Novel Hybrid X GBoost Model to Forecast Soil Shear Strength Based on Some Soil Index Tests

When building geotechnical constructions like retaining walls and dams is of interest,one of the most important factors to consider is the soil’s shear strength parameters.This study makes an effort to propose a novel predictive model of shear strength.The study implements an extreme gradient boosting(XGBoost)technique coupled with a powerful optimization algorithm,the salp swarm algorithm(SSA),to predict the shear strength of various soils.To do this,a database consisting of 152 sets of data is prepared where the shear strength(τ)of the soil is considered as the model output and some soil index tests(e.g.,dry unit weight,water content,and plasticity index)are set as model inputs.Themodel is designed and tuned using both effective parameters of XGBoost and SSA,and themost accuratemodel is introduced in this study.Thepredictionperformanceof theSSA-XGBoostmodel is assessedbased on the coefficient of determination(R2)and variance account for(VAF).Overall,the obtained values of R^(2) and VAF(0.977 and 0.849)and(97.714%and 84.936%)for training and testing sets,respectively,confirm the workability of the developed model in forecasting the soil shear strength.To investigate the model generalization,the prediction performance of the model is tested for another 30 sets of data(validation data).The validation results(e.g.,R^(2) of 0.805)suggest the workability of the proposed model.Overall,findings suggest that when the shear strength of the soil cannot be determined directly,the proposed hybrid XGBoost-SSA model can be utilized to assess this parameter.

Antecedent Precipitation Index to Estimate Soil Moisture and Correlate as a Triggering Process in the Occurrence of Landslides

Landslides are highly dangerous phenomena that occur in different parts of the world and pose significant threats to human populations. Intense rainfall events are the main triggering process for landslides in urbanized slope regions, especially those considered high-risk areas. Various other factors contribute to the process;thus, it is essential to analyze the causes of such incidents in all possible ways. Soil moisture plays a critical role in the Earth’s surface-atmosphere interaction systems;hence, measurements and their estimations are crucial for understanding all processes involved in the water balance, especially those related to landslides. Soil moisture can be estimated from in-situ measurements using different sensors and techniques, satellite remote sensing, hydrological modeling, and indicators to index moisture conditions. Antecedent soil moisture can significantly impact runoff for the same rainfall event in a watershed. The Antecedent Precipitation Index (API) or “retained rainfall,” along with the antecedent moisture condition from the Natural Resources Conservation Service, is generally applied to estimate runoff in watersheds where data is limited or unavailable. This work aims to explore API in estimating soil moisture and establish thresholds based on landslide occurrences. The estimated soil moisture will be compared and calibrated using measurements obtained through multisensor capacitance probes installed in a high-risk area located in the mountainous region of Campos do Jordão municipality, São Paulo, Brazil. The API used in the calculation has been modified, where the recession coefficient depends on air temperature variability as well as the climatological mean temperature, which can be considered as losses in the water balance due to evapotranspiration. Once the API is calibrated, it will be used to extrapolate to the entire watershed and consequently estimate soil moisture. By utilizing recorded mass movements and comparing them with API and soil moisture, it will be possible to determine thresholds, thus enabling anticipation of landslide occurrences.

Development of Empirical Models for the Estimation of CBR Value of Soil from Their Index Properties: A Case Study of the Ogbia-Nembe Road in Niger Delta Region of Nigeria

This study developed empirical-mathematical models to predict the California Bearing Ratio (CBR) using soil index properties in Ogbia-Nembe road in the Niger Delta region of Nigeria. The determination of CBR of soil is a laborious operation that requires a longer time and materials leading to increased cost and schedule;this can be reduced by adopting an empirical-mathematical model that can predict the CBR using other simpler soil index properties such as Plastic Limit (PL), the Liquid Limit (LL), the Plasticity Index (PI) and the Moisture Content (MC), which are less laborious and take lesser time to obtain. Thirteen models were developed to understand the relationship between these soil index properties: the independent variable and the California Bearing Ratio (CBR): the dependent variable;Six linear, Six quadratic and One multiple linear regression models were developed for this relationship. Analysis of variance (ANOVA) on the thirteen models showed that the Optimum Moisture Content (OMC) and the Maximum Dry Density (MDD) are better independent variables for the prediction of the CBR value of Ogbia-Nembe soil generating a quadratic model and a multiple linear regression model having a better coefficient of determination R2 = 0.96 and 0.94 respectively, mean square error (MSE) of 0.74 and 1.152 respectively with Root mean square errors of 0.861 and 1.073 accordingly. These models were used to predict the CBR of the soil. The CBR values predicted by the model were further compared with those of the actual experimental test and found to be relatively consistent with minimal variance. This establishes that CBR of any soil can be predicted from the Index Property of the soil and this is more economical and takes lesser time and can be universally adopted for soil investigation.

