STUDY ON OPTIMIZATION OF HIGH PERFORMANCE CONCRETE ADMIXTURES

Influences of admixtures on the workability and strength of high performance concrete （HPC） are in- vestigated. The types of investigated admixtures include naphthalene series high range water reducing agent, polycarboxlic series high range water reduce agent and sodium sulfate hardening accelerating agent. Two kinds of curing condition, namely steam curing condition and standard curing condition, are adopted. The result shows that HPC, added with polycarboxlic series of high performance water reducer, has high workability and strength, while sodium sulfate accelerating agent causes poor workability and low strength. Thus for vapor-cured HPC and its formulations, naphthalene series high range water reducing agent with less sodium sulfate should be given pri- ority. Therefore, the differences of curing conditions should be considered when selecting HPC admixtures.

INFLUENCE OF AIRCRAFT DEICER ON FREEZE-THAW DURABILITY OF HIGH PERFORMANCE CONCRETE

The influence of glycol,the main composition of the most frequently used aircraft dicer,on the freeze-thaw durability of high performance concrete（HPC）is investigated.Freeze-thaw durability of HPC is tested by accelerated freeze-thaw test.Four kinds of the solution,i.e.,tap water,3.5% NaCl solution,glycol solutions,and a LBR-A type commercial aircraft deicer are employed.Results show that freeze-thaw durability of HPC exposed to glycol solutions is closely related to the solution concentrations.The failure of HPC exposed to 3.5% glycol solution is similar to that of those exposed to 3.5% NaCl solution,i.e.,serious surface scaling.While the damage of HPC exposed to 12.5%—25% glycol solutions is postponed.Compared with glycol solution,the commercial aircraft deicer has much more negative effects on HPC freeze-thaw durability compared with 3.5% NaCl solution.In the presence of commercial aircraft deicer for HPC subjected to freeze-thaw cycles,the deterioration is mainly due to scaling and spalling.

The Frost-resisting Durability of High Strength Self-Compacting Pervious Concrete in Deicing Salt Environment

A high strength self-compacting pervious concrete(SCPC) with top-bottom interconnected pores was prepared in this paper. The frost-resisting durability of such SCPC in different deicing salt concentrations(0%, 3%, 5%, 10%, and 20%) was investigated. The mass-loss rate, relative dynamic modulus of elasticity, compressive strength, flexural strength and hydraulic conductivity of SCPC after 300 freeze-thaw cycles were measured to evaluate the frost-resisting durability. In addition, the microstructures of SCPC near the top-bottom interconnected pores after 300 freeze-thaw cycles were observed by SEM. The results show that the high strength SCPC possesses much better frost-resisting durability than traditional pervious concrete(TPC) after 300 freeze-thaw cycles, which can be used in heavy loading roads. The most serious freeze-thaw damage emerges in the SCPC immersed in the 3% of Na Cl solution, while there is no obvious damage in 20% of Na Cl solution. Furthermore, it can be deduced that the high strength SCPC can be used for 100 years in a cold environment.

Effect of SAP on Properties of High Performance Concrete under Marine Wetting and Drying Cycles

The internal curing effect of superabsorbent polymer(SAP) on the properties of high performance concrete(HPC) under marine wetting and drying cycles(WD cycles) was investigated. Compressive strength, hydration and chloride migration were experimentally investigated and the results were evaluated by compasison with those under fresh water curing(FW). Water absorption and porosity were also evaluated only under WD cycles. The results showed the important influence of wetting and drying cycles on the properties of SAP modified HPC properties. Carefully designed, SAP minimized the long-term compressive strength of HPC under marine WD cycles. The hydration rate was faster in the initial curing, but became lower as compared with that cured in FW. In addition, SAP improved the long-term water absorption resistance and chloride migration resistance of HPC under marine WD cycles. The examination of the porosity showed a lower increase of the volume of capillary pores in SAP modified HPC under long term WD cycles compared with that without SAP. Therefore, internal curing by SAP could improve the durability properties of HPC under marine WD cycles.

