In this paper, a kind of rationalism theory of shell is established which is of different mechanic characters in tension and in compression, and the finite element numerical analysis method is also described.
It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown ...It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown theorem for kinematic hardening materials has been made, and it is applied to analyze the shakedown of shell structures Though the residual stress of a real stale is related to plastic strain, the time-independent residual stress field as we will show in the theorem may be unrelated to the time-independent kinematically admissible plastic strain field For the engineering application, it will lie much more convenient to point this out clearly and definitely, otherwise it will be very difficult. Also, we have proposed a new method of proving this theorem.The above theorem is applied to the shakedown analysis of a cylindrical shell with hemispherical ends. According to the elastic solution, various possible residual sfcss and plastic strain Jlelds, the shakedown analysis of the structure can be reduced to a mathematical programming problem.The results of calculation show that the shakedown load oj strain hardening materials is about 30-40% higher than that of ideal plastic materials. So it is very important to consider the hardening of materials in the shakedown analysis,for it can greatly increase the structure design capacity, and meanwhile provide ascicntific basis to improve the design of shell structures.展开更多
Non-spherical Cu@Cu S yolk–shell structures are successfully obtained using Cu_2 O cube templates in a process combining rapid surface sulfidation followed by disproportionation of the Cu_2 O core upon treatment with...Non-spherical Cu@Cu S yolk–shell structures are successfully obtained using Cu_2 O cube templates in a process combining rapid surface sulfidation followed by disproportionation of the Cu_2 O core upon treatment with a hydrochloric acid solution. By employing the above method,Cu@Cu S yolk–shell structures with different morphologies,including octahedral, truncated octahedral, and cuboctahedral shapes, can be synthesized. The void space within the hollow structures provides a unique confined space, where the metallic copper present in the core of a shell can be protected from agglomeration and oxidation. Furthermore,the presence of metal copper in these hollow structurescontributes to improvement in the photocatalytic properties of these materials. The application of these Cu@Cu S structures indeed shows clearly improved photocatalytic performance.展开更多
Reticulated shell structures (RSSs) are characterized as cyclically periodic structures. Mistuning of RSSs will induce structural mode localization. Mode localization has the following two features: some modal vect...Reticulated shell structures (RSSs) are characterized as cyclically periodic structures. Mistuning of RSSs will induce structural mode localization. Mode localization has the following two features: some modal vectors of the structure change remarkably when the values of its physical parameters (mass or stiffness) have a slight change; and the vibration of some modes is mainly restricted in some local areas of the structure. In this paper, two quantitative assessment indexes are introduced that correspond to these two features. The first feature is studied through a numerical example of a RSS, and its induced causes are analyzed by using the perturbation theory. The analysis showed that internally, mode localization is closely related to structural frequencies and externally, slight changes of the physical parameters of the structure cause instability to the RSS. A scaled model experiment to examine mode localization was carried out on a Kiewit single-layer spherical RSS, and both features of mode localization are studied. Eight tests that measured the changes of the physical parameters were carried out in the experiment. Since many modes make their contribution in structural dynamic response, six strong vibration modes were tested at random in the experimental analysis. The change and localization of the six modes are analyzed for each test. The results show that slight changes to the physical parameters are likely to induce remarkable changes and localization of some modal vectors in the RSSs.展开更多
To fit in with the strict geometrical integrity and ensure dimensionally consistent fabrication of the welded aerospace structures. the low stress no distortion(LSND)welding, a technique for thin materials, was poinee...To fit in with the strict geometrical integrity and ensure dimensionally consistent fabrication of the welded aerospace structures. the low stress no distortion(LSND)welding, a technique for thin materials, was poineered and developed to provide an ininprocess active control of welding distortion. Satisfactory distortion free results were achieved in both welding of jet engine cases of heat-resistance alloys and rocket fuel tanks of aluminuim alloys, and there need no. reworking operations for post-weld distortion correction. Based on the 'static' method a newly developed method for dvnamic in-process control is also discussed in this paper. Both methods provide quanutiative in-process control of incompatible strains in weld zone and low stress no distortion welding results.展开更多
