Strontium aluminate long persistence phos phors are synthesized by combustion method. By control- ling the raw material ratio （Sr/Al）, the effects of phase composition on subsequent spectroscopic properties of phosp...Strontium aluminate long persistence phos phors are synthesized by combustion method. By control- ling the raw material ratio （Sr/Al）, the effects of phase composition on subsequent spectroscopic properties of phosphors are studied. Results show that the phase com-position changes from strontium-rich phase to aluminum- rich phase with the decrease of Sr/AI： when the rate of Al/Sr changes from 3：1 to 1：1, the main crystal phase of samples is Sr3Al206, and it exhibits the characteristic fluorescence of Eu^3＋ in the lattice of Sr3Al206; when the rate of Al/Sr is between 1：2 and 2：7, phase composition is the mixture of SrAl204 and SrAl4OT, and it emits the characteristic fluorescence of Eu^2＋ in SrAl204 but not in SrAl4OT; when Al/Sr decreases to 1：4 or even 1：12, the main crystal phase of samples transform into SrAl12019, and the characteristic emission peak is about 470 nm, which corresponds to the characteristic emission of Eu2＋ in SrAl12019. At the end of the article, the influence laws of two different synthesis methods on phase composition of samples between high-temperature solid method and combustion method are compared. Compared with the high-temperature solid method, the rule of influence is similar, but the mole ratio of Al/Sr in products is always higher than the initial ratio of the raw material, and com-pounds like Sr4Al14025 are not obtained by combustion method.展开更多
The reconstruction of paleohydrology,especially paleosalinity,is an important component of paleoenvironmental research.Researches on the modern characteristics of lake water chemistry and the relationship between lake...The reconstruction of paleohydrology,especially paleosalinity,is an important component of paleoenvironmental research.Researches on the modern characteristics of lake water chemistry and the relationship between lake salinity and hydrochemistry are the basis of paleoenvironment reconstruction.The modern hydrochemical characteristics and the relationship between ion composition and salinity of modern lakes are the basis of paleosalinity reconstruction.In this study,hydrochemical analysis of 21 lakes in the Badain Jaran Desert(BJD)was carried out.The relationships between the Sr/Ca and Mg/Ca ratios and total dissolved solids(TDS)were analyzed.The results show that Na^(+),K^(+),Cl-and SO_(4)^(2-)have high positive correlations with TDS,and Mg^(2+),Sr^(2+),CO_(3)_(2-)and HCO_(3)^(-)have lower correlations with TDS.The Sr/Ca and Mg/Ca ratios do not increase linearly with TDS.Hydrochemical analysis indicates that the studied lakes are in the carbonate precipitation stage and that evaporation is the main factor controlling lake evolution in the BJD.The relationships between the Mg/Ca and Sr/Ca ratios and TDS are mainly influenced by lake evolution stage and the hydrochemical types of the lakes.On the basis of comprehensive previous studies,the factors affecting lake evolution,the Mg and Sr partition coefficients and other hydrochemical parameters that change with lake evolution all affect the relationship between chemical composition and salinity.To reconstruct paleosalinity more accurately,more detailed research on the modern hydrochemical characteristics of lakes and the relationship between the element ratios of carbonates and water salinity should be carried out.展开更多
Ba0.6Sr0.4TiO3 (BST) thin films were fabricated on Pt coated Si (100) substrates by sol-gel techniques with molar ratio of (Ba+Sr) to Ti changing from 0.76 to 1.33. The effect of (Ba+Sr)/Ti ratio deviating from the st...Ba0.6Sr0.4TiO3 (BST) thin films were fabricated on Pt coated Si (100) substrates by sol-gel techniques with molar ratio of (Ba+Sr) to Ti changing from 0.76 to 1.33. The effect of (Ba+Sr)/Ti ratio deviating from the stoichiometry on microstructure, grain growth, dielectric and tunable properties of BST thin films were investigated. TiO2 and (Ba,Sr)2TiO4 were found as a second phase at the ratios of 0.76 and 1.33, respectively. The variation of the ratio reveals more significant effect on the grain size in B-site rich samples than that in A-site rich samples. The dissipation factor decreases rapidly from 0.1 to 0.01 at 1 MHz with decreasing (Ba+Sr)/Ti ratio. The tunability increases with decreasing ratio from 1.33 to 1.05, and then decreases with decreasing ratio from 1.05 to 0.76. The film with (Ba+Sr)/Ti ratio of 1.05 has a maximum tunability of 32% and a dissipation factor of 0.03 at 1 MHz.展开更多
