Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and...Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and its key controlling processes are not well understood,which limits our comprehension of the physiological mechanisms of various management practices.In this study,four forest management measures(no thinning:NT;understory removal:UR;light thinning:LT;and heavy thinning:HT)were carried out in Pinus massoniana plantations in a subtropical region of China.Photosynthetic capacity and needle stable carbon isotope composition(δ^(13)C)were measured to assess instantaneous water use efficiency(WUE_(inst))and long-term water use efficiency(WUE_(i)).Multiple regression models and structural equation modelling(SEM)identified the effects of soil properties and physiological performances on WUE_(inst)and WUE_(i).The results show that WUE_(inst)values among the four treatments were insignificant.However,compared with the NT stand(35.8μmol·mol^(-1)),WUE_(i)values significantly increased to 41.7μmol·mol^(-1)in the UR,50.1μmol·mol^(-1)in the LT and 46.6μmol·mol^(-1)in HT treatments,largely explained by photosynthetic capacity and soil water content.Understory removal did not change physiological performance(needle water potential and photosynthetic capacity).Thinning increased the net photosynthetic rate(A_n)but not stomatal conductance(g_s)or predawn needle water potential(ψ_(pd)),implying that the improvement in water use efficiency for thinned stands was largely driven by radiation interception than by soil water availability.In general,thinning may be an appropriate management measure to promote P.massoniana WUE to cope with seasonal droughts under future extreme climates.展开更多
Based on the monitoring data of PM_(2.5) concentration in Bengbu Environmental Monitoring Station and precipitation observation data of Bengbu National Meteorological Observation Station from 2016 to 2019, the influen...Based on the monitoring data of PM_(2.5) concentration in Bengbu Environmental Monitoring Station and precipitation observation data of Bengbu National Meteorological Observation Station from 2016 to 2019, the influence of precipitation on PM_(2.5) mass concentration in Bengbu City was analyzed. The results show that precipitation had a washing and removal effect on PM_(2.5) in the air, and the removal effect was related to precipitation level, precipitation intensity, precipitation duration and PM_(2.5) concentration. The removal effect of precipitation on PM_(2.5) increased with the increase of precipitation level, and the seasonal difference was obvious. Precipitation intensity was positively correlated with the removal effect of PM_(2.5) , but the average removal rate began to decline when precipitation intensity exceeded 10 mm. With the increase of precipitation intensity, the proportion of positive removal showed an overall upward trend, but there was a low-value area as precipitation intensity was 3-10 mm. Precipitation duration was also positively correlated with the removal effect of PM_(2.5) , and there was a low-value area when precipitation duration was 10-15 h. When PM_(2.5) concentration was low before the precipitation process began, the removal effect was not good, and the average removal rate was negative. As PM_(2.5) concentration was high before the precipitation process started, the removal effect was obvious.展开更多
Electrocatalytic reduction of ethylenediamine tetraacetic acid copper(CuEDTA),a typical refractory heavy metal complexation pollutant,is an environmental benign method that operates at mild condition.Unfortunately,the...Electrocatalytic reduction of ethylenediamine tetraacetic acid copper(CuEDTA),a typical refractory heavy metal complexation pollutant,is an environmental benign method that operates at mild condition.Unfortunately,the selective reduction of CuEDTA is still a big challenge in cathodic process.In this work,we report a MoS_(2) nanosheet/graphite felt(GF)cathode,which achieves an average Faraday efficiency of 29.6%and specific removal rate(SRR)of 0.042 mol/cm^(2)/h for CuEDTA at−0.65 V vs SCE(saturated calomel electrode),both of which are much higher than those of the commonly reported electrooxidation technology-based removal systems.Moreover,a proofof-concept CuEDTA/Zn battery with Zn anode and MoS_(2)/GF cathode is demonstrated,which has bifunctions of simultaneous CuEDTA removal and energy output.This is one of the pioneer studies on the electrocatalytic reduction of heavy metal complex and CuEDTA/Zn battery,which brings new insights in developing efficient electrocatalytic reduction system for pollution control and energy output.展开更多
The nitrate nitrogen removal efficiency of iron-carbon micro-electrolysis system was discussed in treating pharmaceutical wastewater with high nitrogen and refractory organic concentration. The results show that the g...The nitrate nitrogen removal efficiency of iron-carbon micro-electrolysis system was discussed in treating pharmaceutical wastewater with high nitrogen and refractory organic concentration. The results show that the granularity of fillings,pH,volume ratios of iron-carbon and gas-water,and HRT. have significant effects on the nitrogen removal efficiency of iron-carbon micro-electrolysis system. The iron-carbon micro-electrolysis system has a good removal efficiency of pharmaceutical wastewater with high nitrogen and refractory organic concentration when the influent TN,NH4+-N,NO3--N and BOD5/CODCr are 823 mg/L,30 mg/L,793 mg/L and 0.1,respectively,at the granularity of iron and carbon 0.425 mm,pH 3,iron-carbon ratio 3,gas-water ratio 5,HRT 1.5 h,and the removal rates of TN,NH4+-N and NO3--N achieve 51.5%,70% and 50.94%,respectively.展开更多
