Solid-state cooling technologies have been considered as potential alternatives for vapor compression cooling systems.The search for refrigeration materials displaying a unique combination of pronounced caloric effect...Solid-state cooling technologies have been considered as potential alternatives for vapor compression cooling systems.The search for refrigeration materials displaying a unique combination of pronounced caloric effect,low hysteresis,and high reversibility on phase transformation was very active in recent years.Here,we achieved increase in the elastocaloric reversibility and decrease in the friction dissipation of martensite transformations in the superelastic nano-grained NiTi alloys obtained by cold rolling and annealing treatment,with very low stress hysteresis(6.3 MPa)under a large applied strain(5%).Large adiabatic temperature changes(△T_(max)=16.3 K atε=5%)and moderate COP_(mater)values(maximum COP_(mater)=11.8 atε=2%)were achieved.The present nano-grained NiTi alloys exhibited great potential for applications as a highly efficient elastocaloric material.展开更多
The effect of deformation on recovery stress of Ni144.7Ti46.3Nb9 alloy has been studjed using tensile test at various temperatures and TEM observation. It ls shown that the recovery stress increases with jncreasing to...The effect of deformation on recovery stress of Ni144.7Ti46.3Nb9 alloy has been studjed using tensile test at various temperatures and TEM observation. It ls shown that the recovery stress increases with jncreasing total strain ET and reaches a maximum value (max) as ET= 9% but the maximum recov erV strain of the alloy is only about 4.6%. This is different from that of Ti-Ni binary alloy in which is obtained usually at maximum recovery strain and the reason of the difference is dis Cussed. Deformation temperature Td has a little effect on recovery stress when Td is less than Ms However, recovery stress decreases sharply when Td is higher than M, and lowers approximately down to zero near Msσ展开更多
Total strain controlled cyclic test was performed on 316 LN under uniaxial loadings. Through the partitioning of hysteresis loops, the evolution of two components of cyclic flow stress, the internal and effective stre...Total strain controlled cyclic test was performed on 316 LN under uniaxial loadings. Through the partitioning of hysteresis loops, the evolution of two components of cyclic flow stress, the internal and effective stresses, was reported. The former one determines the cyclic stress response. Based on the transmission electron microscopic（TEM） observation on specimens loaded with scheduled cycles, it is found that planar dislocation structures prevail during the entire cyclic process at low strain amplitude, while a remarkable dislocation rearrangement from planar structures to heterogeneous spatial distributions is companied by a cyclic softening behavior at high strain amplitude. The competition between the evolution of the intergranular and the intragranular components of the internal stress caused by the transition of slip mode induces the cyclic hardening and softening at high strain levels. The intergranular internal stress represents the most part of the internal stress at low strain level.展开更多
基金Project supported by the Science Fund of the Key Laboratory of Cryogenic Science and Technology(Grant Nos.CRYO20230203 and CRYO202106)the National Natural Science Foundation of China(Grant Nos.51872299 and 52071223)the National Key Research and Development Program of China(Grant No.2019YFA0704904)。
文摘Solid-state cooling technologies have been considered as potential alternatives for vapor compression cooling systems.The search for refrigeration materials displaying a unique combination of pronounced caloric effect,low hysteresis,and high reversibility on phase transformation was very active in recent years.Here,we achieved increase in the elastocaloric reversibility and decrease in the friction dissipation of martensite transformations in the superelastic nano-grained NiTi alloys obtained by cold rolling and annealing treatment,with very low stress hysteresis(6.3 MPa)under a large applied strain(5%).Large adiabatic temperature changes(△T_(max)=16.3 K atε=5%)and moderate COP_(mater)values(maximum COP_(mater)=11.8 atε=2%)were achieved.The present nano-grained NiTi alloys exhibited great potential for applications as a highly efficient elastocaloric material.
文摘The effect of deformation on recovery stress of Ni144.7Ti46.3Nb9 alloy has been studjed using tensile test at various temperatures and TEM observation. It ls shown that the recovery stress increases with jncreasing total strain ET and reaches a maximum value (max) as ET= 9% but the maximum recov erV strain of the alloy is only about 4.6%. This is different from that of Ti-Ni binary alloy in which is obtained usually at maximum recovery strain and the reason of the difference is dis Cussed. Deformation temperature Td has a little effect on recovery stress when Td is less than Ms However, recovery stress decreases sharply when Td is higher than M, and lowers approximately down to zero near Msσ
基金Funded by the Nuclear Power Major Project(No.2011zx06004-002)
文摘Total strain controlled cyclic test was performed on 316 LN under uniaxial loadings. Through the partitioning of hysteresis loops, the evolution of two components of cyclic flow stress, the internal and effective stresses, was reported. The former one determines the cyclic stress response. Based on the transmission electron microscopic（TEM） observation on specimens loaded with scheduled cycles, it is found that planar dislocation structures prevail during the entire cyclic process at low strain amplitude, while a remarkable dislocation rearrangement from planar structures to heterogeneous spatial distributions is companied by a cyclic softening behavior at high strain amplitude. The competition between the evolution of the intergranular and the intragranular components of the internal stress caused by the transition of slip mode induces the cyclic hardening and softening at high strain levels. The intergranular internal stress represents the most part of the internal stress at low strain level.
