This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry prepar...This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry preparing, delivering and model filling. The rheological properties of SSM (semi-solid metal) slurry was described by an analytical model in terms of microstructural parameters, which consist of effective solid fraction, particle size and shape, and flow parameters such as mean velocity, fluctuant velocity and relative velocity between liquid and solid phase. The model was verified in the experiment of A356 alloys with a coaxial double-bucket rheometer. And the maximum relative error between the theoretical value and measured one is less than 20%. The results of experiment and theoretical calculation also indicate that the microstructural parameters and flow parameters are two major factors that affect the apparent viscosity of semi-solid alloys, and fluctuant velocity and relative velocity between liquid and solid phase are the key factors to distinguish between steady and transient rheological properties.展开更多
The corrosion behavior(in chloride medium) of the surface layer of SSM-HPDC plates of alloys 7075-T6 and 2024-T6 was compared with that of the wrought alloys 7075-T6 and 2024-T6.Potentiodynamic testing was performed i...The corrosion behavior(in chloride medium) of the surface layer of SSM-HPDC plates of alloys 7075-T6 and 2024-T6 was compared with that of the wrought alloys 7075-T6 and 2024-T6.Potentiodynamic testing was performed in deaerated 3.5%NaCl solution.In separate tests,the open-circuit potential was monitored in aerated 3.5% NaCl for 30 min after immersion.The electrochemical tests show that there is no significant difference in the pitting potential of the wrought alloys and that of the Cu-enriched surfaces of the SSM-HPDC alloys.展开更多
The shearing/cooling roll (SCR) process was adopted to prepare semi-solid A2017 alloy. The formation and evolution of non-dendritic microstructures in semi-solid A2017 alloy were studied. It is shown that the micros...The shearing/cooling roll (SCR) process was adopted to prepare semi-solid A2017 alloy. The formation and evolution of non-dendritic microstructures in semi-solid A2017 alloy were studied. It is shown that the microstructures of semi-solid billets transform from coarse dendrites into fine equiaxed grains as the pouring temperature of molten alloy decreases o.r roll-shoe cavity height is reduced. From the inlet to the exit of roll-shoe cavity, microstructure of semi-solid slurry near the shoe surface is in the order of coarse dendrites, degenerated dendrites or equiaxed grains, but fine equiaxed grains are near the roll surface. Microstructural evolution of semi-solid slurry prepared by SCR process is that the molten alloy nucleates and grows into dendrite firstly on the roll and shoe's surface. Under the shearing and stirring given by the rotating roll, the dendrites crush off and disperse into the melt. Under the shearing and stirring on semi-solid slurry with high volume fraction of solid, the dendrite arms fracture and form equiaxed grain microstructures.展开更多
The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotati...The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotation speed of barrel, can give rise to a transition of the growth morphology of primary α(Al) from coarse-dendritic to coarse-particle-like and further to fine-globular. The combined effects of both localized rapid cooling and vigorous mixing during the initial stage of solidification can enhance wall nucleation and nuclei survival, which leads to the formation of fine-globular primary α(Al). By using semi-solid slurry prepared by LSPSF, direct squeeze cast cup-shaped component with improved mechanical properties such as yield strength of 198 MPa, ultimate tensile strength of 306 MPa and elongation of 10.4%, can be obtained.展开更多
The gas induced semi-solid(GISS) is a rheocasting process that produces semi-solid slurry by applying fine gas bubble injection through a graphite diffuser.The process is developed to be used in the die casting indust...The gas induced semi-solid(GISS) is a rheocasting process that produces semi-solid slurry by applying fine gas bubble injection through a graphite diffuser.The process is developed to be used in the die casting industry.To apply the GISS process with a die casting process,a GISS maker unit is designed and attached to a conventional die casting machine with little modifications.The commercial parts are developed and produced by the GISS die casting process.The GISS die casting shows the feasibility to produce industrial parts with aluminum 7075 and A356 with lower porosity than liquid die casting.展开更多
The rate of microstructural coarsening of recrystallisation and partial melting (RAP) and cooling slope (CS) processed materials in the semi-solid state is compared with rates found in the literature.The rate of coars...The rate of microstructural coarsening of recrystallisation and partial melting (RAP) and cooling slope (CS) processed materials in the semi-solid state is compared with rates found in the literature.The rate of coarsening depended on the liquid fraction but RAP route 2014 alloy with 37% liquid coarsened slightly more slowly than the CS route 2014 alloy with a lower liquid fraction of 17%, contrary to expectations.For the CS route, an increase in liquid fraction resulted in faster coarsening.A modified 2014 alloy with Fe, Mn and Zn stripped out of the composition gave a relatively high coarsening rate.The coarsening rate was also relatively high for CS 201 alloy in comparison with either RAP 2014 or CS 2014.Low coarsening rates are thought to be associated with the presence of particles which inhibit the migration of liquid film grain boundaries.This could be the result of pinning or of the liquid film impeding diffusion at the boundary.展开更多