In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effe...In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effect of various factors, such as gap size between dielectric barrier and discharge needles, environmental humidity, and inlet speed of gas flow upon the removal efficiency of air purification is analyzed. The studies show that SOs removal efficiency improves with the increase in the gap size between dielectric barrier and discharge needles in the case of a fixed space between two electrodes, and also improves with the increase in the environmental humidity. For a mixed gas with a fixed concentration, there is an optimal inlet speed of gas flow, which leads to the best removal efficiency.展开更多
To master theoretical calculation for dust removal efficiency of high pressure atomization in an underground coal mine, the corresponding atomization characteristics and dust removal efficiency were both comprehensive...To master theoretical calculation for dust removal efficiency of high pressure atomization in an underground coal mine, the corresponding atomization characteristics and dust removal efficiency were both comprehensively studied in theory by virtue of related theories of hydromechanics and aerosol.According to actual measurements of flow coefficients and atomization angles of X-type swirl nozzle,computational formula was derived for atomized particle sizes of such a nozzle in conjunction with relevant empirical equation. Moreover, a mathematical model for applying high pressure atomization to dust removal in underground coal mine was also established to deduce theoretical computation formula of fractional efficiency. Then, Matlab was adopted to portray the relation curve between fractional efficiency and influence factors. In addition, a theoretical formula was also set up for removal efficiency of respirable dust and total coal dust based on dust size and frequency distribution equations. In the end,impacts of dust characteristic parameters on various dust removal efficiencies were analyzed.展开更多
Modeling of filter performance is very difficult because of complexity of the defining physical and chemical events in the filtration system whereas the knowledge of functionality of filter coefficient. The main objec...Modeling of filter performance is very difficult because of complexity of the defining physical and chemical events in the filtration system whereas the knowledge of functionality of filter coefficient. The main objective of this study is to predict the performance of multimedia filter and to evaluate both the initial and transient stage of suspended solid removal efficiency depending on experimental data. Fuzzy logic has been used to build a model of multi input and one output (MISO) for the removal efficiency of multimedia filter which it consists from sand and granular activated carbon (GAC) mediums. The control parameters of (FLC) of Sugeno model are seven parameters which are media depths, media grains size for both sand and GAC, filtration rate, diameter of suspension particle, feed concentration, and operation time. The output parameter is removal efficiency of media filter whereas these data are collocated from pilot scale deep bed filter, thus, the removal efficiency of filter was modeled by 575 rules as a function of different control parameters. An adaptive of neuron fuzzy inference system (ANFIS) had used to simulate the experimental data. The simulation results were evaluated using mean absolute percentage error (MAPE), whereas the results showed that the prediction of ANFIS model has a good agreement with experimental data when the MAPE is equal to 7.0458 and fuzzy rule -based modeling proved a reliable and flexible tool to study the performance of multimedia filter. The conclusion showed that there is a relationship between flow rate, effective size and optimum bed depth for all filter media, the increment of effective size generates a higher value of optimum filter bed depth for a lower value of filtration rate. It was concluded that the optimal removal efficiency (95-100) achieved by (0.5-0.7 mm) grain size of sand, (1.5-1.9) mm grain size of granular activated carbon (GAC), with media depths should range from 0.3 to 0.6 m.展开更多
Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading dr...Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.展开更多
