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Extensive Resetting of Feldspar Pb Isotopic Composition in Archean–Paleoproterozoic Granitic Rocks from the Kongling Terrane,South China:Implications for Tracing Thermal Evolutionary History
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作者 MENG Fanxue LU Jie +2 位作者 ZOU Zongqi GUO Jingliang MENG Yuanku 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第2期386-398,共13页
Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb... Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb isotopic composition of feldspar hosted in granitic rocks(thirteen Archean and one Paleoproterozoic)from the northern Kongling terrane,Yangtze Craton,South China,is analyzed.The samples reveal a substantial variation in their Pb isotopic composition,spanning the gap between the 1.9 Ga and present-day geochrons,which indicates extensive resetting by later tectonothermal events.This resetting was interpreted to have likely resulted from Paleoproterozoic and Neoproterozoic tectonothermal events related to the assembly and breakup of the Columbia and Rodinia supercontinents.These results suggest that Pb isotopes should be used cautiously when tracing magma sources and petrogenesis in magmatic rocks that have experienced post-magmatic reworking.However,the in situ Pb isotopic composition of feldspar in ancient granitoids may also potentially be used to reveal later tectonothermal events.The extensive resetting of the Pb isotopic composition in feldspar by regional thermal events may also provide new insights into our understanding of the Pb isotope paradox. 展开更多
关键词 in situ pb isotope pb isotope resetting thermal event Archean-Paleoproterozoic Kongling terrane
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滇西北浪都夕卡岩矿床致矿岩体的岩石地球化学、年代学、Sr-Nd-Pb同位素组成及其地质意义
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作者 莫雷 沈啟武 +7 位作者 陈喜连 吴练荣 张传昱 董桥峰 苏肖宇 施宝生 余海军 冷成彪 《沉积与特提斯地质》 CAS CSCD 北大核心 2024年第2期421-436,共16页
滇西北浪都侵入岩体位于义敦岛弧南段的中甸弧,在空间上属浪都夕卡岩型铜矿床的致矿岩体。本文以浪都致矿岩体中石英二长斑岩为对象,对其开展了锆石SIMS(二次离子质谱)U-Pb定年、岩石地球化学和Sr-Nd-Pb同位素研究。锆石U-Pb定年结果显... 滇西北浪都侵入岩体位于义敦岛弧南段的中甸弧,在空间上属浪都夕卡岩型铜矿床的致矿岩体。本文以浪都致矿岩体中石英二长斑岩为对象,对其开展了锆石SIMS(二次离子质谱)U-Pb定年、岩石地球化学和Sr-Nd-Pb同位素研究。锆石U-Pb定年结果显示浪都石英二长斑岩的成岩年龄为219.2±1.8 Ma(2σ,MSWD=1.3,n=13),与中甸弧中晚三叠世侵入岩体成岩年龄基本一致。浪都石英二长斑岩具有中等SiO2含量(w(SiO_(2))为60.42%~66.44%),高Al_(2)O_(3)(w(Al2O3)为14.56%~16%)和高K2O(w(K_(2)O)为3.49%~4.49%)含量,以富集LREE和Rb、Ba、Sr等大离子亲石元素,相对亏损HREE和Ta、Nb、Ti等高场强元素为特征,在化学成分上属于高钾钙碱性系列。此外,浪都石英二长斑岩的87Sr/86Sr初始值为0.7054~0.7061,εNd(t)值为-3.5~-2.5,且所有样品在Pb同位素构造模式图上均落在造山带演化线附近。结合浪都石英二长斑岩的成岩时代、岩石化学和同位素特征,本文认为浪都致矿岩体形成于晚三叠世甘孜-理塘洋壳西向俯冲增生的构造背景,是交代地幔部分熔融形成的熔体在上升过程中受到下地壳物质混染,并经历分离结晶作用形成的产物。浪都石英二长斑岩的高Sr/Y比值和高V/Sc比值,指示岩浆具有高含量H2O和较高的氧逸度,是该区斑岩-夕卡岩铜矿床形成的关键。 展开更多
关键词 浪都 致矿岩体 岩石地球化学 锆石U-pb年龄 sr-nd-pb同位素
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胶东西南部三合山岩体岩石成因和构造背景:年代学、地球化学及Sr-Nd-Pb-Hf同位素约束
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作者 邹占春 刘俊玉 +7 位作者 陈建 李景波 丁正江 孙丽莎 李双飞 唐名鹰 张蕾 王欣然 《中国地质》 CAS CSCD 北大核心 2024年第4期1387-1410,共24页
