Transient Spectroscopic Properties of [60]Fullerene-Containing Cyclic Sulphoxide

The properties of the triplet excited state of [60]fullerene-containing cyclic sulphoxide have been investigated by time-resolved absorption spectroscopy. Transient absorption bands of [60]fullerene-containing cyclic sulphoxide showed two decay-components, which were attributed to triplet excited states of different spin multiplicity. The properties of photoexcited states of [60]fullerene-containing cyclic sulphoxide are also reported.

The Synthesis of Neodymium Complexes with Polymers Containing Thiol and Sulphoxide and Their Catalytic Activities

Introduction Polymers containing thiol and sulphoxide which have active—SH and—SO groups respectively, have wide application to biological, pharmaceutical, industrial and other chemical field and—SH and—SO groups are easy to form complexes with metals, so they have aroused an increasing interest of many authors. A large number of functional resins and corresponding metal complexes have been synthesized.

Photophysical Properties and Photoinduced Electron Transfer between [60] Fullerene-Containing Cyclic Sulphoxide [C_(60)-C_6H_8SO] and Tetrathiafulvalene (TTF) by Laser Flash Photolysis

Photoinduced electron transfer (PET) processes between C 60-C 6H 8SO and Tetrathiafulvalene (TTF) have been studied by nanosecond laser photolysis. Quantum yields (Φ et) and rate constants of electron transfer (k et) from TTF to excited triplet state of fullerene-containing cyclic sulphoxide in benzonitrile (BN) have been evaluated by observing the transient absorption bands in the NIR region. With the decay of excited triplet state of fullerene-containing cyclic sulphoxide, the rise of radical anion of fullerene-containing cyclic sulphoxide is observed.

Phenyl iodonium bis(perfluoroalkanesulphonyl)-methide-dimethyl sulphoxide complex——Its formation and X-ray structure analysis

Irradiation of phenyl iodonium bis(perfluoroalkanesulphonyl)methide in DMSO yields an 1:1 adduct, DMSO·PhI=C(SO_2R_F)_2 (2) which was confirmed by X-ray crystal structure analysis.

Investigation of hydrogen bonding in neat dimethyl sulfoxide and binary mixture(dimethyl sulfoxide + water) by concentration-dependent Raman study and ab initio calculation

In this study, our vibrational spectroscopic analysis is made on hydrogen-bonding between dimethyl sulfoxide and water comprises both experimental Raman spectra and ab initio calculations on structures of various dimethyl sulfoxide/water clusters with increasing water content. The Raman peak position of the v（S=O） stretching mode of dimethyl sulfoxide serves as a probe for monitoring the degree of hydrogen-bonding between dimethyl sulfoxide and water. In addition, the two vibrational modes, namely, the CH3 symmetric stretching mode and the CH3 asymmetric stretching mode have been analysed under different concentrations. We relate the computational results to the experimental vibrational wavenumber trends that are observed in our concentration-dependent Raman study. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the nature of the hydrogen bonding and the structures of the hydrogen-bonded complexes studied.