Changes in Organic Carbon Index of Grey Desert Soil in Northwest China After Long-Term Fertilization

Soil organic carbon （SOC）, soil microbial biomass carbon （SMBC） and SMBC quotient （SMBC/SOC, qSMBC） are key indexes of soil biological fertility because of the relationship to soil nutrition supply capacity. Yet it remains unknown how these three indexes change, which limits our understanding about how soil respond to different fertilization practices. Based on a 22-yr （1990-2011） long-term fertilization experiment in northwest China, we investigated the dynamics of SMBC and qSMBC during the growing period of winter wheat, the relationships between the SMBC, qSMBC, soil organic carbon （SOC） concentrations, the carbon input and grain yield of wheat as well. Fertilization treatments were 1） nonfertilization （control）; 2） chemical nitrogen plus phosphate plus potassium （NPK）; 3） NPK plus animal manure （NPKM）; 4） double NPKM （hNPKM） and 5） NPK plus straw （NPKS）. Results showed that the SMBC and qSMBC were significantly different among returning, jointing, flowering and harvest stages of wheat under long-term fertilization. And the largest values were observed in the flowering stage. Values for SMBC and qSMBC ranged from 37.5 to 106.0 mg kg1 and 0.41 to 0.61%, respectively. The mean value rank of SMBC during the whole growing period of wheat was hNPKM〉NPK_M〉NPKS〉CK〉NPK. But there were no statistically significant differences between hNPKM and NPKM, or between CK and NPK. The order for qSMBC was NPKS〉NPKM〉CK〉hNPKM〉NPK. These results indicated that NPKS significantly increased the ratio of SMBC to SOC, i.e., qSMBC, compared with NPK fertilizer or other two NPKM fertilizations. Significant linear relationships were observed between the annual carbon input and SOC （P〈0.01） or SMBC （P〈0.05）, and between the relative grain yield of wheat and the SOC content as well （P〈0.05）. But the qSMBC was not correlated with the annual carbon input. It is thus obvious that the combination of manure, straw with mineral fertilizer may be benefit to increase SOC and improve soil quality than using only mineral fertilizer.

Using geoaccumulation index to study source profiles of soil dust in China

Source apportionment studies of TSP （atmospheric particulate matter with aerodynamic diameters ≤ 100 μm） and PM10 （atmospheric particulate matter with aerodynamic diameters ≤ 10 μm） have revealed that soil dust is an important source of these particulates in China. In this study, the contamination of soil dust was assessed through the use of a geoaccumulation index （Igeo）. The mass concentration profiles of 17 elements （Na, Mg, Al, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Br, Ba, and Pb） were established for urban soil dusts. Geochemical compositions of soils from 15 cities were used to represent background urban soil compositions. The results of this study indicated that a number of cities are severely polluted by particulates containing Ca, Cr, Ni, and Cu in both size fractions （TSP and PM10）. Contamination with Zn, Pb, Co, and Br was moderate to severe （Igeo 〉 2）. The Al and Fe concentrations were not high enough for them to be considered contaminants.