A two-step reheating process was proposed and applied to perform reheating experiments on the semi-solid 2024 alloy billet. In this process, the semi-solid billet was firstly heated over liquidus temperature and then ...A two-step reheating process was proposed and applied to perform reheating experiments on the semi-solid 2024 alloy billet. In this process, the semi-solid billet was firstly heated over liquidus temperature and then isothermally held at solid-liquid zone temperature. Microstructure evolution of the semi-solid billet during two-step reheating was studied by optical microscope and compared with that during isothermal reheating. The results show that the remelting rate of the semi-solid billet during two-step reheating is faster than that during isothermal reheating. Under the same reheating time, the grains of the semi-solid billet reheated by two-step reheating process are finer and rounder than those by isothermal reheating process. The present experimental results indicate that accelerating the formation of liquid phase during the two-step reheating process can restrain the coalescence of grains to a certain extent, and thus refine the grain size and promote the grain spheroidization.展开更多
Simulating semi-solid metal forming requires modelling semi-solid behaviour.However, such modelling is difficult because semi-solid behavior is thixotropic and depends on the liquid-solid spatial distribution within t...Simulating semi-solid metal forming requires modelling semi-solid behaviour.However, such modelling is difficult because semi-solid behavior is thixotropic and depends on the liquid-solid spatial distribution within the material.In order to better understand and model relationships between microstructure and behavior, a model based on micromechanical approaches and homogenisation techniques is presented.This model is an extension of a previous model established in a pure viscoplastic framework to account for elasticity.Indeed, experimental load-displacement signals reveal the presence of an elastic-type response in the earlier stages of deformation when semi-solids are loaded under rapid compression.This elastic feature of the behaviour is attributed to the response of the porous solid skeleton saturated by incompressible liquid.A good quantitative agreement is found between the elastic-viscoplastic predicted response and the experimental data.More precisely, the strong initial rising part of the load-displacement curve, the peak load and the subsequent fall in load are well captured.The effect of solid fraction on mechanical response is in qualitative agreement with experiments.展开更多
An aluminum extrusion process is mainly used to fabricate long tubes, beams and rods for various applications.However, this process has a high production cost due to the need for investment of high-pressure machinery....An aluminum extrusion process is mainly used to fabricate long tubes, beams and rods for various applications.However, this process has a high production cost due to the need for investment of high-pressure machinery.The objective of this work is to develop a new semi-solid extrusion process using semi-solid slurry at low solid fractions.A laboratory extrusion system was used to fabricate aluminum rods with the diameter of 12 mm.The semi-solid metal process used in this study was the gas induced semi-solid (GISS) technique.To study the feasibility of the GISS extrusion process, the effects of extrusion parameters such as plunger speed and solid fraction on the extrudability, microstructure, and mechanical properties of extruded samples were investigated.The results show that the plunger speed and solid fraction of the semi-solid metal need to be carefully controlled to produce complete extruded parts.展开更多
The microstructural evolution of the A2017 semi-solid alloy billets provided with rheocasting and extruding/extending forming by shearing-cooling-rolling(SCR) technology during reheating in semi-solid state was invest...The microstructural evolution of the A2017 semi-solid alloy billets provided with rheocasting and extruding/extending forming by shearing-cooling-rolling(SCR) technology during reheating in semi-solid state was investigated. The microstructural differences and their generation causes for both billets were also analyzed. The results show that during reheating, the grains of rheocasting billets grow up and spheroidize gradually with the prolongation of isothermal holding time, the eutectic liquid phase at low melting point forms mainly among the grains. However, the grains of the extruding/extending forming billets grow up abnormally through grain coalescence in the initial stage of the reheating, the entrapment of large amount of liquid within grains occurs, and the grain sizes in the reheating billets are coarse and inhomogeneous. Compared with extruding/extending forming billets, rheocasting billets have smaller and uniform grains in reheating microstructure and can rapidly form liquid phase among grains. Therefore, rheocasting billets are more suitable for the semi-solid forming than the extruding/extending forming billets.展开更多