To evaluate the removal efficiency of organic pollutants in the sewage by Harbin municipal sewage treatment plant,the influent and effluent samples from the plant were pretreated by liquid-liquid extraction (LLE) unde...To evaluate the removal efficiency of organic pollutants in the sewage by Harbin municipal sewage treatment plant,the influent and effluent samples from the plant were pretreated by liquid-liquid extraction (LLE) under conditions of acidity,neutrality and alkalescence in sequence,and then were analyzed by gas chromatograph-mass spectrum (GC-MS) procedures.Results indicate that there are 70 species of organic pollutants in the influent sample of the plant,which mainly consist of alkyls,benzene series,esters,and heterocyclic compounds.Some of these organic pollutants are biotoxic and belong to persistent organic pollutants (POPs).Four species among them are on the list of Prior Pollutants of Environmental Protection Agency of USA (USEPA).However,7 species of organic pollutants appearing in the effluent sample mainly include alkyls of multi-carbons and phthalate esters.The removal efficiency of phthalates is poor because of their poor biodegradability.The sewage treatment technique is effective in removing most of organics pollutants.展开更多
The cyclone dust collector is an important subsystem of straw crushers used in agriculture.In the present study,a new type of dust collector with involute morphology is proposed to obtain better dust removal efficienc...The cyclone dust collector is an important subsystem of straw crushers used in agriculture.In the present study,a new type of dust collector with involute morphology is proposed to obtain better dust removal efficiency with respect to that of classical tangential and spiral dust collectors.A discrete phase model(DPM)method is used in synergy with a turbulence model,and the SIMPLE algorithm to simulate the flow field inside the dust collector and the related particle dynamics.It is shown that the internal flow field features a primary swirl,a secondary swirl and blockage effects.Moreover,for the involute dust collector,the tangential velocity in the initial stage and the pressure in the high-pressure area are larger than those obtained for the classical types.The dust removal efficiency is 37.11%,25.3%,and 16.37%for the involute type dust collector,the tangential type and the spiral type,respectively.展开更多
The non-thermal plasma created by high voltage pulsed power supply can be used to remove sulfur dioxide in the air, but how to increase the removing efficiency is not clear. It is novel to apply the magnetic field in ...The non-thermal plasma created by high voltage pulsed power supply can be used to remove sulfur dioxide in the air, but how to increase the removing efficiency is not clear. It is novel to apply the magnetic field in removing SO2 as discussed in this paper. The mechanisms of removing sulfur dioxide by non-thermal plasma along with the application of the magnetic field are analyzed, and the related factors affecting the removal efficiency, such as the magnitude of pulsed voltage, the polarity of the pulse, the layout of the discharge electrode, especially the magnetic field are experimentally investigated. It can be concluded that the purification efficiency is improved significantly by applying the magnetic field.展开更多
In this study constructed wetlands (CWs) were used to remove three heavy metals (Zn, Cu and Pb). The two tested substrates were made of coke and gravel, respectively. First order dynamic model was appropriate to descr...In this study constructed wetlands (CWs) were used to remove three heavy metals (Zn, Cu and Pb). The two tested substrates were made of coke and gravel, respectively. First order dynamic model was appropriate to describe removing of Zn and Cu. The experimental results showed that first dynamic removal rate constants of Zn in CWs with coke and gravel were 0.2326 h-1 and 0.1222 h-1, respectively. And those of Cu in CWs with coke and gravel were 0.2017 h-1 and 0.3739 h-1. However, removal efficiencies of Pb in the coke system and the gravel system were within 95-99%, so the first order dynamic model failed to fit the experimental data because the hydraulic resident times of Pb did not affect outlet concentration of Pb. From the removal rate constants, it is found that the coke and gravel system have different absorption efficiencies of heavy metal pollutants. Therefore, it is suggested that the removal efficiencies of heavy metals are influenced by the choice of substrates to some extent.展开更多
The removal efficiencies of heavy metals(As, Cr, Cu, Ni, Pb and Zn) were investigated in the 17 operating municipal wastewater treatment plants(WWTPs) and compared with those in four main activated sludge processes. S...The removal efficiencies of heavy metals(As, Cr, Cu, Ni, Pb and Zn) were investigated in the 17 operating municipal wastewater treatment plants(WWTPs) and compared with those in four main activated sludge processes. Significant differences of heavy metal removal efficiencies were observed among four activated sludge processes. The removal efficiency for As(75.5%) in the oxidation ditch(OD) process is significantly higher than that in the conventional activated sludge(CAS) process(38.6%) or sequencing batch reactor(SBR) process(51.4%). The mean removal efficiencies for Cu and Ni in the OD process are 90.5% and 46.7%, respectively, while low mean removal efficiencies are observed for Cu(69.9%) and Ni(16.5%), respectively, in the SBR process. The removal efficiencies for Cu and Ni in the OD process are significantly higher than those in the anaerobic-anoxic-oxic(A2-O) process. These results highlight the differences of removal efficiencies for heavy metals in different processes and should be considered when selecting a wastewater treatment process.展开更多
