Natural gas containing hydrogen sulphide （H2S） has been found in several petroliferous basins in China, such as the Sichuan Basin, Bohai Bay Basin, Ordos Basin, Tarim Basin, etc. Natural gas with higher HES contents...Natural gas containing hydrogen sulphide （H2S） has been found in several petroliferous basins in China, such as the Sichuan Basin, Bohai Bay Basin, Ordos Basin, Tarim Basin, etc. Natural gas with higher HES contents （HES 〉5 % mol.） is mostly distributed in both the gas reservoirs of Dukouhe, Luojiazhai, Puguang and Tieshanpo, which belong to the Triassic Feixianguan Formation in the northeastern Sichuan Basin and those of the Kongdian-Shahejie formations in the northeastern Jinxian Sag of the Jizhong Depression, Bohai Bay Basin. In the Sichuan Basin, the HES contents of natural gas average over 9% and some can be 17 %, while those of the Bohai Bay Basin range from 40 % to 92 %, being then one of the gas reservoirs with the highest H2S contents in the world. Based on detailed observation and sample analysis results of a total 5000 m of core from over 70 wells in the above-mentioned two basins, especially sulfur isotopic analysis of gypsum, brimstone, pyrite and natural gas, also with integrated study of the geochemical characteristics of hydrocarbons, it is thought that the natural gas with high HES contents resulted from thermochemical sulfate reduction （TSR） reactions. Among them, the natural gas in the Feixianguan Formation resulted from TSR reactions participated by hydrocarbon gas, while that in the Zhaolanzhuang of the Jinxian Sag being the product of TSR participated by crude oil. During the consumption process of hydrocarbons due to TSR, the heavy hydrocarbons were apt to react with sulfate, which accordingly resulted in the dry coefficient of natural gas increasing and the carbon isotopes becoming heavier.展开更多
The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct res...The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct result of precipitation by chemically distinct fluids occurring at different times and at different intensities. Based on this evidence, dolomitization and multiple fluid flow events are analyzed, and three types of fluid evolution models are proposed. Results of analysis show that Precambrian Dengying Formation carbonates were deposited in a restricted peritidal environment （630- 542 Ma）. A high temperature and high Mg2＋ concentration seawater was a direct result of dolomitization for the micrite matrix, and for fibrous aragonite in primary pores. Geochemical evidence shows low δ18O values of micritic dolomite varying from -1.29%o to -4.52%o PDB, abundant light rare earth elements （REEs）, and low dolomite order degrees. Microbes and meteoric water significantly altered dolomite original chemical signatures, resulting in algal micritic dolomite and the fine-grained, granular, dolosparite dolomite having very negative δ18O values. Finely crystalline cement dolomite （536.3-280 Ma） and coarsely crystalline cement dolomite have a higher crystallization degree and higher order degree. The diagenetic sequence and fluid inclusion evidence imply a linear correlation between their burial depth and homogenization temperatures, which closely resemble the temperature of generated hydrocarbon. Compared with finely crystalline dolomite, precipitation of coarsely crystalline dolomite was more affected by restricted basinal fluids. In addition, there is a trend toward a more negative δ18O value, higher salinity, higher Fe and Mn concentrations, REE-rich. Two periods of