Architects have been following nature in their constructions for a long time.Observations of nature reveal that it has many highly developed structures that provide scientists and engineers with a lot of useful clues ...Architects have been following nature in their constructions for a long time.Observations of nature reveal that it has many highly developed structures that provide scientists and engineers with a lot of useful clues for creating more efficient structures and building forms.Therefore,revealing systematic thinking about natural species is a crucial requirement for today’s buildings.A software analysis method was used to design four modules in the roof structure of the Iranian University of Science and Technology’s exhibition.The roof structure is based on the Voronax structure,which is a relaxed form of Voronoi,which is seen in the structures of many natural creatures.They were analyzed in terms of optimization and structural simulation using Grasshopper plugins and tools by taking into account Von Mises stress in the structural design.The results indicated that by increasing the density of Voronax cells in the areas with high Von Mises stress concentration,a more efficient structure could be achieved in terms of load-bearing and designing predefined free-form roof structures.By analyzing predefined roof structures in an optimum way,the study took a step toward optimizing these kinds of structures.展开更多
Haima cold seep ecosystem is on the northwestern slope of the South China Sea,which is characterised by high pressure,low temperature,hypoxia,and low pH value.The deep-sea mussel Gigantidas haimaensis is distributed i...Haima cold seep ecosystem is on the northwestern slope of the South China Sea,which is characterised by high pressure,low temperature,hypoxia,and low pH value.The deep-sea mussel Gigantidas haimaensis is distributed in this ecosystem.Previous studies have focused on its adaptation to abiotic stress,biogeography,ecotoxicology,genomes,immunity and symbiosis,but knowledge on biomineralisation remains lacking.Herein,we generated a comprehensive transcript dataset from G.haimaensis mantle tissue,and 30255 unigenes were assembled.The top 20 most highly expressed genes are related to energy supply,such as mitochondrial genes,suggesting they may mediate the adaptability of this deep-sea mussel to the high pressure and hypoxia environment.Eleven shell matrix protein(SMP)-related genes were identified from the transcriptome data.Quantitative PCR analyses showed that five of ten acidic SMPs and nacreous-layer-matrix-protein genes(nacrein,perlucin,perlwapin,pif and mantle protein)were highly expressed in mantle tissue,while the expressions of other five genes(chitinase,SPARC,TRY,papilin and calmodulin)were low.Scanning electron microscopy showed that the shell was composed of a prismatic layer and a nacreous layer,and every nacreous layer was made of the whole pieces of aragonite that stacked on top of each other.These results indicated the conservation of the structure and functions of nacreous matrix genes in G.haimaensis.Moreover,the nacreous layer was made of whole pieces of aragonite that were not quadrilateral or polygonal pieces.Studying these genes will likely reveal the molecular mechanisms of biomineralisation in G.haimaensis and other deep-sea mussels.展开更多
The purpose of the present work is to study the buckling problem with plate/shell topology optimization of orthotropic material. A model of buckling topology optimization is established based on the independent, conti...The purpose of the present work is to study the buckling problem with plate/shell topology optimization of orthotropic material. A model of buckling topology optimization is established based on the independent, continuous, and mapping method, which considers structural mass as objective and buckling critical loads as constraints. Firstly, composite exponential function (CEF) and power function (PF) as filter functions are introduced to recognize the element mass, the element stiffness matrix, and the element geometric stiffness matrix. The filter functions of the orthotropic material stiffness are deduced. Then these filter functions are put into buckling topology optimization of a differential equation to analyze the design sensitivity. Furthermore, the buckling constraints are approximately expressed as explicit functions with respect to the design variables based on the first-order Taylor expansion. The objective function is standardized based on the second-order Taylor expansion. Therefore, the optimization model is translated into a quadratic program. Finally, the dual sequence quadratic programming (DSQP) algorithm and the global convergence method of moving asymptotes algorithm with two different filter functions (CEF and PF) are applied to solve the optimal model. Three numerical results show that DSQP&CEF has the best performance in the view of structural mass and discretion.展开更多
A facile strategy to fabricate gold nanorod@polyacrylic acid/calcium phosphate(Au NR@-PAA/Ca P) yolk–shell nanoparticles(NPs) composed with a PAA/Ca P shell and an Au NR yolk is reported. The asobtained Au NR@PAA/Ca ...A facile strategy to fabricate gold nanorod@polyacrylic acid/calcium phosphate(Au NR@-PAA/Ca P) yolk–shell nanoparticles(NPs) composed with a PAA/Ca P shell and an Au NR yolk is reported. The asobtained Au NR@PAA/Ca P yolk–shell NPs possess ultrahigh doxorubicin(DOX) loading capability(1 mg DOX/mg NPs), superior photothermal conversion property(26%)and p H/near-infrared(NIR) dual-responsive drug delivery performance. The released DOX continuously increased due to the damage of the Ca P shell at low p H values. When the DOX-loaded Au NR@PAA/Ca P yolk–shell NPs wereexposed to NIR irradiation, a burst-like drug release occurs owing to the heat produced by the Au NRs. Furthermore,Au NR@PAA/Ca P yolk–shell NPs are successfully employed for synergic dual-mode X-ray computed tomography/photoacoustic imaging and chemo-photothermal cancer therapy. Therefore, this work brings new insights for the synthesis of multifunctional nanomaterials and extends theranostic applications.展开更多
Lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs) have received much attention in energy storage system. In particular, among the great efforts on enhancing the performance of LIBs and SIBs, yolk–shell(YS) s...Lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs) have received much attention in energy storage system. In particular, among the great efforts on enhancing the performance of LIBs and SIBs, yolk–shell(YS) structured materials have emerged as a promising strategy toward improving lithium and sodium storage. YS structures possess unique interior void space, large surface area and short diffusion distance, which can solve the problems of volume expansion and aggregation of anode materials, thus enhancing the performance of LIBs and SIBs. In this review, we present a brief overview of recent advances in the novel YS structures of spheres, polyhedrons and rods with controllable morphology and compositions. Enhanced electrochemical performance of LIBs and SIBs based on these novel YS structured anode materials was discussed in detail.展开更多
A rapid and more efficient method was developed to prepare nucleus/shell titania/hydroxyapatite (TiO2/HAP) complex nanophotocatalyst. Hydroxyapatite (5 μm) which had been dissolved with 0.1 mol/L HCI was formed o...A rapid and more efficient method was developed to prepare nucleus/shell titania/hydroxyapatite (TiO2/HAP) complex nanophotocatalyst. Hydroxyapatite (5 μm) which had been dissolved with 0.1 mol/L HCI was formed on the surface of the nanosized anatase titania powders by increasing the pH value of the solution at 90℃ in the water bath for only several hours .The microstructure and morphology of the resulting sample were investigated by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrum (EDS) and atomic force microscope (AFM). The results indicated that nucleus/shell structural TiO2/HAP was formed in our experiments, and the thickness of the coating layer was about 5 nm. Photocatalytic decomposition of methyl orange was utilized to test the photocatalysis of the resulting samples and the result was compared with that of pure anatase titania powders (about 20 nm). It was shown that the photocatalytic activity of the sample was not decreased due to the coating of HAP.展开更多
Bamboo shoot shell(BSS),a by-product from bamboo shoot processing industries,is a natural resource of cellulose. In this study,high-pressure homogenization assisted with acidolysis treatment was employed to produce ...Bamboo shoot shell(BSS),a by-product from bamboo shoot processing industries,is a natural resource of cellulose. In this study,high-pressure homogenization assisted with acidolysis treatment was employed to produce BSS cellulose nanofiber(CNF),and the structure was characterized by powder X-ray diffraction(XRD),Fourier-transform infrared(FT-IR) spectroscopy,atomic force microscopy(AFM),high resolution transmission electron microscopy(HTTEM),thermogravimetric analysis(TGA),and ^13 C nuclear magnetic resonance(NMR). Moreover,the structure and properties of CNF were compared with those of BSS insoluble dietary fiber(IDF). The results showed that CNF was in the form of a grid-like micro fiber,and its particle size was obviously reduced,while the crystallinity,thermal stability and solubility were increased. The results indicated that high-pressure homogenization assisted with acidolysis treatment was an effective method to prepare the BSS CNF,which could be a promising biopolymer reinforced material.展开更多
The local maxima of water density in the space near the single-helical of Konjac glucomannan as well as the dominant conformation of the system was studied by molecular dyna-mics under the water environment. The resul...The local maxima of water density in the space near the single-helical of Konjac glucomannan as well as the dominant conformation of the system was studied by molecular dyna-mics under the water environment. The results indicate that the hydration shell,potential energy,and its hydrogen bond network with water bridges of the left-handed single-helix conformation was favored compared to those of right-handed single-helix conformation. This work suggests that the left-handed single-helix conformation was the dominant conformation of KGM in the water environment.展开更多
In this paper, Fe30Pt70/Fe3O4 core/shell nanoparticles were synthesized by chemical routine and the layered polyethylenimine (PEI)-Fe30Pt70/Fe3O4 structure was constructed by molecule-mediated self-assembly techniqu...In this paper, Fe30Pt70/Fe3O4 core/shell nanoparticles were synthesized by chemical routine and the layered polyethylenimine (PEI)-Fe30Pt70/Fe3O4 structure was constructed by molecule-mediated self-assembly technique. The dimension of core/shell structured nanoparticles was that of 4nm core and 2 nm shell. After annealing under a flow of forming gas (50%Ar2+30%H2) for 1 h at or above 400℃, the iron oxide shell was reduced to Fe and diffused to Pt-rieh core, which leaded to the formation of L1. phase FePt at low temperature. The x-ray diffraction results and magnetic properties measurement showed that the chemical ordering temperature of Fe30Pt70/Fe3O4 core/shell nanoparticles assembly can be reduced to as low as 400℃. The sample annealed at 400℃ showed the eoereivity of 4KOe with the applied field of 1.5T. The core/shell structure was suggested to be an effective way to reduce the ordering temperature obviously.展开更多