A soil quality index for evaluation of degradation under land use and soil erosion categories in a small mountainous catchment, Iran

Soil erosion and land use type have long been viewed as being particularly important drivers of soil degradation.The objectives of this study,therefore,were to select a new soil quality index(SQI)which varies significantly with land use/soil erosion,and to evaluate the new SQI using expert opinion.In total,18 soil physical,chemical,and biochemical properties(indicators)were measured on 56 soil samples collected from four land use/soil erosion categories(rangeland/surface erosion,rangeland/subsurface erosion,cultivated land/surface erosion and dry-farming land/surface erosion).Principal component and classification analysis(PCCA)identified five PCs that explained 77.7%of the variation in soil properties with the biochemical PC varying significantly with land use/soil erosion.General discriminant analysis(GDA)selected urease and clay as the most sensitive properties distinguishing the land use/soil erosion categories.The GDA canonical scores for the new SQI were significantly correlated with expert opinion soil surface summed scores(for soil movement,surface litter,pedestalling,rills and flow pattern)derived using the U.S.Department of the Interior Bureau of Land Management(BLM)method.A forward stepwise general regression model revealed that the new SQI values were explained by soil movement,surface litter,and the summed values of the soil surface factors.Overall,this study confirmed that soil quality in the study area in Iran is controlled by land use and corresponding soil erosion.

Vegetation/Soil Synthesis Water Index Using MODIS Data

In consideration of the spectral character of MODIS (Moderate Resolution Imaging Spectroradiometer) dataand the reflective spectrum of vegetation and soil, NDVI (Normalized Difference Vegetation Index) and NDWI (Nor-malized Difference Water Index) are deduced using one visible band (0.66μm) and two near-infrared bands (0.86μm,1.24 μm). Vegetation canopy temperature is derived using two thermal infrared bands (8.6 μm and 11μm). Then thevegetation/soil synthesis water index (VSWI) is acquired through analyzing the coupling character of three indexeswhich can reflect the water condition of vegetation. Finally, the synthesis index is verified by equivalent water contentof a single leaf. The matching results show that the synthesis index is directly proportional to the modeled data,which means that the vegetation water content can be reflected using the synthesis index effectively.

Food-Security Indexes Related to Combined Pollution of Chromium and Phenol in Soil-Rice Systems

The pot-culture method combined with chemical and statistical analyses was used to get basic data for determination of the food-security indexes related to combined pollution of Cr and phenol in soil-rice systems.Regression analyses according to the experimental result indicated that the critical concentrations of Cr andphenol in brown rice were 0.37 and 0.33 mg kg-1, respectively, under the condition of Cr-phenol combined pollution.

Utilization of Wood Biomass for Organic Soil Based on the Soil Fertility Index (SOFIX)

Possibility of wood biomass for preparing organic soil was examined to construct reproducible and stable organic standard soil. Seven organic soils were constructed from base soils and additive materials based on the recommended values of the soil fertility index (SOFIX) (total carbon ≥ 25,000 mg/kg, total nitrogen ≥ 1500 mg/kg, total phosphorus ≥ 1100, and total potassium of 2500 to 10,000 mg/kg). Base soils were prepared from two types of wood biomass (big- and small-sized wood chips) at 50%, 60%, and 70% (v/v) and other organic materials such as peat moss, black soil, and mountain soil. Additive materials (soybean meal, oil cake, cow manure, and bone meal) were amended into all organic soils at the same amount. Incubation experiment showed that bacterial biomass in all organic soil was greater than 6 × 108 cells/g-soil after addition of 30% of water content for 1 week. In addition, polymerase chain reaction denaturing gradient gel electrophoresis (PCR-DGGE) analysis resulted in a stable bacterial diversity of the organic soil prepared from the small size wood chip at 70%. Chemical properties of all organic soils were within the recommended values of SOFIX. The plant cultivation experiment showed that fresh Brassica rapa var. peruviridis weights in the organic soils with 50%, 60%, and 70% of small-sized wood chip were 5%, 16%, and 27% higher than that of the chemical fertilizer-amended soil. The organic soil with 70% of small wood chip was the best in the seven organic soils in this study.