Computer modeling of semi-solid structure formation is of significance in both understanding the mechanisms of globular structure formation and determining the effect of solidification conditions on final microstructu...Computer modeling of semi-solid structure formation is of significance in both understanding the mechanisms of globular structure formation and determining the effect of solidification conditions on final microstructure.A modified cellular automaton(mCA) model has been developed,which is coupled with macroscopic models for heat transfer calculation and microscopic models for nucleation and grain growth.The mCA model is applied to A356 Al alloy-one of the most widely used semi-solid alloys,to predict grain morphology and grain size during semi-solid solidification,and determines the effects of pouring temperature on the final microstructure.The modeling results show that the lower the initial temperature,the finer grain size will be obtained.In addition,the model can be used to predict the solutal micro-segregation.展开更多
In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by ...In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by a mechanical stirring semi-solid process. The appropriate processing parameters of slurry preparation were obtained, and the mold filling ability of semi-solid slurry for thin-walled casting was examined. Results indicate that the solid volume fraction of non-dendritic microstructure increases with a decrease in pouring temperature of magnesium melt and the barrel preheating temperature of the screw mixer. Also the grain size of primary α-phase is reduced. Furthermore, the solid volume fraction of semi-solid nondendritic structure decreases with an increase of shear rate. The fine and round granular microstructure with 30~50 μm in size of semi-solid AZ91D magnesium alloy was presented. Finally, a 1.0 mm thin-walled casting with a clear contour and good soundness was successfully made by semi-solid rheo-diecasting.展开更多
Continuous extruding/ extending formiug process for A2017 alloy in semi-solid state was proposed through installing extending die at the outlet of shearing- cooling- rolling (SCR) machine. A series of experiments to...Continuous extruding/ extending formiug process for A2017 alloy in semi-solid state was proposed through installing extending die at the outlet of shearing- cooling- rolling (SCR) machine. A series of experiments to produce fiat bar of A2017 alloy were carried oat. The forming process, metal flow behavior in die and microstructure and mechanical property of prodacts were investigated. It is shown that if the pouring temperature of melt was higher, the die was filled with semi-solid slurry with low solid fraction and periodical cracks would occur on the product surface ; If its pouring temperature was lower or the preheating temperature of die was lower, semisolid slurry would solidify rapidly and block the die after entering the cavity. The analysis of mass flow trace shows that the semi-solid slurry move forward layer by layer and fills the die extending cavity in radiation manner and the velocity of mass flow in the central area of extending cavity and exit of mould is the maximum, and then decreases gradually from the center to both sides of die wall. By inereasiug the die extending angle, the velocity of mass flow becomes more homogeneous. Under rational process control and die design, the A2017 fiat bar with transverse section of 10 × 50 mm and with good surface and fine equiaxed grains can be obtained by continuous extruding/extending forming process. The product's tensile strength and elongation are 420.5 MPa and 14.2% , respectively.展开更多
文摘This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry preparing, delivering and model filling. The rheological properties of SSM (semi-solid metal) slurry was described by an analytical model in terms of microstructural parameters, which consist of effective solid fraction, particle size and shape, and flow parameters such as mean velocity, fluctuant velocity and relative velocity between liquid and solid phase. The model was verified in the experiment of A356 alloys with a coaxial double-bucket rheometer. And the maximum relative error between the theoretical value and measured one is less than 20%. The results of experiment and theoretical calculation also indicate that the microstructural parameters and flow parameters are two major factors that affect the apparent viscosity of semi-solid alloys, and fluctuant velocity and relative velocity between liquid and solid phase are the key factors to distinguish between steady and transient rheological properties.
文摘The corrosion behavior(in chloride medium) of the surface layer of SSM-HPDC plates of alloys 7075-T6 and 2024-T6 was compared with that of the wrought alloys 7075-T6 and 2024-T6.Potentiodynamic testing was performed in deaerated 3.5%NaCl solution.In separate tests,the open-circuit potential was monitored in aerated 3.5% NaCl for 30 min after immersion.The electrochemical tests show that there is no significant difference in the pitting potential of the wrought alloys and that of the Cu-enriched surfaces of the SSM-HPDC alloys.
基金The authors would like to thank the National Natural Science Foundation of China and Baoshan Iron&Steel Co.of Shanghai for financial support under the grant No.50274020.
