Herein we would like to comment on the paper ＂Estimation of potential distribution of gas hydrate in the northern South China Sea＂ by Wang et al. 2010 in Chinese Journal of Oceanology and Lirnnology, 28（3）： 693-6...Herein we would like to comment on the paper ＂Estimation of potential distribution of gas hydrate in the northern South China Sea＂ by Wang et al. 2010 in Chinese Journal of Oceanology and Lirnnology, 28（3）： 693-699. The purpose of this comment is to point out that the given probabilities of gas hydrate occtwrence in the northern Zhujiang Mouth Basin and the Yinggehai Basin in the figure of Wang et al. （2010） are improper. After introducing our work of estimation of gas hydrate stability distribution in the northern South China Sea, we suggest that Wang et al. （2010） dismissed the basic P-T rule for the existence of gas hydrate. They should consider more the variables of water depth, seabed temperature and geothermal gradient in their gas hydrate distribution model in future studies.展开更多
Based on the geothermal and gravitation methods, this paper investigated the rheological and thermal structure of the lithosphere under the northern margin of South China Sea. The result shows that the temperature of ...Based on the geothermal and gravitation methods, this paper investigated the rheological and thermal structure of the lithosphere under the northern margin of South China Sea. The result shows that the temperature of the upper crust is 150–300°C lower than that of the lower crust, and the viscous coefficient of the upper crust is 2–3 orders of magnitude larger than that of the lower crust. It reveals that the upper crust is characterized by brittle deformation while the lower crust by ductile deformation. A channel of lower-viscosity should be formed between the upper and lower crust when the lithosphere is scattered and spreads out toward ocean from northwest to southeast along the northern margin of South China Sea. And, a brittle deformation takes place in the upper part of the lithosphere while a ductile deformation takes place in the lower part of the lithosphere due to different viscous coefficients and temperature. The layered deformation leads the faulted blocks to rotate along the faulting and the marginal grabens to appear in the northern margin of South China Sea in Cenozoic tectonic expansion.展开更多
Elemental sulfur(ES) is one of the intermediates in the inorganic sulfur cycle and thus plays a key role in the fractionation of stable sulfur isotopes in different reservoirs and the marine environment. In this study...Elemental sulfur(ES) is one of the intermediates in the inorganic sulfur cycle and thus plays a key role in the fractionation of stable sulfur isotopes in different reservoirs and the marine environment. In this study, solid ES is discovered in sediments near the Jiulong Methane Reef in the northern South China Sea by scanning electron microscopy and Raman spectroscopy. Combining the morphology and distribution of ES, pyrite concentrations, and sulfur isotopes, we conclude that:(1) solid ES coexists with pyrite microcrystals and sulfide(oxyhydr)oxides as well as clay minerals, and they are mainly distributed on the surface of mineral aggregates;(2) ES mainly occurs within and near the sulfate-methane transition zone(SMTZ) despite little morphological diversity;(3) ES formation might be related to hydrogen sulfide oxidation and is therefore linked with fluctuations in the SMTZ. Within the SMTZ, hydrogen sulfide is produced and pyrite precipitates because of enhanced anaerobic oxidation of methane coupled with dissimilatory sulfate reduction. This enhances the efficiency of the inorganic sulfur cycle and provides favorable conditions for ES formation. The discovery of solid ES in sediments near the Jiulong Methane Reef suggests an important relationship with SMTZ fluctuations that could have implications for the evolution of methane hydrate in the South China Sea.展开更多
基金Supported by the National Natural Science Foundation of China (No. 40774033)National Basic Research Program of China (973 Program) (No. 2009CB219503)the National High Technology Research and Development Program of China (863 Program) (No. 2006AA09A203-05)
文摘Herein we would like to comment on the paper ＂Estimation of potential distribution of gas hydrate in the northern South China Sea＂ by Wang et al. 2010 in Chinese Journal of Oceanology and Lirnnology, 28（3）： 693-699. The purpose of this comment is to point out that the given probabilities of gas hydrate occtwrence in the northern Zhujiang Mouth Basin and the Yinggehai Basin in the figure of Wang et al. （2010） are improper. After introducing our work of estimation of gas hydrate stability distribution in the northern South China Sea, we suggest that Wang et al. （2010） dismissed the basic P-T rule for the existence of gas hydrate. They should consider more the variables of water depth, seabed temperature and geothermal gradient in their gas hydrate distribution model in future studies.
基金the National Natural Science Foundation of China (Grant Nos.49732005, 49733011) and the Chinese Academy of Sciences (Grant No. KZ951-A1-401). We wish to thank Prof. Xu Houze and Lu Yang for their contribution in gravitational model. The authors also than
文摘Based on the geothermal and gravitation methods, this paper investigated the rheological and thermal structure of the lithosphere under the northern margin of South China Sea. The result shows that the temperature of the upper crust is 150–300°C lower than that of the lower crust, and the viscous coefficient of the upper crust is 2–3 orders of magnitude larger than that of the lower crust. It reveals that the upper crust is characterized by brittle deformation while the lower crust by ductile deformation. A channel of lower-viscosity should be formed between the upper and lower crust when the lithosphere is scattered and spreads out toward ocean from northwest to southeast along the northern margin of South China Sea. And, a brittle deformation takes place in the upper part of the lithosphere while a ductile deformation takes place in the lower part of the lithosphere due to different viscous coefficients and temperature. The layered deformation leads the faulted blocks to rotate along the faulting and the marginal grabens to appear in the northern margin of South China Sea in Cenozoic tectonic expansion.
基金supported by the National Natural Science Foundation of China(Grants Nos.41472085 and 41172102)the National Basic Research Program of China(Grants Nos.2011CB808805 and 2009CB21950605)the National Project of Exploration and Test Production for Gas Hydrate(Grants Nos.GZH20110030-50603 and GZH20110030-6WX02)
文摘Elemental sulfur(ES) is one of the intermediates in the inorganic sulfur cycle and thus plays a key role in the fractionation of stable sulfur isotopes in different reservoirs and the marine environment. In this study, solid ES is discovered in sediments near the Jiulong Methane Reef in the northern South China Sea by scanning electron microscopy and Raman spectroscopy. Combining the morphology and distribution of ES, pyrite concentrations, and sulfur isotopes, we conclude that:(1) solid ES coexists with pyrite microcrystals and sulfide(oxyhydr)oxides as well as clay minerals, and they are mainly distributed on the surface of mineral aggregates;(2) ES mainly occurs within and near the sulfate-methane transition zone(SMTZ) despite little morphological diversity;(3) ES formation might be related to hydrogen sulfide oxidation and is therefore linked with fluctuations in the SMTZ. Within the SMTZ, hydrogen sulfide is produced and pyrite precipitates because of enhanced anaerobic oxidation of methane coupled with dissimilatory sulfate reduction. This enhances the efficiency of the inorganic sulfur cycle and provides favorable conditions for ES formation. The discovery of solid ES in sediments near the Jiulong Methane Reef suggests an important relationship with SMTZ fluctuations that could have implications for the evolution of methane hydrate in the South China Sea.
