Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb...Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb isotopic composition of feldspar hosted in granitic rocks(thirteen Archean and one Paleoproterozoic)from the northern Kongling terrane,Yangtze Craton,South China,is analyzed.The samples reveal a substantial variation in their Pb isotopic composition,spanning the gap between the 1.9 Ga and present-day geochrons,which indicates extensive resetting by later tectonothermal events.This resetting was interpreted to have likely resulted from Paleoproterozoic and Neoproterozoic tectonothermal events related to the assembly and breakup of the Columbia and Rodinia supercontinents.These results suggest that Pb isotopes should be used cautiously when tracing magma sources and petrogenesis in magmatic rocks that have experienced post-magmatic reworking.However,the in situ Pb isotopic composition of feldspar in ancient granitoids may also potentially be used to reveal later tectonothermal events.The extensive resetting of the Pb isotopic composition in feldspar by regional thermal events may also provide new insights into our understanding of the Pb isotope paradox.展开更多
The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to colli...The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to collision.However,the late Paleozoic tectonic evolutionary history,especially for the time of the ocean-continent transition,is still debated although the origin and tectonic settings for the Paleozoic volcanic,felsic igneous magmatism in TO and reginal geology have been done in the last decades.In contrast,the researches on the mafic dykes in TO was not systematically carried out till now.Reginal-scale mafic dykes are commonly regarded as the products created in a extensional setting,and used to identify the major tectonic events such as rifting and continental break-up and further trace the mantle natures and geodynamic mechanism(Halls,1982;Bleeker and Ernst,2006;Li et al.,2008;Ernst et al.,2010;Srivastava,2011;Hou,2012;Peng,2015;Peng et al.,2019).There are widespread late Paleozoic mafic dykes beside the huge of intermediate-acid igneous rocks in the TO,being an idea object to reveal the extensional events,tectonic evolution and the mantle nature and geodynamic processes.We present the ICPMS in situ zircon U–Pb dating,Lu-Hf and whole-rock Sr-Nd isotopes as well as the geochemistry data for these mafic dykes to better constraint their petrogenesis and mantle nature.New zircon U-Pb dating for 12 samples from the representative basic dykes and basalts yield three distinct stages of^332 Ma,316–302 Ma and 288–282 Ma,respectively.In which,the first stage of mafic dykes is mainly occurred in both East Tianshan Orogen(ETO)and West Tianshan Orogen(WTO),and composed of dolerite with minor basalts.The second stage of mafic dyke also can be found in both ETO and WTO.However,in contrast to the first stage of mafic dykes,they have relatively variable rock types from the dolerite/or gabbros to gabbroic diorite.The third stage of mafic dykes are slightly intermediate in composition,and chiefly consist of andesitic-basaltic dolerite with some diorites.They are widely developed not only in both ETO and WTO,but also in the Beishan area to the east of the ETO,indicating a large-scale mafic magmatism in Tianshan and adjacent areas.展开更多
The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range, NE China. Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite. Sr...The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range, NE China. Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite. Sr-Nd-Pb isotopes of the intrusions show that the porphyritic syenogranite has initial ^87Sr/^86Sr ratios of 0.70418-0.70952, ENd(t) values of 1.3 to 2.1 (t=143 Ma), ^206Pb/^204Pb ratios of 19.191-19.573, ^207Tpb/^204pb ratios of 15.551-15.572, and ^208Pb/^204Pb ratios of 38.826-39.143. The monzogranite has initial 87Sr/86Sr ratios of 0.70293-0.71305, εNd(t) values of 1.1 to 2.0 (t=-147 Ma), ^206Pb/^204pb ratios of 19.507-20.075, ^207Pb/^204Pb ratios of 15.564-15.596, and ^208Pb/^204Pb ratios of 39.012-39.599. The calculated Nd model ages (TDM) for monzogranite and porphyritic syenogranite range from 866 to 1121 Ma and 795 to 1020 Ma, respectively. The granitic rocks in the Hashitu area have the same isotope range as granites in the southern parts of the Great Hinggan Range. The isotope composition indicates that these granites are derived from the partial melting of a juvenile lower crust originating from a depleted mantle with minor contamination by ancient continental crust. The integrating our results with published data and the Late Mesozoic regional tectonic setting of the region suggest that the granites in the Hashitu area formed in an intra-continent extensional setting, and they are related to the thinning of the thickened lithosphere and upwelling of the asthenosphere.展开更多