【研究目的】胶东地区是中国最大的金矿矿集区,也是山东省最为重要的铜钼多金属矿成矿区。加强中生代花岗岩的岩相学、岩石地球化学和年代学等方面的研究,有利于进一步促进该区金及多金属矿的找矿工作。【研究方法】本文以胶东半岛西南... 【研究目的】胶东地区是中国最大的金矿矿集区,也是山东省最为重要的铜钼多金属矿成矿区。加强中生代花岗岩的岩相学、岩石地球化学和年代学等方面的研究,有利于进一步促进该区金及多金属矿的找矿工作。【研究方法】本文以胶东半岛西南部三合山岩体中细粒二长花岗岩和花岗斑岩为研究对象,开展系统的岩相学、LA-ICP-MS锆石U-Pb年代学、主微量元素地球化学、全岩Sr-Nd-Pb同位素及锆石Lu-Hf同位素研究,旨在探讨其岩石成因、岩浆源区性质和构造背景。【研究结果】LA-ICP-MS锆石U-Pb定年结果表明,中细粒二长花岗岩的成岩年龄为(115.42±0.27)Ma,花岗斑岩的形成年龄为(115.21±0.25)Ma,形成时代均属中生代早白垩晚期;岩石地球化学特征表明,中细粒二长花岗岩和花岗斑岩均属高钾钙碱性I型花岗质岩石,LREE较HREE分馏明显,具弱Ce负异常和明显Eu中等负异常,富集Rb、K、Zr和Hf,亏损Sr、Ba、Nb、P、Ti;全岩Sr-Nd-Pb及锆石Hf同位素分析结果表明,三合山岩体起源于重熔的下地壳,并受到了幔源物质的混染。【结论】三合山岩体形成于早白垩世太平洋板块相对欧亚板块俯冲导致的陆内伸展背景下,为中国东部岩石圈减薄过程中壳幔相互作用的产物。 展开更多
关键词 地球化学 地质年代学 sr-nd-pb-Hf同位素 地质调查工程 胶东 山东省
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胶东大疃刘家铍矿床碱性岩岩石成因及对成矿的制约:锆石U-Pb年代学、地球化学及Sr-Nd-Hf同位素证据
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作者 唐文龙 邹键 +1 位作者 张锋 党智财 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第8期2429-2449,共21页
胶东大疃刘家铍矿床位于华北板块东南缘,矿体受NW向断裂控制,圈定的7条矿体呈透镜状产出,赋存于中细粒正长岩中。矿石矿物主要为羟硅铍石,与绢云母、方解石、重晶石、褐铁矿等蚀变矿物密切共生。Be与Mo、Rb、Cs、REE等元素具有良好的正... 胶东大疃刘家铍矿床位于华北板块东南缘,矿体受NW向断裂控制,圈定的7条矿体呈透镜状产出,赋存于中细粒正长岩中。矿石矿物主要为羟硅铍石,与绢云母、方解石、重晶石、褐铁矿等蚀变矿物密切共生。Be与Mo、Rb、Cs、REE等元素具有良好的正相关性,与CaO呈负相关关系,矿床成矿专属性明显。矿区内正长花岗岩为高硅、富碱、高钾、贫镁铁岩石,为准铝质-弱过铝质岩石;正长岩具有低硅、富碱、高钾特征,为准铝质岩石。两类岩石均具有轻重稀土分馏明显,轻稀土富集,无明显负Eu异常的稀土元素特征,稀土及微量元素配分模式相同,微量元素具有富集大离子亲石元素,亏损Nb、Ta、Ti等高场强元素的特征。正长花岗岩锆石LA-ICP-MS U-Pb定年表明其侵位于200.3±1.3Ma,全岩Sr-Nd同位素组成比较均一,ε_(Nd)(t)值为-15.8~-15.4,Hf同位素组成变化范围较大,ε_(Hf)(t)为-25.5~-7.75;正长岩锆石LA-ICP-MS U-Pb定年表明其侵位于200.9±1.4Ma,ε_(Hf)(t)值为-23.2~-15.7。地球化学研究指示正长岩为经历了华南陆壳交代的华北富集岩石圈地幔低程度部分熔融的产物,正长花岗岩来源于俯冲的华南陆壳,二者为华南板块与华北板块碰撞折返阶段岩浆作用的产物。 展开更多
关键词 地球化学 矿床地质 LA-ICP-MS锆石U-pb定年 sr-nd-HF同位素 大疃刘家铍矿床 胶东
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桐柏—大别造山带中部娘娘顶花岗岩成因——锆石U-Pb年龄、岩石地球化学及Sr-Nd同位素证据
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作者 叶健华 方洁 +3 位作者 钟石玉 杨成 张凯玲 周梦阁 《资源环境与工程》 2024年第4期381-392,共12页
娘娘顶花岗岩体位于桐柏—大别造山带中部﹐其侵位时代及形成构造环境还不清楚。采集娘娘顶花岗岩样品,开展锆石U-Pb年代学、岩石地球化学及Sr-Nd同位素研究,探讨其岩浆源区特征、岩石成因、构造环境及其与杨新岩铍矿点的关系。结果表明... 娘娘顶花岗岩体位于桐柏—大别造山带中部﹐其侵位时代及形成构造环境还不清楚。采集娘娘顶花岗岩样品,开展锆石U-Pb年代学、岩石地球化学及Sr-Nd同位素研究,探讨其岩浆源区特征、岩石成因、构造环境及其与杨新岩铍矿点的关系。结果表明,娘娘顶花岗岩的锆石U-Pb年龄为(752.6±9.0)Ma,属南华纪岩浆作用产物,仅构成杨新岩铍矿点的赋矿围岩;具有高硅(SiO_(2)含量为72.56%~77.26%)、富碱(Na_(2)O+K_(2)O含量为7.37%~8.86%)、过铝质(A/CNK为0.97~1.22)等特征,Rb、K、Th等元素相对富集,Ba、Sr、Ti、P等元素明显亏损,稀土元素配分曲线呈右倾的轻稀土元素富集型,具明显负Eu异常(δEu为0.2~0.7),表明岩石为铝质A型花岗岩;(^(87)Sr/^(86)Sr)i为0.710605~0.710608,εNd(t)为-4.94~-5.05,相应的Nd模式年龄t_(DM)为1.83~1.84 Ga,具有大陆上地壳特征,可能为古—中元古代古老基底部分熔融的产物;主量元素CaO、MgO、TFeO、TiO_(2)与SiO_(2)均显示负相关关系,其岩浆演化机制应以结晶分异作用为主。综合来看,娘娘顶花岗岩形成于新元古代伸展背景。 展开更多
关键词 娘娘顶花岗岩体 锆石U-pb测年 sr-nd同位素 南华纪 伸展环境 桐柏—大别造山带
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Late Paleozoic Mantle Source Nature of Tianshan Orogen, Northwest China: Evidence from the Geochemistry, Zircon U-Pb Dating, Hf and Whole Rock Sr-Nd-Pb Isotopes of the Mafic Dykes 被引量:1
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作者 ZHANG Chengli XU Xueyi +3 位作者 WANG Hongliang MA Zhongping GAO Xiaofeng CHEN Junlu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第S01期81-83,共3页
