Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity grad...Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold.展开更多
The importance and the necessary of researches on renewable energy have become a hot topic in recent years due to climate change and global warming. In addition, the fossil fuel reserves is facing rapid depletion on t...The importance and the necessary of researches on renewable energy have become a hot topic in recent years due to climate change and global warming. In addition, the fossil fuel reserves is facing rapid depletion on the earth. Currently, most researches have concentrated on producing biogas for heating, lighting, drying, cooking but lack in researching on electricity production because the possibility of producing biogas at households are common at small scale. Studying on alternative energy sources to replace traditional fuel for electric power generation brings new chances and great opportunities for development. This study presents an assessment electric power generation via water hyacinths and agricultural waste. In this paper, the evaluation electric power is generated by operating internal combustion engines which use biogas fuel to replace traditional fuel (diesel, gasoline). The results of the studies were demonstrated by experiments on the renewable energy production system at Hoa An Biotechnology Research and Experimental Center of Cantho University.展开更多
A deep understanding of the electricity generation mechanism from the interaction between water molecules and carbon material surfaces is attractive for next-generation water-based energy conversion and storage system...A deep understanding of the electricity generation mechanism from the interaction between water molecules and carbon material surfaces is attractive for next-generation water-based energy conversion and storage systems.Herein,an asymmetric generator was assembled based on functionalized carbon nanotubes films to investigate the relative contribution from various oxygen functional groups on carbon surface to the water-electrical performance.Experiments and calculations demonstrate that the electricity mainly originates from the water molecule adsorption by carboxyl groups and dissociation of functional groups on carbon surface,which leads to the formation of electrical double layers at interfaces.This device allows the electricity generation with a variety of water sources,such as deionized water,tap water,as well as seawater.In particular,the generator based on carboxyl carbon nanotubes can induce a voltage of over 200 mV spontaneously in natural seawater with the power density of about 0.11 mW·g^(−1).High voltages can be achieved easily through the series-connection strategy to power electronic products such as a liquid crystal display.This work reveals the dominant role of carboxyl groups in carbon-based water–electricity conversion and is expected to offer inspiration for the preparation of carbon materials with high electrical performance.展开更多
In this paper,we present five basic types of renewable energy sources,namely:wind turbines,solar cells,small hydroelectric plants,biomass,and geothermal sources of energy.Wind turbines transform energy of wind into el...In this paper,we present five basic types of renewable energy sources,namely:wind turbines,solar cells,small hydroelectric plants,biomass,and geothermal sources of energy.Wind turbines transform energy of wind into electrical energy,solar cells transform energy of sun into electric energy,hydroelectric plants transform energy of water into electric energy,devices or machines can be constructed to transform energy of biomass into heat energy,and geothermal energy into some form of energy.In this paper we present basic information and reasons why there is need today to use these forms of energy—called green energies,we present how these devices or machines function,and we propose for future work design of typical devices or machines that will satisfy basic functional needs.展开更多
Water evaporation-induced electricity generation is a promising technology for renewable energy harvesting.However,the output power of some reported two-dimensional(2D)nanofluidic films is still restricted by the rela...Water evaporation-induced electricity generation is a promising technology for renewable energy harvesting.However,the output power of some reported two-dimensional(2D)nanofluidic films is still restricted by the relatively weak water–solid interactions within the tortuous nanochannels.To further enhance the comprehension and utilization of water–solid interactions,it is of utmost importance to conduct an in-depth investigation and propose a regulatory concept encompassing ion transport.Herein,we propose tortuosity regulation of 2D nanofluidic titanium oxide(Ti_(0.87)O_(2))films to optimize the ion transport within the interlayer nanochannel for enhanced efficiency in water evaporation-induced electricity generation for the first time.The significance of tortuosity in ion transport is elucidated by designing three 2D nanofluidic films with different tortuosity.Tortuosity analysis and in situ Raman measurement demonstrate that low tortuosity can facilitate the formation of efficient pathways for hydrated proton transport and promote water–solid interactions.Consequently,devices fabricated with the optimized 2D nanofluidic films exhibited a significantly enhanced output power density of approximately 204.01μW·cm^(−2),far exceeding those prepared by the high-tortuosity 2D nanofluidic films.This work highlights the significance of the construction of low tortuosity channels for 2D nanofluidic films with excellent performance.展开更多
