane.The stacking area of the Neogene beach-bar sandstone is predicted to be 3000 km^(2).The water salinity affects the sedimentation rate and offshore distance of beach-bar sandstone,and the debris input from the source area affects the scale and enrichment of beach-bar sandstone.The ancient landform controls the morphology and stacking style of beach-bar sandstone,and the northwest monsoon driving effect controls the long-axis extension direction of beach-bar sandstone.The beach-bars have a reservoir-forming feature of“one reservoir in one sand body”,with thick beach-bar sand bodies controlling the effective reservoir distribution and oil-source faults controlling the oil/gas migration and accumulation direction.Three favorable exploration target zones in Zhahaquan,Yingdong-eastern Wunan and Huatugou areas are proposed based on the analysis of reservoir-forming elements.

Role of Natural and Anthropogenic Influence on the Salinization of Groundwater from Basement Aquifers in the Middle Part of Mono River Basin, Togo

This study aimed to identify the role of natural and anthropogenic influence on geochemical processes controlling groundwater salinization in the middle portion of the Mono River basin, Togo. Multivariate statistical analysis, geochemical masse balance modeling, and conventional graphical methods were applied to the chemical dataset obtained from 110 groundwater samples collected during two campaigns (March-May 2011 and April 2014). The results showed that groundwater is predominantly fresh, acidic to circumneutral and mixed cations-HCO-3 water types. The proportion of ions (Na+, K+, Cl- and SO2-4) occurring ubiquitously in a saline environment increases substantially with TDS. Two factors, defined as natural and anthropogenic, account for 76.5% of the hydrochemical dataset variance. Based on the hierarchical cluster analysis, groundwater samples are classified into four clusters that corroborate the factor analysis results and illustrate different hydrochemical evolution stages along a topographically-driven groundwater flow path. The primary natural process contributing to cations and bicarbonate ions is the weathering of silicate minerals and possibly secondary carbonates by infiltrating water enriched with soil CO2 gas. Groundwater salinization indicators including Cl-, SO2-4 and NO-3, originate from potential sources such as human and animal wastes, agrochemicals, and deforestation. Thermodynamic equilibrium conditions ranged from saturation to oversaturation with respect to quartz, chalcedony, amorphous silica, calcite, dolomite, sepiolite, and talc. In conjunction with the lowering of CO2 partial pressure and evaporation, these conditions restrict acidic hydrolysis of primary silicates but magnify the groundwater salinization process in the lower elevation areas where soil crusts’ formation is favorable. This study showed the effective use of multivariate statistical analysis and complementary techniques in identifying the significant factors and processes controlling groundwater chemistry.

Development and Utilization of Saline Lake Resources and Protection of Ecological Environment in Qaidam Basin in Qinghai Province

Qaidam basin is an important part of National Key Development Area–Lanzhou-Xining Area,is a key region of resource development in Western Development,is a National Circular Economy Pilot Zone.The focus of

Influence of salinity and moisture on the threshold shear velocity of saline sand in the Qarhan Desert, Qaidam Basin of China: A wind tunnel experiment

Determination of the threshold shear velocity is essential for predicting sand transport,dust release and desertification.In this study,a wind tunnel experiment was conducted to evaluate the influence of salinity and moisture on the threshold shear velocity of saline sand.Saline sand samples(mean particle size of 164.50–186.08μm and the total silt,clay and salt content of 0.80%–8.25%)were collected from three saline sand dunes(one barchan dune and two linear dunes)in the Qarhan Desert,Qaidam Basin of China.Original saline sand samples were placed in two experimental trays for wet and dry processing to simulate deliquescence and desiccation,respectively.Surface moisture content ranging from 0.30% to 1.90% was generated by the steam method so that the saline sand can absorb water in a saturated water vapor environment.The motion of sand particles was determined by the observers with a solid laser.The laser sheet(0.80 cm thick),which was emitted by the solid laser,horizontally covered the sand surface and was bound to the sand.Results show that the cohesion of saline sand results from a combination of salt and water.The threshold shear velocity increases exponentially with the increase in crust thickness for the linear sand dunes.There is a positive linear correlation between the original moisture content and relative threshold shear velocity.The threshold shear velocity of dewatered sand is greater than that of wet sand with the same original moisture content.Our results will provide valuable information about the sand transport of highly saline soil in the desert.

