Linking Diffractive and Geometrical Optics Surface Scattering at a Fundamental Level

Optical surface scattering analyses based on diffractive optics (DO) are typically applied to one surface;however, there is a need for simulating surface scattering losses for devices having many surface interactions such as light pipes. Light pipes are often simulated with geometric optics (GO) using ray tracing, where surface scattering is driven by the surface slope distribution. In the DO case, surface scattering analyses depend on the spatial frequency distribution and amplitude as well as wavelength, with the sinusoidal grating as a fundamental basis. A better understanding of the link, or transition, between DO and GO scattering domains would be helpful for efficiently incorporating scattering loss analyses into ray trace simulations. A formula for the root-mean-square (rms) scattered angle width of a sinusoidal reflection grating that depends only on the surface rms slope is derived from the nonparaxial scalar diffraction theory, thereby linking it to GO. The scatter angle’s mean and rms width are evaluated over a range of grating amplitudes and periods using scalar theory and full vector simulations from the COMSOL® wave optic module for a sinusoidal reflection grating. The conditions under which the diffraction-based solution closely approximates the GO solution, as predicted by the rms slope, are identified. Close agreement is shown between the DO and GO solutions for the same surface rms slope scattering loss due to angular filtering near the critical angle of a total internal reflection (TIR) glass-to-air interface.

Nearest Object Priority Based Integrated Rough Surface Scattering Algorithm for 3D Indoor Propagation Prediction

Since rough surface scattering has a great impact on the accuracy of the propagation prediction algorithm,an integrated algorithm for indoor propagation prediction including rough surface scattering is proposed here.This algorithm is composed of a three dimensional(3D) ray tracing algorithm based on binary space partitioning(BSP) and a diffuse scattering algorithm based on Oren-Nayar's theory.Lack of accuracy and prohibitive time consumption are the main drawbacks of the existing ray tracing based propagation prediction models.To defy these shortcomings,the balanced BSP tree is used in the proposed algorithm to accelerate the ray tracing,while the nearest object priority technique(NOP) and in contact surface(ICS) is used to eliminate the repeated rayobject intersection tests.Therefore,the final criteria of this study are the time consumption as well as accuracy by predicting the field strength and the number of received signals.Using the proposed approaches,our algorithm becomes faster and more accurate than the existing algorithms.A detailed comparative study with existing algorithms shows that the proposed algorithm has at most 37.83%higher accuracy and 34.44%lower time consumption.Moreover,effects of NOP and ICS techniques and scattering factor on time and ray prediction accuracy are also presented.

Quantum Transport and Surface Scattering in Magnetic Metallic Film

Taking into account the quantum size effect and the spin dependence of the electronic band structure,and including the spin dependence of the scattering from bulk impurities and two different sets of surface roughness,wepresent a theory on the electronic transport in magnetic film,in which the average autocorrelation function (ACF) forsurface roughness is described by a Gaussion model.Our result shows that the conductivity is a sensitive function ofsurface roughness and exchange energy.It is also found that in the thin film limit and in the lower-order approximationof the surface scattering,the total conductivity is given by a sum of conductivities of all the subbands and the two spinchannels,for each subband and each spin channel the scattering rates due to the impurities and two surfaces are additive.

Surface Enhanced Raman Scattering on Self-assembled Nano Silver Film Prepared by Electrolysis Method

We demonstrate surface enhanced Raman scattering （SERS） detection of self-assembled nano silver film using a low-cost electrolysis strategy at a proper voltage and silver nitrate concentration in electrolyte. The concentration dependence of SERS from crystal violet （CV） molecules adsorbed to silver film was systematically studied. Importantly, the SERS surface enhancement factor of such nano silver film was 603, which was measured by a portable Raman spectrometer. The minimum concentration of detectable CV molecules can be as low as 10^-11 mol/L. The nano silver film prepared by this electrolysis method is an active, stable, cost-effective, and reusable SERS substrate.