Combined effect of steel fibres and steel rebars on impact resistance of high performance concrete

The impact properties of normal concrete (NC) and reinforced concrete (RC) specimens,steel fibre reinforced concrete (SFRC) specimens and RC+SFRC specimens with different steel fibre dosages were investigated with the drop-weight impact test recommended by ACI Committee 544.The results indicate that the number of blows to final failure is greatly increased by addition of steel fibres.Moreover,the combination of steel fibres and steel rebars demonstrates a significant positive composite effect on the impact resistance,which results in the improvement in impact toughness of concrete specimens.In the view of variation of impact test results,the two-parameter Weibull distribution was adopted to analyze the experimental data.It is proved that the probabilistic distributions of the blows to first crack and to final failure of six types of samples approximately follow two-parameter Weibull distribution.

Carbonation Resistance of Sulphoaluminate Cement-based High Performance Concrete

The influences of water/cement ratio and admixtures on carbonation resistance of sulphoaluminate cement-based high performance concrete （HPC） were investigated. The experimental results show that with the decreasing water/cement ratio, the carbonation depth of sulphoaluminate cement-based HPC is decreased remarkably, and the carbonation resistance capability is also improved with the adding admixtures. The morphologies and structure characteristics of sulphoaluminate cement hydration products before and after carbonation were analyzed using SEM and XRD. The analysis results reveal that the main hydration product of sulphoaluminate cement, that is ettringite （AFt）, decomposes after carbonation.

Pore Size Distribution of High Performance Metakaolin Concrete

The Compressive strength, porosity and pore size distribution of high performance metakaolin (MK) concrete were investigated. Concretes containing 0,5% , 10% and 20% metakaolin were prepared at a water / cementitious material ratio ( W/C) of 0. 30. In parallel, concrete mixtures with the replacement of cement by 20% fly ash or 5 and 10% silica fume were prepared for comparison. The specimens were cured in water at 27℃ for 3 to 90 days. The results show that at the early age of curing (3 days and 7 days), metakaolin replacements increase the compressive strength, but silica fume replacement slightly reduces the compressive strength. At the age of and after 28 days , the compressive strength of the concrete with metakaolin and silica fume replacement increases. A strong reduction in the total porosity and average pore diameter were observed in the concrete with MK 20% and 10% in the first 7 days.

High Performance Concrete and Its Typical Mixes

With the modern development of chemical and mineral admixtures, it is now possible to produce much higher performance concrete than before. Higher performance does not only mean higher strength, but also better durability, lower risk of thermal cracking and higher dimensional stability etc. The three most effective admixtures for producing high performance concrete are superplastieizer, pulverized fuel ash and condensed silica fume. This paper outlines the properties of these materials and presents some practical guidelines for their usage.

Characterization of Surface Hardness and Microstructure of High Performance Concrete

The relationship between compressive strength obtained by universal testing machine and rebound value obtained by the hammer of high performance concrete was systematically investigated at the macro level. And a model of high performance concrete strength curve was established from them. At the micro level, the microstructure, hydration products and pore structure of concrete surface were analyzed by scanning electron microscopy（SEM）, comprehensive thermal analysis（TG-DSC） and mercury intrusion porosimetry（MIP）, respectively. The effect of carbonation on surface strength was also investigated. The results showed that the concrete surface hardness layer grew rapidly at early stage and then stabilized at last with ongoing curing age; the rebound value and compressive strength of concrete with slag were higher than those of concrete with the same content of fly ash. In addition, the strength curve obtained by the least square method can satisfy the local standard requirements with an average relative error of 8.9% and a relative standard deviation of 11.3%. When the carbonation depth was 6 mm, the compressive strength calculated by national uniform strength curve was 25 PMa higher than that by high performance concrete.

Shrinkage Behavior of High Performance Concrete at Different Elevated Temperatures under Different Sealing Conditions

The shrinkage behavior of high performance cement concrete made from Portland cement, ultra fine granulated blast furnace slag and pulverized fly ash with addition of superplasticizer at different temperatures from ambient temperature to 120 ℃ under different seuliug conditions was investigated by means of length change measurement on cylindrical concrete specimens along with curing age. Results show that drying shrinkage deformations of titled concrete specimens increased rapidly as the curing temperature rose. The development of dryiing shrinkage deformatian can be efficiently controlled with the aid of aluminum tape sealing as compared with the unsealed specimens, especially when the curing temperature is below 60℃ , although it will increase dramatically when the curing temperature is elevated to above 90%＂ . Polymer coating on concrete specimens showed a similar effect on the control of drying shrinkage as the sealing operation with aluminum tape.