In order to enhance the nitrogen removal, a subsurface wastewater infiltration system (SWIS) was improved by adding peat in deep soil as carbon source for denitrification process. The effects of addition of carbon s...In order to enhance the nitrogen removal, a subsurface wastewater infiltration system (SWIS) was improved by adding peat in deep soil as carbon source for denitrification process. The effects of addition of carbon source in the underpart of the SWIS on nitrogen removal at different influents (with the total nitrogen (TN) concentration 40 and 80 mg L^-1, respectively) were investigated by soil column simulating experiments. When the relatively light pollution influent with 40 mg L^-1 TN was used, the average concentrations of NO3-N and TN in effluents were (4.69±0.235), (6.18±0.079) mg L^-1, respectively, decreased by 32 and 30.8% than the control; the NO3--N concentration of all effluents was below the maximum contaminant level of 10 mg L^-1; as high as 92.67% of the TN removal efficiency was achieved. When relatively heavy pollution influent with 80 mg LITN was used, the average concentrations of NO3--N and TN in effluents were (10.2±0.265), (12.5±0.148) mg L^-1 respectively, decreased by 20 and 21.2% than the control; the NO3--N concentration of all effluents met the grade Ⅲ of the national quality standard for ground water of China (GB/T 14848-1993) with the values less than 20 mg L^-1; the TN removal efficiency of 94.1% was achieved. In summary, adding peat in the underpart of the SWIS significantly decreased TN and NO3- -N concentration in effluents and the nitrogen removal efficiency improved significantly.展开更多
Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energ...Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.展开更多
In this experiment,cobalt ferrite-supported activated carbon(CF-AC)was developed and characterized via the wet impregnation method for the removal of Cr and Pb(II)ions from tannery wastewater.Batch adsorption was carr...In this experiment,cobalt ferrite-supported activated carbon(CF-AC)was developed and characterized via the wet impregnation method for the removal of Cr and Pb(II)ions from tannery wastewater.Batch adsorption was carried out to evaluate the effect of experimental operating conditions(pH of solution,contact time,adsorbent dose,and temperature),and the removal efficiencies of Cr and Pb(II)ions by the developed adsorbents were calculated and recorded for all experimental conditions.These variables were estimated and reported as removal efficiencies of 98.2%for Cr and 96.4%for Pb(II)ions at the optimal conditions of 5,0.8 g,80 min,and 333 K for pH,adsorbent dose,contact time,and temperature,respectively.The equilibrium for the sorption of Cr and Pb(II)ions was studied using four widely used isotherm models(the Langmuir,Freundlich,Dubinin-Radushkevich,and Temkin isotherm models).It was found that the Freundlich isotherm model fit better with the coefficient of determination(R2)of 0.9484 and a small sum of square error of 0.0006.The maximum adsorption capacities(Qm)of Pb(II)and Cr adsorbed onto CF-AC were determined to be 6.27 and 23.6 mg/g,respectively.The adsorption process conformed well to pseudo-second order kinetics as revealed by the high R2 values obtained for both metals.The thermodynamic parameters showed that adsorption of Cr and Pb(II)ions onto CF-AC was spontaneous,feasible,and endothermic under the studied conditions.The mean adsorption energy(E)values revealed that the adsorption mechanism of Cr and Pb(II)by CF-AC is physical in nature.The results of the study showed that adsorbent developed from CF-AC can be efficiently used as an environmentally friendly alternative adsorbent,for removal of Cr and Pb(II)ions in tannery wastewater.展开更多
Maintaining stable water quality is one of the key processes for recirculating coral aquaculture. Traditional aquarium systems which mainly utilized a nitrification of nitrifying bacteria attached to the surface of ma...Maintaining stable water quality is one of the key processes for recirculating coral aquaculture. Traditional aquarium systems which mainly utilized a nitrification of nitrifying bacteria attached to the surface of massive artificial filter material are difficult to maintain the oligotrophic conditions necessary for coral aquaculture. This study investigated the removal effects of dissolved inorganic nitrogen(ammonia and nitrate) by live rock(LR), a key component in the "Berlin system" coral aquarium. The expression levels of bacterial functional genes, AOA3,amo A and nos Z, were measured on the exterior and interior of LR. The nitrifying and denitrifying bacterial abundance on LR was quantified and the nitrogen nutrient regulatory effects of LR were evaluated. The results demonstrated that LR mainly removed ammonium(NH_4~+) from the water with a mean efficiency of 0.141 mg/(kg·h), while the removal of nitrate(NO_3~–) was not significant. Bacterial diversity analysis showed that ammonia-oxidizing bacteria(AOB) were the most common bacteria on LR, which accounted for 0.5%–1.4% of the total bacterial population, followed by denitrifying bacteria, which accounted for 0.2% of the total population, and the ammonia-oxidizing archaea(AOA) were the least common type(〈0.01%). The low abundance of denitrifying bacteria may be responsible for the poor nitrate(NO_3~–) removal of LR. Thus, other biological filtration methods are needed in coral aquaria to control nitrates generated from nitrification or biological metabolism.展开更多
