A well core-shell composite of Y@meso-Al with a mesoporous alumina shell and a Y zeolite core was synthesized. The mesoporous alumina shell has a wormhole-like structure with large mesopores. The prepared catalytic cr...A well core-shell composite of Y@meso-Al with a mesoporous alumina shell and a Y zeolite core was synthesized. The mesoporous alumina shell has a wormhole-like structure with large mesopores. The prepared catalytic cracking catalyst using this composite has exhibited excellent catalytic performance for heavy oil cracking thanks to its favorable physicochemical properties, such as high surface area, large pore volume and outstanding acid sites accessibility for large molecules provided by the composite. In comparison with the reference catalyst using pure Y zeolite, the oil conversion achieved by the above-mentioned catalyst increased by 2.73 percentage points, while the heavy oil yield and coke yield decreased by 2.23 percentage points and 1.28 percentage points, respectively, with the light oil yield increasing by 2.27 percentage points.展开更多
Based on the measurement of walnut properties,a computational analysis was conducted on the compressive stiffness of the critical value of shell-cracking.As indicated by the results,to crack the walnuts shell from its...Based on the measurement of walnut properties,a computational analysis was conducted on the compressive stiffness of the critical value of shell-cracking.As indicated by the results,to crack the walnuts shell from its longitudinal or edge directions could save lots of efforts.The study provided theoretical basis for the design and improvement of walnut shell-cracking machine as well as theoretical references for the design,making and use of some special cracking-aiding tools such as nutcracker.展开更多
Aiming at the cracking phenomenon of the thin shell mould in the expendable pattern shell casting during the pattern removing process, some systemic researches are presented.The influence of the pattern removing metho...Aiming at the cracking phenomenon of the thin shell mould in the expendable pattern shell casting during the pattern removing process, some systemic researches are presented.The influence of the pattern removing method and temperature on the pattern removing were investigated.The shell mould cracking mechanism was analyzed by using thermo-gravimetric analysis (TGA), and combining the temperature field and the volume change of the expanded polystyrene (EPS) foam pattern being tested.The results indicated that the shell mould was not easily cracked when the pattern removing process was carried out with the furnace being heated little by little because of the shell slowly shrinking with dehydration and shell strength gradually increasing.The shell mould was soon destroyed when it was set directly into the furnace at above 400 oC because of the thin shell mould rapidly shrinking and the foam pattern hindering.However, the shell mould had no cracking when it had been preheated for a long time even if the furnace temperature was above 400 oC and the shell was put into the furnace directly.Moreover, when the shell mould was directly set into the furnace at lower temperatures, 250 to 300 ℃, the shell would shrink slowly and the foam pattern would stay at the maximum expansion stage temperature of 100 to 110 ℃ for a long time; and the shell mould would experience an expansion force from the foam pattern for a long time.The expansion force is related to the pattern removing temperature, holding time, foam pattern thickness and density.Therefore, the foam pattern with higher density could make the shell crack.展开更多
The cylindrical shell is one of the main structural parts in ocean engineering structures.These cylinders are mostly of medium length,which means that the radius of the cross section is significantly smaller than the ...The cylindrical shell is one of the main structural parts in ocean engineering structures.These cylinders are mostly of medium length,which means that the radius of the cross section is significantly smaller than the length of the cylindrical shell.From the viewpoint of the shell theory,they belong to the mid-long cylindrical shell category.To solve mechanical problems on this kind of structure,especially a cracked cylindrical shell,analysis based on shell theory is necessary.At present the generally used solving system for the mid-long cylindrical shell is too complicated,difficult to solve,and inapplicable to engineering.This paper introduced the Sanders' mid-long cylindrical shell theory which reduces the difficulty of the solution process,and will be suitable for solving problems with complicated boundary conditions.On this basis,the engineering applications of this theory were discussed in conjunction with the problem of a mid-long cylindrical shell having a circumferential crack.The solution process is simple,and the closed form solution can usually be found.In practical engineering applications,it gives satisfactory precision.展开更多
The characteristic properties of shell element with similar shapes are used to generate a so-called super element for the analysis of the crack problems for cylindrical pressure vessels. The formulation is processed b...The characteristic properties of shell element with similar shapes are used to generate a so-called super element for the analysis of the crack problems for cylindrical pressure vessels. The formulation is processed by matrix condensation without the involvement of special treatment. This method can deal with various singularity problems and it also presents excellent results to crack problems for cylindrical shell. Especially,the knowledge of the kind of singular order is not necessary in super element generation; it is very economical in terms of computer memory and programming. This method also exhibits versatility to solve the problem of kinked crack at cylindrical shell.展开更多
Two cylindrical vessels under internal pressure are used for this work in order to study the influence of the position and size of defects on their elastic and elastoplastic behavior. One contains two external longitu...Two cylindrical vessels under internal pressure are used for this work in order to study the influence of the position and size of defects on their elastic and elastoplastic behavior. One contains two external longitudinal semi-elliptic defects of different dimensions realized diametrically opposed. The other contains the same defects but is circumferential. These defects are carried out by elect-erosion. Strain gauges are placed in the neighborhood of the defects of which the purpose is to obtain the strain distribution. This work also allows the comparison between two defects of different dimensions, which are of the same shape or different shapes. These defects are longitudinal and circumferential semi-elliptical. The position of these defects relative to the inner radius of a cylindrical pressure vessel is considered. The deformations results are discussed.展开更多
基金financially supported by the Department of Science and Technology Management of Petro China (No. 2011B-2404-0102)
文摘A well core-shell composite of Y@meso-Al with a mesoporous alumina shell and a Y zeolite core was synthesized. The mesoporous alumina shell has a wormhole-like structure with large mesopores. The prepared catalytic cracking catalyst using this composite has exhibited excellent catalytic performance for heavy oil cracking thanks to its favorable physicochemical properties, such as high surface area, large pore volume and outstanding acid sites accessibility for large molecules provided by the composite. In comparison with the reference catalyst using pure Y zeolite, the oil conversion achieved by the above-mentioned catalyst increased by 2.73 percentage points, while the heavy oil yield and coke yield decreased by 2.23 percentage points and 1.28 percentage points, respectively, with the light oil yield increasing by 2.27 percentage points.