The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small u...The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian (426-422 Ma), and their zircons have ~Hf(t) values of-9.4 to 5.9 with the older TDMm ages (0.80-1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements (e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements (e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle (0 ~ 2%o). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.展开更多
Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high S...Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high SiO2 (73.19-77.68 wt%) and Na20+K20 (6.53-8.98 wt%) contents, with enrichment in Rb, Th, U, Pb and LREE, and depletion in Nb, Ta, P and Ti. Three rhyolite samples, one rhyolite porphyry sample, and one volcanic breccia sample yield weighted mean 206pb/23SU ages of 135.1±1.2 Ma, 116.5±1.1 Ma, 121.9±1.0 Ma, 118.1±0.9 Ma and 116.9±1.4 Ma, respectively. All these rocks have moderate (STSr/S6Sr)i values of 0.704912 to 0.705896, slightly negative eNd(t) values of -1.4 to -0.1, and positive Cur(t) values of 3.7 to 8. Their zircon Hf and whole-rock Nd isotopic model ages range from 594 to 1024 Ma. These results suggest that the Early Cretaceous volcanic rocks were originated from melting of subducted oceanic crust and associated sediments during the closure of the Mongol-Okhotsk Ocean.展开更多
The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon...The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca.381.5 Ma.The rock is metaluminous with high(Na2O + K2O) values ranging from 8.46 to 9.66 wt.%.The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies.The Wulanhada rocks exhibit high initial values of(87Sr/86Sr)t = 0.70762-0.70809,low εNd(t) =-12.76 to-12.15 values and negative values of εHf(t) =-23.49 to-17.02 with small variations in(176Hf/177Hf),(0.281873-0.282049).These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC.The Wulanhada rocks,together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions,constitute a post-collisional magmatic belt along the northern NCC.展开更多
Detrital zircon U-Pb geochronology has become the gold standard in evaluating source to sink relationships in sedimentary basins. However, the physical and chemical robustness of zircon, which make it such a useful mi...Detrital zircon U-Pb geochronology has become the gold standard in evaluating source to sink relationships in sedimentary basins. However, the physical and chemical robustness of zircon, which make it such a useful mineral for provenance studies, is also a hindrance as zircon can be recycled through numerous sedimentary basins, thus obscuring the first cycle source to sink relationship. An elegant approach to addressing this potential issue is to compare the Pb isotope composition of detrital K-feldspar, a mineral which is unlikely to survive more than one erosion-transport-deposition cycle, with that of magmatic K-feldspar from potential basement source terranes. Here we present new in situ Pb isotope data on detrital K-feldspar from two Proterozoic arkosic sandstones from Western Australia, and magmatic K-feldspar grains from potential igneous source rocks, as inferred by the age and Hf isotope composition of detrital zircon grains. The data indicate that the detrital zircon and K-feldspar grains could not have been liberated from the same source rocks, and that the zircon has most likely been recycled through older sedimentary basins. These results provide a more complete understanding of apparently simple source to sink relationships in this part of Proterozoic Western Australia.展开更多
基金supported by the Key Laboratory of Gold Mineralization Processes and Resource Utilization,MNRShandong Provincial Key Laboratory of Metallogenic Geological Process and Resource Utilization(Grant No.KFKT202103)National Natural Science Foundation of China(Grant No.41876037)。
文摘Feldspar Pb isotopes have been widely used to trace magmatic formation and evolution processes.However,it remains unclear whether post-magmatic thermal events can affect feldspar Pb isotopic ratios.Here,the in situ Pb isotopic composition of feldspar hosted in granitic rocks(thirteen Archean and one Paleoproterozoic)from the northern Kongling terrane,Yangtze Craton,South China,is analyzed.The samples reveal a substantial variation in their Pb isotopic composition,spanning the gap between the 1.9 Ga and present-day geochrons,which indicates extensive resetting by later tectonothermal events.This resetting was interpreted to have likely resulted from Paleoproterozoic and Neoproterozoic tectonothermal events related to the assembly and breakup of the Columbia and Rodinia supercontinents.These results suggest that Pb isotopes should be used cautiously when tracing magma sources and petrogenesis in magmatic rocks that have experienced post-magmatic reworking.However,the in situ Pb isotopic composition of feldspar in ancient granitoids may also potentially be used to reveal later tectonothermal events.The extensive resetting of the Pb isotopic composition in feldspar by regional thermal events may also provide new insights into our understanding of the Pb isotope paradox.