The development of highly efficient energy conversion technologies to extract energy from wastewater is urgently needed,especially in facing of increasing energy and environment burdens.Here,we successfully fabricated...The development of highly efficient energy conversion technologies to extract energy from wastewater is urgently needed,especially in facing of increasing energy and environment burdens.Here,we successfully fabricated a novel hybrid fuel cell with BiOCl-NH_(4)PTA as photocatalyst.The polyoxometalate(NH_(4)PTA)act as the acceptor of photoelectrons and could retard the recombination of photogenerated electrons and holes,which lead to superior photocatalytic degradation.By utilizing BiOCl-NH_(4)PTA as photocatalysts and Pt/C air-cathode,we successfully constructed an electron and mass transfer enhanced photocatalytic hybrid fuel cell with flow-through field(F-HFC).In this novel fuel cell,dyes and biomass could be directly degraded and stable power output could be obtained.About 87%of dyes could be degraded in 30 min irradiation and nearly 100%removed within 90 min.The current density could reach up to~267.1μA/cm^(2);with maximum power density(Pmax)of~16.2μW/cm^(2) with Rhodamine B as organic pollutant in F-HFC.The power densities were 9.0μW/cm^(2),12.2μW/cm^(2),and 13.9μW/cm^(2) when using methyl orange(MO),glucose and starch as substrates,respectively.This hybrid fuel cell with BiOCl-NH_(4)PTA composite fulfills the purpose of decontamination of aqueous organic pollutants and synchronous electricity generation.Moreover,the novel design cell with separated photodegradation unit and the electricity generation unit could bring potential practical application in water purification and energy recovery from wastewater.展开更多
Electrochemical oxidation/reduction of radicals is a green and environmentally friendly approach to generating fuels.These reactions,however,suffer from sluggish kinetics due to a low local concentration of radicals a...Electrochemical oxidation/reduction of radicals is a green and environmentally friendly approach to generating fuels.These reactions,however,suffer from sluggish kinetics due to a low local concentration of radicals around the electrocatalyst.A large applied electrode potential can enhance the fuel generation efficiency via enhancing the radical concentration around the electrocatalyst sites,but this comes at the cost of electricity.Here,we report about a~45%saving in energy to achieve an electrochemical hydrogen generation rate of 3×10^(16) molecules cm^(–2)s^(–1)(current density:10 mA/cm^(2))through localized electric field-induced enhancement in the reagent concentration(LEFIRC)at laser-induced periodic surface structured(LIPSS)electrodes.The finite element model is used to simulate the spatial distribution of the electric field to understand the effects of LIPSS geometric parameters in field localization.When the LIPSS patterned electrodes are used as substrates to support Pt/C and RuO_(2) electrocatalysts,the η_(10) overpotentials for HER and OER are decreased by 40.4 and 25%,respectively.Moreover,the capability of the LIPSS-patterned electrodes to operate at significantly reduced energy is also demonstrated in a range of electrolytes,including alkaline,acidic,neutral,and seawater.Importantly,when two LIPSS patterned electrodes were assembled as the anode and cathode into a cell,it requires 330 mVs of lower electric potential with enhanced stability over a similar cell made of pristine electrodes to drive a current density of 10 mA/cm^(2).This work demonstrates a physical and versatile approach of electrode surface patterning to boost electrocatalytic fuel generation performance and can be applied to any metal and semiconductor catalysts for a range of electrochemical reactions.展开更多
To this day, only two types of solar power plants have been proposed and built: high temperature thermal solar one and photovoltaic one. It is here proposed a new type of solar thermal plant using glass-top flat surfa...To this day, only two types of solar power plants have been proposed and built: high temperature thermal solar one and photovoltaic one. It is here proposed a new type of solar thermal plant using glass-top flat surface solar collectors, so working at low temperature (i.e., below 100°C). This power plant is aimed at warm countries, i.e., the ones mainly located between -40° and 40° latitude, having available space along their coast. This land based plant, to install on the seashore, is technologically similar to the one used for OTEC (Ocean Thermal Energy Conversion). This plant, apart from supplying electricity with a much better thermodynamic efficiency than OTEC plants, has the main advantage of providing desalinated water for drinking and irrigation. This plant is designed to generate electricity (and desalinated water) night and day and all year round, by means of hot water storage, with just a variation of the power delivered depending on the season.展开更多
基金This work was supported by the National Key Research and Development Program of China(2022YFB4101600,2022YFB4101605)the National Natural Science Foundation of China(52372175,51972040)+1 种基金the Innovation and Technology Fund of Dalian(N2023JJ12GX020,2022JJ12GX023)Liaoning Normal University 2022 Outstanding Research Achievements Cultivation Fund(No.22GDL002).The authors also acknowledge the assistance of the DUT Instrumental Analysis Center.
