According to the "Notice on OrganizationStructure of the State Council", the formerChina Patent Office was changed into StateIntellectual Property Office of P. R. China(SIPO). SIPO falls within the category ...According to the "Notice on OrganizationStructure of the State Council", the formerChina Patent Office was changed into StateIntellectual Property Office of P. R. China(SIPO). SIPO falls within the category ofdirect authorities under State Council and isresponsible for patent work andcomprehensively coordination of the foreignrelated affairs in the field of intellectualproperty.展开更多
A bound state formalism derived from a fermion-boson symmetric Lagrangian has been used to calculate the nucleon masses, the charge neutrality of the neutron, the magnetic moments and the electromagnetic form factor r...A bound state formalism derived from a fermion-boson symmetric Lagrangian has been used to calculate the nucleon masses, the charge neutrality of the neutron, the magnetic moments and the electromagnetic form factor ratios μpGEp/GMpand μnGEn/GMn. A quantitative description is obtained, assuming a mixing of a scalar bound state of 3(f f¯)fstructure with its corresponding vector (f f¯)fstate (f indicating massless elementary fermions). Only a few parameters are needed, mainly fixed by energy and momentum conservation. The nucleon stability is explained by an extra binding in the confinement potential, negative for electric and positive for magnetic binding of the proton, and opposite for the neutron. The stronger electric extra binding of the proton allows a decay of the neutron to proton and electron.展开更多
The electronic and superconducting properties of Fe_(1-δ)Se single-crystal flakes grown hydrothermally are studied by the transport measurements under zero and high magnetic fields up to 38.5 T.The results contrast s...The electronic and superconducting properties of Fe_(1-δ)Se single-crystal flakes grown hydrothermally are studied by the transport measurements under zero and high magnetic fields up to 38.5 T.The results contrast sharply with those previously reported for nematically ordered Fe Se by chemical-vapor-transport(CVT)growth.No signature of the electronic nematicity,but an evident metal-to-nonmetal crossover with increasing temperature,is detected in the normal state of the present hydrothermal samples.Interestingly,a higher superconducting critical temperature T_c of 13.2 K is observed compared to a suppressed T_c of 9 K in the presence of the nematicity in the CVT Fe Se.Moreover,the upper critical field in the zero-temperature limit is found to be isotropic with respect to the field direction and to reach a higher value of-42 T,which breaks the Pauli limit by a factor of 1.8.展开更多
A new coordination polymer, {[Cd(OPY)(tdc)(HO)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand OPY. ...A new coordination polymer, {[Cd(OPY)(tdc)(HO)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand OPY. The structure was fully characterized by elemental analysis, FT-IR spectroscopy, and X-ray single-crystal diffraction analysis. In1, two OPY ligands and one water molecule acted as terminal ligands coordinating to Cdcation to form [Cd(OPY)HO]units, which are then linked by tdc2-ligands to generate a one-dimensional chain. Every two adjacent chains linked by extensive O–H···O hydrogen bonds constitute one-dimensional double-chains, and such chains are extended into two-dimensional layers via O–H···N hydrogen bonds. These layers are further connected to form a three-dimensional supramolecular architecture via π-π stacking interactions. In addition, the thermal stability and solid state fluorescence property of 1 were also investigated.展开更多
PASCA, ESR and Microreactor, have been used to study the states and properties of coking deposits on catalyst. The results indicate that the C exists as three types of states on catalyst surface. The first and second ...PASCA, ESR and Microreactor, have been used to study the states and properties of coking deposits on catalyst. The results indicate that the C exists as three types of states on catalyst surface. The first and second types of carbon are the main reason of the catalyst deactivation, but the third type has a promoting role in n-C_7 hydrocracking reaction. The S_s-C interacts strongly with catalyst, forming metal-carbon-support interaction (MCSI).展开更多