The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to colli... The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to collision.However,the late Paleozoic tectonic evolutionary history,especially for the time of the ocean-continent transition,is still debated although the origin and tectonic settings for the Paleozoic volcanic,felsic igneous magmatism in TO and reginal geology have been done in the last decades.In contrast,the researches on the mafic dykes in TO was not systematically carried out till now.Reginal-scale mafic dykes are commonly regarded as the products created in a extensional setting,and used to identify the major tectonic events such as rifting and continental break-up and further trace the mantle natures and geodynamic mechanism(Halls,1982;Bleeker and Ernst,2006;Li et al.,2008;Ernst et al.,2010;Srivastava,2011;Hou,2012;Peng,2015;Peng et al.,2019).There are widespread late Paleozoic mafic dykes beside the huge of intermediate-acid igneous rocks in the TO,being an idea object to reveal the extensional events,tectonic evolution and the mantle nature and geodynamic processes.We present the ICPMS in situ zircon U–Pb dating,Lu-Hf and whole-rock Sr-Nd isotopes as well as the geochemistry data for these mafic dykes to better constraint their petrogenesis and mantle nature.New zircon U-Pb dating for 12 samples from the representative basic dykes and basalts yield three distinct stages of^332 Ma,316–302 Ma and 288–282 Ma,respectively.In which,the first stage of mafic dykes is mainly occurred in both East Tianshan Orogen(ETO)and West Tianshan Orogen(WTO),and composed of dolerite with minor basalts.The second stage of mafic dyke also can be found in both ETO and WTO.However,in contrast to the first stage of mafic dykes,they have relatively variable rock types from the dolerite/or gabbros to gabbroic diorite.The third stage of mafic dykes are slightly intermediate in composition,and chiefly consist of andesitic-basaltic dolerite with some diorites.They are widely developed not only in both ETO and WTO,but also in the Beishan area to the east of the ETO,indicating a large-scale mafic magmatism in Tianshan and adjacent areas. 展开更多
关键词 mafic dykes GEOCHEMISTRY zircon U-pb dating insitu Hf isotopes whole rock sr-nd isotope Tianshan orogen
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Geochemistry and Sr-Nd-Pb Isotopes of the Granites from the Hashitu Mo Deposit of Inner Mongolia, China: Constraints on Their Origin and Tectonic Setting 被引量:4
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作者 DING Chengwu DAI Pan +6 位作者 BAGAS Leon NIE Fengjun JIANG Sihong WEI Junhao DING Chengzhen ZUO Pengfei ZHANG Ke 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第1期106-120,共15页
The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range, NE China. Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite. Sr... The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range, NE China. Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite. Sr-Nd-Pb isotopes of the intrusions show that the porphyritic syenogranite has initial ^87Sr/^86Sr ratios of 0.70418-0.70952, ENd(t) values of 1.3 to 2.1 (t=143 Ma), ^206Pb/^204Pb ratios of 19.191-19.573, ^207Tpb/^204pb ratios of 15.551-15.572, and ^208Pb/^204Pb ratios of 38.826-39.143. The monzogranite has initial 87Sr/86Sr ratios of 0.70293-0.71305, εNd(t) values of 1.1 to 2.0 (t=-147 Ma), ^206Pb/^204pb ratios of 19.507-20.075, ^207Pb/^204Pb ratios of 15.564-15.596, and ^208Pb/^204Pb ratios of 39.012-39.599. The calculated Nd model ages (TDM) for monzogranite and porphyritic syenogranite range from 866 to 1121 Ma and 795 to 1020 Ma, respectively. The granitic rocks in the Hashitu area have the same isotope range as granites in the southern parts of the Great Hinggan Range. The isotope composition indicates that these granites are derived from the partial melting of a juvenile lower crust originating from a depleted mantle with minor contamination by ancient continental crust. The integrating our results with published data and the Late Mesozoic regional tectonic setting of the region suggest that the granites in the Hashitu area formed in an intra-continent extensional setting, and they are related to the thinning of the thickened lithosphere and upwelling of the asthenosphere. 展开更多
关键词 granite sr-nd-pb isotopes Hashitu Mo deposit Great Hinggan Range
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Geochronology, Geochemistry and Sr-Nd-Pb-Hf Isotopes of No. I Complex from the Shitoukengde Ni–Cu Sulfide Deposit in the Eastern Kunlun Orogen, Western China: Implications for the Magmatic Source, Geodynamic Setting and Genesis 被引量:13
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作者 LI Liang SUN Fengyue +7 位作者 LI Bile LI Shijin CHEN Guangjun WANG Wei YAN Jiaming ZHAO Tuofei DONG Jun ZHANG Dexin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2018年第1期106-126,共21页
The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small u... The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian (426-422 Ma), and their zircons have ~Hf(t) values of-9.4 to 5.9 with the older TDMm ages (0.80-1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements (e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements (e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle (0 ~ 2%o). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian. 展开更多
关键词 sr-nd-pb-Hf isotopes crustal contamination oceanic slab break-off post-collisionalextension Shitoukengde Ni-Cu deposit Eastern Kunlun Orogen
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Geochemistry, U-Pb Geochronology and Sr-Nd-Hf Isotopes of the Early Cretaceous Volcanic Rocks in the Northern Da Hinggan Mountains 被引量:2
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作者 HU Xinlu YAO Shuzhen +2 位作者 HE Mouchun DING Zhenju CHEN Bin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第1期203-216,共14页
Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high S... Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high SiO2 (73.19-77.68 wt%) and Na20+K20 (6.53-8.98 wt%) contents, with enrichment in Rb, Th, U, Pb and LREE, and depletion in Nb, Ta, P and Ti. Three rhyolite samples, one rhyolite porphyry sample, and one volcanic breccia sample yield weighted mean 206pb/23SU ages of 135.1±1.2 Ma, 116.5±1.1 Ma, 121.9±1.0 Ma, 118.1±0.9 Ma and 116.9±1.4 Ma, respectively. All these rocks have moderate (STSr/S6Sr)i values of 0.704912 to 0.705896, slightly negative eNd(t) values of -1.4 to -0.1, and positive Cur(t) values of 3.7 to 8. Their zircon Hf and whole-rock Nd isotopic model ages range from 594 to 1024 Ma. These results suggest that the Early Cretaceous volcanic rocks were originated from melting of subducted oceanic crust and associated sediments during the closure of the Mongol-Okhotsk Ocean. 展开更多
关键词 U-pb geochronology sr-nd-Hf isotopes volcanic rocks Early Cretaceous Da HingganMountains
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Devonian alkaline magmatism in the northern North China Craton:Geochemistry,SHRIMP zircon U-Pb geochronology and Sr-Nd-Hf isotopes 被引量:5
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作者 Dingling Huang Qingye Hou 《Geoscience Frontiers》 SCIE CAS CSCD 2017年第1期171-181,共11页
The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon... The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca.381.5 Ma.The rock is metaluminous with high(Na2O + K2O) values ranging from 8.46 to 9.66 wt.%.The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies.The Wulanhada rocks exhibit high initial values of(87Sr/86Sr)t = 0.70762-0.70809,low εNd(t) =-12.76 to-12.15 values and negative values of εHf(t) =-23.49 to-17.02 with small variations in(176Hf/177Hf),(0.281873-0.282049).These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC.The Wulanhada rocks,together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions,constitute a post-collisional magmatic belt along the northern NCC. 展开更多
关键词 North China Craton SHRIMP zircon geochronology sr-nd-pb-Hf isotopes Post-collisional magmatic belt Tectonics
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皖南伏岭A型花岗岩的成因——地球化学、锆石U-Pb年龄及Lu—Hf同位素特征
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作者 郑伟 陈天虎 +3 位作者 杜建国 陈芳 丁宁 张舒 《地质论评》 CAS CSCD 北大核心 2024年第1期189-206,共18页
伏岭花岗岩体,位于江南造山带东段的皖浙相邻区,岩浆岩沿着近北东向的宁国—绩溪深大断裂断分布。笔者等对伏岭岩体鱼龙川(γ_(5)^(3-2))单元花岗岩开展了系统的全岩岩石地球化学、LA-ICPMS锆石U-Pb同位素年龄和锆石原位Lu—Hf同位素地... 伏岭花岗岩体,位于江南造山带东段的皖浙相邻区,岩浆岩沿着近北东向的宁国—绩溪深大断裂断分布。笔者等对伏岭岩体鱼龙川(γ_(5)^(3-2))单元花岗岩开展了系统的全岩岩石地球化学、LA-ICPMS锆石U-Pb同位素年龄和锆石原位Lu—Hf同位素地球化学研究,结果表明,花岗岩的侵位年龄为131.8±0.9 Ma,富硅、富碱、贫钙、贫铁,具有较高的Rb、Th、U、Ga、Zr和Y含量,较低的Sr、Ba和Nb含量,稀土配分曲线呈现典型的“海鸥式”分布特征,显示强烈的负Eu异常;微量元素原始地幔标准化蛛网图显示明显的Ba、Sr、Nb的负异常。其高SiO_(2)含量和Rb/Sr值、低Ba、Sr含量具备江南造山带东段皖南地区A型花岗岩的典型特征。岩体具有同源岩浆演化特征,源区可能存在磷灰石、钛铁矿的分离结晶作用,而辉石类的分离较少。伏岭岩体主要来源于地壳中镁铁质岩石的部分熔融,其地球化学特征继承于源岩。锆石ε_(Hf)(t)变化范围较小,均在-7.0~-4.6之间,二阶段模式年龄(TDM2)为1478~1630 Ma,伏岭花岗岩可能由中元古代古老下地壳部分熔融形成。伏岭岩体的形成可能受到碰撞作用的影响,岩体形成于后碰撞期,中元古代的基底岩石被大范围的熔融,从而产生了伏岭A型花岗岩。 展开更多
关键词 伏岭 A型花岗岩 岩石地球化学 锆石U-pb年龄 Lu—Hf同位素 构造环境 江南造山带 皖南
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伟晶岩中不同副矿物U-Pb同位素定年和示踪的问题与应用
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作者 蒋少涌 张浩翔 +4 位作者 刘思祺 李雯恬 尹燕梁 车玉滢 苏慧敏 《地质学报》 EI CAS CSCD 北大核心 2024年第5期1573-1599,共27页