This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust parti...This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust particle size was smaller than 180 mesh. The effects of the electrode width, the electrode spacing, voltage, frequency, waveform, and the duty ratio on the dust removal efficiency were studied. The obtained optimum conditions of dust removal were as follows: voltage was 1500 V, frequency was 15 Hz, square wave, 10% duty ratio, the electrode width was 0.5 mm, electrodes spacing was 1.3 mm. Our previous experimental results show that the dust removal efficiency would be up to 95%. But in this experiment, under the optimum conditions, the dust removal efficiency could be up to 99%.展开更多
基金supported by the National Key Research and Development Program of China(2016YFD0600201)the National Nonprofit Institute Research Grant of CAF(CAFYBB2017ZB003)+1 种基金the National Natural Science Foundation of China(3187071631670720)。
文摘Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and its key controlling processes are not well understood,which limits our comprehension of the physiological mechanisms of various management practices.In this study,four forest management measures(no thinning:NT;understory removal:UR;light thinning:LT;and heavy thinning:HT)were carried out in Pinus massoniana plantations in a subtropical region of China.Photosynthetic capacity and needle stable carbon isotope composition(δ^(13)C)were measured to assess instantaneous water use efficiency(WUE_(inst))and long-term water use efficiency(WUE_(i)).Multiple regression models and structural equation modelling(SEM)identified the effects of soil properties and physiological performances on WUE_(inst)and WUE_(i).The results show that WUE_(inst)values among the four treatments were insignificant.However,compared with the NT stand(35.8μmol·mol^(-1)),WUE_(i)values significantly increased to 41.7μmol·mol^(-1)in the UR,50.1μmol·mol^(-1)in the LT and 46.6μmol·mol^(-1)in HT treatments,largely explained by photosynthetic capacity and soil water content.Understory removal did not change physiological performance(needle water potential and photosynthetic capacity).Thinning increased the net photosynthetic rate(A_n)but not stomatal conductance(g_s)or predawn needle water potential(ψ_(pd)),implying that the improvement in water use efficiency for thinned stands was largely driven by radiation interception than by soil water availability.In general,thinning may be an appropriate management measure to promote P.massoniana WUE to cope with seasonal droughts under future extreme climates.
文摘Based on the monitoring data of PM_(2.5) concentration in Bengbu Environmental Monitoring Station and precipitation observation data of Bengbu National Meteorological Observation Station from 2016 to 2019, the influence of precipitation on PM_(2.5) mass concentration in Bengbu City was analyzed. The results show that precipitation had a washing and removal effect on PM_(2.5) in the air, and the removal effect was related to precipitation level, precipitation intensity, precipitation duration and PM_(2.5) concentration. The removal effect of precipitation on PM_(2.5) increased with the increase of precipitation level, and the seasonal difference was obvious. Precipitation intensity was positively correlated with the removal effect of PM_(2.5) , but the average removal rate began to decline when precipitation intensity exceeded 10 mm. With the increase of precipitation intensity, the proportion of positive removal showed an overall upward trend, but there was a low-value area as precipitation intensity was 3-10 mm. Precipitation duration was also positively correlated with the removal effect of PM_(2.5) , and there was a low-value area when precipitation duration was 10-15 h. When PM_(2.5) concentration was low before the precipitation process began, the removal effect was not good, and the average removal rate was negative. As PM_(2.5) concentration was high before the precipitation process started, the removal effect was obvious.
基金supported by the National Key R&D Program of China(2019YFC1905400)the Fundamental Research Funds for the Central Universities(2022-4-ZD-08).
文摘Electrocatalytic reduction of ethylenediamine tetraacetic acid copper(CuEDTA),a typical refractory heavy metal complexation pollutant,is an environmental benign method that operates at mild condition.Unfortunately,the selective reduction of CuEDTA is still a big challenge in cathodic process.In this work,we report a MoS_(2) nanosheet/graphite felt(GF)cathode,which achieves an average Faraday efficiency of 29.6%and specific removal rate(SRR)of 0.042 mol/cm^(2)/h for CuEDTA at−0.65 V vs SCE(saturated calomel electrode),both of which are much higher than those of the commonly reported electrooxidation technology-based removal systems.Moreover,a proofof-concept CuEDTA/Zn battery with Zn anode and MoS_(2)/GF cathode is demonstrated,which has bifunctions of simultaneous CuEDTA removal and energy output.This is one of the pioneer studies on the electrocatalytic reduction of heavy metal complex and CuEDTA/Zn battery,which brings new insights in developing efficient electrocatalytic reduction system for pollution control and energy output.