Magneto-transport properties of insulating bulk states in Bi(111) films are systematically investigated under the parallel field (BⅡ). We find that the magnetotransport of the Bll field is a more powerful tool to...Magneto-transport properties of insulating bulk states in Bi(111) films are systematically investigated under the parallel field (BⅡ). We find that the magnetotransport of the Bll field is a more powerful tool to distinguish the bulk states and the surface states. A large magnetoresistance (MR) up to 20% in the BⅡ field is induced by the insulating bulk states for the suppression of the backward scattering. With the increasing thickness, a positive MR(BⅡ) from magnetic induced boundary scattering appears in the semimetal films. As the thickness is reduced to 1Ohm, the positive MR(BⅡ) is induced by weak anti-localization from the surface states.展开更多
In this paper, the volumetric properties of pure and mixture of ionic liquids are predicted using the developed statistical mechanical equation of state in different temperatures, pressures and mole fractions. The tem...In this paper, the volumetric properties of pure and mixture of ionic liquids are predicted using the developed statistical mechanical equation of state in different temperatures, pressures and mole fractions. The temperature dependent parameters of the equation of state have been calculated using corresponding state correlation based on only the density at 298.15 K as scaling constants. The obtained mean of deviations of modified equation of state for density of all pure ionic liquids for 1662 data points was 0.25%. In addition, the performance of the artificial neural network(ANN) with principle component analysis(PCA) based on back propagation training with28 neurons in hidden layer for predicting of behavior of binary mixtures of ionic liquids was investigated. The AADs of a collection of 568 data points for all binary systems using the EOS and the ANN at various temperatures and mole fractions are 1.03% and 0.68%, respectively. Moreover, the excess molar volume of all binary mixtures is predicted using obtained densities of EOS and ANN, and the results show that these properties have good agreement with literature.展开更多
Brownmillerite-type oxides Ba_2In_(2-x-y)Mn_xAl_yO_(5+x)(0 ≤ x ≤ 0.6, 0 ≤ y ≤ 0.5) were prepared at 1300°C through solid-state reaction. X-ray diffraction(XRD) analysis showed that the structure symm...Brownmillerite-type oxides Ba_2In_(2-x-y)Mn_xAl_yO_(5+x)(0 ≤ x ≤ 0.6, 0 ≤ y ≤ 0.5) were prepared at 1300°C through solid-state reaction. X-ray diffraction(XRD) analysis showed that the structure symmetry evolved from orthorhombic to cubic with increasing Mn and Al contents. When y was greater than 0.3, peaks associated with small amounts of BaAl_2O_4 and Ba_2InAlO_5 impurities were observed in the XRD patterns. When substituted with a small amount of Mn(x ≤ 0.3), the Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) samples exhibited an intense turquoise color. The color changed to green and dark-green with increasing Mn concentration. UV–vis absorbance spectra revealed that the color changed only slightly upon Al doping. The valence state of Mn ions in Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) was confirmed to be +5 on the basis of X-ray photoelectron spectroscopic analysis. According to this analysis, the intense turquoise color of the Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) samples is rooted in the existence of Mn^(5+); thus, the introduction of Al does not affect the optical properties of the compounds.展开更多
We present structural,magnetic and optical characteristics of Zn_(1-x)TM_xTe(TM = Mn,Fe,Co,Ni and x = 6.25%),calculated through Wien2 k code,by using full potential linearized augmented plane wave(FP-LAPW) techn...We present structural,magnetic and optical characteristics of Zn_(1-x)TM_xTe(TM = Mn,Fe,Co,Ni and x = 6.25%),calculated through Wien2 k code,by using full potential linearized augmented plane wave(FP-LAPW) technique.The optimization of the crystal structures have been done to compare the ferromagnetic(FM) and antiferromagnetic(AFM) ground state energies,to elucidate the ferromagnetic phase stability,which further has been verified through the formation and cohesive energies.Moreover,the estimated Curie temperatures T_c have demonstrated above room temperature ferromagnetism(RTFM) in Zn_(1-x)TM_xTe(TM =Mn,Fe,Co,Ni and x= 6.25%).The calculated electronic properties have depicted that Mn- and Co-doped ZnTe behave as ferromagnetic semiconductors,while half-metallic ferromagnetic behaviors are observed in Fe- and Ni-doped ZnTe.The presence of ferromagnetism is also demonstrated to be due to both the p-d and s-d hybridizations between the host lattice cations and TM impurities.The calculated band gaps and static real dielectric constants have been observed to vary according to Penn's model.The evaluated band gaps lie in near visible and ultraviolet regions,which make these materials suitable for various important device applications in optoelectronic and spintronic.展开更多