定年和示踪一直是伟晶岩成岩成矿过程和稀有金属富集机制研究的关键问题。副矿物不仅是伟晶岩中稀有稀土元素的重要载体,还蕴含丰富的微量元素并常常具有较高的U-Th含量,是研究伟晶岩年代学、成岩成矿过程和物质源区的“理想探针”。伟... 定年和示踪一直是伟晶岩成岩成矿过程和稀有金属富集机制研究的关键问题。副矿物不仅是伟晶岩中稀有稀土元素的重要载体,还蕴含丰富的微量元素并常常具有较高的U-Th含量,是研究伟晶岩年代学、成岩成矿过程和物质源区的“理想探针”。伟晶岩中常用的适合于U-Pb同位素定年的副矿物有锆石、铌钽铁矿、独居石、锡石、榍石、褐帘石、磷钇矿和磷灰石等。由于封闭温度、矿物学特性和不同性质流体中元素行为的差异,伟晶岩中不同副矿物的U-Pb系统常表现出复杂的年龄谱系,可能记录了伟晶岩中潜在的后期地质过程,如:自交代、后期变质与流体改造等。因此,基于前期光学显微镜、扫描电镜、冷阴极发光、激光拉曼光谱分析等矿物微观结构研究,对不同期次或世代的副矿物进行原位微区U-Pb定年及主微量元素和同位素地球化学分析,对于全面认知多期地质事件和伟晶岩成岩成矿过程演化历史,进而更准确地构建其构造-岩浆-热液-成矿作用时空框架具有重要的科学意义。 展开更多
关键词 伟晶岩 副矿物 U-pb同位素定年 地球化学示踪
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辽东地区赛马碱性杂岩锆石U-Pb年龄、Hf同位素组成及其对构造背景的制约
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作者 杨凤超 宋运红 +2 位作者 胥嘉 顾玉超 杨宏智 《地质通报》 CAS CSCD 北大核心 2024年第1期76-85,共10页
通过LA-ICP-MS测得辽宁赛马地区浅肉红色霞霓正长岩中的锆石U-Pb年龄为225.8±1.9 Ma,赛马碱性杂岩的侵位时代为晚三叠世。地球化学分析表明,霞霓正长岩SiO_(2)含量为55.87%~60.88%,Na_(2)O为0.41%~5.32%,Al_(2)O_(3)为17.81%~19.53... 通过LA-ICP-MS测得辽宁赛马地区浅肉红色霞霓正长岩中的锆石U-Pb年龄为225.8±1.9 Ma,赛马碱性杂岩的侵位时代为晚三叠世。地球化学分析表明,霞霓正长岩SiO_(2)含量为55.87%~60.88%,Na_(2)O为0.41%~5.32%,Al_(2)O_(3)为17.81%~19.53%,K_(2)O为9.46%~11.91%,MgO为0.46%~1.36%,里特曼指数为7.54~17.01;稀土元素总量较高,高于300×10^(-6),强烈富集轻稀土元素,(La/Yb)N值大于10,个别达到100以上;亏损Nb、Ta、P等高场强元素,富集Rb、Th等大离子亲石元素,总体表现出富碱性岩石特征。锆石ε_(Hf)(t)值为-13.37~-9.30,对应的两阶段Hf模式年龄T_(DM2)为2102~1855 Ma。通过岩石成因分析和构造环境判别,赛马碱性杂岩可能形成于由俯冲挤压向陆内伸展、拉张转换的动力背景下的下地壳(或上地幔)部分熔融。赛马碱性杂岩侵位时代(225.8±1.9 Ma)可能代表了华北克拉通北缘岩石圈开始伸展减薄的时间,也是郯庐断裂形成的时间。 展开更多
关键词 LA-ICP-MS U-pb年龄 HF同位素组成 晚三叠世 赛马碱性杂岩 辽东地区
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赣南铁山垅钨矿田花岗斑岩地球化学特征、锆石U-Pb年龄及Hf同位素特征
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作者 李伟 唐菊兴 +3 位作者 鲁捷 郭娜 袁慧香 连敦梅 《地质论评》 CAS CSCD 北大核心 2024年第1期175-188,共14页
赣南铁山垅钨矿田位于南岭钨锡多金属成矿带东段,已探获黑钨矿资源量超10万吨。铁山垅复式岩体包括主体似斑状黑云母花岗岩和补体细粒二云母花岗岩两部分,花岗斑岩呈脉状分布。矿田内花岗岩具有相似的地球化学特征,都属过铝质高钾钙碱... 赣南铁山垅钨矿田位于南岭钨锡多金属成矿带东段,已探获黑钨矿资源量超10万吨。铁山垅复式岩体包括主体似斑状黑云母花岗岩和补体细粒二云母花岗岩两部分,花岗斑岩呈脉状分布。矿田内花岗岩具有相似的地球化学特征,都属过铝质高钾钙碱性花岗岩类,表现出高硅、富铝、富碱、高钾、富成矿元素(W、Sn、Cu、Mo)和亏损Ba、Sr、Ti、P、REE、Eu,稀土配分曲线呈典型的“海鸥式”分布和M型四分组效应等特征。利用LA-ICP-MS锆石U-Pb定年方法获得花岗斑岩^(206)Pb/^(238)U年龄为146.7±0.5 Ma(MSDW=0.5),成岩时代属晚侏罗世。锆石的n(^(176)Lu)/n(^(177)Hf)=0.000973~0.001989,f_(Lu/Hf)=-0.97~-0.94,ε_(Hf)(t)=-17.9~-10.3,二阶段模式年龄(TDM2)为1.86~2.33 Ga,显示原岩为古元古代地壳。综合分析认为,铁山垅矿田岩浆活动可划分为170~155 Ma、155~150 Ma、150~145 Ma三个阶段,钨锡矿成矿主要集中在第二阶段,且第三阶段花岗斑岩与铜多金属矿成矿关系密切,推测铜岭矿区深部具有较大的找矿前景。 展开更多
关键词 铁山垅钨矿田 花岗斑岩 岩石地球化学特征 锆石U-pb年龄 Lu—Hf同位素 赣南
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南秦岭土地岭早古生代粗面质火山岩成因:来自锆石U-Pb年龄、元素及Sr-Nd同位素证据 被引量:1
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作者 周豹 王飞 +5 位作者 李一鸣 鲁显松 熊意林 魏四华 杨振 刘锐 《大地构造与成矿学》 EI CAS CSCD 北大核心 2023年第3期681-694,共14页
南秦岭土地岭地区火山岩因富含铌钽等稀有金属元素而受到广泛关注,但目前对该类火山岩成因的研究还较为薄弱。通过对土地岭典型粗面质火山岩进行锆石U-Pb年代学、主‒微量元素及Sr-Nd同位素地球化学研究,探讨岩石成因及成岩构造背景。土... 南秦岭土地岭地区火山岩因富含铌钽等稀有金属元素而受到广泛关注,但目前对该类火山岩成因的研究还较为薄弱。通过对土地岭典型粗面质火山岩进行锆石U-Pb年代学、主‒微量元素及Sr-Nd同位素地球化学研究,探讨岩石成因及成岩构造背景。土地岭富铌钽火山岩主要岩石类型有霓石粗面岩、含晶屑粗面质凝灰熔岩、晶屑粗面质熔结凝灰岩、粗面质晶屑凝灰岩及沉凝灰岩。LA-ICP-MS锆石U-Pb定年表明,该火山岩成岩年龄为445±10 Ma,形成于早志留世。地球化学特征表明,火山岩样品具高硅(SiO_(2)=55.97%~66.71%)富碱(K_(2)O+Na_(2)O=8.64%~16.74%)的特征,为一套碱性火山岩;轻稀土元素显示相对富集特征((La/Yb)N=11.2~93.6)。火山岩(87Sr/^(86)Sr)i主体为0.7034~0.7057,ε_(Nd)(t)值为2.2~2.7,相应的Nd模式年龄tDM为0.77~0.89 Ga。土地岭火山岩Sr-Nd同位素组成具有洋岛玄武岩(OIB)特征,可能来自于HIMU,EMⅠ和EMⅡ的混合源区。结合其较高的Nb/U值(10.8~106.1)以及主量元素CaO、MgO、Fe_(2)O)(3)^(T)、TiO_(2)与SiO_(2)均显示负相关关系特征,土地岭赋矿火山岩应该为富集地幔来源岩浆结晶分异作用的产物,可能形成于早古生代华南板块北缘的被动大陆边缘环境。 展开更多