文摘Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold.
文摘The importance and the necessary of researches on renewable energy have become a hot topic in recent years due to climate change and global warming. In addition, the fossil fuel reserves is facing rapid depletion on the earth. Currently, most researches have concentrated on producing biogas for heating, lighting, drying, cooking but lack in researching on electricity production because the possibility of producing biogas at households are common at small scale. Studying on alternative energy sources to replace traditional fuel for electric power generation brings new chances and great opportunities for development. This study presents an assessment electric power generation via water hyacinths and agricultural waste. In this paper, the evaluation electric power is generated by operating internal combustion engines which use biogas fuel to replace traditional fuel (diesel, gasoline). The results of the studies were demonstrated by experiments on the renewable energy production system at Hoa An Biotechnology Research and Experimental Center of Cantho University.
基金the financial support from the National Natural Science Foundation of China(Nos.52172038 and 22179017).
文摘A deep understanding of the electricity generation mechanism from the interaction between water molecules and carbon material surfaces is attractive for next-generation water-based energy conversion and storage systems.Herein,an asymmetric generator was assembled based on functionalized carbon nanotubes films to investigate the relative contribution from various oxygen functional groups on carbon surface to the water-electrical performance.Experiments and calculations demonstrate that the electricity mainly originates from the water molecule adsorption by carboxyl groups and dissociation of functional groups on carbon surface,which leads to the formation of electrical double layers at interfaces.This device allows the electricity generation with a variety of water sources,such as deionized water,tap water,as well as seawater.In particular,the generator based on carboxyl carbon nanotubes can induce a voltage of over 200 mV spontaneously in natural seawater with the power density of about 0.11 mW·g^(−1).High voltages can be achieved easily through the series-connection strategy to power electronic products such as a liquid crystal display.This work reveals the dominant role of carboxyl groups in carbon-based water–electricity conversion and is expected to offer inspiration for the preparation of carbon materials with high electrical performance.
文摘In this paper,we present five basic types of renewable energy sources,namely:wind turbines,solar cells,small hydroelectric plants,biomass,and geothermal sources of energy.Wind turbines transform energy of wind into electrical energy,solar cells transform energy of sun into electric energy,hydroelectric plants transform energy of water into electric energy,devices or machines can be constructed to transform energy of biomass into heat energy,and geothermal energy into some form of energy.In this paper we present basic information and reasons why there is need today to use these forms of energy—called green energies,we present how these devices or machines function,and we propose for future work design of typical devices or machines that will satisfy basic functional needs.
基金supported by the National Natural Science Foundation of China(Nos.22179062,52125202,and U2004209)the Natural Science Foundation of Jiangsu Province(No.BK2023010081)Fundamental Research Funds for the Central Universities(No.30922010303).
文摘Water evaporation-induced electricity generation is a promising technology for renewable energy harvesting.However,the output power of some reported two-dimensional(2D)nanofluidic films is still restricted by the relatively weak water–solid interactions within the tortuous nanochannels.To further enhance the comprehension and utilization of water–solid interactions,it is of utmost importance to conduct an in-depth investigation and propose a regulatory concept encompassing ion transport.Herein,we propose tortuosity regulation of 2D nanofluidic titanium oxide(Ti_(0.87)O_(2))films to optimize the ion transport within the interlayer nanochannel for enhanced efficiency in water evaporation-induced electricity generation for the first time.The significance of tortuosity in ion transport is elucidated by designing three 2D nanofluidic films with different tortuosity.Tortuosity analysis and in situ Raman measurement demonstrate that low tortuosity can facilitate the formation of efficient pathways for hydrated proton transport and promote water–solid interactions.Consequently,devices fabricated with the optimized 2D nanofluidic films exhibited a significantly enhanced output power density of approximately 204.01μW·cm^(−2),far exceeding those prepared by the high-tortuosity 2D nanofluidic films.This work highlights the significance of the construction of low tortuosity channels for 2D nanofluidic films with excellent performance.