基金co-funded by the Land and Resources Survey Project of China(Grant no.12120113042200)National Natural Science Foundation of China(41421002)the MOST Special Fund from State Key Laboratory of Continental Dynamics,Northwest University(201210133)
文摘The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to collision.However,the late Paleozoic tectonic evolutionary history,especially for the time of the ocean-continent transition,is still debated although the origin and tectonic settings for the Paleozoic volcanic,felsic igneous magmatism in TO and reginal geology have been done in the last decades.In contrast,the researches on the mafic dykes in TO was not systematically carried out till now.Reginal-scale mafic dykes are commonly regarded as the products created in a extensional setting,and used to identify the major tectonic events such as rifting and continental break-up and further trace the mantle natures and geodynamic mechanism(Halls,1982;Bleeker and Ernst,2006;Li et al.,2008;Ernst et al.,2010;Srivastava,2011;Hou,2012;Peng,2015;Peng et al.,2019).There are widespread late Paleozoic mafic dykes beside the huge of intermediate-acid igneous rocks in the TO,being an idea object to reveal the extensional events,tectonic evolution and the mantle nature and geodynamic processes.We present the ICPMS in situ zircon U–Pb dating,Lu-Hf and whole-rock Sr-Nd isotopes as well as the geochemistry data for these mafic dykes to better constraint their petrogenesis and mantle nature.New zircon U-Pb dating for 12 samples from the representative basic dykes and basalts yield three distinct stages of^332 Ma,316–302 Ma and 288–282 Ma,respectively.In which,the first stage of mafic dykes is mainly occurred in both East Tianshan Orogen(ETO)and West Tianshan Orogen(WTO),and composed of dolerite with minor basalts.The second stage of mafic dyke also can be found in both ETO and WTO.However,in contrast to the first stage of mafic dykes,they have relatively variable rock types from the dolerite/or gabbros to gabbroic diorite.The third stage of mafic dykes are slightly intermediate in composition,and chiefly consist of andesitic-basaltic dolerite with some diorites.They are widely developed not only in both ETO and WTO,but also in the Beishan area to the east of the ETO,indicating a large-scale mafic magmatism in Tianshan and adjacent areas.
基金part of the ongoing project "Superimposed tectonic activities and large-scale oreforming processes of the Hinggan-Mongolia Orogenic Belt"financially supported by the State Basic Research Program of China(2013CB429805)
文摘The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range, NE China. Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite. Sr-Nd-Pb isotopes of the intrusions show that the porphyritic syenogranite has initial ^87Sr/^86Sr ratios of 0.70418-0.70952, ENd(t) values of 1.3 to 2.1 (t=143 Ma), ^206Pb/^204Pb ratios of 19.191-19.573, ^207Tpb/^204pb ratios of 15.551-15.572, and ^208Pb/^204Pb ratios of 38.826-39.143. The monzogranite has initial 87Sr/86Sr ratios of 0.70293-0.71305, εNd(t) values of 1.1 to 2.0 (t=-147 Ma), ^206Pb/^204pb ratios of 19.507-20.075, ^207Pb/^204Pb ratios of 15.564-15.596, and ^208Pb/^204Pb ratios of 39.012-39.599. The calculated Nd model ages (TDM) for monzogranite and porphyritic syenogranite range from 866 to 1121 Ma and 795 to 1020 Ma, respectively. The granitic rocks in the Hashitu area have the same isotope range as granites in the southern parts of the Great Hinggan Range. The isotope composition indicates that these granites are derived from the partial melting of a juvenile lower crust originating from a depleted mantle with minor contamination by ancient continental crust. The integrating our results with published data and the Late Mesozoic regional tectonic setting of the region suggest that the granites in the Hashitu area formed in an intra-continent extensional setting, and they are related to the thinning of the thickened lithosphere and upwelling of the asthenosphere.