Sea Surface Effects on Sound Scattering in the Persian Gulf Region Based on Empirical Relations

In this paper, sound scattering from the sea surface in the Persian Gulf region is investigated. Chapman-Harris and Ogden-Erskine empirical relations coupled with perturbation theory are implemented. Based on the Ogden and Erskine＇s experiments, sound scattering from the sea surface has three different regimes in which two mechanisms of surface roughness and subsurface bubble clouds are involved. Ogden-Erskine＇s scattering relation which consists of perturbation theory and Chapman-Harris＇s scattering terms are verified by the experimental data of Critical Sea Tests 7. Subsequently, wind speed in the Persian Gulf is provided based on three data bases of Arzanah station, ERA40, and PERGOS. Accordingly, surface scattering strength in the Persian Gulf region is calculated at different grazing angles, frequencies and provided wind speeds. Based on the resulted values of scattering strength, scattered intensity from the sea surface is also studied. These studies indicate that both scattering strength and scattered intensity generally increase as grazing angle, frequency and wind speed increase.

Impact of crystal orientation and surface scattering on DG-MOSFETs in quasi-ballistic region

The characteristics of nano scale n-type double gate MOSFETs with（100） and（110） surfaces are studied using 3 D full band ensemble Monte Carlo simulator. The anisotropic surface scattering mechanism is investigated. The（100） case is sensitive to the gate voltage more than the（110） case. The impact of crystal orientation and surface scattering on transport features mainly reflects in the carrier velocity distribution. The electron transport features with（100） direction are greater than that with（110） direction, but are more likely to be affected by the surface scattering.

Sound Scattering From Rough Bubbly Ocean Surface Based on Modified Sea Surface Acoustic Simulator and Consideration of Various Incident Angles and Sub-surface Bubbles＇ Radii

The aim of the present study is to improve the capabilities and precision of a recently introduced Sea Surface Acoustic Simulator(SSAS) developed based on optimization of the Helmholtz–Kirchhoff–Fresnel(HKF) method. The improved acoustic simulator, hereby known as the Modified SSAS(MSSAS), is capable of determining sound scattering from the sea surface and includes an extended Hall–Novarini model and optimized HKF method. The extended Hall–Novarini model is used for considering the effects of sub-surface bubbles over a wider range of radii of sub-surface bubbles compared to the previous SSAS version. Furthermore, MSSAS has the capability of making a three-dimensional simulation of scattered sound from the rough bubbly sea surface with less error than that of the Critical Sea Tests(CST) experiments. Also, it presents scattered pressure levels from the rough bubbly sea surface based on various incident angles of sound. Wind speed, frequency, incident angle, and pressure level of the sound source are considered as input data, and scattered pressure levels and scattering coefficients are provided. Finally, different parametric studies were conducted on wind speeds, frequencies, and incident angles to indicate that MSSAS is quite capable of simulating sound scattering from the rough bubbly sea surface, according to the scattering mechanisms determined by Ogden and Erskine. Therefore, it is concluded that MSSAS is valid for both scattering mechanisms and the transition region between them that are defined by Ogden and Erskine.

EFFECT OF SOLVENT ON SURFACE ENHANCED RAMAN SCATTERING SPECTRA OF COLLOIDAL SILVER

The effect of solvent on surface enhanced Raman scattering [SERS) of colloidal silver has been studied. Experiments show that the intensity of SERS is related to the polarity and molecular constitution of the solvent. The influence of solvent is due to the change of the adsorption quantity and adsorption intensity.

Surface-enhanced Raman scattering properties of highly ordered self-assemblies of gold nanorods with different aspect ratios

Gold nanorods with aspect ratios of from 1 （particles） to 31.6 were synthesized by the seed-mediated method and packed in a highly ordered structure on a large scale on silicon substrates through capillary force induced self-assembly behaviour during solvent evaporation. The gold nanorod surface exhibits a strong enhancing effect on Raman scattering spectroscopy. The enhancement of Raman scattering for two model molecules （2-naphthalenethiol and rhodamine 6C） is about 5-6 orders of magnitude. By changing the aspect ratio of the Au nanorods, we found that the enhancement factors decreased with the increase of aspect ratios. The observed Raman scattering enhancement is strong and should be ascribed to the surface plasmon coupling between closely packed nanorods, which may result in huge local electromagnetic field enhancements in those confined junctions.

