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Occurrence characteristics of branching structures in equatorial plasma bubbles:a statistical study based on all-sky imagers in China 被引量:2
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作者 Kun Wu JiYao Xu +1 位作者 YaJun Zhu Wei Yuan 《Earth and Planetary Physics》 CSCD 2021年第5期407-415,共9页
Branching structure(BS)is a very important phenomenon in the evolution of equatorial plasma bubbles(EPBs),the mechanism of which is widely studied from observation and from simulation.However,occurrence characteristic... Branching structure(BS)is a very important phenomenon in the evolution of equatorial plasma bubbles(EPBs),the mechanism of which is widely studied from observation and from simulation.However,occurrence characteristics of branching structure of equatorial plasma bubbles(BSEPBs)have not been well addressed.In this work,we used seven-years(2012-2018)of observations from two all-sky imagers to study occurrence of BSEPBs in detail.These data reveal a high incidence of BS in EPB cases;in particular,most EPBs occurring on days with geomagnetic disturbances exhibited BS.Periods when all EPBs exhibited BS increased significantly in the 2014 solar maximum.Occurrence times of BSEPBs varied with local time;most of the BSEPBs began to appear between 21:00 and 22:00 LT.During the solar maximum,some BSEPBs were observed after midnight.The data also reveal that BSEPBs are characterized primarily by two branches or three branches.Multi-branching appeared only in the solar maximum.EPB events with different coexisting branching structures increased from 2012 to 2014 and decreased from 2014 to 2018.These results strongly suggest that BSEPB occurrence is related to solar activity and geomagnetic activity,and thus provide a new perspective for future studies of EPBs as well as enriching our understanding of ionospheric irregularity. 展开更多
关键词 branching structure of equatorial plasma bubble equatorial plasma bubble ionospheric irregularity all-sky imager
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Seismic Sequences’ Branching Structures: Long-Range Interactions and Hazard Levels
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作者 Giulio Riga Paolo Balocchi 《Open Journal of Earthquake Research》 2016年第4期189-205,共17页
Branching structures can provide early information on earthquakes’ preparation process, trigger stage, different breaking patterns that can occur before strong earthquakes and hazard levels reached in the area to be ... Branching structures can provide early information on earthquakes’ preparation process, trigger stage, different breaking patterns that can occur before strong earthquakes and hazard levels reached in the area to be analyzed. In this study, we aim to understand the earthquakes long-range interactions which constitute the nodes of higher order seismic rods in the upper branching structure, and the hazard level reached in each developmental stage as well as to provide a warning time frame for the most energetic seismic events and a sound method to obtain information on the epicentral area. To this end, we have analyzed several branching structures by using both local and global seismicity. The analysis of different branching structures both on global and local scale highlights long-range interactions between the most energetic earthquakes and their triggering by smaller shocks, thus suggesting that the triggering can occur few minutes to decades before the earthquake, depending on a seismic sequence’s development speed and its structure. 展开更多
关键词 branching Structure EARTHQUAKE Microsequence Hierarchization FORESHOCK HAZARD
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Branched fibrous amidoxime adsorbent with ultrafast adsorption rate and high amidoxime utilization for uranium extraction from seawater 被引量:1
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作者 Wan-Ning Ren Xin-Xin Feng +5 位作者 Yu-Long He Ming-Lei Wang Wan-Feng Hong Hong-Wei Han Jiang-Tao Hu Guo-Zhong Wu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第6期79-90,共12页
Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO ... Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO adsorption group utilization remains an issue.We herein fabricated a branched structure containing AO groups on polypropylene/polyethylene spun-laced nonwoven(PP/PE SNW)fibers using grafting polymerization induced by radiation(RIGP)to improve AO utilization.The chemical structures,thermal properties,and surface morphologies of the raw and treated PP/PE SNW fibers were studied.The results show that an adsorptive functional layer with a branching structure was successfully anchored to the fiber surface.The adsorption properties were investigated using batch adsorption experiments in simulated seawater with an initial uranium concentration of 500μg·L^(−1)(pH 4,25℃).The maximum adsorption capacity of the adsorbent material was 137.3 mg·g^(−1)within 24 h;moreover,the uranyl removal reached 96%within 240 min.The adsorbent had an AO utilization rate of 1/3.5 and was stable over a pH range of 4–10,with good selectivity and reusability,demonstrating its potential for seawater uranium extraction. 展开更多
关键词 Radiation graft technology branching structure High amidoxime utilization Seawater uranium extraction Ultrafast adsorption
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Anomalous diffusion in branched elliptical structure
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作者 Kheder Suleiman 张雪岚 +2 位作者 王二辉 刘圣娜 郑连存 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第1期137-144,共8页
