We have investigated the stability, geometrical structure, electronic properties and vibrational spectra of different isomers of hydroxylate (5, 0) zigzag carbon nanotube (CNT) with 60 C atoms and 10 hydrogen (C60H10)...We have investigated the stability, geometrical structure, electronic properties and vibrational spectra of different isomers of hydroxylate (5, 0) zigzag carbon nanotube (CNT) with 60 C atoms and 10 hydrogen (C60H10) by using all-electron density-functional-theory (DFT) methods. Stable arrangements of these molecules were found by means of full geometry optimizations using B3LYP/6-31G(d) level of theory. From symmetrical point of view, four isomers of HO-C60H10 are possible when -OH bonds to the surface. We observed that the molecular properties strongly depend on the position of bonded hydroxyl group on the surface of CNT.展开更多
The exposed and transformed groups of fibrous brucite,wollastonite,chrysotile asbestos,sepiolite,palygorskite,clinoptilolite,crocidolite and diatomaceous earth mineral materials are analyzed by IR spectra after acid a...The exposed and transformed groups of fibrous brucite,wollastonite,chrysotile asbestos,sepiolite,palygorskite,clinoptilolite,crocidolite and diatomaceous earth mineral materials are analyzed by IR spectra after acid and alikali etching,strong mechanical and polarity molecular interaction.The results show the active sites concentrate on the ends in stick mineral materials and on the defect or hole edge in pipe mineral materials.The inside active site of mineral materials plays a main role in small molecular substance.The shape of minerals influence their distribution and density of active site.The strong mechanical impulsion and weak chemical force change the active site feature of minerals,the powder process enables minerals exposed more surface group and more combined types.The surface processing with the small polarity molecular or the brand of middle molecular may produce ionation and new coordinate bond,and change the active properties and level of original mineral materials.展开更多
Based on the plot data from the investigation and the theory of forest ecology and ecological system,the site classification of the eastern forest region of Daxing’an Mountains was made by mean of mathematical method...Based on the plot data from the investigation and the theory of forest ecology and ecological system,the site classification of the eastern forest region of Daxing’an Mountains was made by mean of mathematical method. The main factors were slope, thickness of soil layer, slope position and slope aspect. Grades of slope were used as the division standard for site type group. The slope aspect, slope position and thickness of soil layer were used as the division standards for site type. Altogether 7 site type groups and 15 main site types were determined the region. It provided reliable fundamental basis for the reasonable management and planting design in the area.展开更多
The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR unde...The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR under acid and alkali etched, strong mechanical and polarized molecular interaction. The results show that the active site focuses on ends in stick dusts and on defects or hole edges in pipe dusts. The inside active sites of dusts play the main role in small molecular substance. The shape of dusts affects their distributions and densities of active sites. The strong mechanical and weak chemical force make the active site feature of minerals change, the powder process brings about more naked surface groups and more combined types. The dust activity relates to the type, contribution, and naked level of surface groups. The studied dust surface groups are mainly as follows: OH?, Mg(OH)?, Si-O-Si, Ca-O-Si, -Mg-OH2,-Al(Si)-OH, -Mg(Ca)-OH2, Ca-O,-Si???OH, Mg(Fe)-OH. Due to the difference of surface composition and structure, the minerals have a large disparity on activity and character of surface groups. The one side surface group of chrysotile layer is the same as fibrous brucite and stripped layer with more naked group. The fibrous sepiolite and palygorskite surface OH? similar to crocidolite is naked with their surface structural defects and cleavage. The more development of mineral defects, the higher of OH? (H2O+) content, the main H2O+ of clinoptilolite is partly transformed into H+, NH 4 + or OH?. The acid etched process may change OH? concentration, distribution and increase the defects and porosity of mineral fiber surface. The alkali etched has no effect on Si-O, Si-OH etc. and destroyed Al-O, Al-OH? acid site of sepiolite, palygorskite and clinoptilolite. Some surface groups of remnant differ from original dusts. The surface process of small polarized molecular or middle moleular’s branch may produce ionation and new coordinate bond, and change the active properties and level of original dusts, such as the porous minerals producing展开更多