The effects of strain and surface roughness scattering on the quasi-ballistic characteristics of a Ge nanowire p-channel field-effect transistor

The effects of strain and surface roughness scattering on the quasi-ballistic hole transport in a strained gate-all-around germanium nanowire p-channel field-effect transistor （pFET） are investigated in this work. The valence subbands are shifted up and warped more parabolically by the influence of HfO2 due to the lattice mismatch. However, the boundary force only shifts the subbands downwards and has little effect on the reshaping of bands. Strain induced by HfO2 increases both the hole mobility and ON-current （/ON）, but has little effect on the hole mobility. The/ON is degraded by the surface roughness scattering in both strained and unstrained devices.

Electron mobility limited by surface and interface roughness scattering in Al_xGa_(1-x)N/GaN quantum wells

The electron mobility limited by the interface and surface roughness scatterings of the two-dimensional electron gas in AlxGa1-xN/GaN quantum wells is studied. The newly proposed surface roughness scattering in the AlGaN/GaN quantum wells becomes effective when an electric field exists in the AlxGa1-xN barrier. For the AlGaN/GaN potential well, the ground subband energy is governed by the spontaneous and the piezoelectric polarization fields which are determined by the barrier and the well thicknesses. The thickness fluctuation of the AlGaN barrier and the GaN well due to the roughnesses cause the local fluctuation of the ground subband energy, which will reduce the 2DEG mobility.

Numerical study of electromagnetic scattering from one-dimensional nonlinear fractal sea surface

In recent years, linear fractal sea surface models have been developed for the sea surface in order to establish an electromagnetic backscattering model. Unfortunately, the sea surface is always nonlinear, particularly at high sea states. We present a nonlinear fractal sea surface model and derive an electromagnetic backscattering model. Using this model, we numerically calculate the normalized radar cross section （NRCS） of a nonlinear sea surface. Comparing the averaged NRCS between linear and nonlinear fractal models, we show that the NRCS of a linear fractal sea surface underestimates the NRCS of the real sea surface, especially for sea states with high fractal dimensions, and for dominant ocean surface gravity waves that are either very short or extremely long.

TiO_2/Ag composite nanowires for a recyclable surface enhanced Raman scattering substrate

Multifunctional TiO2/Ag composite nanowires are fabricated with a hydrothermal method by precipitating Ag nanoparticles （NPs） on the surfaces of TiO2 nanowires. This hierarchical one-dimensional （1D） nanostructure can be used as a surface enhanced Raman scattering （SERS） substrate with high sensitivity, for detecting the rhodamine 6G （R6G） in a wide range of low concentrations （from 1 × 10 6 M to 1 × 10-12 M）. In addition, the substrate can be self-cleaned under the irradiation of ultraviolet （UV） light due to the superior photocatalytic capacity of the TiO2/Ag composite nanostructure, making the recycled use of SERS substrates closer to reality. With both the evident SERS performance and high efficiency of photocatalytic capacity, such TiOz/Ag composite nanowires demonstrate considerable potential in the chemical sensing of organic pollutants.

STUDY ON PHOTO-INDUCED ORIENTATION OF A NOVEL PHOTO-ALIGNMENT FILM WITH SURFACE ENHANCED RAMAN SCATTERING (SERS) SPECTROSCOPY

Surface enhanced Raman scattering (SERS) spectroscopy was first utilized to study the photo-orientation behaviour of the photoreactive groups on a novel photo-alignment film surface and elucidate the generation mechanism of pretilt angle. The novel photo-alignment film was prepared by spin-coating a solution of ladderlike polysiloxane (LPS) bearing dual photoreactive group on an ITO surface and by irradiation with linear-polarized ultraviolet (LPUV) light A Si—H terminal compound (M) containing an identical photosensitive part has been used to fabricate a model film for SERS investigation.

Monitoring the penetration and accumulation of gold nanoparticles in rat skin ex vivo using surface-enhanced Raman scattering spectroscopy

Contamination by accidental cutaneous contact with the commercial products and the air pol-hutants raised a considerable health and safety issue.This study aimed to trace the dynamics of the 20 nm gold nanopartide(GNP)penetration and accumulation in rat skin tissues using a surface-enhanced Raman scattering(SERS)techmique.After the topical application of GNPs on rat skin surface,the SERS spectra were recorded for every 15 pum to an overall depth of 75 pum from skin surface for 150 min.The processes of GNP penetration in rat skin were accompanied by aggregation of GNPs,which affected SERS spectra.The results revealed that 20 nm GNPs can penetrate through stratum corneum layer,viable epidermis layer,and then into dermis layer.This study demonstrated for the first time the potential of SERS spectroscopy to monitor the penetration and accumulation of GNPs in rat skin.