Self-compacting concrete(SCC)is a type of concrete which is frequently preferred in different applications due to its advantages such as its fluidity and transition in tight openings between steel reinforcing bars.How...Self-compacting concrete(SCC)is a type of concrete which is frequently preferred in different applications due to its advantages such as its fluidity and transition in tight openings between steel reinforcing bars.However,it is vital that SCC maintains its fresh state characteristics when its transportation phase is taken into consideration.Fiber reinforced in SCC affects the properties of fresh concrete negatively while it had a positive effect on its dynamic properties.In this study,the effect of steel fibers having different aspect ratios on the time dependent fresh properties and mechani-cal properties of self-compacting concrete mixtures was investigated.In addition to the control mixture without fiber,in the mixtures containing fiber,three different twin-hook steel fibers with aspect ratios of 54,64 and 50 were used as 0.6%of total volume.In all of the SCC mixtures,the water/cement ratio,cement dosage and slump-flow value were kept constant.The time dependent rheological properties of the mixtures were investigated.The compressive,split-tensile and flexural strengths as well as fracture energy,the load deflection relation under flexural load and load-crack opening displacement,modulus of elasticity of SCC mixtures were also investigated.Besides,the water absorption capacity and depth of penetration of water under pressure of mixtures were measured.On the basis of the results,the fiber utilization and its aspect ratio had no significant effect on compressive strength and modulus of elasticity of the SCC mixtures.The split-tensile,flexural strengths and fracture energy of SCC mixtures increased by using fiber;the permeability properties of SCC mixture increased by fiber utilization.展开更多
To explore the properties of neutron-rich nuclei with approximately 40 protons,the density-dependent point coupling(DD-PC1)effective interaction parameter is adopted in the relativistic mean-field theory with the comp...To explore the properties of neutron-rich nuclei with approximately 40 protons,the density-dependent point coupling(DD-PC1)effective interaction parameter is adopted in the relativistic mean-field theory with the complex momentum representation(RMF-CMR).The calculated two-neutron separation energy(S_(2n))and root-mean-square(rms)radii support the halo structure that appear in Mo and Ru isotopic chains.Besides,the neutron skin structures appear in Kr and Sr isotopes.The conclusions drawn are also supported by the single-particle energy levels and their occupancy probability and density distribution.Particularly,the energy levels,which reduce to bound states or are approximately 0 MeV with a small orbital angular momentum,are suggested to provide the primary contribution to increasing the neutron radius.Moreover,the single-particle energy levels significantly reflect the shell structure.In addition,the neutron drip line nuclei for Kr,Sr,Mo,and Ru elements are proposed via the changes in S_(2n).展开更多
Polycrystalline cobalt-substituted tungsten bronze ferroelectric ceramics with chemical composition Ba_(5)CaTi_(2-x)Co_(X)Nb_(8)O_(30)(x=0.00,0.02,0.04 and 0.08)were synthesized by solid state reaction technique.X-ray...Polycrystalline cobalt-substituted tungsten bronze ferroelectric ceramics with chemical composition Ba_(5)CaTi_(2-x)Co_(X)Nb_(8)O_(30)(x=0.00,0.02,0.04 and 0.08)were synthesized by solid state reaction technique.X-ray diffraction(XRD)technique was used to confirm the phase formation and it revealed the formation of single phase tetragonal structure with space group P4bm.The surface morphology of the samples was studied by using the scanning electron microscopy(SEM)technique.The dielectric properties such as dielectric constant and dielectric loss have been investigated as a function of temperature and frequency.The P-E and M-H studies confirmed the coexistent of ferroelectricity and magnetism at room temperature.The P-E loop study indicated an increase in the coercive field while the M-H study depicted a decrease in the magnetization with the incorporation of cobalt ions.展开更多
文摘According to the "Notice on OrganizationStructure of the State Council", the formerChina Patent Office was changed into StateIntellectual Property Office of P. R. China(SIPO). SIPO falls within the category ofdirect authorities under State Council and isresponsible for patent work andcomprehensively coordination of the foreignrelated affairs in the field of intellectualproperty.