Diffusion in narrow curved channels with dead-ends as in extracellular space in the biological tissues,e.g.,brain,tumors,muscles,etc.is a geometrically induced complex diffusion and is relevant to different kinds of b... Diffusion in narrow curved channels with dead-ends as in extracellular space in the biological tissues,e.g.,brain,tumors,muscles,etc.is a geometrically induced complex diffusion and is relevant to different kinds of biological,physical,and chemical systems.In this paper,we study the effects of geometry and confinement on the diffusion process in an elliptical comb-like structure and analyze its statistical properties.The ellipse domain whose boundary has the polar equationρ(θ)=b/√1−e^(2)cos^(2)θ with 0<e<1,θ∈[0,2π],and b as a constant,can be obtained through stretched radius r such that Υ=rρ(θ)with r∈[0,1].We suppose that,for fixed radius r=R,an elliptical motion takes place and is interspersed with a radial motion inward and outward of the ellipse.The probability distribution function(PDF)in the structure and the marginal PDF and mean square displacement(MSD)along the backbone are obtained numerically.The results show that a transient sub-diffusion behavior dominates the process for a time followed by a saturating state.The sub-diffusion regime and saturation threshold are affected by the length of the elliptical channel lateral branch and its curvature. 展开更多
关键词 anomalous diffusion Fokker–Planck equation branched elliptical structure
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Analysis on the Composition and Structure of Branches of Two Kinds of Tree Shapes in Korla Fragrant Pear 被引量:2
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作者 成小龙 廖康 +4 位作者 李楠 赵世荣 孙慧瑛 曼苏尔.那斯尔 刘娟 《Agricultural Science & Technology》 CAS 2013年第7期954-958,共5页
ObjectiveThe thesis aims at investigating the distribution and structural characteristics of various branches in canopy of Korla fragrant pear. MethodStatistic work and analysis were conducted on the numbers and distr... ObjectiveThe thesis aims at investigating the distribution and structural characteristics of various branches in canopy of Korla fragrant pear. MethodStatistic work and analysis were conducted on the numbers and distribution characteristics of various branches in each cubic lattice by using the canopy cellular method. ResultThe results showed that: The total number of scaffold branches of evacuation layered tree shape was 97, which mainly distributed in the lower layer and middle part of the canopy; the total number of scaffold branches of open-center tree shape was 94, which mainly distributed in the lower layer and middle part of the canopy. The total number of annual branches of evacuation layered tree shape was 3 920, which mainly distributed in the middle layer and outer part of the canopy; and the total number of annual branches of the open-center tree shape was 3 183, which mainly distributed in middle layer and outer part of the canopy. The total number of perennial branches of evacuation layered tree shape was 2 184, which mainly distributed in lower layer and outer part of the canopy; the total number of perennial branches of open-center tree shape was 1 444, which mainly distributed in middle layer and outer part of the canopy. ConclusionThe total number and the distribution positions of scaffold branches in the canopy of each tree shape were basically the same. The total numbers of annual branches of the two kinds of tree shapes were different, but the distribution positions were basically the same. The total numbers and the distribution positions of perennial branches in the canopy of the two kinds of tree shapes were different. 展开更多
关键词 Korla fragrant pear Tree shape Composition and structure of branch
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Mantle Branch Structure in the South-Central Segment of the Da Hinggan Mts.,Inner Mongolia and Its Ore-controlling Role 被引量:4
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作者 NIU Shuyin SUN Aiqun +5 位作者 WANG Baode NIE Fengjun JIANG Sihong SHAO Ji'an GUO Lijun LIU Jianming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2009年第6期1148-1162,共15页
Mantle branch structure is the third tectonic unit of multiple evolution of a mantle branch. It is not only the main mechanism of intercontinental orogeny, but also an important ore-forming and ore-control structure. ... Mantle branch structure is the third tectonic unit of multiple evolution of a mantle branch. It is not only the main mechanism of intercontinental orogeny, but also an important ore-forming and ore-control structure. Studies on geotectonic evolution, regional geological characteristics and oreforming and ore-control structures have shown that since the Mesozoic the Da Hinggan Mts. region has entered a typical intercontinental orogenic stage, and it is closely related to mantle branch activities. The south-central segment of the Da Hinggan Mts. is a typical mantle branch structure and possesses obvious magmatic-metamorphic complexes in the core, detachment slip beds in the periphery and overlapped fault depression basins. Moreover, all of these are the principal factors leading to ore formation and ore control in the region. This paper also further explores the mechanism of mineralization in the south-central segment of the Da Hinggan, summaries the rules of mineralization, puts forward the models of mineralization and points out future ore-exploring orientation. 展开更多
关键词 mantle branch structure mantle branch metallogenic model Da Hinggan Mts.