文摘The shearing/cooling roll (SCR) process was adopted to prepare semi-solid A2017 alloy. The formation and evolution of non-dendritic microstructures in semi-solid A2017 alloy were studied. It is shown that the microstructures of semi-solid billets transform from coarse dendrites into fine equiaxed grains as the pouring temperature of molten alloy decreases o.r roll-shoe cavity height is reduced. From the inlet to the exit of roll-shoe cavity, microstructure of semi-solid slurry near the shoe surface is in the order of coarse dendrites, degenerated dendrites or equiaxed grains, but fine equiaxed grains are near the roll surface. Microstructural evolution of semi-solid slurry prepared by SCR process is that the molten alloy nucleates and grows into dendrite firstly on the roll and shoe's surface. Under the shearing and stirring given by the rotating roll, the dendrites crush off and disperse into the melt. Under the shearing and stirring on semi-solid slurry with high volume fraction of solid, the dendrite arms fracture and form equiaxed grain microstructures.
基金Project(50474007) supported by the National Natural Science Foundation of ChinaProject(0450050) supported by the Natural Science Foundation of Jiangxi Province, China Projects(GanJiaoZi[2005]2, 24) supported by the Science and Technology Program of Education Department of Jiangxi Province, China
文摘The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotation speed of barrel, can give rise to a transition of the growth morphology of primary α(Al) from coarse-dendritic to coarse-particle-like and further to fine-globular. The combined effects of both localized rapid cooling and vigorous mixing during the initial stage of solidification can enhance wall nucleation and nuclei survival, which leads to the formation of fine-globular primary α(Al). By using semi-solid slurry prepared by LSPSF, direct squeeze cast cup-shaped component with improved mechanical properties such as yield strength of 198 MPa, ultimate tensile strength of 306 MPa and elongation of 10.4%, can be obtained.
基金supports from Prince of Songkla University (No.AGR530031M)the Royal Golden Jubilee Ph.D program (No.PHD/0173/2550)
文摘The gas induced semi-solid(GISS) is a rheocasting process that produces semi-solid slurry by applying fine gas bubble injection through a graphite diffuser.The process is developed to be used in the die casting industry.To apply the GISS process with a die casting process,a GISS maker unit is designed and attached to a conventional die casting machine with little modifications.The commercial parts are developed and produced by the GISS die casting process.The GISS die casting shows the feasibility to produce industrial parts with aluminum 7075 and A356 with lower porosity than liquid die casting.
基金the UK Engineering and Physical Sciences Research Council (EPSRC Grant GR/M89096) and the University of Leicester for financial support
文摘The rate of microstructural coarsening of recrystallisation and partial melting (RAP) and cooling slope (CS) processed materials in the semi-solid state is compared with rates found in the literature.The rate of coarsening depended on the liquid fraction but RAP route 2014 alloy with 37% liquid coarsened slightly more slowly than the CS route 2014 alloy with a lower liquid fraction of 17%, contrary to expectations.For the CS route, an increase in liquid fraction resulted in faster coarsening.A modified 2014 alloy with Fe, Mn and Zn stripped out of the composition gave a relatively high coarsening rate.The coarsening rate was also relatively high for CS 201 alloy in comparison with either RAP 2014 or CS 2014.Low coarsening rates are thought to be associated with the presence of particles which inhibit the migration of liquid film grain boundaries.This could be the result of pinning or of the liquid film impeding diffusion at the boundary.
基金Project(20060400749) supported by the Postdoctoral Science Foundation of ChinaProject supported by the Postdoctoral Novel Science Foundation of South China University of Technology,China
文摘A two-step reheating process was proposed and applied to perform reheating experiments on the semi-solid 2024 alloy billet. In this process, the semi-solid billet was firstly heated over liquidus temperature and then isothermally held at solid-liquid zone temperature. Microstructure evolution of the semi-solid billet during two-step reheating was studied by optical microscope and compared with that during isothermal reheating. The results show that the remelting rate of the semi-solid billet during two-step reheating is faster than that during isothermal reheating. Under the same reheating time, the grains of the semi-solid billet reheated by two-step reheating process are finer and rounder than those by isothermal reheating process. The present experimental results indicate that accelerating the formation of liquid phase during the two-step reheating process can restrain the coalescence of grains to a certain extent, and thus refine the grain size and promote the grain spheroidization.
文摘Simulating semi-solid metal forming requires modelling semi-solid behaviour.However, such modelling is difficult because semi-solid behavior is thixotropic and depends on the liquid-solid spatial distribution within the material.In order to better understand and model relationships between microstructure and behavior, a model based on micromechanical approaches and homogenisation techniques is presented.This model is an extension of a previous model established in a pure viscoplastic framework to account for elasticity.Indeed, experimental load-displacement signals reveal the presence of an elastic-type response in the earlier stages of deformation when semi-solids are loaded under rapid compression.This elastic feature of the behaviour is attributed to the response of the porous solid skeleton saturated by incompressible liquid.A good quantitative agreement is found between the elastic-viscoplastic predicted response and the experimental data.More precisely, the strong initial rising part of the load-displacement curve, the peak load and the subsequent fall in load are well captured.The effect of solid fraction on mechanical response is in qualitative agreement with experiments.