Evaluation of the Shear Strength of Perfobond Rib Connectors in Ultra High Performance Concrete

Since the previous strength prediction models for the perfobond rib connector were proposed based upon the results of push-out tests conducted on concretes with compressive strength below 50 MPa, push-out test is performed on perfobond shear connectors applying ultra high performance concretes with compressive strength higher than 80 MPa to evaluate their shear resistance. The test variables are chosen to be the diameter and number of dowel holes and, the change in the shear strength of the perfobond rib connector is examined with respect to the strength of two types of UHPC: steel fiber-reinforced concrete with compressive strength of 180 MPa and concrete without steel fiber with compressive strength of 80 MPa. The test results reveal that higher concrete strength and larger number of holes increased the shear strength, and that higher increase rate in the shear strength was achieved by the dowel action. The comparison with the predictions obtained by the previous models shows that the experimental results are close to the values given by the model proposed by Oguejiofor and Hosain [1].

Self-compacting Concrete-filled Steel Tubes Prepared from Manufactured Sand with a High Content of Limestone Fines

To meet the requirements of construction of concretes filled in the steel tube arches,a C60 grade micro-expansive self-compacting concrete （SCC） was prepared from manufactured sand （MS）.The utilization of MS with a high content of quarry limestone fines was dealed for SCC applications.The workability,compressive and splitting strength,modulus of elasticity,restrained expansion and chloride ion permeability as well as freeze-thaw resistance of three MS-SCC mixes with fines content of 3%,7% and 10% were tested and compared with those of the natural sand （NS）-SCC mix.The experimental results indicate that the performances of the C60 MS-SCC with fines content of 7% are excellent and compared favorably with those of C60 NS-SCC.

The Corrosion Fatigue Properties of High Performance Concrete

With the loading test equipment of corrosion fatigue specially designed, the corrosion fatigue characteristics of high performance concrete (HPC) withstanding the interaction of third point fatigue loading and Na_2SO_4 solution were investigated and analyzed. The experimental results indicate that water-binder ratio evidently influences the corrosion fatigue characteristics of HPC, and a moderate quantitative fine mineral admixture enhances the corrosion fatigue resistance of HPC. The effect is more significant when fly ash and silica fume are added.

Preparation of High Performance Non-dispersible Concrete

A new-type underwater non-dispersible concrete admixture NDA was prepared,its function mechanism was analyzed,and C40 high performance non-dispersible underwater concrete was manufactured by applying NDA.The results indicate that NDA has a suitable workability,low strength loss,and excellent anti-dispersion;the fresh non-dispersible underwater concrete with NDA has high anti-dispersion,excellent workability such as self-compacting and not bleeding;hardened non-dispersible underwater concrete with NDA has a high strength,high durability such as high anti-abrasion,impermeability and anticorrosion.

Preparation and Application of C60 High Performance Concrete

C60 High Performance Concrete (HPC) was prepared by limiting cement content and adopting compositesuperplasticizer, low-alkalinity expansive agent and high-quality line mixture. The results showed that the performance of the prepared C60 HPC was excellent. By adopting some advanced construction techniques such as usingsecondary vibration and secondary face compaction, controlling temperature difference and paying special attentionto early curing in the construction process, the prepared C60 HPC had been successfully applied in the monolithicstructure of huge building.