基金Project(2009ZX07315-005) supported by the National Water Pollution Controlled and Treatment Great Special of China
文摘The nitrate nitrogen removal efficiency of iron-carbon micro-electrolysis system was discussed in treating pharmaceutical wastewater with high nitrogen and refractory organic concentration. The results show that the granularity of fillings,pH,volume ratios of iron-carbon and gas-water,and HRT. have significant effects on the nitrogen removal efficiency of iron-carbon micro-electrolysis system. The iron-carbon micro-electrolysis system has a good removal efficiency of pharmaceutical wastewater with high nitrogen and refractory organic concentration when the influent TN,NH4+-N,NO3--N and BOD5/CODCr are 823 mg/L,30 mg/L,793 mg/L and 0.1,respectively,at the granularity of iron and carbon 0.425 mm,pH 3,iron-carbon ratio 3,gas-water ratio 5,HRT 1.5 h,and the removal rates of TN,NH4+-N and NO3--N achieve 51.5%,70% and 50.94%,respectively.
基金the National Science Foundation for Distinguished Young Scholars of China (No.50525722)the Science and Technology research key project of MOE
文摘In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effect of various factors, such as gap size between dielectric barrier and discharge needles, environmental humidity, and inlet speed of gas flow upon the removal efficiency of air purification is analyzed. The studies show that SOs removal efficiency improves with the increase in the gap size between dielectric barrier and discharge needles in the case of a fixed space between two electrodes, and also improves with the increase in the environmental humidity. For a mixed gas with a fixed concentration, there is an optimal inlet speed of gas flow, which leads to the best removal efficiency.
基金Financial provided by the National Natural Science Foundation of China (Nos. 51574123 and U1361118)the China Postdoctoral Science Foundation (No. 2015M 582118)
文摘To master theoretical calculation for dust removal efficiency of high pressure atomization in an underground coal mine, the corresponding atomization characteristics and dust removal efficiency were both comprehensively studied in theory by virtue of related theories of hydromechanics and aerosol.According to actual measurements of flow coefficients and atomization angles of X-type swirl nozzle,computational formula was derived for atomized particle sizes of such a nozzle in conjunction with relevant empirical equation. Moreover, a mathematical model for applying high pressure atomization to dust removal in underground coal mine was also established to deduce theoretical computation formula of fractional efficiency. Then, Matlab was adopted to portray the relation curve between fractional efficiency and influence factors. In addition, a theoretical formula was also set up for removal efficiency of respirable dust and total coal dust based on dust size and frequency distribution equations. In the end,impacts of dust characteristic parameters on various dust removal efficiencies were analyzed.
文摘Modeling of filter performance is very difficult because of complexity of the defining physical and chemical events in the filtration system whereas the knowledge of functionality of filter coefficient. The main objective of this study is to predict the performance of multimedia filter and to evaluate both the initial and transient stage of suspended solid removal efficiency depending on experimental data. Fuzzy logic has been used to build a model of multi input and one output (MISO) for the removal efficiency of multimedia filter which it consists from sand and granular activated carbon (GAC) mediums. The control parameters of (FLC) of Sugeno model are seven parameters which are media depths, media grains size for both sand and GAC, filtration rate, diameter of suspension particle, feed concentration, and operation time. The output parameter is removal efficiency of media filter whereas these data are collocated from pilot scale deep bed filter, thus, the removal efficiency of filter was modeled by 575 rules as a function of different control parameters. An adaptive of neuron fuzzy inference system (ANFIS) had used to simulate the experimental data. The simulation results were evaluated using mean absolute percentage error (MAPE), whereas the results showed that the prediction of ANFIS model has a good agreement with experimental data when the MAPE is equal to 7.0458 and fuzzy rule -based modeling proved a reliable and flexible tool to study the performance of multimedia filter. The conclusion showed that there is a relationship between flow rate, effective size and optimum bed depth for all filter media, the increment of effective size generates a higher value of optimum filter bed depth for a lower value of filtration rate. It was concluded that the optimal removal efficiency (95-100) achieved by (0.5-0.7 mm) grain size of sand, (1.5-1.9) mm grain size of granular activated carbon (GAC), with media depths should range from 0.3 to 0.6 m.