基金the financial supports from Prince of Songkla University (Contract number AGR530031M)
文摘An aluminum extrusion process is mainly used to fabricate long tubes, beams and rods for various applications.However, this process has a high production cost due to the need for investment of high-pressure machinery.The objective of this work is to develop a new semi-solid extrusion process using semi-solid slurry at low solid fractions.A laboratory extrusion system was used to fabricate aluminum rods with the diameter of 12 mm.The semi-solid metal process used in this study was the gas induced semi-solid (GISS) technique.To study the feasibility of the GISS extrusion process, the effects of extrusion parameters such as plunger speed and solid fraction on the extrudability, microstructure, and mechanical properties of extruded samples were investigated.The results show that the plunger speed and solid fraction of the semi-solid metal need to be carefully controlled to produce complete extruded parts.
文摘The microstructural evolution of the A2017 semi-solid alloy billets provided with rheocasting and extruding/extending forming by shearing-cooling-rolling(SCR) technology during reheating in semi-solid state was investigated. The microstructural differences and their generation causes for both billets were also analyzed. The results show that during reheating, the grains of rheocasting billets grow up and spheroidize gradually with the prolongation of isothermal holding time, the eutectic liquid phase at low melting point forms mainly among the grains. However, the grains of the extruding/extending forming billets grow up abnormally through grain coalescence in the initial stage of the reheating, the entrapment of large amount of liquid within grains occurs, and the grain sizes in the reheating billets are coarse and inhomogeneous. Compared with extruding/extending forming billets, rheocasting billets have smaller and uniform grains in reheating microstructure and can rapidly form liquid phase among grains. Therefore, rheocasting billets are more suitable for the semi-solid forming than the extruding/extending forming billets.
文摘Computer modeling of semi-solid structure formation is of significance in both understanding the mechanisms of globular structure formation and determining the effect of solidification conditions on final microstructure.A modified cellular automaton(mCA) model has been developed,which is coupled with macroscopic models for heat transfer calculation and microscopic models for nucleation and grain growth.The mCA model is applied to A356 Al alloy-one of the most widely used semi-solid alloys,to predict grain morphology and grain size during semi-solid solidification,and determines the effects of pouring temperature on the final microstructure.The modeling results show that the lower the initial temperature,the finer grain size will be obtained.In addition,the model can be used to predict the solutal micro-segregation.
文摘In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by a mechanical stirring semi-solid process. The appropriate processing parameters of slurry preparation were obtained, and the mold filling ability of semi-solid slurry for thin-walled casting was examined. Results indicate that the solid volume fraction of non-dendritic microstructure increases with a decrease in pouring temperature of magnesium melt and the barrel preheating temperature of the screw mixer. Also the grain size of primary α-phase is reduced. Furthermore, the solid volume fraction of semi-solid nondendritic structure decreases with an increase of shear rate. The fine and round granular microstructure with 30~50 μm in size of semi-solid AZ91D magnesium alloy was presented. Finally, a 1.0 mm thin-walled casting with a clear contour and good soundness was successfully made by semi-solid rheo-diecasting.
基金Funded by the National Natural Science Foundation of China(No.50274020) and Baoshan Iron &Steel Corporation of Shanghai
文摘Continuous extruding/ extending formiug process for A2017 alloy in semi-solid state was proposed through installing extending die at the outlet of shearing- cooling- rolling (SCR) machine. A series of experiments to produce fiat bar of A2017 alloy were carried oat. The forming process, metal flow behavior in die and microstructure and mechanical property of prodacts were investigated. It is shown that if the pouring temperature of melt was higher, the die was filled with semi-solid slurry with low solid fraction and periodical cracks would occur on the product surface ; If its pouring temperature was lower or the preheating temperature of die was lower, semisolid slurry would solidify rapidly and block the die after entering the cavity. The analysis of mass flow trace shows that the semi-solid slurry move forward layer by layer and fills the die extending cavity in radiation manner and the velocity of mass flow in the central area of extending cavity and exit of mould is the maximum, and then decreases gradually from the center to both sides of die wall. By inereasiug the die extending angle, the velocity of mass flow becomes more homogeneous. Under rational process control and die design, the A2017 fiat bar with transverse section of 10 × 50 mm and with good surface and fine equiaxed grains can be obtained by continuous extruding/extending forming process. The product's tensile strength and elongation are 420.5 MPa and 14.2% , respectively.