Stable Isotope and Element Geochemistry of Saline Springs in Evaporite-bearing Mengla Basin,South Yunnan,China

1 Introduction Mengla Basin is a sub-basin in southern evaporitebearing Lanping-Simao Basin.There are many salt springs in the basin.In 2012,11 spring samples were collected for analyses of chemistry and boron,hydrogen and oxygen

利用生物标志化合物划分缅甸Salin盆地含油气系统(英文)

中国石油天然气勘探开发公司于2001年和2002年在缅甸国家油气勘探开发招标中获得4个油气勘探开发区块,总面积3514 km2。由于这些区块勘探程度低,而且区块分布分散,勘探风险大、难度高,为了降低投资风险,争取中方利益最大化,有必要对该区油气地质条件和资源前景进行综合分析。但限于资料和样品,仅选取Salin盆地不同油田不同层位的12个原油样品,在缺乏烃源岩样品的情况下,开展原油生物标志化合物的对比分析。对比结果表明,不同原油生物标志化合物组成特征差异明显,据此将原油分为3类,分别源自3个不同的生烃灶,进而划分出3个可能的含油气系统,并指出不同区块具有不同的勘探目的层系。原油中羽扇烷和双杜松烷的检出,表明原油源自上白垩统或第三系陆相烃源岩。

Distribution of sterane maturity parameters in a lacustrine basin and their control factors:A case study from the Dongying Sag,East China

Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity ratios C29ββ/（ββ＋αα） and C2920S/（20S＋20R） and their control factors in the natural geological profile and sequence. The results showed that progressive changes in molecular maturity parameters are associated with major changes in thermal evolution of related biomarkers. Increases in the C29ββ/（ββ＋αα） and C2920S/（20S＋20R） ratios result from the difference in the relative rate between generation and thermal degradation of isomers involved. The samples from a hyper-saline environment below 3.5 km in which evaporitic rocks deposited shows high response of Sr/Ba, Sr/Ca, Fe/ Mn, Pr/n-C17, Ph/n-C18 and gammacerane and low response of Pr/Ph. There presents negative reversal of biomarker maturity C29ββ/（ββ＋αα, C29ββ/（ββ＋αα） and Ts/（Ts＋Ym） in the samples from hypersaline environment, reflecting that the gypsum- halite have negative effect on the isomerization of biomarker and thermal evolution of organic matter. The minerals in evaporites also retard the conventional thermal indicators including vitrinite reflectance （Ro） and pyrolysis peak temperature Tmax at the depth below 3.4 km （i.e. 〉3.4 km）, and these parameters also show the inhibition from overpressure in the range of 2.4-3.4 kin. This result will be helpful in the interpretation and application of molecular maturity parameters for similar saline lacustrine basins.

Discovery of shale oil in alkaline lacustrine basins:The Late Paleozoic Fengcheng Formation,Mahu Sag,Junggar Basin,China

A new type of shale oil in alkaline lacustrine sediments has been discovered in the Late Paleozoic Fengcheng Formation,Mahu Sag,Junggar Basin,China.The fine-grained sedimentary rocks deposited in this alkaline lacustrine environment can be divided into four types and eight sub-types:mudstone(with no alkali minerals),including massive dolomitic mudstone,and massive and laminated calcareous mudstone;dolomite,including massive argillaceous dolomite(with alkali minerals),and massive and laminated argillaceous dolomite(with no alkali minerals);evaporites;and pyroclastic rocks.The massive argillaceous dolomite(with alkali minerals)and pyroclastic rocks have the highest shale oil potential,with average oil saturation index(OSI)values of 344.67 and 124.65 mg HC/g TOC,respectively.Shale oil exploration in the representative well MY1 indicates that the Fengcheng Formation is thick and contains abundant natural fractures,brittle minerals,and mobile oil.The entire Fengcheng Formation is oilbearing and contains three concentrated stratigraphic intervals of shale oil(i.e.,sweet spots).Well MY1 indicates that,compared with source rocks developed in marine and sulfate-type saline basins,the fine-grained sedimentary rocks deposited in alkaline lacustrine environments can also have high shale oil potential.The co-existence and regular distribution of conventional and unconventional reservoirs in the Fengcheng Formation indicate that it is an ideal exploration target for multiple resource types.

