Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs

Based on the microfluidic technology,a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage(UGS)rebuilt from water-invaded gas reservoirs.Through analysis of the gas-liquid contact stabilization mechanism,flow and occurrence,the optimal control method for lifecycle efficient operation of UGS was explored.The results show that in the initial construction stage of UGS,the action of gravity should be fully utilized by regulating the gas injection rate,so as to ensure the macroscopically stable migration of the gas-liquid contact,and greatly improve the gas sweeping capacity,providing a large pore space for gas storage in the subsequent cyclical injection-production stage.In the cyclical injection-production stage of UGS,a constant gas storage and production rate leads to a low pore space utilization.Gradually increasing the gas storage and production rate,that is,transitioning from small volume to large volume,can continuously break the hydraulic equilibrium of the remaining fluid in the porous media,which then expands the pore space and flow channels.This is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

Dynamics of iron and aluminum storages in a subtropical forest headwater stream

The forest headwater streams are important hubs for connecting terrestrial and aquatic ecosystems,with plant litter and sediments as the major carriers for material migrations;however,until now we knew little about the dynamics of trace elements such as iron(Fe)and aluminum(Al)in forest headwater streams.Here,we quantitatively identified the spatiotemporal dynamics of Fe and Al storages in plant litter and sediments and their influencing factors in a subtropical forest headwater stream,and assessed the potential pollution risk.The results showed that:(1)the mean concentrations of Fe and Al in plant litter(sediments)were 5.48 and 8.46(7.39 and 47.47)g·kg^(-1),and the mean storages of Fe and Al in plant litter(sediments)were 0.26 and 0.43(749.04 and 5030.90)g·m^(-2),respectively;(2)the storages of Fe and Al in plant litter and sediments significantly fluctuated from January to December,and showed a decreasing pattern from the source to mouth;and(3)storages of Fe and Al had no significant correlation with riparian forest type and the present of tributary and the Fe and Al storages in plant litter were mainly affected by water temperature and water alkalinity,and their storages in sediments were mainly affected by water temperature and frequency of rainfall;and(4)there were no anthropogenic pollution in Fe and Al in the forest headwater stream.Our study revealed the primary factors of concentrations and storages of Fe and Al in plant litter and sediments in a forest headwater stream,which will improve our understanding of the role of headwater streams in forest nutrient storage and cycling along with hydrological processes.

“Extreme utilization” theory and practice in gas storages with complex geological conditions

Based on more than 20-year operation of gas storages with complex geological conditions and a series of research findings, the pressure-bearing dynamics mechanism of geological body is revealed. With the discovery of gas-water flowing law of multi-cycle relative permeability hysteresis and differential utilization in zones, the extreme utilization theory targeting at the maximum amount of stored gas, maximum injection-production capacity and maximum efficiency in space utilization is proposed to support the three-in-one evaluation method of the maximum pressure-bearing capacity of geological body, maximum well production capacity and maximum peak shaving capacity of storage space. This study realizes the full potential of gas storage(storage capacity) at maximum pressure, maximum formation-wellbore coordinate production, optimum well spacing density match with finite-time unsteady flow, and peaking shaving capacity at minimum pressure, achieving perfect balance between security and capacity. Operation in gas storages, such as Hutubi in Xinjiang, Xiangguosi in Xinan, and Shuang6 in Liaohe, proves that extreme utilization theory has promoted high quality development of gas storages in China.

Comparisons of carbon storages in Cunninghamia lanceolata and Michelia macclurei plantations during a 22-year period in southern China

Tree species composition was important for carbon storage within the same climate range.To quantify the dynamics of ecosystem carbon allocation as affected by different tree species,we measured the above-and below-ground biomass accumulation in 22 years,as well as the tissue carbon concentrations of trees in Cunninghamia lanceolata plantation and Michelia macclurei plantation.Results indicated that M.macclurei plantation significantly stored more carbon（174.8 tons/hm2） than C.lanceolata plantation（154.3 tons/hm2）.Most of the carbon was found in the soil pool（57.1% in M.macclurei plantation,55.2% in C.lanceolata plantation）.Tree and soil component of M.macclurei plantation possessed significantly higher carbon storage than that of C.lanceolata plantation（p 〈 0.05）.No significant difference was found in the carbon storage of understory and forest floor.These results suggest that the broadleaved species（M.macclurei） possesses greater carbon sequestration potential than the coniferous species（C.lanceolata） in southern China.

