A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone(PVP) before the electroless plating proc...A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone(PVP) before the electroless plating process. Infrared(IR) spectroscopy,field emission scanning electron microscopy(FESEM), and x-ray diffraction(XRD) were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.展开更多
This work aimed to analyze the glass material used for sealing the end of a thermal collector in a parabolic trough solar power plant. Based on matched sealing requirements and application performance of glass and Kov...This work aimed to analyze the glass material used for sealing the end of a thermal collector in a parabolic trough solar power plant. Based on matched sealing requirements and application performance of glass and Kovar alloy 4J29, one borosilicate glass material (GD480S), whose expansion coefficient was similar to that of Kovar alloy 4J29, was studied. Moreover, the effect of the ratio of SiO2 to B203 on the glass properties was explored in detail by Fourier transform infrared spectroscopy. As the SiO2 to B203 ratio in the glass increased from 4.18 to 5.77, the expansion coefficient showed a decreasing trend from 4.95×10-6/℃ to 4.55℃ 10-6/℃. In addition, the water resistance performance improved, enabling the glass material to seal well with the alloy for application in a trough solar power plant. Thus, the increase in the SiO2 to B2O3 ratio made the glass structure more compact and improved the glass performance to meet the requirements of an industrial tubular receiver.展开更多
A cerium-iron oxide solar control coating on glass was prepared by citric acid sol-gel method, dip-coating techniques and proper heat treatment process. Results show that the cerium-iron glass coating is composed of n...A cerium-iron oxide solar control coating on glass was prepared by citric acid sol-gel method, dip-coating techniques and proper heat treatment process. Results show that the cerium-iron glass coating is composed of nanocrystalline CeO2, Fe2O3, and nano holes. The cerium-iron glass coating has high transmittance in visible light, low UV and near IR transmittance. The wavelength of absorption edge for most glass coating has an obvious redshift to about 375 nm. There exist a wide absorption band at the range of 800-1600 nm and high transmittance at the wavelength from 400 nm to 800 nm, and the solar energy and visible transmittances are 50% and 65%, respectively. It ascribes to the high content of trivalence cerium and bivalence iron ions in the cerium/iron coating. It is indicated that this kind of glass coating has very good UV-sheering and heat-insulating property, can be used as an effective solar control glass in automobile and architecture.展开更多
Solar water heaters which provide a cost-effective and environmental friendly approach to hot water generation are in widespread application. Evacuated tube solar water heaters perform better than flat plate solar wat...Solar water heaters which provide a cost-effective and environmental friendly approach to hot water generation are in widespread application. Evacuated tube solar water heaters perform better than flat plate solar water heaters as a result of their greater surface area exposed for sunlight absorption. Water-in-glass evacuated tube solar water heaters are widely used as compared to heat-pipe solar water heaters due to their short payback periods. In this study, the performance of water-in-glass evacuated tube solar water heater is investigated through experiments under the climatic conditions in Kenya. The results revealed a daily efficiency range of 0.58 - 0.65 and a daily final outlet temperature greater than 55<span style="white-space:normal;">°</span>C given an initial temperature of 25°C.展开更多
This study investigates the steam generating potential of a solar steam generation system and the potential for utility scale implementation in Libya oil for steam demanding enhanced oil recovery (EOR) methods. The pr...This study investigates the steam generating potential of a solar steam generation system and the potential for utility scale implementation in Libya oil for steam demanding enhanced oil recovery (EOR) methods. The proposed system uses parabolic troughs as solar collectors. The technology is proved to be technically feasible. Solar EOR should be seen as an add-on to existing plants due to the abundance of solar energy in Libya. The System Advisor Model (SAM) model system, developed by the National Office of Renewable Energy (NRE), was used to assess the plant’s active and economic performance.展开更多
Experimental studies were carried out to determine the influence of solar radiation, temperatures variations, basin water amount, wind speed, glass cover thickness and salinity on the daily production of the distillat...Experimental studies were carried out to determine the influence of solar radiation, temperatures variations, basin water amount, wind speed, glass cover thickness and salinity on the daily production of the distillate output using solar desalination process, namely single slope solar still to produce fresh water from seawater in the context of Djibouti. The temperatures variations increase in relation to solar radiation. Consequently the hourly distillate output increases and reaches a maximum around noon when the solar still receives maximum intensity of solar radiation. An inverse relation is found between glass cover thickness, basin water amount and distillate output production. The variation wind speed has an effect on the daily production;which increases in relation to wind speed. In order to assess the effect of salinity on the daily production, the solar still is provided with brackish water to compare the daily production obtained from seawater. Experimental results show that the cumulative productivity decreases when there is an increase of salinity. In addition, the quality of the distillate output was tested by measuring TDS, EC, pH, hardness water and chlorides and was compared to WHO standards. The values obtained for these parameters were in accordance with the requirements of WHO and good removal efficiency for four parameters.展开更多
文摘A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone(PVP) before the electroless plating process. Infrared(IR) spectroscopy,field emission scanning electron microscopy(FESEM), and x-ray diffraction(XRD) were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.