文摘A bound state formalism derived from a fermion-boson symmetric Lagrangian has been used to calculate the nucleon masses, the charge neutrality of the neutron, the magnetic moments and the electromagnetic form factor ratios μpGEp/GMpand μnGEn/GMn. A quantitative description is obtained, assuming a mixing of a scalar bound state of 3(f f¯)fstructure with its corresponding vector (f f¯)fstate (f indicating massless elementary fermions). Only a few parameters are needed, mainly fixed by energy and momentum conservation. The nucleon stability is explained by an extra binding in the confinement potential, negative for electric and positive for magnetic binding of the proton, and opposite for the neutron. The stronger electric extra binding of the proton allows a decay of the neutron to proton and electron.
基金Supported by the National Key Research and Development Program of China (Grant Nos.2016YFA0300300 and 2017YFA0303003)the National Natural Science Foundation of China (Grant Nos.12061131005,11834016 and 11888101)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No.XDB25000000)the Strategic Priority Research Program and Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (Grant Nos.QYZDY-SSW-SLH001)。
文摘The electronic and superconducting properties of Fe_(1-δ)Se single-crystal flakes grown hydrothermally are studied by the transport measurements under zero and high magnetic fields up to 38.5 T.The results contrast sharply with those previously reported for nematically ordered Fe Se by chemical-vapor-transport(CVT)growth.No signature of the electronic nematicity,but an evident metal-to-nonmetal crossover with increasing temperature,is detected in the normal state of the present hydrothermal samples.Interestingly,a higher superconducting critical temperature T_c of 13.2 K is observed compared to a suppressed T_c of 9 K in the presence of the nematicity in the CVT Fe Se.Moreover,the upper critical field in the zero-temperature limit is found to be isotropic with respect to the field direction and to reach a higher value of-42 T,which breaks the Pauli limit by a factor of 1.8.
基金Supported by the National Natural Science Foundation of China(Nos.21361023 and 21461023)
文摘A new coordination polymer, {[Cd(OPY)(tdc)(HO)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand OPY. The structure was fully characterized by elemental analysis, FT-IR spectroscopy, and X-ray single-crystal diffraction analysis. In1, two OPY ligands and one water molecule acted as terminal ligands coordinating to Cdcation to form [Cd(OPY)HO]units, which are then linked by tdc2-ligands to generate a one-dimensional chain. Every two adjacent chains linked by extensive O–H···O hydrogen bonds constitute one-dimensional double-chains, and such chains are extended into two-dimensional layers via O–H···N hydrogen bonds. These layers are further connected to form a three-dimensional supramolecular architecture via π-π stacking interactions. In addition, the thermal stability and solid state fluorescence property of 1 were also investigated.
文摘PASCA, ESR and Microreactor, have been used to study the states and properties of coking deposits on catalyst. The results indicate that the C exists as three types of states on catalyst surface. The first and second types of carbon are the main reason of the catalyst deactivation, but the third type has a promoting role in n-C_7 hydrocracking reaction. The S_s-C interacts strongly with catalyst, forming metal-carbon-support interaction (MCSI).