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Timing of mineralization at the Shihu gold deposit in the middle segment of the Taihang Mountain, China 被引量:4
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作者 Chao Chen Shuyin Niu +7 位作者 Fang Wang Fuxiang Zhang Qinglian Zhang Baojun Ma Aiqun Sun Jianzhen Zhang Yaqi Cao Xiaoqing Zhang 《Acta Geochimica》 EI CAS CSCD 2018年第1期80-89,共10页
The Shihu gold deposit, located in the middlesouth section of the core of the Fuping mantle branch structure, is hosted in the Archean Fuping Group and adjacent to the quartz diorite porphyrite. The gold deposit is th... The Shihu gold deposit, located in the middlesouth section of the core of the Fuping mantle branch structure, is hosted in the Archean Fuping Group and adjacent to the quartz diorite porphyrite. The gold deposit is the only large gold deposit with reserves of more than 30 tons gold discovered in western Hebei Province so far. In order to constrain the timing of mineralization of this ore deposit, this paper focuses on the isotopic dating of zircon and pyrite. Zircons in gold-bearing quartz veins are magmatic in origin and no hydrothermal zircon has been found in such quartz veins, indicating that zircons were derived from the wall rocks. U–Pb ages of zircons fall mainly in the two domains: 2492 ± 82 and 136 ± 4 Ma, respectively,indicative of the contribution of the Fuping-Group TTG gneiss and Yanshanian igneous rocks, respectively. The Re–Os isotopic compositions of pyrites in the gold-bearing quartz veins yield an isochron age of 127 ± 31 Ma. Combined with other dating results, we suggest that the main metallogenic age of the Shihu gold deposit is 120–127 Ma. 展开更多
关键词 Mantle branch structure Shihu gold deposit Zircon U–Pb dating Pyrite Re–Os dating Gold-bearing quartz vein
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Large Eddy Simulation of Gasoline-Air Mixture Explosion in Long Duct with Branch Structure 被引量:3
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作者 Chong Liu Yang Du +3 位作者 Jianjun Liang Hong Meng Jian Wang Peili Zhang 《Fluid Dynamics & Materials Processing》 EI 2020年第3期537-547,共11页
Gas explosion is a process involving complex hydrodynamics and chemical reactions.In order to investigate the interaction between the flame behavior and the dynamic overpressure resulting from the explosion of a premi... Gas explosion is a process involving complex hydrodynamics and chemical reactions.In order to investigate the interaction between the flame behavior and the dynamic overpressure resulting from the explosion of a premixed gasoline-air mixture in a confined space,a large eddy simulation(LES)strategy coupled with sub-grid combustion model has been implemented.The considered confined space consists of a long duct and four branches symmetrically distributed on both sides of the long duct.Comparisons between the simulated and experimental results have been considered with regard to the flame structure,flame speed and overpressure characteristics.It is shown that the explosion process can qualitatively be reproduced by the numerical simulation.Due to the branch structure,vortices are generated near the joint of the branch and long duct.Vortices rotate in opposite directions in the different branches.When the flame propagates into the branch,the flame front is influenced by the flow field structure and becomes more and more distorted.The overpressure displays a similar behavior in the two branches which have a different distance from the ignition point.It is finally shown that the overpressure change law can directly be put in relation with the shape of flame front. 展开更多
关键词 Branch structure large eddy simulation premixed gasoline-air mixture explosion
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Short-Term Earthquake Forecast with the Seismic Sequence Hierarchization Method 被引量:4
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作者 Giulio Riga Paolo Balocchi 《Open Journal of Earthquake Research》 2016年第2期79-96,共18页
All strong earthquakes are preceded by branching structures having different durations whose development scheme is partly largely predictable because it follows a well organized and recognizable pattern. By using a se... All strong earthquakes are preceded by branching structures having different durations whose development scheme is partly largely predictable because it follows a well organized and recognizable pattern. By using a seismic sequence hierarchization method, this study graphically explains the preparation process of an earthquake, called “branching structure”. In addition, criteria apt to distinguish the structures that will produce shocks of average magnitude from strong earthquakes’ will be defined. Based on the temporal oscillations of the magnitude values, we explain the procedure for identifying the developmental stages that characterize the energy accumulation stage of the branching structure, in order to early detect the energy release stage’s trigger point and obtain information on how it will develop over time. The study identifies also some pre-signals (trigger points) of various magnitudes in the energy release stage, which allows us to early predict the foreshocks and mainshock time position. The method we developed constitutes a truly innovative approach for the earthquake forecasting analysis, which dramatically differs from those developed so far, as it considers the structure of the seismic sequence not only as a magnitude values’ oscillation, but also as a sequence of developmental stages that may begin much earlier. 展开更多