hydrothermal fluids are identified, as the exceptionally high temperatures as opposed to the temperatures of burial history, in addition to the presence of high salinity fluid inclusions. The early hydrothermal fluid flow event was characterized by hot magnesium- and silicon-rich fluids, as demonstrated by the recrystallized matrix dolomite that is intimately associated with flint, opal, and microcrystalline quartz in intergranular or intercrystalline pores. This event was likely the result of a seafloor hydrothermal chimney eruption during Episode I of the Tongwan Movement （536.3-5.5 Ma）. In contrast, later hydrothermal fluids, which caused precipitation of saddle dolomite, were characterized by high salinity （15-16.05wt% NaCI equivalent） and homogenization temperatures （250 to 265℃）, δ18O values that were more enriched, and REE signatures. Geochemical data and the paragenetic sequence indicate that this hydrothermal fluid was related to extensive Permian large igneous province activity （360-280 Ma）. This study demonstrates the presence of complicated dolomitization processes occurring during various paleoclimates, tectonic cycles, and basinal fluids flow; results are a useful reference for these dolomitized Precambrian carbonates reservoirs.展开更多
对四川盆地东北部巴中地区和西部雅安地区早白垩世红层分别采集9块手标本,进行了详细的古地磁学研究.系统退磁获得两地的特征剩磁,其中巴中地区平均方向为,倾斜校正之前:D_g/I_g=25.3°/19.0°,k=18.6,α_(95)=8.8°;倾斜...对四川盆地东北部巴中地区和西部雅安地区早白垩世红层分别采集9块手标本,进行了详细的古地磁学研究.系统退磁获得两地的特征剩磁,其中巴中地区平均方向为,倾斜校正之前:D_g/I_g=25.3°/19.0°,k=18.6,α_(95)=8.8°;倾斜校正之后:D_s/I_s=25.8°/18.9°,k=24.3,α_(95)=7.6°.雅安地区平均方向为,倾斜校正之前:D_g/I_g=24.5°/45.0°,k=15.7,α_(95)=9.0°;倾斜校正之后:D_s/I_s=356.7°/35.6°,k=28.5,α_(95)=6.6°.磁化率各向异性实验结果显示两地均未受到显著的构造应力影响.等温剩磁各向异性(AIR)实验结果,巴中地区IRMz/IRMLx平均值为0.8194,表明18%的压实率;雅安地区IRMz/IRMx平均值为0.8909,表明11%的压实率,计算得到巴中和雅安地区校正后的磁倾角分别为22.7°和38.8°.根据等温剩磁各向异性(AIR)实验和Tauxe and Kent(2004)提出的EI校正法得到的结果表明,四川盆地早白垩世陆相碎屑岩层中存在沉积压实作用造成的磁倾角偏低现象,而且川东北巴中地区的偏低程度强于川西雅安地区.展开更多
文摘Natural gas containing hydrogen sulphide （H2S） has been found in several petroliferous basins in China, such as the Sichuan Basin, Bohai Bay Basin, Ordos Basin, Tarim Basin, etc. Natural gas with higher HES contents （HES 〉5 % mol.） is mostly distributed in both the gas reservoirs of Dukouhe, Luojiazhai, Puguang and Tieshanpo, which belong to the Triassic Feixianguan Formation in the northeastern Sichuan Basin and those of the Kongdian-Shahejie formations in the northeastern Jinxian Sag of the Jizhong Depression, Bohai Bay Basin. In the Sichuan Basin, the HES contents of natural gas average over 9% and some can be 17 %, while those of the Bohai Bay Basin range from 40 % to 92 %, being then one of the gas reservoirs with the highest H2S contents in the world. Based on detailed observation and sample analysis results of a total 5000 m of core from over 70 wells in the above-mentioned two basins, especially sulfur isotopic analysis of gypsum, brimstone, pyrite and natural gas, also with integrated study of the geochemical characteristics of hydrocarbons, it is thought that the natural gas with high HES contents resulted from thermochemical sulfate reduction （TSR） reactions. Among them, the natural gas in the Feixianguan Formation resulted from TSR reactions participated by hydrocarbon gas, while that in the Zhaolanzhuang of the Jinxian Sag being the product of TSR participated by crude oil. During the consumption process of hydrocarbons due to TSR, the heavy hydrocarbons were apt to react with sulfate, which accordingly resulted in the dry coefficient of natural gas increasing and the carbon isotopes becoming heavier.