In this paper, some formulas are derived for the numerical computation of the fundamental solution obtained in ref. [1] and relevant computer methods are also discussed in detail. As an application of the fundamental ...In this paper, some formulas are derived for the numerical computation of the fundamental solution obtained in ref. [1] and relevant computer methods are also discussed in detail. As an application of the fundamental solution, problems of a concentrated normal force acting on infinite shallow shells having positive, zero and negative Gaussian curvatures are calculated according to the numerical methods given in the paper.展开更多
The linear buckling problems of plates and shells were analysed using a recently developped quadrilateral,16-degrees of freedom flat shell element (called DKQ16).The geometrical stiffness matrix was established.Compar...The linear buckling problems of plates and shells were analysed using a recently developped quadrilateral,16-degrees of freedom flat shell element (called DKQ16).The geometrical stiffness matrix was established.Comparison of the numerical results for several typical problems shows that the DKQ16 element has a very good precision for the linear buckling problems of plates and shells.展开更多
Giving up any assumption about displacement models and stress distribution, and introducing delta function, the state equation for the open cylindrical shells with four clamped edges was established based on some prev...Giving up any assumption about displacement models and stress distribution, and introducing delta function, the state equation for the open cylindrical shells with four clamped edges was established based on some previous works. An identical exact solution was obtained for the thin, moderately thick and thick laminated open cylindrical shells.展开更多
Rupturing the alumina shell(shell-breaking)is a prerequisite for releasing energy from aluminum powder.Thermal stress overload in a high-temperature environment is an important factor in the rupture of the alumina she...Rupturing the alumina shell(shell-breaking)is a prerequisite for releasing energy from aluminum powder.Thermal stress overload in a high-temperature environment is an important factor in the rupture of the alumina shell.COMSOL Multiphysics was used to simulate and analyze the shell-breaking response of micron-scale aluminum particles with different particle sizes at 650℃in vacuum.The simulation results show that the thermal stability time and shell-breaking response time of 10μm–100μm aluminum particles are 0.15μs–11.44μs and 0.08μs–3.94μs,respectively.They also reveal the direct causes of shell breaking for aluminum particles with different particle sizes.When the particle size is less than 80μm,the shell-breaking response is a direct result of compressive stress overload.When the particle size is between80μm and 100μm,the shell-breaking response is a direct result of tensile stress overload.This article provides useful guidance for research into the energy release of aluminum powder.展开更多
LaF_3:Yb^(3 +),Er^(3 +) nanoparticles were successfully synthesized using solvothermal treatment,and LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 core /shell nanoparticles were also prepared with reverse microemulsion technique.The...LaF_3:Yb^(3 +),Er^(3 +) nanoparticles were successfully synthesized using solvothermal treatment,and LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 core /shell nanoparticles were also prepared with reverse microemulsion technique.The crystal structure,morphology and photoluminescence properties of as-prepared core /shell nanoparticles were investigated by X-ray diffraction,transmission electron microscopy and fluorescence spectrophotometer.The results showed that LaF_3:Yb^(3 +),Er^(3 +) nanoparticles are of hexagonal structure and SiO_2 shell is amorphous.The size of LaF_3:Yb^(3 +),Er^(3 +) nanoparticles is 13 nm and the LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 nanoparticles present clearly a core /shell structure with 12 nm shell thickness.The solubility of LaF_3:Yb^(3 +),Er^(3 +) nanocrystals in water and the biocompatibility are both improved by the SiO_2 shell.The upconversion luminescence spectra suggested that the SiO_2 shell has small effect on the upconversion luminescence properties of the LaF_3:Yb^(3 +),Er^(3 +) nanocrystals.The core /shell structure LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 nanoparticles are expected to be used in biological applications.展开更多
The elastic pulse buckling of a thin-thickness cylindrical shell (radius a/thickness h)=480) with a finite length (L/a=1) under a cosine impulse load was analyzed through using the Lagrange method and assuming the def...The elastic pulse buckling of a thin-thickness cylindrical shell (radius a/thickness h)=480) with a finite length (L/a=1) under a cosine impulse load was analyzed through using the Lagrange method and assuming the deformation mode based on some relevant experimental results. The dynamic buckling equations were derived and solved by using numerical method, and the obtained results were compared with both the relevant calculated and experimental results obtained by other authors with satisfaction.展开更多
文摘In this paper, a kind of rationalism theory of shell is established which is of different mechanic characters in tension and in compression, and the finite element numerical analysis method is also described.
