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Reshaping Li–Mg hybrid batteries:Epitaxial electrodeposition and spatial confinement on MgMOF substrates via the lattice‐matching strategy
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作者 Yongqin Wang Fulin Cheng +2 位作者 Jiawen Ji Chenyang Cai Yu Fu 《Carbon Energy》 SCIE EI CAS CSCD 2024年第8期248-261,共14页
The emergence of Li–Mg hybrid batteries has been receiving attention,owing to their enhanced electrochemical kinetics and reduced overpotential.Nevertheless,the persistent challenge of uneven Mg electrodeposition rem... The emergence of Li–Mg hybrid batteries has been receiving attention,owing to their enhanced electrochemical kinetics and reduced overpotential.Nevertheless,the persistent challenge of uneven Mg electrodeposition remains a significant impediment to their practical integration.Herein,we developed an ingenious approach that centered around epitaxial electrocrystallization and meticulously controlled growth of magnesium crystals on a specialized MgMOF substrate.The chosen MgMOF substrate demonstrated a robust affinity for magnesium and showed minimal lattice misfit with Mg,establishing the crucial prerequisites for successful heteroepitaxial electrocrystallization.Moreover,the incorporation of periodic electric fields and successive nanochannels within the MgMOF structure created a spatially confined environment that considerably promoted uniform magnesium nucleation at the molecular scale.Taking inspiration from the“blockchain”concept prevalent in the realm of big data,we seamlessly integrated a conductive polypyrrole framework,acting as a connecting“chain,”to interlink the“blocks”comprising the MgMOF cavities.This innovative design significantly amplified charge‐transfer efficiency,thereby increasing overall electrochemical kinetics.The resulting architecture(MgMOF@PPy@CC)served as an exceptional host for heteroepitaxial Mg electrodeposition,showcasing remarkable electrostripping/plating kinetics and excellent cycling performance.Surprisingly,a symmetrical cell incorporating the MgMOF@PPy@CC electrode demonstrated impressive stability even under ultrahigh current density conditions(10mAcm^(–2)),maintaining operation for an extended 1200 h,surpassing previously reported benchmarks.Significantly,on coupling the MgMOF@PPy@CC anode with a Mo_(6)S_(8) cathode,the assembled battery showed an extended lifespan of 10,000 cycles at 70 C,with an outstanding capacity retention of 96.23%.This study provides a fresh perspective on the rational design of epitaxial electrocrystallization driven by metal–organic framework(MOF)substrates,paving the way toward the advancement of cuttingedge batteries. 展开更多
关键词 epitaxial electrodeposition lattice‐matching strategy Li-Mg hybrid batteries MOF substrate spatial confinement
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Underwater Image Bidirectional Matching for Localization Based on SIFT 被引量:4
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作者 Yan Lin Bo Liu 《Journal of Marine Science and Application》 2014年第2期225-229,共5页
For the purpose of identifying the stern of the SWATH (Small Waterplane Area Twin Hull) availably and perfecting the detection technique of the SWATH ship's performance, this paper presents a novel bidirectional im... For the purpose of identifying the stern of the SWATH (Small Waterplane Area Twin Hull) availably and perfecting the detection technique of the SWATH ship's performance, this paper presents a novel bidirectional image registration strategy and mosaicing technique based on the scale invariant feature transform (SIFT) algorithm. The proposed method can help us observe the stern with a great visual angle for analyzing the performance of the control fins of the SWATH. SIFT is one of the most effective local features of the scale, rotation and illumination invariant. However, there are a few false match rates in this algorithm. In terms of underwater machine vision, only by acquiring an accurate match rate can we find an underwater robot rapidly and identify the location of the object. Therefore, firstly, the selection of the match ratio principle is put forward in this paper; secondly, some advantages of the bidirectional registration algorithm are concluded by analyzing the characteristics of the unidirectional matching method. Finally, an automatic underwater image splicing method is proposed on the basis of fixed dimension, and then the edge of the image's overlapping section is merged by the principal components analysis algorithm. The experimental results achieve a better registration and smooth mosaicing effect, demonstrating that the proposed method is effective. 展开更多