LTT switch unit for capacitive energy storages

When the capacitor cell is discharged in the short-circuit mode, the current pulse amplitude and duration are maximal. Therefore, this mode is the most severe for discharge switches of capacitive energy storage. The characteristics of the transient process of the discharge capacitive energy storage and the current loads acting in the facility discharge circuit have been defined for this mode. The test bench for definition of the LTT(Light Triggered Thyristors) loading capacity is described. The limiting characteristics have been experimentally obtained for LTT, at which there emerges the thermo-generation peak.The process of OFF-ON switching of LTTs has been investigated, the necessity is shown to use the speedup R-C circuits to ensure fast and stable transition of LTT into the conducting state. The design of the switch unit for the capacitive energy storage comprising LTTs and crowbar diodes is described, and the transient processes of current switching in crowbar diodes are considered. The tests carried out during switching of pul se current up to 100 kA at a voltage of 6 kV have confirmed the workability of the switch unit.

Characteristics of soil organic carbon andtotal nitrogen storages for differentland-use types in Central Yunnan Plateau

Two-factor analysis of variance and redundancy analysis were used to analyze the characte-ristics of soil organic carbon total nitrogen storage in garden land,forestland,grassland,farmland,and bare land in the Dachunhe watershed of Jinning District,Kunming City,Yunnan Province,China.The effects of the soil organic carbon,total nitrogen stratification ratio,soil physical and chemical factors on the storage characteristics of organic carbon and total nitrogen of different land-use types were analyzed.The results show that the rates of carbon and nitrogen stratification in soil from 0-20 cm and 40-60 cm of the same land-use types differed are statistically significant(P<0.05).The organic carbon and total nitrogen stratification ratio SR1 of garden land soil are 38.5%and 25.3%,respectively,which are higher than SR^(2).The soil organic carbon and total nitrogen stratification ratio SR^(2) of different land-use types are greater than SR1.There are statistically significant differences in the SR^(2) soil organic carbon and total nitrogen stratification ratios(P<0.05).Soil organic carbon and total nitrogen storage of diffe-rent land-use types gradually decrease with increasing soil depth,with the maximum soil organic carbon and total nitrogen storage in the 0-20 cm soil layer.Soil organic carbon and total nitrogen sto-rage at the same soil depth are significantly different(P<0.05).Soil organic carbon and total nitrogen storage in the garden land are greater than those in the other land-use types.Soil organic carbon and total nitrogen storage in 0-20 cm garden land are 4.96 and 3.19 times than those in bare land,respectively;soil organic carbon and total nitrogen storage are explained by 93.66%and 1.53%in redundancy analysis RDA1 and RDA2,respectively.All physicochemical factors except Available Phosphorus and pH are statistically significance with carbon and nitrogen storage(P<0.05).Soil cationic exchange capacity,Available Phosphorus,C/N ratio,and Moisture Content are positively correlated with organic carbon and total nitrogen storage.In contrast,soil Bulk Density is negatively correlated with organic carbon storage and total nitrogen storage.Available Phosphorus,C/N ratio,and Moisture Content are the main factors promoting soil organic carbon and total nitrogen accumulation.

Controllable all-optical stochastic logic gates and their delay storages based on the cascaded VCSELs with optical-injection

Using the dynamical properties of the polarization bistability that depends on the detuning of the injected light,we propose a novel approach to implement reliable all-optical stochastic logic gates in the cascaded vertical cavity surface emitting lasers（VCSELs） with optical-injection.Here,two logic inputs are encoded in the detuning of the injected light from a tunable CW laser.The logic outputs are decoded from the two orthogonal polarization lights emitted from the optically injected VCSELs.For the same logic inputs,under electro-optic modulation,we perform various digital signal processing（NOT,AND,NAND,XOR,XNOR,OR,NOR） in the all-optical domain by controlling the logic operation of the applied electric field.Also we explore their delay storages by using the mechanism of the generalized chaotic synchronization.To quantify the reliabilities of these logic gates,we further demonstrate their success probabilities.