Modelling the Soil Loss in the Watershed of the Chaddad Wadi in Terms of Both Rockiness and Soil Slaking Indexes

Currently we are at a phase where morphogenesis is gaining more prominence and dimension regarding the pedogenesis. The numerous multidisciplinary studies on the soil showed that the erosive action as well as the various problems that result from it, bring out a very serious state of soil degradation in the semi-arid field [1]-[9]. Several attempts have established to set empirical and experimental methods for a quantitative estimation of soil loss caused by diffuse erosion. In this perspective, this research intends to track soil losses in the watershed of the Chaddad wadi, the average-flowing stream of the Nebhana wadi belonging to the lower semi-arid field. The main stream and its tributaries drain an area of 26.5 km2 from the eastern slopes of Ejhaf mountain (517 m) and Fartout mountain (476 m), as well as the southern slope of Ediour mountain (405 m). The dividing line of the waters with the Khalfallah wadi and Bel Assoued wadi is caused by rows of hills with an altitude ranging between 220 m and 306 m such as the hills of Sidi Salah and those of Es-Souida and Ain Fres. The Wischmeier Equation will be improved by two corrective parameters: the rockiness on the one hand and the soil slaking index on the other, aiming to develop and optimize the potential of this empirical model. This application allowed overcoming some of the limitations that came with the Wischmeier equation, which is primarily designed for an application within different physical conditions on the scale of a land plot. This research is an opportunity to make a detailed contribution to the potential sensitivity of the watershed to water erosion. A good demarcation of the physical anthropogenic framework of the erosive action will provide substantial support in terms of soil protection and the stabilization of watersheds emitting sediments.

Combined Pollution and Pollution Index of Heavy Metals in Red Soil

A field experiment was conducted to study the effects of Pb, Cd, Cu, Zn and As coexisting in red soilon growth of rice (Oryza sativa L.), mung bean (Vigna rabiata (Linn.) Wilczek), alfalfa (Medicago sativaL.), slash pine (Pinus elliottii Engelm.) and aspen (Populus L.). Results showed that rice, mung bean andalfalfa were significantly innuenced by combined pollution of the heavy metals. The contents of Pb, cd andAs in rice grains greatly exceeded the National Standards for Food Hygiene of China. Heavy metals at ahigh concentration seriously retarded growth of mung bean and alfalfa, but not so obviously with slash pineand aspen. The composite index is suggested for evaluating the relativity of combined pollution witll heavymetals in soil.

Soil quality index as a tool for Scots pine(Pinus sylvestris) monoculture conversion planning on afforested,reclaimed mine land

In Central Europe, a large portion of post-mining sites were afforested with Scots pine, which is characterized by good adaptability and a tolerance for poor habitat at the beginning of forest ecosystem development. Conversion of monoculture on mine sites into more biodi- verse mixed hardwood forests, especially on more fertile deposits, can be an emerging need in this part of Europe in next decades. The ability to classify the forests at these post-mining sites will facilitate proper species selection as well as the management and formation of the developed ecosystem＇s stability. This work describes the guidelines that can be followed to assess reclaimed mine soil （RMS） quality, using the mine soil quality index （MSQI） and a classification of developed forest sites as a basis of tree-stand species selection and conversion of pine monocul- tures. The research was conducted on four post-mining facilities （lignite, hard coal, sulphur, and sand pit mining areas） on different RMS sub- strates dominant in Central Europe. Soil quality assessment takes into account the following features of the soil： texture soil nutrients （Ca, Mg, K, Na, P）; acidity （pH KC1）; and Corg-to-Nt ratio in the initial organic horizon. An analysis was conducted of classification systems using the MSQI validation correlation （at p =0.05） with vegetation features af- fected by succession： aboveground biomass of forest floor and ecological indicators of vascular plants （calculated on the basis of EUenberg＇s （2009） system）. Eventually, in the analysed data set, the MSQI ranged from 0.270 for soils on quaternary sands to 0.720 for a mix of quaternary loamy sands with neogene clays. Potential forest habitat types and the role of the pine in the next generation of tree stands on different RMS parent rock substrate were proposed.