基金Supported by University Students Science and Technology Innovation Project in Zhejiang Province(100411)
文摘Based on the measurement of walnut properties,a computational analysis was conducted on the compressive stiffness of the critical value of shell-cracking.As indicated by the results,to crack the walnuts shell from its longitudinal or edge directions could save lots of efforts.The study provided theoretical basis for the design and improvement of walnut shell-cracking machine as well as theoretical references for the design,making and use of some special cracking-aiding tools such as nutcracker.
基金supported by the National High Technology Research and Development Program of China (No.2007AA03Z113)
文摘Aiming at the cracking phenomenon of the thin shell mould in the expendable pattern shell casting during the pattern removing process, some systemic researches are presented.The influence of the pattern removing method and temperature on the pattern removing were investigated.The shell mould cracking mechanism was analyzed by using thermo-gravimetric analysis (TGA), and combining the temperature field and the volume change of the expanded polystyrene (EPS) foam pattern being tested.The results indicated that the shell mould was not easily cracked when the pattern removing process was carried out with the furnace being heated little by little because of the shell slowly shrinking with dehydration and shell strength gradually increasing.The shell mould was soon destroyed when it was set directly into the furnace at above 400 oC because of the thin shell mould rapidly shrinking and the foam pattern hindering.However, the shell mould had no cracking when it had been preheated for a long time even if the furnace temperature was above 400 oC and the shell was put into the furnace directly.Moreover, when the shell mould was directly set into the furnace at lower temperatures, 250 to 300 ℃, the shell would shrink slowly and the foam pattern would stay at the maximum expansion stage temperature of 100 to 110 ℃ for a long time; and the shell mould would experience an expansion force from the foam pattern for a long time.The expansion force is related to the pattern removing temperature, holding time, foam pattern thickness and density.Therefore, the foam pattern with higher density could make the shell crack.
基金Supported by the National Natural Science Foundation of China under Grant No.（50579023）.
文摘The cylindrical shell is one of the main structural parts in ocean engineering structures.These cylinders are mostly of medium length,which means that the radius of the cross section is significantly smaller than the length of the cylindrical shell.From the viewpoint of the shell theory,they belong to the mid-long cylindrical shell category.To solve mechanical problems on this kind of structure,especially a cracked cylindrical shell,analysis based on shell theory is necessary.At present the generally used solving system for the mid-long cylindrical shell is too complicated,difficult to solve,and inapplicable to engineering.This paper introduced the Sanders' mid-long cylindrical shell theory which reduces the difficulty of the solution process,and will be suitable for solving problems with complicated boundary conditions.On this basis,the engineering applications of this theory were discussed in conjunction with the problem of a mid-long cylindrical shell having a circumferential crack.The solution process is simple,and the closed form solution can usually be found.In practical engineering applications,it gives satisfactory precision.
基金Project (No. NSC-95-2221-E-167-002) supported by the National Science Council of Taiwan, China
文摘The characteristic properties of shell element with similar shapes are used to generate a so-called super element for the analysis of the crack problems for cylindrical pressure vessels. The formulation is processed by matrix condensation without the involvement of special treatment. This method can deal with various singularity problems and it also presents excellent results to crack problems for cylindrical shell. Especially,the knowledge of the kind of singular order is not necessary in super element generation; it is very economical in terms of computer memory and programming. This method also exhibits versatility to solve the problem of kinked crack at cylindrical shell.
文摘Two cylindrical vessels under internal pressure are used for this work in order to study the influence of the position and size of defects on their elastic and elastoplastic behavior. One contains two external longitudinal semi-elliptic defects of different dimensions realized diametrically opposed. The other contains the same defects but is circumferential. These defects are carried out by elect-erosion. Strain gauges are placed in the neighborhood of the defects of which the purpose is to obtain the strain distribution. This work also allows the comparison between two defects of different dimensions, which are of the same shape or different shapes. These defects are longitudinal and circumferential semi-elliptical. The position of these defects relative to the inner radius of a cylindrical pressure vessel is considered. The deformations results are discussed.