Multi-Objective Sizing of Solar-Wind-Hydro Hybrid Power System with Doubled Energy Storages Under Optimal Coordinated Operational Strategy

More and more attention has been paid to the high penetration of renewable energy in recent years.The randomness and intermittency of solar and wind energy make it an inevitable trend that renewables are coupled with energy storage technologies.Pumped hydro storage(PHS)is the most widelyused storage form in the power grid but the capacity is limited by geographic conditions.The concentrated solar power(CSP)plant with a thermal energy storage(TES)system can realize easier grid connections and effective peak shaving.Therefore,this paper proposes a solar-wind-hydro hybrid power system with PHS-TES double energy storages,and investigates the optimal coordinated operational strategy and multi-objective sizing.The optimal sizing problem which considers the minimum levelized cost of energy(LCOE)and loss of power supply probability(LPSP)as objectives is solved by multi-objective particle swarm optimization.Moreover,the seasonal uncertainties of renewables are considered by applying a scenario-based analysis using Kmeans clustering.Finally,a case study reveals the effectiveness of the coordinated operational strategy and double energy storages from the perspectives of economy and reliability.The comparisons of optimal sizing results show that the PV-WindCSP-PHS system decreases the LCOE by 19.1%compared to a PV-Wind-CSP system under the same LPSP,and reduces the LPSP compared to PV-Wind-PHS systems with limited reservoir capacity,which indicates that the proposed system with double energy storages has better economy and reliability performance compared to single storage.

Electrochemical activation of oxygen atom of SnO2 to expedite efficient conversion reaction for alkaline-ion(Li+/Na+/K+)storages

SnO2-based anode materials have attracted much attention due to high capacity and relatively mild voltage platforms.However,limited by low initial Coulombic efficiency(ICE)and poor stability,its practical application is still challenging.Recently,it has been found that compositing carbon or metal particles with SnO2 is an effective strategy to achieve high alkaline-ion storages.Although this strategy may improve the kinetics and ICE of the electrochemical reaction,the specific mechanism has not been clearly elucidated.In this work,we found that the invalidation SnO2 may go through two steps:1)the conversion process from SnO2 to Sn and Li2O;2)the collapse of the electrode material resulted from huge volume changes during the alloyed Sn with alkaline ions.To address these issues,a unique robust Co-NC shell derived from ZIF-67 is introduced,in which the transited metallic Co nanoparticles could accelerate the decomposition of Sn-O and Li-O bonds,thus expedite the kinetics of conversion reaction.As a result,the SnO2@Co-NC electrode achieves a more complete and efficient transfer between SnO2 and Sn phases,possessing a potential to achieve high alkaline-ion(Li+/Na+/K+)storages.

Soil organic carbon storages and bacterial communities along a restored mangrove soil chronosequence in the Jiulong River Estuary:From tidal flats to mangrove afforestation

Among many ecological services provided by mangrove ecosystems,soil organic carbon(SOC)storages have recently received much attention owing to the increasing atmospheric partial pressure of dissolved CO_(2)(pCO_(2)).Bacteria are fundamental to ecosystem functions and strongly influence the coupling of coastal carbon,nitrogen,and sulfur cycling in soils.The SOC storage and bacterial communities along a restored mangrove soil chronosequence in the Jiulong River Estuary were explored using the 16S rDNA sequencing technique.The results showed the SOC storage in the 100 cm soil profile was 103.31±5.87 kg C m^(−2)and 93.10±11.28 kg C m^(−2)for mangroves with afforestation ages of 36 and 60 years,respectively.The total nitrogen(TN)and total sulfur(TS)contents exhibited significant correlations with the SOC in the mangrove soils,but only TN and SOC showed significant correlation in tidal flat soils.Although the tidal flats and mangroves occupied the contiguous intertidal zone within several kilometers,the variations in the SOC storage along the restored mangrove soil chronosequence were notably higher.The Functional Annotation of Prokaryotic Taxa(FAPROTAX)database was used to annotate the metabolic functions of the bacteria in the soils.The annotation revealed that only four metabolic functions were enriched with a higher relative abundance of the corresponding bacteria,and these enriched functions were largely associated with sulfate reduction.In addition,the specifically critical bacterial taxa that were associated with the SOC accumulation and nutrient cycling,shaped the distinct metabolic functions,and consequently facilitated the SOC accumulation in the mangrove soils with various afforestation ages.The general homogenization of the microbial community and composition along the intertidal soil chronosequence was primarily driven by the reciprocating tidal flows and geographical contiguity.