Here we provide an example of simultaneous polyandry based on genetic evidence in Feirana kangxianensis. This stream-dwelling species occurs only in Kangxian County, southern Gansu Province, where it is sympatric with...Here we provide an example of simultaneous polyandry based on genetic evidence in Feirana kangxianensis. This stream-dwelling species occurs only in Kangxian County, southern Gansu Province, where it is sympatric with its sibling species E quadranus. During the breeding season the sex ratio of E kangxianensis was marginally female- biased （44~：59~） and the encounter rate in a relatively pristine habitat was significantly higher than that in heavily quarried habitats （9.6 ± 4.8 indiv./km vs. 3.2 ± 2.5 indiv./km）. Three egg masses containing an average of 698 eggs were deposited on the underside of one or two adjacent flat rocks, 6.0-10.0 cm under the water surface and 1.0-3.5 cm above the streambed. Using Bayesian sibship clustering of nine polymorphic microsatellite genotypes, two females were detected as group-spawning in one oviposition site, with three males fertilizing each female＇s eggs simultaneously. We also discuss the conservation requirements of this range-restricted species and the evolutionary implication of its unusual reproductive strategy.展开更多
The Bose-Hubbard model with an effective off-site three-body tunneling,characterized by jumps towards one another,between one atom on a site and a pair atoms on the neighborhood site,is studied systematically on a one...The Bose-Hubbard model with an effective off-site three-body tunneling,characterized by jumps towards one another,between one atom on a site and a pair atoms on the neighborhood site,is studied systematically on a one-dimensional（1D） lattice,by using the density matrix renormalization group method.The off-site trimer superfluid,condensing at momentum k = 0,emerges in the softcore Bose-Hubbard model but it disappears in the hardcore Bose-Hubbard model.Our results numerically verify that the off-site trimer superfluid phase derived in the momentum space from[Phys.Rev.A81,011601（R）（2010）]is stable in the thermodynamic limit.The off-site trimer superfluid phase,the partially off-site trimer superfluid phase and the Mott insulator phase are found,as well as interesting phase transitions,such as the continuous or first-order phase transition from the trimer superfluid phase to the Mott insulator phase.Our results are helpful in realizing this novel off-site trimer superfluid phase by cold atom experiments.展开更多
良渚遗址群是距杭州市西北18 km的良渚镇和瓶窑镇毗邻地带间许多遗址的总称,代表了良渚文化发展的最高成就,是良渚文化的中心。根据在2007年发现的良渚古城墙外侧开挖的良渚北剖面、良渚西剖面沉积样品的粒度分析、孢粉分析数据,以及综...良渚遗址群是距杭州市西北18 km的良渚镇和瓶窑镇毗邻地带间许多遗址的总称,代表了良渚文化发展的最高成就,是良渚文化的中心。根据在2007年发现的良渚古城墙外侧开挖的良渚北剖面、良渚西剖面沉积样品的粒度分析、孢粉分析数据,以及综合区域内多个剖面地层对比,恢复了该地区全新世环境的演变过程。研究表明,全新世良渚遗址群内环境演变可以分为4个阶段：（1）7 ka BP以前的平原区多为静水沉积环境,水域范围较大,水位较高,且水深逐渐增加,不太适合人类活动;（2）7~5.1 ka BP区域水位有所下降,水域面积缩小,部分较高的地区露出水面,较少接受沉积,一些低洼地区接受了沼泽相或河流泛滥相沉积,一些人类活动遗址开始出现;（3）5.1~4.3 ka BP水位较低,文化快速发展,平原上多见良渚文化遗迹,一些遗址堆积了较厚的良渚文化层;（4）4.3 ka BP以后水位再次升高,良渚文化衰落,多数良渚文化层之上都覆盖一套黄色或黄褐色泛滥相沉积。该地区全新世时期的水位波动与人类文化兴衰演化历史相关的现象表明,良渚遗址区域内地貌特征及水文环境的变化是影响良渚文化兴衰演化的重要原因之一。展开更多
文摘We have investigated the stability, geometrical structure, electronic properties and vibrational spectra of different isomers of hydroxylate (5, 0) zigzag carbon nanotube (CNT) with 60 C atoms and 10 hydrogen (C60H10) by using all-electron density-functional-theory (DFT) methods. Stable arrangements of these molecules were found by means of full geometry optimizations using B3LYP/6-31G(d) level of theory. From symmetrical point of view, four isomers of HO-C60H10 are possible when -OH bonds to the surface. We observed that the molecular properties strongly depend on the position of bonded hydroxyl group on the surface of CNT.
基金FundedbytheNationalNaturalScienceFoundationofChi na (No .4 0 0 72 0 2 0 )andtheTRAPforOutstandingYoungTeachersinHigherEducationInstitutionsofMOE China
文摘The exposed and transformed groups of fibrous brucite,wollastonite,chrysotile asbestos,sepiolite,palygorskite,clinoptilolite,crocidolite and diatomaceous earth mineral materials are analyzed by IR spectra after acid and alikali etching,strong mechanical and polarity molecular interaction.The results show the active sites concentrate on the ends in stick mineral materials and on the defect or hole edge in pipe mineral materials.The inside active site of mineral materials plays a main role in small molecular substance.The shape of minerals influence their distribution and density of active site.The strong mechanical impulsion and weak chemical force change the active site feature of minerals,the powder process enables minerals exposed more surface group and more combined types.The surface processing with the small polarity molecular or the brand of middle molecular may produce ionation and new coordinate bond,and change the active properties and level of original mineral materials.
文摘Based on the plot data from the investigation and the theory of forest ecology and ecological system,the site classification of the eastern forest region of Daxing’an Mountains was made by mean of mathematical method. The main factors were slope, thickness of soil layer, slope position and slope aspect. Grades of slope were used as the division standard for site type group. The slope aspect, slope position and thickness of soil layer were used as the division standards for site type. Altogether 7 site type groups and 15 main site types were determined the region. It provided reliable fundamental basis for the reasonable management and planting design in the area.