基金supported by the National Natural Science Foundation of China(Nos.51738013,52022048 and 51978371)the Excellent Innovation Project of Research Center for EcoEnvironmental Sciences(No.CAS RCEES-EEI-2019-02).
文摘The development of highly efficient energy conversion technologies to extract energy from wastewater is urgently needed,especially in facing of increasing energy and environment burdens.Here,we successfully fabricated a novel hybrid fuel cell with BiOCl-NH_(4)PTA as photocatalyst.The polyoxometalate(NH_(4)PTA)act as the acceptor of photoelectrons and could retard the recombination of photogenerated electrons and holes,which lead to superior photocatalytic degradation.By utilizing BiOCl-NH_(4)PTA as photocatalysts and Pt/C air-cathode,we successfully constructed an electron and mass transfer enhanced photocatalytic hybrid fuel cell with flow-through field(F-HFC).In this novel fuel cell,dyes and biomass could be directly degraded and stable power output could be obtained.About 87%of dyes could be degraded in 30 min irradiation and nearly 100%removed within 90 min.The current density could reach up to~267.1μA/cm^(2);with maximum power density(Pmax)of~16.2μW/cm^(2) with Rhodamine B as organic pollutant in F-HFC.The power densities were 9.0μW/cm^(2),12.2μW/cm^(2),and 13.9μW/cm^(2) when using methyl orange(MO),glucose and starch as substrates,respectively.This hybrid fuel cell with BiOCl-NH_(4)PTA composite fulfills the purpose of decontamination of aqueous organic pollutants and synchronous electricity generation.Moreover,the novel design cell with separated photodegradation unit and the electricity generation unit could bring potential practical application in water purification and energy recovery from wastewater.
基金National Natural Science Foundation of China (grant nos.62134009,62121005)the Innovation Grant of Changchun Institute of Optics,Fine Mechanics and Physics (CIOMP),Jilin Provincial Science and Technology Development Project (grant no:YDZJ202102CXJD002)Bill&Melinda Gates Foundation (grant no:OPP1157723)
文摘Electrochemical oxidation/reduction of radicals is a green and environmentally friendly approach to generating fuels.These reactions,however,suffer from sluggish kinetics due to a low local concentration of radicals around the electrocatalyst.A large applied electrode potential can enhance the fuel generation efficiency via enhancing the radical concentration around the electrocatalyst sites,but this comes at the cost of electricity.Here,we report about a~45%saving in energy to achieve an electrochemical hydrogen generation rate of 3×10^(16) molecules cm^(–2)s^(–1)(current density:10 mA/cm^(2))through localized electric field-induced enhancement in the reagent concentration(LEFIRC)at laser-induced periodic surface structured(LIPSS)electrodes.The finite element model is used to simulate the spatial distribution of the electric field to understand the effects of LIPSS geometric parameters in field localization.When the LIPSS patterned electrodes are used as substrates to support Pt/C and RuO_(2) electrocatalysts,the η_(10) overpotentials for HER and OER are decreased by 40.4 and 25%,respectively.Moreover,the capability of the LIPSS-patterned electrodes to operate at significantly reduced energy is also demonstrated in a range of electrolytes,including alkaline,acidic,neutral,and seawater.Importantly,when two LIPSS patterned electrodes were assembled as the anode and cathode into a cell,it requires 330 mVs of lower electric potential with enhanced stability over a similar cell made of pristine electrodes to drive a current density of 10 mA/cm^(2).This work demonstrates a physical and versatile approach of electrode surface patterning to boost electrocatalytic fuel generation performance and can be applied to any metal and semiconductor catalysts for a range of electrochemical reactions.
文摘To this day, only two types of solar power plants have been proposed and built: high temperature thermal solar one and photovoltaic one. It is here proposed a new type of solar thermal plant using glass-top flat surface solar collectors, so working at low temperature (i.e., below 100°C). This power plant is aimed at warm countries, i.e., the ones mainly located between -40° and 40° latitude, having available space along their coast. This land based plant, to install on the seashore, is technologically similar to the one used for OTEC (Ocean Thermal Energy Conversion). This plant, apart from supplying electricity with a much better thermodynamic efficiency than OTEC plants, has the main advantage of providing desalinated water for drinking and irrigation. This plant is designed to generate electricity (and desalinated water) night and day and all year round, by means of hot water storage, with just a variation of the power delivered depending on the season.