关键词 branching Structure EARTHQUAKE Microsequence Hierarchization FORESHOCK
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Branch Structure of Corona Discharge: Experimental Simulation and Chemical Properties
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作者 邹吉军 刘昌俊 《Plasma Science and Technology》 SCIE EI CAS CSCD 2004年第6期2585-2588,共4页
The branch structure of corona discharge has been investigated via C2H2 corona discharge. Carbon filament with excellent branch structure is formed in the discharge. This carbon filament offers a direct mimic of the b... The branch structure of corona discharge has been investigated via C2H2 corona discharge. Carbon filament with excellent branch structure is formed in the discharge. This carbon filament offers a direct mimic of the branch structure of corona discharge. It provides a very useful way to study on the average energy, physical and chemical characteristics of corona discharge. On this basis, the chemical property of corona discharge for methane conversion is discussed. 展开更多
关键词 corona discharge branch structure ACETYLENE carbon filament methane con- version
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Diffusion dynamics in branched spherical structure
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作者 Kheder Suleiman Xue-Lan Zhang +1 位作者 Sheng-Na Liu Lian-Cun Zheng 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第11期172-178,共7页
Diffusion on a spherical surface with trapping is a common phenomenon in cell biology and porous systems.In this paper,we study the diffusion dynamics in a branched spherical structure and explore the influence of the... Diffusion on a spherical surface with trapping is a common phenomenon in cell biology and porous systems.In this paper,we study the diffusion dynamics in a branched spherical structure and explore the influence of the geometry of the structure on the diffusion process.The process is a spherical movement that occurs only for a fixed radius and is interspersed with a radial motion inward and outward the sphere.Two scenarios govern the transport process in the spherical cavity:free diffusion and diffusion under external velocity.The diffusion dynamics is described by using the concepts of probability density function(PDF)and mean square displacement(MSD)by Fokker–Planck equation in a spherical coordinate system.The effects of dead ends,sphere curvature,and velocity on PDF and MSD are analyzed numerically in detail.We find a transient non-Gaussian distribution and sub-diffusion regime governing the angular dynamics.The results show that the diffusion dynamics strengthens as the curvature of the spherical surface increases and an external force is exerted in the same direction of the motion. 展开更多
关键词 anomalous diffusion Fokker-Planck equation branched spherical structure
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Heterocyclic Molecules Tethered Branched Polymers with Innate Immune Stimulating Activity
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作者 Jiayu Zhao Liping Liu +7 位作者 Yibo Wang Zichao Huang Yu Zhang Ruirui Qiao Thomas P.Davis Zhaohui Tang Wantong Song Xuesi Chen 《CCS Chemistry》 CSCD 2024年第5期1278-1288,共11页
We report herein an interesting finding that heterocyclic molecules tethered branched polymers exhibit innate immune stimulating activity.When we conjugated a series of five-,six-,or seven-membered heterocyclic molecu... We report herein an interesting finding that heterocyclic molecules tethered branched polymers exhibit innate immune stimulating activity.When we conjugated a series of five-,six-,or seven-membered heterocyclic molecules to branched polyethylenimine(bPEI),over 70%of them could induce the secretion of interferon-β(IFN-β)from murine dendritic and human leukemia monocytic(DC2.4 and THP-1)cells through activating the stimulator of interferon genes(STING)pathway.We further proved that this kind of innate stimulating activity was dependent on the macromolecular architecture as heterocyclic molecules tethered linear PEI(lPEI)or dendritic polyamidoamine(PAMAM)induced no or much less IFN-βsecretion.Furthermore,we prepared a series of poly-L-lysine(PLL)-derivatives with different branches to tether with heterocyclic molecules and proved that this kind of bPEI-like structure was important in en hancing the binding affinity with STING proteins and for exhibiting innate stimulating activity. 展开更多