Assessment of Soil Water Content in Field with Antecedent Precipitation Index and Groundwater Depth in the Yangtze River Estuary

To better understand soil moisture dynamics in the Yangtze River Estuary （YRE） and predict its variation in a simple way, a field monitoring experiment was carried out along the north branch of the Yangtze River, where seawater intrusion was strong and salt-water variation is one of the limiting factors of local agriculture. In present paper, relation between antecedent precipitation index （API） and soil water content is studied, and effects of groundwater depth on soil water content was analyzed. A relatively accurate prediction result of soil water content was reached using a neural network model. The impact analysis result showed that the variation of the API was consistent with soil water content and it displayed significant correlations with soil water content in both 20 and 50 cm soil layer, and higher correlation was observed in the layer of 20 cm. Groundwater impact analysis suggested that soil moisture was affected by the depth of groundwater, and was affected more greatly by groundwater at depth of 50 cm than that at 20 cm layer. By introducing API, groundwater depth and temperature together, a BP artificial network model was established to predict soil water content and an acceptable agreement was achieved. The model can be used for supplementing monitoring data of soil water content and predicting soil water content in shallow groundwater areas, and can provide favorable support for the research of water and salt transport in estuary area.

Characterization of Orchard Fields Based on Soil Fertility Index (SOFIX)

Soil samples from 139 agricultural orchard fields (apple, grape, tea, and others) were analyzed using the soil fertility index. From these samples, an orchard field database was constructed and the soil properties between orchard, upland, and paddy fields were compared. The average value of bacterial biomass in the orchard fields was 7.4 × 108 cells/g-soil, ranging from not detected (lower than 6.6 × 106 cells/g-soil) to 7.7 × 109 cells/g-soil. The average values of total carbon (TC), total nitrogen (TN), total phosphorus (TP), and total potassium (TK), were 24,000 mg/kg (2670 to 128,100 mg/kg), 1460 mg/kg (133 to 6400 mg/kg), 1030 mg/kg (142 to 5362 mg/kg), and 5370 mg/kg (1214 to 18,155 mg/kg), respectively. The C/N and C/P ratios were 19 (3 to 85) and 27 (2 to 101), respectively. Soil properties of the orchard fields were compared with those of the upland and the paddy fields. The average value of bacterial biomass in the orchard fields was almost the same as that in the upland fields (8.0 × 108 cells/g-soil), but the number was lower than that in the paddy fields (12.9 × 108 cells/g-soil). The average values of TC and TN in the orchard fields fell between those in the upland fields (TC: 33,120 mg/kg, TN: 2010 mg/kg) and the paddy fields (TC: 15,420 mg/kg, TN: 1080 mg/kg). The relationship between the bacterial biomass and TC in the orchard fields resembled that in the upland fields. A suitable soil condition for the orchard fields was determined as TC: ≥25,000 mg/kg, TN: ≥1500 mg/kg, TP: ≥900 mg/kg and TK: 2500 - 10,000 mg/kg. These recommended values will be effective for the improvement of the soil quality in the orchard fields by enhancing the number and activities of microorganisms.

Robust Soil Quality Index for Tropical Soils Influenced by Agricultural Activities

The knowledge of the soil quality plays a vital role in the agricultural sector. Despite its importance, there is scarce scientific information concerning this regard. The objective of this research is to develop a methodology to identify and select the most appropriate indicators of Soil Quality Index (SQI) in a region with high agricultural activity. For its conformation, a descriptive statistical analysis and a Pearson correlation matrix were performed and the indicators that showed greater variation were identified using a Principal Components Analysis (PCA). A sensitivity analysis was carried out and the most sensible soil indicators of?SQI?were identified. This statistical procedure was also used to specify the weights of the indicators in?SQI. The variables resulting from the multiparametric statistical analysis were pH, organic matter, sodium, calcium, iron, zinc, cation exchange capacity and electrical conductivity. The robustness of the?SQI?obtained in this study was demonstrated through simulations carried out by the numerical optimization through simplex method. The Soil Quality Index range obtained (0.54 - 0.75) locates Culiacan Valley soils as moderate/high quality.