基金We thank Esther Posner,PhD,from Edanz Group China(www.liwenbianji.cn/ac)for English language editing on an earlier draft of this manuscript.This work was supported by the 2017 Hunan Provincial Graduate Research Innovation Project of China(No.CX2017B649)the National Natural Science Foundation of China(No.51774134)+2 种基金the Excellent Youth Project of Hunan Provincial Department of Education(No.19B223)the Hunan Provincial Natural Science Foundation of China(No.2019JJ60044)the Hunan Provincial Natural Science Foundation of China(No.2018JJ64028).
文摘Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.
文摘To evaluate the removal efficiency of organic pollutants in the sewage by Harbin municipal sewage treatment plant,the influent and effluent samples from the plant were pretreated by liquid-liquid extraction (LLE) under conditions of acidity,neutrality and alkalescence in sequence,and then were analyzed by gas chromatograph-mass spectrum (GC-MS) procedures.Results indicate that there are 70 species of organic pollutants in the influent sample of the plant,which mainly consist of alkyls,benzene series,esters,and heterocyclic compounds.Some of these organic pollutants are biotoxic and belong to persistent organic pollutants (POPs).Four species among them are on the list of Prior Pollutants of Environmental Protection Agency of USA (USEPA).However,7 species of organic pollutants appearing in the effluent sample mainly include alkyls of multi-carbons and phthalate esters.The removal efficiency of phthalates is poor because of their poor biodegradability.The sewage treatment technique is effective in removing most of organics pollutants.
基金supported by the Independent Research Fund of the State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines(No.SKLMRDPC20ZZ06)and the Program in the Youth Elite Support Plan in Universities of Anhui Province(No.gxyq2020013).
文摘The cyclone dust collector is an important subsystem of straw crushers used in agriculture.In the present study,a new type of dust collector with involute morphology is proposed to obtain better dust removal efficiency with respect to that of classical tangential and spiral dust collectors.A discrete phase model(DPM)method is used in synergy with a turbulence model,and the SIMPLE algorithm to simulate the flow field inside the dust collector and the related particle dynamics.It is shown that the internal flow field features a primary swirl,a secondary swirl and blockage effects.Moreover,for the involute dust collector,the tangential velocity in the initial stage and the pressure in the high-pressure area are larger than those obtained for the classical types.The dust removal efficiency is 37.11%,25.3%,and 16.37%for the involute type dust collector,the tangential type and the spiral type,respectively.
基金The project supported by the Teaching and Research Award Program for Outstanding Young Teachers in Higher EducationInstitutions under the MOE, China (No. 123-2002)
文摘The non-thermal plasma created by high voltage pulsed power supply can be used to remove sulfur dioxide in the air, but how to increase the removing efficiency is not clear. It is novel to apply the magnetic field in removing SO2 as discussed in this paper. The mechanisms of removing sulfur dioxide by non-thermal plasma along with the application of the magnetic field are analyzed, and the related factors affecting the removal efficiency, such as the magnitude of pulsed voltage, the polarity of the pulse, the layout of the discharge electrode, especially the magnetic field are experimentally investigated. It can be concluded that the purification efficiency is improved significantly by applying the magnetic field.
文摘In this study constructed wetlands (CWs) were used to remove three heavy metals (Zn, Cu and Pb). The two tested substrates were made of coke and gravel, respectively. First order dynamic model was appropriate to describe removing of Zn and Cu. The experimental results showed that first dynamic removal rate constants of Zn in CWs with coke and gravel were 0.2326 h-1 and 0.1222 h-1, respectively. And those of Cu in CWs with coke and gravel were 0.2017 h-1 and 0.3739 h-1. However, removal efficiencies of Pb in the coke system and the gravel system were within 95-99%, so the first order dynamic model failed to fit the experimental data because the hydraulic resident times of Pb did not affect outlet concentration of Pb. From the removal rate constants, it is found that the coke and gravel system have different absorption efficiencies of heavy metal pollutants. Therefore, it is suggested that the removal efficiencies of heavy metals are influenced by the choice of substrates to some extent.
基金Project(2012AA06A202)supported by Hi-tech Research and Development Project of China
文摘The removal efficiencies of heavy metals(As, Cr, Cu, Ni, Pb and Zn) were investigated in the 17 operating municipal wastewater treatment plants(WWTPs) and compared with those in four main activated sludge processes. Significant differences of heavy metal removal efficiencies were observed among four activated sludge processes. The removal efficiency for As(75.5%) in the oxidation ditch(OD) process is significantly higher than that in the conventional activated sludge(CAS) process(38.6%) or sequencing batch reactor(SBR) process(51.4%). The mean removal efficiencies for Cu and Ni in the OD process are 90.5% and 46.7%, respectively, while low mean removal efficiencies are observed for Cu(69.9%) and Ni(16.5%), respectively, in the SBR process. The removal efficiencies for Cu and Ni in the OD process are significantly higher than those in the anaerobic-anoxic-oxic(A2-O) process. These results highlight the differences of removal efficiencies for heavy metals in different processes and should be considered when selecting a wastewater treatment process.