基金Funded by the Special Projects of Major Scientific and Technological Achievements of Hebei Province(No.13041110Z)
文摘This work aimed to analyze the glass material used for sealing the end of a thermal collector in a parabolic trough solar power plant. Based on matched sealing requirements and application performance of glass and Kovar alloy 4J29, one borosilicate glass material (GD480S), whose expansion coefficient was similar to that of Kovar alloy 4J29, was studied. Moreover, the effect of the ratio of SiO2 to B203 on the glass properties was explored in detail by Fourier transform infrared spectroscopy. As the SiO2 to B203 ratio in the glass increased from 4.18 to 5.77, the expansion coefficient showed a decreasing trend from 4.95×10-6/℃ to 4.55℃ 10-6/℃. In addition, the water resistance performance improved, enabling the glass material to seal well with the alloy for application in a trough solar power plant. Thus, the increase in the SiO2 to B2O3 ratio made the glass structure more compact and improved the glass performance to meet the requirements of an industrial tubular receiver.
基金This work was financially supported by the Tsinghua University Fundamental Research Foundation (No.JCq2005045).
文摘A cerium-iron oxide solar control coating on glass was prepared by citric acid sol-gel method, dip-coating techniques and proper heat treatment process. Results show that the cerium-iron glass coating is composed of nanocrystalline CeO2, Fe2O3, and nano holes. The cerium-iron glass coating has high transmittance in visible light, low UV and near IR transmittance. The wavelength of absorption edge for most glass coating has an obvious redshift to about 375 nm. There exist a wide absorption band at the range of 800-1600 nm and high transmittance at the wavelength from 400 nm to 800 nm, and the solar energy and visible transmittances are 50% and 65%, respectively. It ascribes to the high content of trivalence cerium and bivalence iron ions in the cerium/iron coating. It is indicated that this kind of glass coating has very good UV-sheering and heat-insulating property, can be used as an effective solar control glass in automobile and architecture.
文摘Solar water heaters which provide a cost-effective and environmental friendly approach to hot water generation are in widespread application. Evacuated tube solar water heaters perform better than flat plate solar water heaters as a result of their greater surface area exposed for sunlight absorption. Water-in-glass evacuated tube solar water heaters are widely used as compared to heat-pipe solar water heaters due to their short payback periods. In this study, the performance of water-in-glass evacuated tube solar water heater is investigated through experiments under the climatic conditions in Kenya. The results revealed a daily efficiency range of 0.58 - 0.65 and a daily final outlet temperature greater than 55<span style="white-space:normal;">°</span>C given an initial temperature of 25°C.
文摘This study investigates the steam generating potential of a solar steam generation system and the potential for utility scale implementation in Libya oil for steam demanding enhanced oil recovery (EOR) methods. The proposed system uses parabolic troughs as solar collectors. The technology is proved to be technically feasible. Solar EOR should be seen as an add-on to existing plants due to the abundance of solar energy in Libya. The System Advisor Model (SAM) model system, developed by the National Office of Renewable Energy (NRE), was used to assess the plant’s active and economic performance.
文摘Experimental studies were carried out to determine the influence of solar radiation, temperatures variations, basin water amount, wind speed, glass cover thickness and salinity on the daily production of the distillate output using solar desalination process, namely single slope solar still to produce fresh water from seawater in the context of Djibouti. The temperatures variations increase in relation to solar radiation. Consequently the hourly distillate output increases and reaches a maximum around noon when the solar still receives maximum intensity of solar radiation. An inverse relation is found between glass cover thickness, basin water amount and distillate output production. The variation wind speed has an effect on the daily production;which increases in relation to wind speed. In order to assess the effect of salinity on the daily production, the solar still is provided with brackish water to compare the daily production obtained from seawater. Experimental results show that the cumulative productivity decreases when there is an increase of salinity. In addition, the quality of the distillate output was tested by measuring TDS, EC, pH, hardness water and chlorides and was compared to WHO standards. The values obtained for these parameters were in accordance with the requirements of WHO and good removal efficiency for four parameters.