关键词 SWATH underwater image registration SIFT bidirectional matching strategy automatic stitching
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New code match strategy for wideband code division multiple access code tree management 被引量:1
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作者 杨宗凯 刘光然 何建华 《Journal of Central South University of Technology》 2006年第3期265-269,共5页
Orthogonal variable spreading factor channelization codes are widely used to provide variable data rates for supporting different bandwidth requirements in wideband code division multiple access (WCDMA) systems. A new... Orthogonal variable spreading factor channelization codes are widely used to provide variable data rates for supporting different bandwidth requirements in wideband code division multiple access (WCDMA) systems. A new code match scheme for WCDMA code tree management was proposed. The code match scheme is similar to the existing crowed-first scheme. When choosing a code for a user, the code match scheme only compares the one up layer of the allocated codes, unlike the crowed-first scheme which perhaps compares all up layers. So the operation of code match scheme is simple, and the average time delay is decreased by 5.1%. The simulation results also show that the code match strategy can decrease the average code blocking probability by 8.4%. 展开更多
关键词 orthogonal variable spreading factor code placement strategy code match strategy code blocking probability
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Novel Matching Strategy for the Coupling of Heat Flux in Furnace Side and CO_(2)Temperature in Tube Side to Control the Cooling Wall Temperatures 被引量:2
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作者 LIU Chao MIAO Zheng +2 位作者 XU Jinliang XU Zeyu LI Mingjia 《Journal of Thermal Science》 SCIE EI CAS CSCD 2021年第4期1251-1267,共17页
Required by the supercritical carbon dioxide(s CO_(2))coal-fired power cycle,s CO_(2)entering a boiler has a high temperature and can cause overheating of tubes.To eliminate the pressure drop penalty effect,the s CO_(... Required by the supercritical carbon dioxide(s CO_(2))coal-fired power cycle,s CO_(2)entering a boiler has a high temperature and can cause overheating of tubes.To eliminate the pressure drop penalty effect,the s CO_(2)boiler consists of several modules,each having different heat flux received from the furnace side(q)and different CO_(2)temperature in the cooling wall tube(T_f).We aim to search for the best matching strategy coupling furnace side and tube side to obtain the lowest temperature of tubes.By theoretically analyzing the wall temperature influenced by q,T_f and a comprehensive thermal resistance C,two matching methods are introduced:the heat flux-temperature matching(HTM)which matches higher q with lower T_f,and the heat flux-heat flux matching(HHM)that matches higher q with higher allowable-heat-flux at the temperature limit of tubes.HTM is a conventional method but HHM is newly proposed here.We show that,if C is identical for different modules,the two methods coincide;otherwise,HHM is recommended.For a s CO_(2)boiler driving 1000 MWe power plant,smaller cooling wall temperatures are obtained by HHM than HTM.Based on HHM,the mid-partition wall,heat transfer enhancement,and downward flow are comprehensively used,decreasing the wall temperature significantly. 展开更多
关键词 sCO_(2)power cycle sCO_(2)modular boiler cooling wall temperature allowable heat flux matching strategy
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Perceptual Models of Art students and Its Enlightenment on English Teaching 被引量:1
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《International English Education Research》 2014年第1期45-47,共3页
Art students, as a whole, have a variety of learning style of sensory receivers. The Variety of learning styles requires the variety of teaching strategies. The analysis of learners' learning styles is one of the fac... Art students, as a whole, have a variety of learning style of sensory receivers. The Variety of learning styles requires the variety of teaching strategies. The analysis of learners' learning styles is one of the factors on which the design of learning strategies should be based. Matching teaching strategies and mismatching strategies are chosen intentionally according to the teaching contents, the teaching goals, and the learner's learning styles. Matching teaching strategies can reach the best result of teaching and learning. On the contrary, mismatching strategies can remedy the disadvantages caused by learning styles and be helpful for the development of learning styles. 展开更多
关键词 Learning Styles of Sensory Receivers matching Teaching Strategies Mismatching Teaching Strategies
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