关键词 锆石U-pb年龄 元素地球化学 sr-nd同位素 富铌钽火山岩 土地岭 南秦岭
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东昆仑浪木日镁铁质-超镁铁质岩成因:锆石U-Pb年代学和Sr-Nd-Hf同位素特征 被引量:1
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作者 张斌武 于淼 +2 位作者 杨牧 张琛明 陈海福 《矿床地质》 CAS CSCD 北大核心 2023年第1期211-228,共18页
浪木日镁铁质-超镁铁质岩体位于东昆仑造山带东段,临近昆中断裂,主要由橄榄岩、橄榄辉石岩、辉石岩和辉长岩组成,且局部发育星点状和浸染状硫化物矿化。辉石岩和橄榄辉石岩获得的锆石U-Pb年龄分别为(421.2±1.2)Ma和(421.10±0.... 浪木日镁铁质-超镁铁质岩体位于东昆仑造山带东段,临近昆中断裂,主要由橄榄岩、橄榄辉石岩、辉石岩和辉长岩组成,且局部发育星点状和浸染状硫化物矿化。辉石岩和橄榄辉石岩获得的锆石U-Pb年龄分别为(421.2±1.2)Ma和(421.10±0.96)Ma,表明岩体侵位于晚志留世。岩石地球化学特征显,浪木日镁铁质-超镁铁质岩具有较高的Mg#(Mg#>80),富集LILE(Rb、Th、U等),亏损HFSE(Nb、Ta、Ti等),轻、重稀土元素分馏程度较强((La/Yb)N=6.28~50.91,(La/Sm)N=1.45~4.15,(Gd/Yb)N=1.43~9.71),具有弱的负Eu异常(δEu=0.226~0.824)。锆石Lu-Hf(εHf(t)=-2.9~-10)和全岩Sr-Nd(εNd(t)=-10.3~-8.9)同位素特征显示,其岩浆源区主要来自富集地幔,与俯冲洋壳脱水交代上覆地幔楔活动有关。综合研究表明,浪木日镁铁质-超镁铁质岩体是原特提斯洋洋壳俯冲晚期的产物,随着俯冲的深入,板片最终断离形成板片窗,导致软流圈上涌促使地幔楔发生部分熔融形成镁铁质-超镁铁质岩浆,岩浆上升过程中与地壳发生混染最终形成浪木日岩体。 展开更多
关键词 地球化学 镁铁质-超镁铁质岩体 锆石U-pb年代学 sr-nd-HF同位素 浪木日 东昆仑
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东秦岭伟晶岩型高纯石英矿地球化学、锆石U-Pb及Hf同位素研究:对高纯石英找矿方向的探讨 被引量:1
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作者 赵海波 王红杰 +2 位作者 张勇 马驰 朱黎宽 《中国地质》 CAS CSCD 北大核心 2024年第1期42-56,共15页
[研究目的]高纯石英是战略性新兴产业的关键基础材料,是世界稀缺的战略性矿产资源。目前美国以Spruce-Pine花岗伟晶岩作为原料生产的4N8及以上高端石英砂产品几乎垄断国际市场。东秦岭4N级伟晶岩型高纯石英矿点的发现为研究高纯石英形... [研究目的]高纯石英是战略性新兴产业的关键基础材料,是世界稀缺的战略性矿产资源。目前美国以Spruce-Pine花岗伟晶岩作为原料生产的4N8及以上高端石英砂产品几乎垄断国际市场。东秦岭4N级伟晶岩型高纯石英矿点的发现为研究高纯石英形成机制、实现找矿突破和建立成矿模型提供了难得的机遇。[研究方法]通过对东秦岭新发现的伟晶岩型高纯石英矿点开展野外调查,并与美国Spruce-Pine高纯石英矿床伟晶岩开展岩石地球化学、锆石U-Pb同位素年代学和Hf同位素等方面的对比研究。[研究结果]东秦岭10号高纯石英矿形成于早泥盆世,锆石U-Pb年龄为(406.8±0.8)Ma,稍早于美国Spruce-Pine的高纯石英花岗伟晶岩形成时代。东秦岭高纯石英矿点伟晶岩与美国Spruce-Pine高纯石英矿床伟晶岩形成温度均为600℃左右。东秦岭高纯石英矿点伟晶岩与美国Spruce-Pine高纯石英矿床伟晶岩具有相似的岩石地球化学特征,表现I型花岗岩和高分异演化特征,源区物质来源既有下地壳,也有幔源物质。仅通过对东秦岭高纯石英矿点伟晶岩和灰池子花岗岩体空间关系、形成时代和岩石地球化学特征,是不足以完全反演源区特征及成岩成矿过程,对于东秦岭高纯石英矿点伟晶岩和灰池子花岗岩体是否存在同源演化仍需要进一步研究。[结论]东秦岭与美国Spruce-Pine高纯石英矿床在花岗岩类型、岩浆特征和形成温度等方面具有相似性,为进一步揭示高纯石英成矿地质背景和实现找矿突破提供理论依据。 展开更多
关键词 岩石地球化学 锆石U-pb HF同位素 高纯石英 伟晶岩 矿产勘查工程 东秦岭
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湘西沃溪金锑钨矿床燕山期幕式成矿作用:来自原位白钨矿U-Pb定年与黄铁矿元素-同位素的约束 被引量:1
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作者 李彬 许德如 +5 位作者 柏道远 陈旭 邹少浩 代俊峰 马文 曾广乾 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第1期215-240,共26页
沃溪矿床位于江南造山带中段,是一座同时具有金、锑、钨大规模成矿的大型金矿,近年的研究揭示其主要形成于燕山期,但该矿的成矿物质源区及矿床成因尚存争议。基于此,本文利用SEM、EPMA、LA-MC-IF-ICP-MS等原位分析技术,对该矿床多世代... 沃溪矿床位于江南造山带中段,是一座同时具有金、锑、钨大规模成矿的大型金矿,近年的研究揭示其主要形成于燕山期,但该矿的成矿物质源区及矿床成因尚存争议。基于此,本文利用SEM、EPMA、LA-MC-IF-ICP-MS等原位分析技术,对该矿床多世代黄铁矿的结构、成分及同位素组成和成矿期白钨矿的U-Pb年代学进行了研究。在沃溪矿床中,识别出3个世代5种类型黄铁矿(Py),即成矿前Py1,成矿第二阶段Py2和第三阶段的Py3a、Py3b和Py3c。黄铁矿微区成分及围岩蚀变特征指示,成矿期Au、As和Cu耦合,Au主要以固溶体(Au+)的形式存在于Py3b的晶格中;As-取代S-进入黄铁矿是促进晶格金富集的主要因素;而强烈的水-岩反应是导致成矿期热液黄铁矿Co/Ni<1的原因。黄铁矿的原位微量元素和S-Pb同位素组成(δ34 S V-CDT值:Py2为-4.33‰~-1.61‰,Py3a为-6.36‰~3.59‰,Py3b为-4.36‰~3.59‰,Py3c为-2.21‰~-0.65‰;206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb值:Py2分别为18.029、15.618和38.653,Py3a分别为18.047~18.341、15.594~15.698、38.781~39.394)及其在环带结构中的变化,指示第二及第三成矿阶段流体性质存在显著差异。成矿第三阶段白钨矿的LA-ICP-MS U-Pb定年结果为132.7±7.9Ma(1σ,n=31,MSWD=0.43)。结合前人研究成果,我们认为沃溪金锑钨矿床主要形成于燕山期148~140Ma的黑钨矿(少量白钨矿、黄铁矿和金)和~130Ma的金-锑-白钨矿两阶段幕式成矿作用。早阶段成矿为下伏基底岩石重熔岩浆演化出的相对高温的还原性流体;晚阶段金-锑-白钨矿成矿以脉冲性幔源流体为主,金主要具地幔来源,而锑和钨可能来源于壳源与幔源流体混合演化出的富矿热液,成矿的脉动性可能与深部断层阀机制有关。金的主要沉淀机制为水岩反应和硫化作用,流体混合是辉锑矿与白钨矿的沉淀机制。富集交代的岩石圈地幔活化和古太平洋板块俯冲后撤、拆沉导致的岩石圈大规模伸展是江南造山带中段(湖南)燕山晚期金多金属大规模成矿的关键因素及构造背景,区域上具有进一步寻找陆内弧后伸展背景金多金属矿床的潜力。 展开更多