SURFACE ENHANCED RAMAN SCATTERING OF C_(60) FILMS ON VARIOUS ACTIVE SUBSTRATES

In this paper,we report the study of surface-enhanced Raman Scattering of C_(60)films on roughed Ag,Cu and glass surface.The experiment results indicate that the C_(60)films on Ag substrate possess large enhance effect.An explanation of the enhancement with roughed glass surface is proposed based on waveguide Raman Scattering.

An Alternative Method to Study Wave Scattering by Semi-infinite Inertial Surfaces

A new method to solve the boundary value problem arising in the study of scattering of two-dimensional surface water waves by a discontinuity in the surface boundary conditions is presented in this paper. The discontinuity arises due to the floating of two semi-infinite inertial surfaces of different surface densities. Applying Green＇s second identity to the potential functions and appropriate Green＇s functions, this problem is reduced to solving two coupled Fredholm integral equations with regular kernels. The solutions to these integral equations are used to determine the reflection and the transmission coefficients. The results for the reflection coefficient are presented graphically and are compared to those obtained earlier using other research methods. It is observed from the graphs that the results computed from the present analysis match exactly with the previous results.

Investigation of Simulating Radar Images Concerning the Multipath Scattering Effect

In the composed system of a target and rough surface, the electromagnetic scattering mechanism, especially the multipath scattering, is investigated. Using physical optics double bouncing algorithm, the multipath scattering model of the system has been established. Simulated by a wide-band radar signal and based on fractal rough surface, the artificial echo of the target has been obtained in virtue of the established multipath scattering model. By simulating to image the target in one dimension using the artificial echo, two kinds of range profiles are attained. It is found that one is from the target and the other is from the multipath scattering effect. Key words multipath scattering - radar imaging - rough surface scattering CLC number O 451 Foundation item: Supported by the Key Laboratory Foundation of National Defense Science and Technology (99JS93. 1. 2. JW1204)Biography: Yang Chun-hua(1978-), male, Ph. D candidate, research direction: radio wave propagation and wiresless communication.

Green synthesis of MIL⁃101/Au composite particles and their sensitivity to Raman detection of thiram

Metal⁃organic framework(MOF)MIL⁃101 and surface plasmon polariton(SPP)supported gold nanoparti⁃cles(Au NPs)hybrid systems were developed as a highly sensitive and reproducible surface⁃enhanced Raman scat⁃tering(SERS)detection platform,in which a green electrostatic self⁃assembly technology was adopted to construct the substrate.In an aqueous solution,the electronegativity of the particles can be used to prepare the composite sub⁃strate without any surface modifier.Due to the enrichment capacity of MIL⁃101 and the electromagnetic enhance⁃ment from Au NPs,the well⁃designed MIL⁃101/Au composites possessed ultrahigh sensitivity with the detection limit of Rhodamine 6G(R6G)as low as 10^(-10) mol·L^(-1).Meanwhile,the substrate exhibits high stability,excellent reproduc⁃ibility,and recyclability.Additionally,the novel substrate can be explored for direct capture,and sensitively detect pesticide residues such as thiram.

Influence of local environment on the intensity of the localized surface plasmon polariton of Ag nanoparticles

A combined Ag nanoparticle with an insulating or conductive layer structure has been designed tor molecular detection using surface enhanced Raman scattering microscopy. Optical absorption studies revealed localized surface plasmon resonance, which shows regular red shift with increasing environmental dielectric constant. With the combined structure of surface enhanced Raman scattering substrates and rhodamine 6C as a test molecule, the results in this paper show that the absorption has a linear relationship with the local electromagnetic field for insulating substrates, and the electrical property of the substrate has a non-negligible effect on the intensity of the local electromagnetic field and hence the Raman enhancement.