文摘It is of great practical importance to analyze the shakedown of shell structures under cyclic loading, especially of those made of strain hardening materials.In this paper, same further understanding of the shakedown theorem for kinematic hardening materials has been made, and it is applied to analyze the shakedown of shell structures Though the residual stress of a real stale is related to plastic strain, the time-independent residual stress field as we will show in the theorem may be unrelated to the time-independent kinematically admissible plastic strain field For the engineering application, it will lie much more convenient to point this out clearly and definitely, otherwise it will be very difficult. Also, we have proposed a new method of proving this theorem.The above theorem is applied to the shakedown analysis of a cylindrical shell with hemispherical ends. According to the elastic solution, various possible residual sfcss and plastic strain Jlelds, the shakedown analysis of the structure can be reduced to a mathematical programming problem.The results of calculation show that the shakedown load oj strain hardening materials is about 30-40% higher than that of ideal plastic materials. So it is very important to consider the hardening of materials in the shakedown analysis,for it can greatly increase the structure design capacity, and meanwhile provide ascicntific basis to improve the design of shell structures.
基金supported by the National Natural Science Foundation of China (Grant Nos. 21671085, 21473081, 21201088)the Natural Science Foundation of Jiangsu Province (BK20161160)the Qing Lan Project and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Non-spherical Cu@Cu S yolk–shell structures are successfully obtained using Cu_2 O cube templates in a process combining rapid surface sulfidation followed by disproportionation of the Cu_2 O core upon treatment with a hydrochloric acid solution. By employing the above method,Cu@Cu S yolk–shell structures with different morphologies,including octahedral, truncated octahedral, and cuboctahedral shapes, can be synthesized. The void space within the hollow structures provides a unique confined space, where the metallic copper present in the core of a shell can be protected from agglomeration and oxidation. Furthermore,the presence of metal copper in these hollow structurescontributes to improvement in the photocatalytic properties of these materials. The application of these Cu@Cu S structures indeed shows clearly improved photocatalytic performance.
基金National Natural Science Foundation of China Under Grant No. 50878010
文摘Reticulated shell structures (RSSs) are characterized as cyclically periodic structures. Mistuning of RSSs will induce structural mode localization. Mode localization has the following two features: some modal vectors of the structure change remarkably when the values of its physical parameters (mass or stiffness) have a slight change; and the vibration of some modes is mainly restricted in some local areas of the structure. In this paper, two quantitative assessment indexes are introduced that correspond to these two features. The first feature is studied through a numerical example of a RSS, and its induced causes are analyzed by using the perturbation theory. The analysis showed that internally, mode localization is closely related to structural frequencies and externally, slight changes of the physical parameters of the structure cause instability to the RSS. A scaled model experiment to examine mode localization was carried out on a Kiewit single-layer spherical RSS, and both features of mode localization are studied. Eight tests that measured the changes of the physical parameters were carried out in the experiment. Since many modes make their contribution in structural dynamic response, six strong vibration modes were tested at random in the experimental analysis. The change and localization of the six modes are analyzed for each test. The results show that slight changes to the physical parameters are likely to induce remarkable changes and localization of some modal vectors in the RSSs.
文摘To fit in with the strict geometrical integrity and ensure dimensionally consistent fabrication of the welded aerospace structures. the low stress no distortion(LSND)welding, a technique for thin materials, was poineered and developed to provide an ininprocess active control of welding distortion. Satisfactory distortion free results were achieved in both welding of jet engine cases of heat-resistance alloys and rocket fuel tanks of aluminuim alloys, and there need no. reworking operations for post-weld distortion correction. Based on the 'static' method a newly developed method for dvnamic in-process control is also discussed in this paper. Both methods provide quanutiative in-process control of incompatible strains in weld zone and low stress no distortion welding results.