关键词 江南造山带 沃溪Au-Sb-W矿 白钨矿U-pb定年 黄铁矿 S-pb同位素
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热电离质谱计测定国家标准火成岩粉末Sr-Nd-Pb同位素组成
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作者 王智毅 程泓 +4 位作者 赵静欣 叶日胜 李为用 贺剑峰 陈福坤 《高校地质学报》 CAS CSCD 北大核心 2023年第5期679-692,共14页
文章以美国地质调查局制备的标准岩石粉末(BCR-2玄武岩、BHVO-2玄武岩、AGV-2安山岩)作为参考物质,运用同位素稀释法和热电离质谱计同位素比值测量方法,分析中国三种火成岩标准粉末(GSR-1花岗岩、GSR-2安山岩、GSR-3玄武岩)Sr-Nd-Pb同... 文章以美国地质调查局制备的标准岩石粉末(BCR-2玄武岩、BHVO-2玄武岩、AGV-2安山岩)作为参考物质,运用同位素稀释法和热电离质谱计同位素比值测量方法,分析中国三种火成岩标准粉末(GSR-1花岗岩、GSR-2安山岩、GSR-3玄武岩)Sr-Nd-Pb同位素组成,观察其同位素组成及均一性特征。分析结果表明:这三种火成岩岩石标准粉末都具有均一的Sr和Nd同位素组成;相比GSR-1花岗岩,GSR-2安山岩和GSR-3玄武岩的Pb同位素组成相对均一。GSR-1花岗岩的Pb同位素组成有较大的变化范围,不均一性特征可能受高U和高Th矿物的放射性成因Pb同位素组成叠加影响。根据测量结果,作者认为三种国家火成岩标准粉末适合作为Sr和Nd同位素组成分析的参考物质,GSR-2安山岩和GSR-3玄武岩也是理想的Pb同位素组成分析的参考物质。 展开更多
关键词 标准岩石粉末 GSR-1花岗岩 GSR-2安山岩 GSR-3玄武岩 sr-nd-pb同位素
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The complexity of sediment recycling as revealed by common Pb isotopes in K-feldspar 被引量:6
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作者 Simon P.Johnson Christopher L.Kirkland +2 位作者 Noreen J.Evans Brad J.McDonald Huntly N.Cutten 《Geoscience Frontiers》 SCIE CAS CSCD 2018年第5期1515-1527,共13页
Detrital zircon U-Pb geochronology has become the gold standard in evaluating source to sink relationships in sedimentary basins. However, the physical and chemical robustness of zircon, which make it such a useful mi... Detrital zircon U-Pb geochronology has become the gold standard in evaluating source to sink relationships in sedimentary basins. However, the physical and chemical robustness of zircon, which make it such a useful mineral for provenance studies, is also a hindrance as zircon can be recycled through numerous sedimentary basins, thus obscuring the first cycle source to sink relationship. An elegant approach to addressing this potential issue is to compare the Pb isotope composition of detrital K-feldspar, a mineral which is unlikely to survive more than one erosion-transport-deposition cycle, with that of magmatic K-feldspar from potential basement source terranes. Here we present new in situ Pb isotope data on detrital K-feldspar from two Proterozoic arkosic sandstones from Western Australia, and magmatic K-feldspar grains from potential igneous source rocks, as inferred by the age and Hf isotope composition of detrital zircon grains. The data indicate that the detrital zircon and K-feldspar grains could not have been liberated from the same source rocks, and that the zircon has most likely been recycled through older sedimentary basins. These results provide a more complete understanding of apparently simple source to sink relationships in this part of Proterozoic Western Australia. 展开更多
关键词 DETRITAL ZIRCON K-FELDSPAR pb isotopes SEDIMENT PROVENANCE SEDIMENT RECYCLING
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