Drivers of the Chemical Quality of Market Gardening Soils in the Urban and Peri-Urban Environment of Bobo-Dioulasso (Burkina Faso): Impact of Fertilizers Sources and Sites Location

Urban and peri-urban agriculture plays a key role by providing many goods and services. In particular, it provides diversified food and employment for vulnerable groups (youth and women). However, it often involves negative externalities due to non-conventional soils fertility management practices. This study aimed to investigate the chemical quality of soils over six (06) sites of the market gardening area of Bobo-Dioulasso (Burkina Faso) as affected by fertilizers uses and sites location. Thirty (30) representative market gardening farms, located in urban, semi-urban and rural areas, were randomly selected from a baseline survey database. Within each farm, composite soil samples made up of 3 individual cores were taken over the 0 - 15 cm soil depth for determining soils carbon, total nitrogen, available phosphorus contents and pH-water. These data were normalized and summarized to compute a synthetic Soil Fertility Index (SFI). The data processing was focused on a Principal Component Analysis and an Ascendant Hierarchical Classification in order to make a typology of the vegetable farms. Fertilizers management effects on soils quality were compared through Variance Analysis (ANOVA) following a GLM procedure in Rstudio software. As main results, soils chemical parameters, except for available K, were affected by the location of the sites. Soils in urban farms are less acidic (on average pH = 6.9), while semi-urban and rural sites (Samadeni, Nakaguana) have more acidic soils. However, the latter site had the highest values of C and N. Moreover, the long-term application of organic matter sources results in improving of the chemical quality of the market garden soil. The SFI is positively correlated with the rate of applied organic fertilizers, and the cultivation duration. On the other hand, soil quality tends to decrease with the expansion of the area, due to a dilution effect of the organic fertilizer doses. All these results suggest that there is a real scope to reinforce the position of the market garden as an opportunity for recycling organic wastes and sequestration of carbon by promoting relevant fertilization packages that strongly rely on organic matters sources (Compost, Biochar, etc.).

Effects of Soil-Cement Stabilization on the Index Properties of Subgrades of Three Selected Roads in the Niger Delta Region of Nigeria

In this study, the impact of soil-cement stabilization on the index properties of the subgrade of roads was investigated. Efforts were on the means of improving the bearing capacity of the subgrade of a flexible pavement structure. Three selected roads (Ogbia-Nembe, section of the East-West Road and section of Port Harcourt-Aba Road) in the Niger Delta Region of Nigeria were examined to determine the effect of sand-cement stabilization on the compaction index property of their undisturbed subgrade and the optimal ratio of soil-cement on the expansive soils at which the California Bearing Ratio (CBR) is optimized. Disturbed soil samples were collected from twenty trial pits on each of the three study roads using a hand ulger and tested for their respective compaction index properties. It was discovered that their California Bearing Ratio (CBR) was very low. Some of the collected specimen materials were stabilized with varying percentages of soil-cement contents ranging from 6% - 14% in order to ascertain its effects on the compaction index properties of the sample soils. Results of the various stabilization test procedures show that: Stabilization of the soil using Soil-Cement Stabilization affected the Compaction Index properties of the soil and further improved the California Bearing Ratio (CBR). On the Ogbia-Nembe Road;Soil-Cement stabilization improved the CBR and is optimized at a 10% sand-cement ratio with optimum moisture content ranging from 6.2% - 14%, maximum dry density ranges from 1700 - 1780 kg/m3, yielding an average CBR of 42.7% for soaked samples. On the section of East-West Road from Eleme Junction to Etteh Junction;Soil-Cement stabilization improved the CBR and is optimized at a 14% sand-cement ratio with optimum moisture content ranging from 6.2% - 14.2%, maximum dry density ranges from 1660 - 1800 kg/m3, yielding an average CBR of 43.9% for soaked samples. On the section of Port Harcourt-Aba Express Road from Eleme Junction to Osisioma Junction;Soil-Cement stabilization improved the CBR and is optimized at a 12% sand-cement ratio having an optimum moisture content ranging from 5.4% - 17.3%, maximum dry density ranges from 1610 - 1740 kg/m3, and an average California Bearing Ratio for soaked samples at 40%.