An HESS Based on a Modified MMCC-TSBC Converter Integrating Energy Storages

This paper presents a modified modular multilevel cascaded converter based on a triple star bridge cell(MMCCTSBC)for integrating different types of energy storage to form a hybrid energy storage system(HESS).The proposed HESS comprises battery energy storage,supercapacitor energy storage and a doubly-fed induction machine(DFIM)based variable speed pump storage(VSPS).Different low-rated energy storage units can be intermixed in this converter to form an HESS.This is possible due to the modular structure of the modified converter and provides an advantage in a high-power energy storage system.To validate the performance of HESS,real-time power variation data is accumulated from online sources and a weighted median filter(WMF)is employed for generating appropriate references for battery energy storage system(BESS)and supercapacitor storage to mitigate both low frequency and high-frequency power variations.Here,the control approach permits independent regulation of grid current and DFIM current through the modified MMCC-TSBC converter.The simulation and experimental results validate the effectiveness of the control scheme for the proposed HESS.

Energy Storage Systems Technologies, Evolution and Applications

Energy in its varied forms and applications has become the main driver of today’s modern society. However, recent changes in power demand and climatic changes (decarbonization policy) has awakened the need to rethink through the current energy generating and distribution system. This led to the exploration of other energy sources of which renewable energy (like thermal, solar and wind energy) is fast becoming an integral part of most energy system. However, this innovative and promising energy source is highly unreliable in maintaining a constant peak power that matches demand. Energy storage systems have thus been highlighted as a solution in managing such imbalances and maintaining the stability of supply. Energy storage technologies absorb and store energy, and release it on demand. This includes gravitational potential energy (pumped hydroelectric), chemical energy (batteries), kinetic energy (flywheels or compressed air), and energy in the form of electrical (capacitors) and magnetic fields. This paper provides a detailed and comprehensive overview of some of the state-of-the-art energy storage technologies, its evolution, classification, and comparison along with various area of applications. Also highlighted in this paper is a plethora of power electronic Interface technologies that plays a significant role in enabling optimum performance and utilization of energy storage systems in different areas of application.

Challenges and opportunities for battery health estimation:Bridging laboratory research and real-world applications

Addressing climate change demands a significant shift away from fossil fuels,with sectors like electricity and transportation relying heavily on renewable energy.Integral to this transition are energy storage systems,notably lithium-ion batteries.Over time,these batteries degrade,affecting their efficiency and posing safety risks.Monitoring and predicting battery aging is essential,especially estimating its state of health(SOH).Various SOH estimation methods exist,from traditional model-based approaches to machine learning approaches.

Oxygen functionalization-assisted anionic exchange toward unique construction of flower-like transition metal chalcogenide embedded carbon fabric for ultra-long life flexible energy storage and conversion

The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storage and conversion application.The NiCCZ was then oxygen functionalized,facilitating the next step of stoichiometric sulfur anion diffusion during hydrothermal sulfurization,generating a flower-like metal hydroxysulfide structure(NiCCZOS)with strong partial implantation inside CC.Thus obtained NiCCZOS shows an excellent capacity when tested as a supercapacitor electrode in a three-electrode configuration.Moreover,when paired with the biomass-derived nitrogen-rich activated carbon,the asymmetric supercapacitor device shows almost 100%capacity retention even after 45,000 charge–discharge cycles with remarkable energy density(59.4 Wh kg^(-1)/263.8μWh cm^(–2))owing to a uniquely designed cathode.Furthermore,the same electrode performed as an excellent bifunctional water-splitting electrocatalyst with an overpotential of 271 mV for oxygen evolution reaction(OER)and 168.4 mV for hydrogen evolution reaction(HER)at 10 mA cm−2 current density along with 30 h of unhinged chronopotentiometric stability performance for both HER and OER.Hence,a unique metal chalcogenide composite electrode/substrate configuration has been proposed as a highly stable electrode material for flexible energy storage and conversion applications.