文摘Architects have been following nature in their constructions for a long time.Observations of nature reveal that it has many highly developed structures that provide scientists and engineers with a lot of useful clues for creating more efficient structures and building forms.Therefore,revealing systematic thinking about natural species is a crucial requirement for today’s buildings.A software analysis method was used to design four modules in the roof structure of the Iranian University of Science and Technology’s exhibition.The roof structure is based on the Voronax structure,which is a relaxed form of Voronoi,which is seen in the structures of many natural creatures.They were analyzed in terms of optimization and structural simulation using Grasshopper plugins and tools by taking into account Von Mises stress in the structural design.The results indicated that by increasing the density of Voronax cells in the areas with high Von Mises stress concentration,a more efficient structure could be achieved in terms of load-bearing and designing predefined free-form roof structures.By analyzing predefined roof structures in an optimum way,the study took a step toward optimizing these kinds of structures.
基金supported by the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory,Guangzhou,China(No.GML2019ZD0401)the Major Project of Basic and Applied Basic Research of Guangdong Province(No.2019 B030302004)the Science and Technology Planning Project of Guangdong Province,China(No.2020B1212060058).
文摘Haima cold seep ecosystem is on the northwestern slope of the South China Sea,which is characterised by high pressure,low temperature,hypoxia,and low pH value.The deep-sea mussel Gigantidas haimaensis is distributed in this ecosystem.Previous studies have focused on its adaptation to abiotic stress,biogeography,ecotoxicology,genomes,immunity and symbiosis,but knowledge on biomineralisation remains lacking.Herein,we generated a comprehensive transcript dataset from G.haimaensis mantle tissue,and 30255 unigenes were assembled.The top 20 most highly expressed genes are related to energy supply,such as mitochondrial genes,suggesting they may mediate the adaptability of this deep-sea mussel to the high pressure and hypoxia environment.Eleven shell matrix protein(SMP)-related genes were identified from the transcriptome data.Quantitative PCR analyses showed that five of ten acidic SMPs and nacreous-layer-matrix-protein genes(nacrein,perlucin,perlwapin,pif and mantle protein)were highly expressed in mantle tissue,while the expressions of other five genes(chitinase,SPARC,TRY,papilin and calmodulin)were low.Scanning electron microscopy showed that the shell was composed of a prismatic layer and a nacreous layer,and every nacreous layer was made of the whole pieces of aragonite that stacked on top of each other.These results indicated the conservation of the structure and functions of nacreous matrix genes in G.haimaensis.Moreover,the nacreous layer was made of whole pieces of aragonite that were not quadrilateral or polygonal pieces.Studying these genes will likely reveal the molecular mechanisms of biomineralisation in G.haimaensis and other deep-sea mussels.
基金supported by the National Natural Science Foundation of China (Grants 11072009, 11172013)the Beijing Education Committee Development Project (Grant SQKM2016100 05001)the Beijing University of Technology Basic Research Fund (Grant 001000514313003)
文摘The purpose of the present work is to study the buckling problem with plate/shell topology optimization of orthotropic material. A model of buckling topology optimization is established based on the independent, continuous, and mapping method, which considers structural mass as objective and buckling critical loads as constraints. Firstly, composite exponential function (CEF) and power function (PF) as filter functions are introduced to recognize the element mass, the element stiffness matrix, and the element geometric stiffness matrix. The filter functions of the orthotropic material stiffness are deduced. Then these filter functions are put into buckling topology optimization of a differential equation to analyze the design sensitivity. Furthermore, the buckling constraints are approximately expressed as explicit functions with respect to the design variables based on the first-order Taylor expansion. The objective function is standardized based on the second-order Taylor expansion. Therefore, the optimization model is translated into a quadratic program. Finally, the dual sequence quadratic programming (DSQP) algorithm and the global convergence method of moving asymptotes algorithm with two different filter functions (CEF and PF) are applied to solve the optimal model. Three numerical results show that DSQP&CEF has the best performance in the view of structural mass and discretion.
