La（O,F）BiSe2 is a layered superconductor and has the same crystal structure with La（O,F）BiS2. We investigate the electronic structure of La（O,F）BiSe2 using the angle-resolved photoemission spectroscopy. Two elec...La（O,F）BiSe2 is a layered superconductor and has the same crystal structure with La（O,F）BiS2. We investigate the electronic structure of La（O,F）BiSe2 using the angle-resolved photoemission spectroscopy. Two electron-like Fermi surfaces around X（π, 0） are observed, corresponding to the electron doping of 0.23 per Bi site. We clearly resolve anisotropic band splitting along both Г-X and M-X due to the cooperative effects of large spin-orbit coupling and interlayer coupling. Moreover, we observe an almost non-dispersive electronic state around -0.2 eV between the electron-like bands. This state vanishes after in-situ K evaporation, indicating that it could be the localized surface state caused by defects on the cleaved surface.展开更多
The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.79...The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.790(10), V=2717.7(6)A3, Z=3, and R=0.0333 for 4789 unique reflections. The complex anion has a pseudo-octahedral structure distorted more than the CrⅢand CoⅢ analogs, in which cach iminodiacetato ligand (ida2-) is coordinated in a facial fashion with the two N atoms in a cis configuration, resulting in an unsyin-fac structure.展开更多
Intersubband linear and third-order nonlinear optical properties of conical quantum dots with infinite barrier potential are studied. The electronic structure of conical quantum dots through effective mass approximati...Intersubband linear and third-order nonlinear optical properties of conical quantum dots with infinite barrier potential are studied. The electronic structure of conical quantum dots through effective mass approximation is determined analytically. Linear, nonlinear, and total absorption coefficients, as well as the refractive indices of GaAs conical dots, are calculated. The effects of the size of the dots and of the incident electromagnetic field are investigated. Results show that the total absorption coefficient and the refractive index of the dots largely depend on the size of the dots and on the intensity and polarization of the incident electromaenetic field.展开更多
基金Supported by the National Basic Research Program of China under Grant Nos 2015CB921300,2013CB921700 and 2016YFA0300404the National Natural Science Foundation of China under Grant Nos 11474340,11234014,U1532267 and 11674327the Chinese Academy of Sciences under Grant No XDB07000000
文摘La（O,F）BiSe2 is a layered superconductor and has the same crystal structure with La（O,F）BiS2. We investigate the electronic structure of La（O,F）BiSe2 using the angle-resolved photoemission spectroscopy. Two electron-like Fermi surfaces around X（π, 0） are observed, corresponding to the electron doping of 0.23 per Bi site. We clearly resolve anisotropic band splitting along both Г-X and M-X due to the cooperative effects of large spin-orbit coupling and interlayer coupling. Moreover, we observe an almost non-dispersive electronic state around -0.2 eV between the electron-like bands. This state vanishes after in-situ K evaporation, indicating that it could be the localized surface state caused by defects on the cleaved surface.
文摘The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.790(10), V=2717.7(6)A3, Z=3, and R=0.0333 for 4789 unique reflections. The complex anion has a pseudo-octahedral structure distorted more than the CrⅢand CoⅢ analogs, in which cach iminodiacetato ligand (ida2-) is coordinated in a facial fashion with the two N atoms in a cis configuration, resulting in an unsyin-fac structure.
文摘Intersubband linear and third-order nonlinear optical properties of conical quantum dots with infinite barrier potential are studied. The electronic structure of conical quantum dots through effective mass approximation is determined analytically. Linear, nonlinear, and total absorption coefficients, as well as the refractive indices of GaAs conical dots, are calculated. The effects of the size of the dots and of the incident electromagnetic field are investigated. Results show that the total absorption coefficient and the refractive index of the dots largely depend on the size of the dots and on the intensity and polarization of the incident electromaenetic field.