文摘The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR under acid and alkali etched, strong mechanical and polarized molecular interaction. The results show that the active site focuses on ends in stick dusts and on defects or hole edges in pipe dusts. The inside active sites of dusts play the main role in small molecular substance. The shape of dusts affects their distributions and densities of active sites. The strong mechanical and weak chemical force make the active site feature of minerals change, the powder process brings about more naked surface groups and more combined types. The dust activity relates to the type, contribution, and naked level of surface groups. The studied dust surface groups are mainly as follows: OH?, Mg(OH)?, Si-O-Si, Ca-O-Si, -Mg-OH2,-Al(Si)-OH, -Mg(Ca)-OH2, Ca-O,-Si???OH, Mg(Fe)-OH. Due to the difference of surface composition and structure, the minerals have a large disparity on activity and character of surface groups. The one side surface group of chrysotile layer is the same as fibrous brucite and stripped layer with more naked group. The fibrous sepiolite and palygorskite surface OH? similar to crocidolite is naked with their surface structural defects and cleavage. The more development of mineral defects, the higher of OH? (H2O+) content, the main H2O+ of clinoptilolite is partly transformed into H+, NH 4 + or OH?. The acid etched process may change OH? concentration, distribution and increase the defects and porosity of mineral fiber surface. The alkali etched has no effect on Si-O, Si-OH etc. and destroyed Al-O, Al-OH? acid site of sepiolite, palygorskite and clinoptilolite. Some surface groups of remnant differ from original dusts. The surface process of small polarized molecular or middle moleular’s branch may produce ionation and new coordinate bond, and change the active properties and level of original dusts, such as the porous minerals producing
基金supported by the National Natural Science Foundation of China (31471964, 31200411)the Chinese Academy of Sciences (Y3C3011100)
文摘Here we provide an example of simultaneous polyandry based on genetic evidence in Feirana kangxianensis. This stream-dwelling species occurs only in Kangxian County, southern Gansu Province, where it is sympatric with its sibling species E quadranus. During the breeding season the sex ratio of E kangxianensis was marginally female- biased （44~：59~） and the encounter rate in a relatively pristine habitat was significantly higher than that in heavily quarried habitats （9.6 ± 4.8 indiv./km vs. 3.2 ± 2.5 indiv./km）. Three egg masses containing an average of 698 eggs were deposited on the underside of one or two adjacent flat rocks, 6.0-10.0 cm under the water surface and 1.0-3.5 cm above the streambed. Using Bayesian sibship clustering of nine polymorphic microsatellite genotypes, two females were detected as group-spawning in one oviposition site, with three males fertilizing each female＇s eggs simultaneously. We also discuss the conservation requirements of this range-restricted species and the evolutionary implication of its unusual reproductive strategy.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11305113)the Project GDW201400042 for the“High End Foreign Experts Program”
文摘The Bose-Hubbard model with an effective off-site three-body tunneling,characterized by jumps towards one another,between one atom on a site and a pair atoms on the neighborhood site,is studied systematically on a one-dimensional（1D） lattice,by using the density matrix renormalization group method.The off-site trimer superfluid,condensing at momentum k = 0,emerges in the softcore Bose-Hubbard model but it disappears in the hardcore Bose-Hubbard model.Our results numerically verify that the off-site trimer superfluid phase derived in the momentum space from[Phys.Rev.A81,011601（R）（2010）]is stable in the thermodynamic limit.The off-site trimer superfluid phase,the partially off-site trimer superfluid phase and the Mott insulator phase are found,as well as interesting phase transitions,such as the continuous or first-order phase transition from the trimer superfluid phase to the Mott insulator phase.Our results are helpful in realizing this novel off-site trimer superfluid phase by cold atom experiments.
文摘良渚遗址群是距杭州市西北18 km的良渚镇和瓶窑镇毗邻地带间许多遗址的总称,代表了良渚文化发展的最高成就,是良渚文化的中心。根据在2007年发现的良渚古城墙外侧开挖的良渚北剖面、良渚西剖面沉积样品的粒度分析、孢粉分析数据,以及综合区域内多个剖面地层对比,恢复了该地区全新世环境的演变过程。研究表明,全新世良渚遗址群内环境演变可以分为4个阶段：（1）7 ka BP以前的平原区多为静水沉积环境,水域范围较大,水位较高,且水深逐渐增加,不太适合人类活动;（2）7~5.1 ka BP区域水位有所下降,水域面积缩小,部分较高的地区露出水面,较少接受沉积,一些低洼地区接受了沼泽相或河流泛滥相沉积,一些人类活动遗址开始出现;（3）5.1~4.3 ka BP水位较低,文化快速发展,平原上多见良渚文化遗迹,一些遗址堆积了较厚的良渚文化层;（4）4.3 ka BP以后水位再次升高,良渚文化衰落,多数良渚文化层之上都覆盖一套黄色或黄褐色泛滥相沉积。该地区全新世时期的水位波动与人类文化兴衰演化历史相关的现象表明,良渚遗址区域内地貌特征及水文环境的变化是影响良渚文化兴衰演化的重要原因之一。