关键词 bioactive materials POLYMERS HETEROCYCLES branched structure IMMUNITY
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Tree-inspired dendriforms and fractal-like branching structures in architecture: A brief historical overview 被引量:14
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作者 Iasef Md Rian Mario Sassone 《Frontiers of Architectural Research》 CSCD 2014年第3期298-323,共26页
The shapes of trees are complex and fractal-like, and they have a set of physical, mechanical and biological functions. The relation between them always draws attention of human beings throughout history and, focusing... The shapes of trees are complex and fractal-like, and they have a set of physical, mechanical and biological functions. The relation between them always draws attention of human beings throughout history and, focusing on the relation between shape and structural strength, architects have designed a number of treelike structures, referred as dendriforms. The replication and adoption of the treelike patterns for constructing architectural structures have been varied in different time periods based on the existing and advanced knowledge and available technologies. This paper, by briefly discussing the biological functions and the mechanical properties of trees with regard to their shapes, overviews and investigates the chronological evolution and advancements of dendriform and arboreal structures in architec- ture referring to some important historical as well as contemporary examples. 展开更多
关键词 ARCHITECTURE TREE Dendriforms Fractal geometry branching structures TECHNOLOGY
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The Effect of Branching Structure on the Properties of Entangled or Non-covalently Crosslinked Polyisoprene
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作者 Mo-Kun Chen Rong Zhang +2 位作者 Mao-Zhu Tang Guang-Su Huang Yun-Xiang Xu 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2021年第1期113-121,I0008,共10页
The branching structures in natural rubber(NR) were believed to be critical for its superior mechanical properties. However, it is challenging to unravel the branching structure-function relationship of NR due to the ... The branching structures in natural rubber(NR) were believed to be critical for its superior mechanical properties. However, it is challenging to unravel the branching structure-function relationship of NR due to the complexity of the system. Herein, polyisoprene-(polyisoprene-g-polylactide)(PI-PLA) as model compound containing branching structure was designed and synthesized, which can improve the modulus, strength and viscoelasticity activation energy compared to those of the pristine polyisoprene(PI). The reason is that the branching structure contributes to the entanglement between polyisoprene chains. In order to probe the effect of branching structure on noncovalently crosslinked system, the polyisoprene block of PI-PLA was epoxidized and mixed with Fe3+ ions to introduce coordination bonds. Compared with the linear counterpart, the branching structure obviously enhanced activation energy of coordinated polyisoprenes, remarkably improving the mechanical properies of elastomer. 展开更多
关键词 Natural rubber branching structure Noncovalent interaction POLYISOPRENE
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Architecting Branch Structure in Terpolymer of CO_(2),Propylene Oxide and Phthalic Anhydride:An Enhancement in Thermal and Mechanical Performances 被引量:7
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作者 Wen-Jing Wang Shu-Xian Ye +5 位作者 Jia-Xin Liang Cong-Xiao Fan Yong-Lan Zhu Shuan-Jin Wang Min Xiao Yue-Zhong Meng 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2022年第5期462-468,共7页
Poly(propylene carbonate phthalate)(PPC-P)is a chemically modified poly(propylene carbonate)(PPC)biodegradable thermoplastic by introducing phthalic anhydride(PA)as the third monomer into the copolymerization of propy... Poly(propylene carbonate phthalate)(PPC-P)is a chemically modified poly(propylene carbonate)(PPC)biodegradable thermoplastic by introducing phthalic anhydride(PA)as the third monomer into the copolymerization of propylene oxide(PO)and CO_(2).To enhance the thermal and mechanical properties of PPC-P,a branching agent pyromellitic anhydride(PMDA)was introduced into the terpolymerization of PO,PA and CO_(2).The resulting copolymers with branched structure,named branched PPC-P,can be obtained using metal-free Lewis pair consisting of triethyl borane(TEB)and bis(triphenylphosphine)iminium chloride(PPNCl)as catalyst.The products obtained were analyzed by NMR spectroscopy and their thermal,mechanical properties and melt processability were evaluated by DSC,TGA,tensile test and melt flow index(MFI)measurement.The obtained branched PPC-P has a high molecular weight up to 156.0 kg·mol^(-1).It shows an increased glass transition temperature(Tg)higher than 50℃and an enhanced tensile strength as high as 38.9 MPa.Noteworthily,the MFI value decreases obviously,indicative of an improved melt strength arising from the branched structure and high molecular weight.What is more,the branched PPC-P exhibits reasonable biodegradability,which demonstrates the great potential as a new green thermoplastic for the family of biodegradable plastics. 展开更多