基金Supported by the Fundamental Research Funds for the Central Universities,and the Research Funds of Renmin University of China under Grant No 10XNF086
文摘Magneto-transport properties of insulating bulk states in Bi(111) films are systematically investigated under the parallel field (BⅡ). We find that the magnetotransport of the Bll field is a more powerful tool to distinguish the bulk states and the surface states. A large magnetoresistance (MR) up to 20% in the BⅡ field is induced by the insulating bulk states for the suppression of the backward scattering. With the increasing thickness, a positive MR(BⅡ) from magnetic induced boundary scattering appears in the semimetal films. As the thickness is reduced to 1Ohm, the positive MR(BⅡ) is induced by weak anti-localization from the surface states.
文摘In this paper, the volumetric properties of pure and mixture of ionic liquids are predicted using the developed statistical mechanical equation of state in different temperatures, pressures and mole fractions. The temperature dependent parameters of the equation of state have been calculated using corresponding state correlation based on only the density at 298.15 K as scaling constants. The obtained mean of deviations of modified equation of state for density of all pure ionic liquids for 1662 data points was 0.25%. In addition, the performance of the artificial neural network(ANN) with principle component analysis(PCA) based on back propagation training with28 neurons in hidden layer for predicting of behavior of binary mixtures of ionic liquids was investigated. The AADs of a collection of 568 data points for all binary systems using the EOS and the ANN at various temperatures and mole fractions are 1.03% and 0.68%, respectively. Moreover, the excess molar volume of all binary mixtures is predicted using obtained densities of EOS and ANN, and the results show that these properties have good agreement with literature.
基金financially supported by the National Natural Science Foundation of China (No.51402016)the Fundamental Research Funds for the Central Universities (No.FRF-TP-15-008A2)
文摘Brownmillerite-type oxides Ba_2In_(2-x-y)Mn_xAl_yO_(5+x)(0 ≤ x ≤ 0.6, 0 ≤ y ≤ 0.5) were prepared at 1300°C through solid-state reaction. X-ray diffraction(XRD) analysis showed that the structure symmetry evolved from orthorhombic to cubic with increasing Mn and Al contents. When y was greater than 0.3, peaks associated with small amounts of BaAl_2O_4 and Ba_2InAlO_5 impurities were observed in the XRD patterns. When substituted with a small amount of Mn(x ≤ 0.3), the Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) samples exhibited an intense turquoise color. The color changed to green and dark-green with increasing Mn concentration. UV–vis absorbance spectra revealed that the color changed only slightly upon Al doping. The valence state of Mn ions in Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) was confirmed to be +5 on the basis of X-ray photoelectron spectroscopic analysis. According to this analysis, the intense turquoise color of the Ba_2In_(2-x-y)Mn_xAl_yO_(5+x) samples is rooted in the existence of Mn^(5+); thus, the introduction of Al does not affect the optical properties of the compounds.
基金the University of the Punjab, Lahore for financial support through faculty research grant program
文摘We present structural,magnetic and optical characteristics of Zn_(1-x)TM_xTe(TM = Mn,Fe,Co,Ni and x = 6.25%),calculated through Wien2 k code,by using full potential linearized augmented plane wave(FP-LAPW) technique.The optimization of the crystal structures have been done to compare the ferromagnetic(FM) and antiferromagnetic(AFM) ground state energies,to elucidate the ferromagnetic phase stability,which further has been verified through the formation and cohesive energies.Moreover,the estimated Curie temperatures T_c have demonstrated above room temperature ferromagnetism(RTFM) in Zn_(1-x)TM_xTe(TM =Mn,Fe,Co,Ni and x= 6.25%).The calculated electronic properties have depicted that Mn- and Co-doped ZnTe behave as ferromagnetic semiconductors,while half-metallic ferromagnetic behaviors are observed in Fe- and Ni-doped ZnTe.The presence of ferromagnetism is also demonstrated to be due to both the p-d and s-d hybridizations between the host lattice cations and TM impurities.The calculated band gaps and static real dielectric constants have been observed to vary according to Penn's model.The evaluated band gaps lie in near visible and ultraviolet regions,which make these materials suitable for various important device applications in optoelectronic and spintronic.
