Thermal stability has long been recognized as a major limitation for the application of ligand modification in high-temperature reactions. Herein, we demonstrate polymeric phosphate as an efficient and stable ligand t...Thermal stability has long been recognized as a major limitation for the application of ligand modification in high-temperature reactions. Herein, we demonstrate polymeric phosphate as an efficient and stable ligand to tune the selectivity of propane oxidative dehydrogenation. Beneficial from the weakened affinity of propene, NiO modified with polymeric phosphate shows a selectivity 2–3 times higher than NiO towards the production of propene. The success of this regulation verifies the feasibility of ligand modification in high-temperature gas-phase reactions and shines a light on its applications in other important industrial reactions.展开更多
The Hard X-ray Modulation Telescope(HXMT) will perform an all-sky survey in the hard X-ray band as well as deep imaging of a series of small sky regions.We expect various compact objects to be detected in these imag...The Hard X-ray Modulation Telescope(HXMT) will perform an all-sky survey in the hard X-ray band as well as deep imaging of a series of small sky regions.We expect various compact objects to be detected in these imaging observations. Point source detection performance of HXMT imaging observation depends not only on the instrument but also on the data analysis method that is applied since images are reconstructed from HXMT observed data with numerical methods. The denoising technique used plays an important part in the HXMT imaging data analysis pipeline along with demodulation and source detection. In this paper we have implemented several methods for denoising HXMT data and evaluated the point source detection performances in terms of sensitivities and location accuracies. The results show that direct demodulation with 1-fold cross-correlation should be the default reconstruction and regularization method, although both sensitivity and location accuracy could be further improved by selecting and tuning numerical methods in data analysis used for HXMT imaging observations.展开更多
In this study,we investigated orientation selectivity in cat primary visual cortex(V1) and its relationship with various parameters.We found a strong correlation between circular variance(CV) and orthogonal-topref...In this study,we investigated orientation selectivity in cat primary visual cortex(V1) and its relationship with various parameters.We found a strong correlation between circular variance(CV) and orthogonal-topreferred response ratio(O/P ratio),and a moderate correlation between tuning width and O/P ratio.Moreover,the suppression far from the peak that accounted for the lower CV in cat V1 cells also contributed to the narrowing of the tuning width of cells.We also studied the dependence of orientation selectivity on the modulation ratio for each cell,which is consistent with robust entrainment of the neuronal response to the phase of the drifting grating stimulus.In conclusion,the CV(global measure) and tuning width(local measure) are significantly correlated with the modulation ratio.展开更多
基金was supported by the National Natural Science Foundation of China(91545113,21703050)the China Postdoctoral Science Foundation(2017M610363,2018T110584)+2 种基金Shell Global Solutions International B.V.(PT71423,PT74557)the Fok Ying Tong Education Foundation(131015)the Science&Technology Program of Ningbo(2017C50014)~~
文摘Thermal stability has long been recognized as a major limitation for the application of ligand modification in high-temperature reactions. Herein, we demonstrate polymeric phosphate as an efficient and stable ligand to tune the selectivity of propane oxidative dehydrogenation. Beneficial from the weakened affinity of propene, NiO modified with polymeric phosphate shows a selectivity 2–3 times higher than NiO towards the production of propene. The success of this regulation verifies the feasibility of ligand modification in high-temperature gas-phase reactions and shines a light on its applications in other important industrial reactions.
基金supported by the National Natural Science Foundation of China (NSFC, Grant Nos. 11373025, 11173038 and 11403014)the Tsinghua University Initiative Scientific Research Program (Grant No. 20111081102)+1 种基金supported by the Young Scientist Project of the National Natural Science Foundation of China (Grant No. 11303059)the Chinese Academy of Sciences Youth Innovation Promotion Association
文摘The Hard X-ray Modulation Telescope(HXMT) will perform an all-sky survey in the hard X-ray band as well as deep imaging of a series of small sky regions.We expect various compact objects to be detected in these imaging observations. Point source detection performance of HXMT imaging observation depends not only on the instrument but also on the data analysis method that is applied since images are reconstructed from HXMT observed data with numerical methods. The denoising technique used plays an important part in the HXMT imaging data analysis pipeline along with demodulation and source detection. In this paper we have implemented several methods for denoising HXMT data and evaluated the point source detection performances in terms of sensitivities and location accuracies. The results show that direct demodulation with 1-fold cross-correlation should be the default reconstruction and regularization method, although both sensitivity and location accuracy could be further improved by selecting and tuning numerical methods in data analysis used for HXMT imaging observations.
基金supported by the National Basic Research Development Program of China (2013CB329401)the National Natural Science Foundation of China (91420105, 61105116, 91120013, and 90820301)Shanghai Municipal Committee of Science and Technology (088014158 and 098014026)
文摘In this study,we investigated orientation selectivity in cat primary visual cortex(V1) and its relationship with various parameters.We found a strong correlation between circular variance(CV) and orthogonal-topreferred response ratio(O/P ratio),and a moderate correlation between tuning width and O/P ratio.Moreover,the suppression far from the peak that accounted for the lower CV in cat V1 cells also contributed to the narrowing of the tuning width of cells.We also studied the dependence of orientation selectivity on the modulation ratio for each cell,which is consistent with robust entrainment of the neuronal response to the phase of the drifting grating stimulus.In conclusion,the CV(global measure) and tuning width(local measure) are significantly correlated with the modulation ratio.