Groundwater hydrochemistry and isotope geochemistry in the Turpan Basin, northwestern China

The Turpan Basin is located in the arid zone of northwestern China and is a typical closed inland basin surrounded by high mountains. It is one of the most arid regions in the world and, as a result, the groundwater in this area is very important for both domestic and agricultural uses. In the present study, the relationships of major elements（K＋, Na＋, Ca2＋, Mg2＋, HCO3-, SO42- and Cl-） and environmental isotopes（δ18O, δ2H and T） in groundwater were analyzed to investigate the evolution of the regional hydrochemistry within the Turpan Basin. The hydrochemistry results demonstrate that groundwater with high total dissolved solids（TDS） concentration is dominated by sodium chloride（Na-Cl） and sodium sulfate（Na-SO4） type water, whereas that with low TDS concentration（typically from near mountain areas） is dominated by calcium bicarbonate（Ca-HCO3） type water. The evolution of groundwater hydrochemistry within the Turpan Basin is a result of calcium carbonate precipitation, evaporation concentration, cation exchange and dissolution of evaporites（i.e. halite, mirabilite and gypsum）. Furthermore, evaporite dissolution associated with irrigation practice plays a key role in the groundwater salinization, especially in the central part of the basin. Environmental isotopes reveal that the groundwater is recharged by precipitation in the mountain areas and fast vertical infiltration of irrigation return flow. In the southern sub-basin the shallow groundwater and the deep groundwater is separated at a depth of about 40 m, with substantial differences in terms of hydrochemical and isotopic characteristics. The results are useful for decision making related to sustainable water resource utilization in the Turpan Basin and other regions in northwestern China.

Responses of germination and radicle growth of two Populus species to water potential and salinity

Abstract The effects of water potential, NaCl and Na2SO4 on germination and radicle growth of two riparian tree species, Populus euphratica Oliv. and P. pruinosa Schrenk （Salicaceae）, were tested. Growth chamber studies revealed an optimum temperature range for seed germination of both species between 15-35℃. The final germination percentage of both species decreases with decreasing water potential in all types of solution applied in the experiments. P. pruinosa was less tolerant to low ψw stress than P. euphratica, especially in salt solutions. Germination percentages fell below 20% for P. pruinosa at -0.6 MPa （NaCl） or -0.4 MPa （Na2SO4） and for P. euphratica at -1.2 MPa （NaCl） or -0.6 MPa （Na2SO4）. Radicle growth of both species was inhibited by high concentrations of PEG1 NaCl and Na2SO4. However, growth was enhanced at -0.13 and -0.29 MPa in PEG or at -0.13 MPa in NaCl solutions compared to distilled water. Radicle growth of P. euphratica was higher than that of P pruinosa. Germination and radicle growth of both species exhibited ion toxicity. Na2SO4 was more toxic than iso-osmotic solutions of NaCl. Radicle growth proved to be more sensitive than seed germination. Thus, flooding does not only yield the necessary soil moisture for germination but also favors seedling establishment of both species through leaching of salts from the soil surface. The different sensitivity of the species during their early growth stages might, moreover, contribute to the observed differences in their distribution in the Talim Basin （northwest China）.

Cretaceous Phytoplankton Assemblages from Songke Core-1,North and South(SK-1,N and S) of Songliao Basin,Northeast China

Cretaceous phytoplankton from the newly completed core hole （SK-1, N＆S） in the central Songliao Basin was studied. The target interval is from the upper Quantou Formation of Upper Cretaceous to Mingshui Formation. Twelve genera of dinoflagellates, six of acritarcha and three of chlorophyta were identified in 588 samples from the 2300-m deep core. Ten phytoplankton assemblages have been classified： Tetranguladinium.Subtilisphaera.Botryococcus, Botryococcus- Pediastrum, Pediastrum, Dinogymniopsis-Chlamydophrella-Vesperopsis bifurcate, Dinogymniopsis minor-Balmula, Pediastrum.Botryococcus, Schizosporis-Campenia, Kiokansium.Dinogymniopsis- Botryococcus, Dinogymniopsis-Granodiscus-Filisphaeridium and Granodiscus. According to the findings mentioned above, the age of the upper Qantou Formation is Cenomanian, the Qingshankou Formation belongs to upper Cenomanian-Turonian, the Yaojia Formation to Coniancian-Santonian age, the Nenjiang Formation is of Campanian age, and Sifangtai-Mingshui formations are referred to Maastrichtian stage. The ecology of phytoplankton is closely related to water salinity. Each type of phytoplankton is within a certain living water mass whose evolution type reflects salinity change of the Songliao Lake. The assemblages from the SK-1 indicate that water salinity changes with the cycle of freshwater-slight brackish water-brackish water-slight brackish water-freshwater in the lake.