基金support provided by Bursa Uludag University Scientific Research Projects Centre(BAP)under grant number KUAP(MH)-2017/11 and AYP(MH)-2016/16.
文摘Self-compacting concrete(SCC)is a type of concrete which is frequently preferred in different applications due to its advantages such as its fluidity and transition in tight openings between steel reinforcing bars.However,it is vital that SCC maintains its fresh state characteristics when its transportation phase is taken into consideration.Fiber reinforced in SCC affects the properties of fresh concrete negatively while it had a positive effect on its dynamic properties.In this study,the effect of steel fibers having different aspect ratios on the time dependent fresh properties and mechani-cal properties of self-compacting concrete mixtures was investigated.In addition to the control mixture without fiber,in the mixtures containing fiber,three different twin-hook steel fibers with aspect ratios of 54,64 and 50 were used as 0.6%of total volume.In all of the SCC mixtures,the water/cement ratio,cement dosage and slump-flow value were kept constant.The time dependent rheological properties of the mixtures were investigated.The compressive,split-tensile and flexural strengths as well as fracture energy,the load deflection relation under flexural load and load-crack opening displacement,modulus of elasticity of SCC mixtures were also investigated.Besides,the water absorption capacity and depth of penetration of water under pressure of mixtures were measured.On the basis of the results,the fiber utilization and its aspect ratio had no significant effect on compressive strength and modulus of elasticity of the SCC mixtures.The split-tensile,flexural strengths and fracture energy of SCC mixtures increased by using fiber;the permeability properties of SCC mixture increased by fiber utilization.
基金Supported by the National Natural Science Foundation of China(11875070)the Natural Science Foundation of Anhui Province(1908085MA16)。
文摘To explore the properties of neutron-rich nuclei with approximately 40 protons,the density-dependent point coupling(DD-PC1)effective interaction parameter is adopted in the relativistic mean-field theory with the complex momentum representation(RMF-CMR).The calculated two-neutron separation energy(S_(2n))and root-mean-square(rms)radii support the halo structure that appear in Mo and Ru isotopic chains.Besides,the neutron skin structures appear in Kr and Sr isotopes.The conclusions drawn are also supported by the single-particle energy levels and their occupancy probability and density distribution.Particularly,the energy levels,which reduce to bound states or are approximately 0 MeV with a small orbital angular momentum,are suggested to provide the primary contribution to increasing the neutron radius.Moreover,the single-particle energy levels significantly reflect the shell structure.In addition,the neutron drip line nuclei for Kr,Sr,Mo,and Ru elements are proposed via the changes in S_(2n).
基金the Deanship of Scientific Research at King Saud University for its funding through the Research Group Project No.RG-1437-030.
文摘Polycrystalline cobalt-substituted tungsten bronze ferroelectric ceramics with chemical composition Ba_(5)CaTi_(2-x)Co_(X)Nb_(8)O_(30)(x=0.00,0.02,0.04 and 0.08)were synthesized by solid state reaction technique.X-ray diffraction(XRD)technique was used to confirm the phase formation and it revealed the formation of single phase tetragonal structure with space group P4bm.The surface morphology of the samples was studied by using the scanning electron microscopy(SEM)technique.The dielectric properties such as dielectric constant and dielectric loss have been investigated as a function of temperature and frequency.The P-E and M-H studies confirmed the coexistent of ferroelectricity and magnetism at room temperature.The P-E loop study indicated an increase in the coercive field while the M-H study depicted a decrease in the magnetization with the incorporation of cobalt ions.