基金financially supported by the National Natural Science Foundation of China(grants No.41272159 and 41572099 and 41772272)China Geological Survey(grants No.1212011120964 and DD20180008)+2 种基金China Postdoctoral Science Foundation(Study on fluid diversity and genetic model of hydrothermal dolomitization,grant No.2016M601088)Liu Baojun Geoscience Foundation for Youthsthe Opening Foundation of Shandong Provincial Key Laboratory of Depositional Mineralization&Sedimentary Mineral(grant No.DMSM2017041)
文摘The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct result of precipitation by chemically distinct fluids occurring at different times and at different intensities. Based on this evidence, dolomitization and multiple fluid flow events are analyzed, and three types of fluid evolution models are proposed. Results of analysis show that Precambrian Dengying Formation carbonates were deposited in a restricted peritidal environment （630- 542 Ma）. A high temperature and high Mg2＋ concentration seawater was a direct result of dolomitization for the micrite matrix, and for fibrous aragonite in primary pores. Geochemical evidence shows low δ18O values of micritic dolomite varying from -1.29%o to -4.52%o PDB, abundant light rare earth elements （REEs）, and low dolomite order degrees. Microbes and meteoric water significantly altered dolomite original chemical signatures, resulting in algal micritic dolomite and the fine-grained, granular, dolosparite dolomite having very negative δ18O values. Finely crystalline cement dolomite （536.3-280 Ma） and coarsely crystalline cement dolomite have a higher crystallization degree and higher order degree. The diagenetic sequence and fluid inclusion evidence imply a linear correlation between their burial depth and homogenization temperatures, which closely resemble the temperature of generated hydrocarbon. Compared with finely crystalline dolomite, precipitation of coarsely crystalline dolomite was more affected by restricted basinal fluids. In addition, there is a trend toward a more negative δ18O value, higher salinity, higher Fe and Mn concentrations, REE-rich. Two periods of hydrothermal fluids are identified, as the exceptionally high temperatures as opposed to the temperatures of burial history, in addition to the presence of high salinity fluid inclusions. The early hydrothermal fluid flow event was characterized by hot magnesium- and silicon-rich fluids, as demonstrated by the recrystallized matrix dolomite that is intimately associated with flint, opal, and microcrystalline quartz in intergranular or intercrystalline pores. This event was likely the result of a seafloor hydrothermal chimney eruption during Episode I of the Tongwan Movement （536.3-5.5 Ma）. In contrast, later hydrothermal fluids, which caused precipitation of saddle dolomite, were characterized by high salinity （15-16.05wt% NaCI equivalent） and homogenization temperatures （250 to 265℃）, δ18O values that were more enriched, and REE signatures. Geochemical data and the paragenetic sequence indicate that this hydrothermal fluid was related to extensive Permian large igneous province activity （360-280 Ma）. This study demonstrates the presence of complicated dolomitization processes occurring during various paleoclimates, tectonic cycles, and basinal fluids flow; results are a useful reference for these dolomitized Precambrian carbonates reservoirs.
文摘对四川盆地东北部巴中地区和西部雅安地区早白垩世红层分别采集9块手标本,进行了详细的古地磁学研究.系统退磁获得两地的特征剩磁,其中巴中地区平均方向为,倾斜校正之前:D_g/I_g=25.3°/19.0°,k=18.6,α_(95)=8.8°;倾斜校正之后:D_s/I_s=25.8°/18.9°,k=24.3,α_(95)=7.6°.雅安地区平均方向为,倾斜校正之前:D_g/I_g=24.5°/45.0°,k=15.7,α_(95)=9.0°;倾斜校正之后:D_s/I_s=356.7°/35.6°,k=28.5,α_(95)=6.6°.磁化率各向异性实验结果显示两地均未受到显著的构造应力影响.等温剩磁各向异性(AIR)实验结果,巴中地区IRMz/IRMLx平均值为0.8194,表明18%的压实率;雅安地区IRMz/IRMx平均值为0.8909,表明11%的压实率,计算得到巴中和雅安地区校正后的磁倾角分别为22.7°和38.8°.根据等温剩磁各向异性(AIR)实验和Tauxe and Kent(2004)提出的EI校正法得到的结果表明,四川盆地早白垩世陆相碎屑岩层中存在沉积压实作用造成的磁倾角偏低现象,而且川东北巴中地区的偏低程度强于川西雅安地区.