Role of lipids in the control of autophagy and primary cilium signaling in neurons

The brain is,after the adipose tissue,the organ with the greatest amount of lipids and diversity in their composition in the human body.In neurons,lipids are involved in signaling pathways controlling autophagy,a lysosome-dependent catabolic process essential for the maintenance of neuronal homeostasis and the function of the primary cilium,a cellular antenna that acts as a communication hub that transfers extracellular signals into intracellular responses required for neurogenesis and brain development.A crosstalk between primary cilia and autophagy has been established;however,its role in the control of neuronal activity and homeostasis is barely known.In this review,we briefly discuss the current knowledge regarding the role of autophagy and the primary cilium in neurons.Then we review the recent literature about specific lipid subclasses in the regulation of autophagy,in the control of primary cilium structure and its dependent cellular signaling in physiological and pathological conditions,specifically focusing on neurons,an area of research that could have major implications in neurodevelopment,energy homeostasis,and neurodegeneration.

Data Secure Storage Mechanism for IIoT Based on Blockchain

With the development of Industry 4.0 and big data technology,the Industrial Internet of Things(IIoT)is hampered by inherent issues such as privacy,security,and fault tolerance,which pose certain challenges to the rapid development of IIoT.Blockchain technology has immutability,decentralization,and autonomy,which can greatly improve the inherent defects of the IIoT.In the traditional blockchain,data is stored in a Merkle tree.As data continues to grow,the scale of proofs used to validate it grows,threatening the efficiency,security,and reliability of blockchain-based IIoT.Accordingly,this paper first analyzes the inefficiency of the traditional blockchain structure in verifying the integrity and correctness of data.To solve this problem,a new Vector Commitment(VC)structure,Partition Vector Commitment(PVC),is proposed by improving the traditional VC structure.Secondly,this paper uses PVC instead of the Merkle tree to store big data generated by IIoT.PVC can improve the efficiency of traditional VC in the process of commitment and opening.Finally,this paper uses PVC to build a blockchain-based IIoT data security storage mechanism and carries out a comparative analysis of experiments.This mechanism can greatly reduce communication loss and maximize the rational use of storage space,which is of great significance for maintaining the security and stability of blockchain-based IIoT.

Failure transition of shear-to-dilation band of rock salt under triaxial stresses

Great potential of underground gas/energy storage in salt caverns seems to be a promising solution to support renewable energy.In the underground storage method,the operating cycle unfortunately may reach up to daily or even hourly,which generates complicated pressures on the salt cavern.Furthermore,the mechanical behavior of rock salt may change and present distinct failure characteristics under different stress states,which affects the performance of salt cavern during the time period of full service.To reproduce a similar loading condition on the cavern surrounding rock mass,the cyclic triaxial loading/unloading tests are performed on the rock salt to explore the mechanical transition behavior and failure characteristics under different confinement.Experimental results show that the rock salt samples pre-sent a diffused shear failure band with significant bulges at certain locations in low confining pressure conditions(e.g.5 MPa,10 MPa and 15 MPa),which is closely related to crystal misorientation and grain boundary sliding.Under the elevated confinement(e.g.20 MPa,30 MPa and 40 MPa),the dilation band dominates the failure mechanism,where the large-size halite crystals are crushed to be smaller size and new pores are developing.The failure transition mechanism revealed in the paper provides additional insight into the mechanical performance of salt caverns influenced by complicated stress states.