基金financially supported by the National Natural Science Foundation of China(No.NSFC50962001)the Scientific Research Foundation of Beifang Ethnic University for Nationalities(No.2010Y042)
文摘Strontium aluminate long persistence phos phors are synthesized by combustion method. By control- ling the raw material ratio （Sr/Al）, the effects of phase composition on subsequent spectroscopic properties of phosphors are studied. Results show that the phase com-position changes from strontium-rich phase to aluminum- rich phase with the decrease of Sr/AI： when the rate of Al/Sr changes from 3：1 to 1：1, the main crystal phase of samples is Sr3Al206, and it exhibits the characteristic fluorescence of Eu^3＋ in the lattice of Sr3Al206; when the rate of Al/Sr is between 1：2 and 2：7, phase composition is the mixture of SrAl204 and SrAl4OT, and it emits the characteristic fluorescence of Eu^2＋ in SrAl204 but not in SrAl4OT; when Al/Sr decreases to 1：4 or even 1：12, the main crystal phase of samples transform into SrAl12019, and the characteristic emission peak is about 470 nm, which corresponds to the characteristic emission of Eu2＋ in SrAl12019. At the end of the article, the influence laws of two different synthesis methods on phase composition of samples between high-temperature solid method and combustion method are compared. Compared with the high-temperature solid method, the rule of influence is similar, but the mole ratio of Al/Sr in products is always higher than the initial ratio of the raw material, and com-pounds like Sr4Al14025 are not obtained by combustion method.
基金financially supported by the Basic Research Program of Chinese Academy of Geological Sciences(CAGS)(YK202302)the projects of the China Geological Survey(DD20221929,121201106000150093)the National Natural Science Foundation of China(41807420)。
文摘The reconstruction of paleohydrology,especially paleosalinity,is an important component of paleoenvironmental research.Researches on the modern characteristics of lake water chemistry and the relationship between lake salinity and hydrochemistry are the basis of paleoenvironment reconstruction.The modern hydrochemical characteristics and the relationship between ion composition and salinity of modern lakes are the basis of paleosalinity reconstruction.In this study,hydrochemical analysis of 21 lakes in the Badain Jaran Desert(BJD)was carried out.The relationships between the Sr/Ca and Mg/Ca ratios and total dissolved solids(TDS)were analyzed.The results show that Na^(+),K^(+),Cl-and SO_(4)^(2-)have high positive correlations with TDS,and Mg^(2+),Sr^(2+),CO_(3)_(2-)and HCO_(3)^(-)have lower correlations with TDS.The Sr/Ca and Mg/Ca ratios do not increase linearly with TDS.Hydrochemical analysis indicates that the studied lakes are in the carbonate precipitation stage and that evaporation is the main factor controlling lake evolution in the BJD.The relationships between the Mg/Ca and Sr/Ca ratios and TDS are mainly influenced by lake evolution stage and the hydrochemical types of the lakes.On the basis of comprehensive previous studies,the factors affecting lake evolution,the Mg and Sr partition coefficients and other hydrochemical parameters that change with lake evolution all affect the relationship between chemical composition and salinity.To reconstruct paleosalinity more accurately,more detailed research on the modern hydrochemical characteristics of lakes and the relationship between the element ratios of carbonates and water salinity should be carried out.
基金Project (50332030) supported by the National Natural Science Foundation of China
文摘Ba0.6Sr0.4TiO3 (BST) thin films were fabricated on Pt coated Si (100) substrates by sol-gel techniques with molar ratio of (Ba+Sr) to Ti changing from 0.76 to 1.33. The effect of (Ba+Sr)/Ti ratio deviating from the stoichiometry on microstructure, grain growth, dielectric and tunable properties of BST thin films were investigated. TiO2 and (Ba,Sr)2TiO4 were found as a second phase at the ratios of 0.76 and 1.33, respectively. The variation of the ratio reveals more significant effect on the grain size in B-site rich samples than that in A-site rich samples. The dissipation factor decreases rapidly from 0.1 to 0.01 at 1 MHz with decreasing (Ba+Sr)/Ti ratio. The tunability increases with decreasing ratio from 1.33 to 1.05, and then decreases with decreasing ratio from 1.05 to 0.76. The film with (Ba+Sr)/Ti ratio of 1.05 has a maximum tunability of 32% and a dissipation factor of 0.03 at 1 MHz.