An Assessment of Heavy-Metal Contamination in Soils within Auto-Mechanic Workshops Using Enrichment and Contamination Factors with Geoaccumulation Indexes

Soil characterization and heavy metals in different layers (0 - 15 cm;15 - 30 cm and 30 - 45 cm depth) of automobile mechanic waste dumps were studied. The soils showed remarkably high levels of all the metals above background concentrations with most (Ni, Cu, Fe, Cr and Cd) decreasing with soil depth. The distribution pattern were in the following order Fe > Cu > Zn > Pb > Cr > Ni > Cd. Across all the sampling locations and profiles, Fe and Cd showed the highest (476.4 μg·g-1) and least (37.5 μg·g-1) mean concentrations respectively. Pollution load index (PLI) and index of geoaccumulation (Igeo) revealed overall high and moderate contamination respectively but the enrichment factors (EFs) for Pb Ni and Cd are severe. The inter-element relationship revealed the identical source of elements in the soils of the studied area. The accuracy of the results has been cheeked using the standard reference material;SRM (PACS-2). The mechanic waste dumps represent potential sources of heavy metal pollution to environment. The elevated levels of heavy metals in these soil profiles constitute a serious threat to both surface and groundwater.

Investigation of Pollution Level of Traces Metals Elements in Agricultural Soil of Oubritenga Province of Burkina Faso

The purpose of this study was to investigate the pollution level of trace metals As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Se and Zn in agricultural soil around the water reservoir. A total of 36 soil samples were collected both during off-season agriculture and pluvial agriculture from April to October 2022. The samples were analyzed for trace metals according to the standard methods of the US EPA 2007 with a microwave plasma atomic emission spectrometer (MP-AES), Agilent Model 4210. The pollution level was assessed using contamination factor (Cf) and modified contamination degree (mCd). During the off-season, the concentration of trace metals followed in descending order as Mn > Cr > Cu > Pb > Zn. As, Cd, Co, Hg, Ni, Sb and Se were below the detectable limits. In pluvial season, the concentration of traces of metal follows the order Mn > Cr > Zn > Cu > Ni > Pb > Hg > As. Cd, Co, Sb and Se remain below the detectable limits. The concentrations of Cr, Mn and Zn were lower in the off-season agriculture than in pluvial agriculture. For Cu and Pb, the concentrations were higher in the off-season than in pluvial agriculture. The Cf ranges from 0.24 to 11.70 depending on the considered trace metal. The Cf values of As, Ni, Pb, Zn and Mn indicated that the agricultural study soil was lowery contaminated by these trace metals. The agricultural study soil was moderately contaminated by Cr and Cu, and highly contaminated by Hg. Globally the agricultural study soil presents a moderate degree of contamination (mCd 2.25) by the eight trace metals studied. This result provides information on understanding the risks of trace metal contamination of agricultural soil. It is important to anticipate the control of soil contamination through regular monitoring of toxic metals in agricultural soils, control the quality of chemicals used in agriculture and regulate their use.

Phosphorus Fertilizer Effects on Near-Surface Soil Aggregation in Furrow-Irrigated Rice on a Silt-Loam Soil

Well-aggregated soil has been shown to improve soil infiltration and reduce runoff and soil erosion, making well-aggregated soil important for productive, sustainable agriculture. One factor that may influence near-surface soil aggregate stability is fertilizer application. Rapid dissolution of fertilizers, which are mostly salts, can potentially disperse clays and destabilize aggregates. The objective of this study was to evaluate the potential effect of various fertilizer-phosphorus (P) and -nitrogen (N) sources [i.e., triple superphosphate (TSP), monoammonium phosphate (MAP), chemically precipitated struvite (CPST), electrochemically precipitated struvite (ECST), environmentally smart nitrogen (ESN)] and soil depth on water-stable aggregates (WSA) in furrow-irrigated rice on a silt-loam soil (Typic Albaqualf). Total WSA (TWSA) concentration was unaffected (P > 0.05) by fertilizer treatment or soil depth, while WSA concentration was numerically largest (P ∙g-1), which did not differ from CPST, ECST, and ESN in the 0 - 5 cm depth or the unamended control in the 0 - 5 and 5 - 10 cm depths, and was at least 1.7 times larger than ESN in the 5 - 10 cm depth (0.03 g∙g-1). Results indicated that WSA concentration among non-struvite fertilizer-P sources was generally similar to that from the struvite fertilizer materials. Principal component analysis determined that 32% of the variation of TWSA was mainly explained by changes in soil bulk density, pH, and electrical conductivity. Long-term, continual annual application of fertilizer-P and N could negatively impact soil aggregate stability, soil structure, and potentially erosion.