基金the National Natural Science Foundation of China(Grant Nos.21573040 and 21603029)the Natural Science Foundation and Science and Technology Development Planning of Jilin Province(20150204086GX and20170520148JH)+3 种基金the Fundamental Research Funds for the Central Universities(2412016KJ007 and 2412016KJ020)the China Postdoctoral Science Foundation(2016M600224)the Jilin Provincial Research Foundation for Basic Research(20160519012JH)Jilin Provincial Key Laboratory of Advanced Energy Materials(Northeast Normal University)
文摘A facile strategy to fabricate gold nanorod@polyacrylic acid/calcium phosphate(Au NR@-PAA/Ca P) yolk–shell nanoparticles(NPs) composed with a PAA/Ca P shell and an Au NR yolk is reported. The asobtained Au NR@PAA/Ca P yolk–shell NPs possess ultrahigh doxorubicin(DOX) loading capability(1 mg DOX/mg NPs), superior photothermal conversion property(26%)and p H/near-infrared(NIR) dual-responsive drug delivery performance. The released DOX continuously increased due to the damage of the Ca P shell at low p H values. When the DOX-loaded Au NR@PAA/Ca P yolk–shell NPs wereexposed to NIR irradiation, a burst-like drug release occurs owing to the heat produced by the Au NRs. Furthermore,Au NR@PAA/Ca P yolk–shell NPs are successfully employed for synergic dual-mode X-ray computed tomography/photoacoustic imaging and chemo-photothermal cancer therapy. Therefore, this work brings new insights for the synthesis of multifunctional nanomaterials and extends theranostic applications.
基金supported by National Program on Key Basic Research Project (973 Program) No. 2013CB933301National Natural Science Foundation of China No. 51272038 and 61474015
文摘Lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs) have received much attention in energy storage system. In particular, among the great efforts on enhancing the performance of LIBs and SIBs, yolk–shell(YS) structured materials have emerged as a promising strategy toward improving lithium and sodium storage. YS structures possess unique interior void space, large surface area and short diffusion distance, which can solve the problems of volume expansion and aggregation of anode materials, thus enhancing the performance of LIBs and SIBs. In this review, we present a brief overview of recent advances in the novel YS structures of spheres, polyhedrons and rods with controllable morphology and compositions. Enhanced electrochemical performance of LIBs and SIBs based on these novel YS structured anode materials was discussed in detail.
文摘A rapid and more efficient method was developed to prepare nucleus/shell titania/hydroxyapatite (TiO2/HAP) complex nanophotocatalyst. Hydroxyapatite (5 μm) which had been dissolved with 0.1 mol/L HCI was formed on the surface of the nanosized anatase titania powders by increasing the pH value of the solution at 90℃ in the water bath for only several hours .The microstructure and morphology of the resulting sample were investigated by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrum (EDS) and atomic force microscope (AFM). The results indicated that nucleus/shell structural TiO2/HAP was formed in our experiments, and the thickness of the coating layer was about 5 nm. Photocatalytic decomposition of methyl orange was utilized to test the photocatalysis of the resulting samples and the result was compared with that of pure anatase titania powders (about 20 nm). It was shown that the photocatalytic activity of the sample was not decreased due to the coating of HAP.
文摘Bamboo shoot shell(BSS),a by-product from bamboo shoot processing industries,is a natural resource of cellulose. In this study,high-pressure homogenization assisted with acidolysis treatment was employed to produce BSS cellulose nanofiber(CNF),and the structure was characterized by powder X-ray diffraction(XRD),Fourier-transform infrared(FT-IR) spectroscopy,atomic force microscopy(AFM),high resolution transmission electron microscopy(HTTEM),thermogravimetric analysis(TGA),and ^13 C nuclear magnetic resonance(NMR). Moreover,the structure and properties of CNF were compared with those of BSS insoluble dietary fiber(IDF). The results showed that CNF was in the form of a grid-like micro fiber,and its particle size was obviously reduced,while the crystallinity,thermal stability and solubility were increased. The results indicated that high-pressure homogenization assisted with acidolysis treatment was an effective method to prepare the BSS CNF,which could be a promising biopolymer reinforced material.
基金supported by the National Natural Science Foundation of China (30871749,30901004,31071518)Natural Science Foundation of Fujian Province (2009J01061)
文摘The local maxima of water density in the space near the single-helical of Konjac glucomannan as well as the dominant conformation of the system was studied by molecular dyna-mics under the water environment. The results indicate that the hydration shell,potential energy,and its hydrogen bond network with water bridges of the left-handed single-helix conformation was favored compared to those of right-handed single-helix conformation. This work suggests that the left-handed single-helix conformation was the dominant conformation of KGM in the water environment.