Design and Preparation of High Elastic Modulus Self-compacting Concrete for Pre-stressed Mass Concrete Structures

Requirements of self-compacting concrete （SCC） applied in pre-stressed mass concrete structures include high fluidity, high elastic modulus, low adiabatic temperature rise and low drying shrinkage, which cannot be satisfied by ordinary SCC. In this study, in order to solve the problem, a few principles of SCC design were proposed and the effects of binder amount, fly ash （FA） substitution, aggregate content and gradation on the workability, temperature rise, drying shrinkage and elastic modulus of SCC were investigated. The results and analysis indicate that the primary factor influencing the fluidity was paste content, and the main methods improving the elastic modulusof SCC were a lower sand ratio and an optimized coarse aggregate gradation. Lower adiabatic temperature rise and drying shrinkage were beneficial for decreasing the cement content. Further, based on the optimization of mixture, a C50 grade SCC （with binder amount of only 480 kg/ m3, fly ash substitution of 40%, sand ratio of 51% and proper coarse aggregate gradation （Vs.~0 mm： V10-16 ram： V16.20 mm= 30%： 30%：40%）） with superior workability was successfully prepared. The temperature rise and drying shrinkage of the prepared SCC were significantly reduced, and the elastic modulus reached 37.6 GPa at 28 d.

A Simple Mix Proportion Design Method Based on Frost Durability for Recycled High Performance Concrete Using Fully Coarse Recycled Aggregate

Durability design of recycled high performance concrete（RHPC） is fundamental for improving the use rate and level of concrete waste as coarse recycled aggregate（CRA）. We discussed a frostdurability-based mix proportion design method for RHPC using 100 % CRA and natural sand. Five groups of RHPC mixes with five strength grades（40, 50, 60, 70 and 80 MPa） were produced using CRA with four quality classes, and their workability, 28 d compressive strengths and frost resistances（measured by the compressive strength loss ratio and the relative dynamic modulus of elasticity） were tested. Relationships between the 28 d compressive strength, the frost resistance and the CRA quality characteristic parameter, water absorption, were then developed. The criterion of a CRA maximum water absorption limit value for RHPC was suggested, independent of its source and quality class. The results show that all RHPC mixes achieve the expected target workability, strength, and frost durability. The research results demonstrate that the application of the proposed method does not require trial testing prior to use.

A Survey of High Performance Concrete Developments in Civil Engineering Field

High Performance concrete (HPC) has received increased attention in the development of infrastructure Viz., Buildings, Industrial Structures, Hydraulic Structures, Bridges and Highways etc. leading to utilization of large quantity of concrete. This paper presents a comprehensive coverage of High Performance concrete developments in civil engineering field. It highlights the High Performance concrete features and requirements over conventional concrete. Furthermore, recent trends with regard to High Performance Concrete development in this area are explored. This paper also includes effect of Mineral and Chemical Admixtures used to improve performance of concrete.

A Study on the Bond Strength between High Performance Concrete and Reinforcing Bar

As a preliminary study for the erection of floating structures using high performance concrete, this paper examines the bond characteristics between concrete and the reinforcing bar. Since the floating structure is constructed in aquatic environment, corrosion of the reinforcing steel is likely to develop more prematurely than in onshore structure in case of concrete cracking. A solution to this corrosion problem could use FRP rebar instead of steel reinforcement. To that goal, an experimental study is conducted on the concrete-FRP bond strength to verify if such FRP rebar develops performance comparable to the conventional steel rebar. A series of tests are performed considering the bond length of ordinary steel rebar and G-FRP rebar as test variable with respect to the strength of concrete, and the results are presented.

Anti-chloride permeability and anti-chloride corrodibility of a green high performance concrete admixture in concrete

The effects of green high performance concrete (GHPC) admixture on the anti-chloride permeability and anti- chloride corrodibility of concrete are studied by a series of experiments designed on the basis of the diffusion principle and electro-chemical principle. The GHPC admixture consists of fly ash, gangue, slag, red mud, etc., of which the mass fraction of industrial residues is over 96 %. The anti-permeabilities and anti-corrodibilities of the tested GHPC and normal concrete (NC) are evaluated by the Diffusion Coefficients of chloride which was obtained by measuring the concentration of chloride in the tested systems by the voltage difference method. It is found that the adoption of GHPC admixture greatly improves the anti-chloride permeability and anti-chloride corrodibility by modifying the inner structure and contracting the porosity of concrete to the reduce considerably the diffusion rate of chloride. The admixture is desirable regarding its engineering performances as well as economical and environmental interests.