In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups c...In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mo- bility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%, respectively, which is better than that of the reference compound （13.18%）. Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD （16.87%）.展开更多
The hole reaming and side cutting characteristics of offset one-cone bit and conventional one- cone bit were investigated on simulated drilling experimental equipment. The borehole diameter was a little larger than th...The hole reaming and side cutting characteristics of offset one-cone bit and conventional one- cone bit were investigated on simulated drilling experimental equipment. The borehole diameter was a little larger than the bit diameter due to side force. However, the reaming effect was not very apparent, whether drilling with an offset or conventional one-cone bit. The side cutting displacement increased gradually with increasing depth of drilling and side force. The side cutting displacement of offset onecone bits was larger than that of conventional ones under the same conditions of weight-on-bit （WOB）, rotary speed, side force and borehole depth.展开更多
基金supported by the National Basic Research Program of China (No. 2015CB932200)the CAS-Iranian Vice Presidency for Science and Technology Joint Research Project (No. 116134KYSB20160130)+2 种基金the Natural Science Foundation of Anhui Province (No. 1508085SMF224)the National Natural Science Foundation of China (No. 51474201)the External Cooperation Program of BIC, Chinese Academy of Sciences (No. GJHZ1607)
文摘In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mo- bility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%, respectively, which is better than that of the reference compound （13.18%）. Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD （16.87%）.
文摘The hole reaming and side cutting characteristics of offset one-cone bit and conventional one- cone bit were investigated on simulated drilling experimental equipment. The borehole diameter was a little larger than the bit diameter due to side force. However, the reaming effect was not very apparent, whether drilling with an offset or conventional one-cone bit. The side cutting displacement increased gradually with increasing depth of drilling and side force. The side cutting displacement of offset onecone bits was larger than that of conventional ones under the same conditions of weight-on-bit （WOB）, rotary speed, side force and borehole depth.