A double-halocline structure in the Canada Basin of the Arctic Ocean

A year-round halocline is a particular hydrographic structure in the upperArctic Ocean. On the basis of an analysis of the hydrographic data collected in the Arctic Ocean, itis found that a double-halocline structure exists in the upper layer of the southern Canada Basin,which is absolutely different from the Cold Halocline Layer (CHL) in the Eurasian Basin. ThePacific-origin water is the primary factor in the formation of the double-halocline structure. Theupper halocline lies between the summer modification and the winter modification of thePacific-origin water while the lower halocline results from the Pacific-origin water overlying uponthe Atlantic-origin water. Both haloclines are all the year-round although seasonal and interannualvariations have been detected in the historical data.

Uranium in Saline Lakes of Mongolia and Adjacent Areas

1 Introduction Increasing demand for uranium raw materials for the nuclear industry has stimulated interest in non-traditional sources,including hydromineral ones[Qin,2009].Those are saline lakes located in the uranium ore districts.Accumulation of uranium in such lakes results from the leaching of uranium from the rocks by surface and ground

Geochemical characterization of aromatic hydrocarbons in crude oils from the Tarim,Qaidam and Turpan Basins,NW China

Based on the systematic study of aromatic hydrocarbons in over 100 crude oil samples collected from the Tabei and Tazhong uplifts in the Tarim Basin,the western depression area in the Qaidam Basin and the Tabei depression in the Turpan Basin,the geochemical characteristics of the marine（Tarim Basin）,saline lacustrine（Qaidam Basin）,and swamp（Turpan Basin） oils were investigated.The marine oils from the Tarim basin are characterized by relatively low abundance of diaromatic hydrocarbons such as biphenyl and naphthalene,and relatively high abundance of triaromatic hydrocarbons including phenanthrene,dibenzothiophene and fluorene.In contrast,the swamp oils from the Turpan Basin are dominated by the highest relative abundance of diaromatic hydrocarbons and the lowest relative abundance of triaromatic hydrocarbons in all the oil samples in this study.The relative abundance of diaromatic and triaromatic hydrocarbons in the saline lacustrine oils from Qaidam Basin is between that in Tarim oils and Turpan oils.Aromatic parameters based on the isomer distributions of dimethylnaphthalenes（DMN）,trimethylnaphthalenes（TMN）,tetramethylnaphthalenes（TeMN） and methylphenanthrenes（MP）,i.e.,1,2,5-trimethylnaphthalene（TMN）/1,3,6-TMN ratio,1,2,7-TMN/1,3,7TMN ratio,（2,6-＋2,7-）-dimethylnaphthalenes（DMN）/1,6-DMN ratio,1,3,7-TMN/（1,2,5-＋1,3,7-）TMN,1,3,6,7-TeMN/（1,3,6,7-＋1,2,5,6-＋1,2,3,5-）-TeMN ratio and MP index,may reflect the diversity of organic source input,thermal maturity and depositional environments.In addition,the dibenzothiophenes（DBTs）/fluorenes（Fs） and dibenzofurans（DBFs）/Fs ratios were found to the very useful and effective in determining genetic types of crude oils for the marine,saline lacustrine,and swamp depositional environments,and for oil-oil correlations.

Mg/Ca Variation in Planktonic Foraminiferal Tests:Assessing Influence of Salinity and Diagenetic Carbonate Dissolution for Reconstruction of Palaeo-seawater Temperature

Over the past decade,the Mg/Ca ratio in foraminiferal tests has emerged as a valuable paleotemperature proxy.In this study we describe the application of the Mg/Ca paleothermometer with the aim of illustrate its use in the Mediterranean Basin.We value the influence of the salinity and diagenetic carbonate processes besides temperature as an important environmental factor controlling the foraminiferal Mg/Ca.For this purpose 3 species of