Thermo-hydro-mechanical (THM) coupled simulation of the land subsidence due to aquifer thermal energy storage (ATES) system in soft soils

Aquifer thermal energy storage(ATES)system has received attention for heating or cooling buildings.However,it is well known that land subsidence becomes a major environmental concern for ATES projects.Yet,the effect of temperature on land subsidence has received practically no attention in the past.This paper presents a thermo-hydro-mechanical(THM)coupled numerical study on an ATES system in Shanghai,China.Four water wells were installed for seasonal heating and cooling of an agriculture greenhouse.The target aquifer at a depth of 74e104.5 m consisted of alternating layers of sand and silty sand and was covered with clay.Groundwater level,temperature,and land subsidence data from 2015 to 2017 were collected using field monitoring instruments.Constrained by data,we constructed a field scale three-dimensional(3D)model using TOUGH(Transport of Unsaturated Groundwater and Heat)and FLAC3D(Fast Lagrangian Analysis of Continua)equipped with a thermo-elastoplastic constitutive model.The effectiveness of the numerical model was validated by field data.The model was used to reproduce groundwater flow,heat transfer,and mechanical responses in porous media over three years and capture the thermo-and pressure-induced land subsidence.The results show that the maximum thermoinduced land subsidence accounts for about 60%of the total subsidence.The thermo-induced subsidence is slightly greater in winter than that in summer,and more pronounced near the cold well area than the hot well area.This study provides some valuable guidelines for controlling land subsidence caused by ATES systems installed in soft soils.

Exploring innovative synthetic solutions for advanced polymer-based electrochromic energy storage devices:Phenoxazine as a promising chromophore

The current investigation offers an innovative synthetic solution regarding electrochromic(EC)and energy storage applications by exploring phenoxazine(POZ)moiety.Subsequently,three POZ-based polymers(polyimide,polyazomethine,and polyamide)were synthesized to ascertain the superior performer.The polyamide exhibited remarkable attributes,including high redox stability during 500 repetitive CVs,optical contrast of 61.98%,rapid response times of 1.02 and 1.38 s for coloring and bleaching,EC efficiency of 280 cm^(2)C^(-1).and decays of the optical density and EC efficiency of only 12.18%and 6.23%after 1000 cycles.Then,the energy storage performance of polyamide PA was tested,for which the following parameters were obtained:74.7 F g^(-1)(CV,scan rate of 10 mV s^(-1))and 118 F g^(-1)(GCD,charging current of 0.1 A g^(-1)).Then,the polyamide was tested in EES devices,which yielded the following EC parameters:an optical contrast of 62.15%,response times of 9.24 and 5.01 s for coloring and bleaching,EC efficiency of 178 cm^(2)C^(-1),and moderate decays of 20.25%and 23.24%for the optical density and EC efficiency after 500 cycles.The energy storage performance included a capacitance of 106 F g^(-1)(CV,scan rate of 0.1 mV s^(-1))and 9.23 F g^(-1)(GCD,charging current of 0.1 A g^(-1)),capacitance decay of 11.9%after500 cycles,and 1.7 V retention after 2 h.Also,two EES devices connected in series powered a 3 V LED for almost 30 s.

Anion storing,oxygen vacancy incorporated perovskite oxide composites for high-performance aqueous dual ion hybrid supercapacitors

Dual ion storage hybrid supercapacitors(HsCs)are considered as a promising device to overcome the limited energy density of existing supercapacitors while preserving high power and long cyclability.However,the development of high-capacity anion-storing materials,which can be paired with fast charg-ing capacitive electrodes,lags behind cation-storing counterparts.Herein,we demonstrate the surface faradaic OH-storage mechanism of anion storing perovskite oxide composites and their application in high-performance dual ion HsCs.The oxygen vacancy and nanoparticle size of the reduced LaMnO_(3)(r-LaMnO_(3))were controlled,while r-LaMnO_(3) was chemically coupled with ozonated carbon nanotubes(oCNTs)for the improved anion storing capacity and cycle performance.As taken by in-situ and ex-situ spectroscopic and computational analyses,OH-ions are inserted into the oxygen vacancies coordi-nating with octahedral Mn with the increase in the oxidation state of Mn during the charging process or vice versa.Configuring OH-storing r-LaMnO_(3)/oCNT composite with Na*storing MXene,the as-fabricated aqueous dual ion HSCs achieved the cycle performance of 73.3%over 10,000 cycles,delivering the max-imum energy and power densities of 47.5 w h kg^(-1) and 8 kw kg^(-1),respectively,far exceeding those of previously reported aqueous anion and dual ion storage cells.This research establishes a foundation for the unique anion storage mechanism of the defect engineered perovskite oxides and the advancement of dual ion hybrid energy storage devices with high energy and power densities.