基金financially supported by the National Natural Science Foundation of China(No.41272093)China geological survey project(No.12120114080901)
文摘The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian (426-422 Ma), and their zircons have ~Hf(t) values of-9.4 to 5.9 with the older TDMm ages (0.80-1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements (e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements (e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle (0 ~ 2%o). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.
基金supported by the resource compensation of Heilongjiang Province(Grant Nos.SDK2010-25)the Special Scientific Research Fund of Public Welfare Profession of China(Grant Nos.201211008)
文摘Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high SiO2 (73.19-77.68 wt%) and Na20+K20 (6.53-8.98 wt%) contents, with enrichment in Rb, Th, U, Pb and LREE, and depletion in Nb, Ta, P and Ti. Three rhyolite samples, one rhyolite porphyry sample, and one volcanic breccia sample yield weighted mean 206pb/23SU ages of 135.1±1.2 Ma, 116.5±1.1 Ma, 121.9±1.0 Ma, 118.1±0.9 Ma and 116.9±1.4 Ma, respectively. All these rocks have moderate (STSr/S6Sr)i values of 0.704912 to 0.705896, slightly negative eNd(t) values of -1.4 to -0.1, and positive Cur(t) values of 3.7 to 8. Their zircon Hf and whole-rock Nd isotopic model ages range from 594 to 1024 Ma. These results suggest that the Early Cretaceous volcanic rocks were originated from melting of subducted oceanic crust and associated sediments during the closure of the Mongol-Okhotsk Ocean.
基金supported by the SinoProbe 04-02,Natural Science Foundation of China(40603011)Government's Scientific Research Foundation of Inner Mongolia(05-6-YS2)
文摘The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca.381.5 Ma.The rock is metaluminous with high(Na2O + K2O) values ranging from 8.46 to 9.66 wt.%.The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies.The Wulanhada rocks exhibit high initial values of(87Sr/86Sr)t = 0.70762-0.70809,low εNd(t) =-12.76 to-12.15 values and negative values of εHf(t) =-23.49 to-17.02 with small variations in(176Hf/177Hf),(0.281873-0.282049).These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC.The Wulanhada rocks,together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions,constitute a post-collisional magmatic belt along the northern NCC.
基金funded via an Australian Geophysical Observing System grant provided to Au Scope Pty Ltd.the AQ44 Australian Education Investment Fund programpartly funded by the Western Australian Exploration Incentive Scheme
文摘Detrital zircon U-Pb geochronology has become the gold standard in evaluating source to sink relationships in sedimentary basins. However, the physical and chemical robustness of zircon, which make it such a useful mineral for provenance studies, is also a hindrance as zircon can be recycled through numerous sedimentary basins, thus obscuring the first cycle source to sink relationship. An elegant approach to addressing this potential issue is to compare the Pb isotope composition of detrital K-feldspar, a mineral which is unlikely to survive more than one erosion-transport-deposition cycle, with that of magmatic K-feldspar from potential basement source terranes. Here we present new in situ Pb isotope data on detrital K-feldspar from two Proterozoic arkosic sandstones from Western Australia, and magmatic K-feldspar grains from potential igneous source rocks, as inferred by the age and Hf isotope composition of detrital zircon grains. The data indicate that the detrital zircon and K-feldspar grains could not have been liberated from the same source rocks, and that the zircon has most likely been recycled through older sedimentary basins. These results provide a more complete understanding of apparently simple source to sink relationships in this part of Proterozoic Western Australia.