基金Project supported by the National Natural Science Foundation of China (Grant No 50641006) and the Science Foundation of Education Commission of Beijing, China.
文摘In this paper, Fe30Pt70/Fe3O4 core/shell nanoparticles were synthesized by chemical routine and the layered polyethylenimine (PEI)-Fe30Pt70/Fe3O4 structure was constructed by molecule-mediated self-assembly technique. The dimension of core/shell structured nanoparticles was that of 4nm core and 2 nm shell. After annealing under a flow of forming gas (50%Ar2+30%H2) for 1 h at or above 400℃, the iron oxide shell was reduced to Fe and diffused to Pt-rieh core, which leaded to the formation of L1. phase FePt at low temperature. The x-ray diffraction results and magnetic properties measurement showed that the chemical ordering temperature of Fe30Pt70/Fe3O4 core/shell nanoparticles assembly can be reduced to as low as 400℃. The sample annealed at 400℃ showed the eoereivity of 4KOe with the applied field of 1.5T. The core/shell structure was suggested to be an effective way to reduce the ordering temperature obviously.
基金The Project supported by the National Natural Science Foundation of china
文摘In this paper, some formulas are derived for the numerical computation of the fundamental solution obtained in ref. [1] and relevant computer methods are also discussed in detail. As an application of the fundamental solution, problems of a concentrated normal force acting on infinite shallow shells having positive, zero and negative Gaussian curvatures are calculated according to the numerical methods given in the paper.
文摘The linear buckling problems of plates and shells were analysed using a recently developped quadrilateral,16-degrees of freedom flat shell element (called DKQ16).The geometrical stiffness matrix was established.Comparison of the numerical results for several typical problems shows that the DKQ16 element has a very good precision for the linear buckling problems of plates and shells.
文摘Giving up any assumption about displacement models and stress distribution, and introducing delta function, the state equation for the open cylindrical shells with four clamped edges was established based on some previous works. An identical exact solution was obtained for the thin, moderately thick and thick laminated open cylindrical shells.
基金the National Natural Science Foundation of China(Grant No.11802160)。
文摘Rupturing the alumina shell(shell-breaking)is a prerequisite for releasing energy from aluminum powder.Thermal stress overload in a high-temperature environment is an important factor in the rupture of the alumina shell.COMSOL Multiphysics was used to simulate and analyze the shell-breaking response of micron-scale aluminum particles with different particle sizes at 650℃in vacuum.The simulation results show that the thermal stability time and shell-breaking response time of 10μm–100μm aluminum particles are 0.15μs–11.44μs and 0.08μs–3.94μs,respectively.They also reveal the direct causes of shell breaking for aluminum particles with different particle sizes.When the particle size is less than 80μm,the shell-breaking response is a direct result of compressive stress overload.When the particle size is between80μm and 100μm,the shell-breaking response is a direct result of tensile stress overload.This article provides useful guidance for research into the energy release of aluminum powder.
文摘LaF_3:Yb^(3 +),Er^(3 +) nanoparticles were successfully synthesized using solvothermal treatment,and LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 core /shell nanoparticles were also prepared with reverse microemulsion technique.The crystal structure,morphology and photoluminescence properties of as-prepared core /shell nanoparticles were investigated by X-ray diffraction,transmission electron microscopy and fluorescence spectrophotometer.The results showed that LaF_3:Yb^(3 +),Er^(3 +) nanoparticles are of hexagonal structure and SiO_2 shell is amorphous.The size of LaF_3:Yb^(3 +),Er^(3 +) nanoparticles is 13 nm and the LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 nanoparticles present clearly a core /shell structure with 12 nm shell thickness.The solubility of LaF_3:Yb^(3 +),Er^(3 +) nanocrystals in water and the biocompatibility are both improved by the SiO_2 shell.The upconversion luminescence spectra suggested that the SiO_2 shell has small effect on the upconversion luminescence properties of the LaF_3:Yb^(3 +),Er^(3 +) nanocrystals.The core /shell structure LaF_3:Yb^(3 +),Er^(3 +) /SiO_2 nanoparticles are expected to be used in biological applications.
文摘The elastic pulse buckling of a thin-thickness cylindrical shell (radius a/thickness h)=480) with a finite length (L/a=1) under a cosine impulse load was analyzed through using the Lagrange method and assuming the deformation mode based on some relevant experimental results. The dynamic buckling equations were derived and solved by using numerical method, and the obtained results were compared with both the relevant calculated and experimental results obtained by other authors with satisfaction.