关键词 CO_(2)utilization Pyromellitic anhydride BIODEGRADABILITY Branched structure Melt flow index
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In-situ growth of Ni nanoparticle-encapsulated N-doped carbon nanotubes on carbon nanorods for efficient hydrogen evolution electrocatalysis 被引量:6
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作者 Xiaoxiao Yan Minyi Gu +3 位作者 Yao Wang Lin Xu Yawen Tang Renbing Wu 《Nano Research》 SCIE EI CAS CSCD 2020年第4期975-982,共8页
Searching for inexpensive,efficient and durable electrocatalysts with earth-abundant elements toward the hydrogen evolution reaction(HER)is of vital importance for the future sustainable hydrogen economy,yet still rem... Searching for inexpensive,efficient and durable electrocatalysts with earth-abundant elements toward the hydrogen evolution reaction(HER)is of vital importance for the future sustainable hydrogen economy,yet still remains a formidable challenge.Herein,a facile template-engaged strategy is demonstrated for the direct in-situ growth of Ni nanoparticles and N-doped carbon nanotubes on carbon nanorod substrates,forming a hierarchically branched architecture(abbreviated as Ni@N-C NT/NRs hereafter).The elaborate construction of such unique hierarchical structure with tightly encapsulated Ni nanoparticles and open configuration endows the as-fabricated Ni@N-C NT/NRs with abundant well-dispersed active sites,enlarged surface area,reduced resistances of charge transfer and mass diffusion,and reinforced mechanical robustness.As a consequence,the optimal Ni@N-C NT/NR catalyst demonstrates superior electrocatalytic activity with relatively low overpotential of 134 mV to deliver a current density of 10 mA·cm^-2 and excellent stability for HER in 0.1 M KOH,holding a great promise for practical scalable H2 production.More importantly,this work offers a reliable methodology for feasible fabrication of robust high-performance carbon-based hierarchical architectures for a variety of electrochemical applications. 展开更多
关键词 hydrogen evolution reaction nitrogen-doped carbon nanotubes Ni nanoparticles carbon nanorods hierarchically branched structure
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Reactive processing of poly(lactic acid)/poly(ethylene octene) blend film with tailored interfacial intermolecular entanglement and toughening mechanism 被引量:5
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作者 Wenjun He Lin Ye +2 位作者 Phil Coates Fin Caton-Rose Xiaowen Zhao 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第3期186-196,共11页
In order to obtain a uniform and effectively toughened poly(lactic acid)film by blending with low content of poly(ethylene octene)(POE)with high elasticity,the tailored interfacial intermolecular interaction and entan... In order to obtain a uniform and effectively toughened poly(lactic acid)film by blending with low content of poly(ethylene octene)(POE)with high elasticity,the tailored interfacial intermolecular interaction and entanglement between the two phases of the PLA/POE blend was innovatively constructed via the facile reactive melt blending process through the reaction of the epoxy/anhydride groups grafted on the POE chains with the end groups of PLA chains(PLA/GPOE-MPOE).It was observed that POE domains were embedded tightly in PLA matrix with a fuzzy interface and abundant interface transition area,and the impact fractured surface of the blend showed an obvious plastic deformation with less occurrence of fibrillation of PLA matrix or interfacial de-bonding.Compared with neat PLA and directly blended PLA/POE blends,the PLA/GPOE-MPOE blend exhibited much higher complex viscosity/storage modulus,much lower tanδvalues in the terminal region,and obvious strain-hardening behavior.The deviation in viscoelastic behavior of PLA/GPOE-MPOE from linear PLA indicated the enhanced molecular entanglement between the long-branched chains,resulting in an enhancement of the stretching ability during biaxial drawing of the blend.Uniform PLA/GPOE-MPOE films with draw ratio as high as 7×7 were obtained through biaxial stretching,which showed much higher tensile strength and the elongation at break than that of neat PLA and PLA/POE film.This work provides a facile method for fabricating toughening PLA films with application potentials. 展开更多
关键词 Poly(lactic acid)/poly(ethylene octene)(PLA/POE)blend film Reactive processing Tailored interfacial intermolecular interaction Long-chain branched structure Toughening mechanism
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