基金supported by the Key Technologies R&D Program of China during the 11th Five-Year Plan period (2008BADC4B17 and 2006 BAD16B09)the Beijing Key Discipline Construction Project of Biomass Engineering Interdisciplinary
文摘In order to enhance the nitrogen removal, a subsurface wastewater infiltration system (SWIS) was improved by adding peat in deep soil as carbon source for denitrification process. The effects of addition of carbon source in the underpart of the SWIS on nitrogen removal at different influents (with the total nitrogen (TN) concentration 40 and 80 mg L^-1, respectively) were investigated by soil column simulating experiments. When the relatively light pollution influent with 40 mg L^-1 TN was used, the average concentrations of NO3-N and TN in effluents were (4.69±0.235), (6.18±0.079) mg L^-1, respectively, decreased by 32 and 30.8% than the control; the NO3--N concentration of all effluents was below the maximum contaminant level of 10 mg L^-1; as high as 92.67% of the TN removal efficiency was achieved. When relatively heavy pollution influent with 80 mg LITN was used, the average concentrations of NO3--N and TN in effluents were (10.2±0.265), (12.5±0.148) mg L^-1 respectively, decreased by 20 and 21.2% than the control; the NO3--N concentration of all effluents met the grade Ⅲ of the national quality standard for ground water of China (GB/T 14848-1993) with the values less than 20 mg L^-1; the TN removal efficiency of 94.1% was achieved. In summary, adding peat in the underpart of the SWIS significantly decreased TN and NO3- -N concentration in effluents and the nitrogen removal efficiency improved significantly.
基金Project(MSV-2013-09)supported by State Key Laboratory of Mechanical System and Vibration,China
文摘Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.
文摘In this experiment,cobalt ferrite-supported activated carbon(CF-AC)was developed and characterized via the wet impregnation method for the removal of Cr and Pb(II)ions from tannery wastewater.Batch adsorption was carried out to evaluate the effect of experimental operating conditions(pH of solution,contact time,adsorbent dose,and temperature),and the removal efficiencies of Cr and Pb(II)ions by the developed adsorbents were calculated and recorded for all experimental conditions.These variables were estimated and reported as removal efficiencies of 98.2%for Cr and 96.4%for Pb(II)ions at the optimal conditions of 5,0.8 g,80 min,and 333 K for pH,adsorbent dose,contact time,and temperature,respectively.The equilibrium for the sorption of Cr and Pb(II)ions was studied using four widely used isotherm models(the Langmuir,Freundlich,Dubinin-Radushkevich,and Temkin isotherm models).It was found that the Freundlich isotherm model fit better with the coefficient of determination(R2)of 0.9484 and a small sum of square error of 0.0006.The maximum adsorption capacities(Qm)of Pb(II)and Cr adsorbed onto CF-AC were determined to be 6.27 and 23.6 mg/g,respectively.The adsorption process conformed well to pseudo-second order kinetics as revealed by the high R2 values obtained for both metals.The thermodynamic parameters showed that adsorption of Cr and Pb(II)ions onto CF-AC was spontaneous,feasible,and endothermic under the studied conditions.The mean adsorption energy(E)values revealed that the adsorption mechanism of Cr and Pb(II)by CF-AC is physical in nature.The results of the study showed that adsorbent developed from CF-AC can be efficiently used as an environmentally friendly alternative adsorbent,for removal of Cr and Pb(II)ions in tannery wastewater.
基金The Regional Demonstration of Marine Economy Innovative Development Project under contract No.16PZY002SF18the Xiamen Southern Ocean Research Center Project under contract No.14CZY037HJ11+1 种基金the Guangxi Natural Science Foundation under contract No.2016GXNSFBA380228the China-ASEAN Maritime Cooperation Fund Project under contract No.HX150702
文摘Maintaining stable water quality is one of the key processes for recirculating coral aquaculture. Traditional aquarium systems which mainly utilized a nitrification of nitrifying bacteria attached to the surface of massive artificial filter material are difficult to maintain the oligotrophic conditions necessary for coral aquaculture. This study investigated the removal effects of dissolved inorganic nitrogen(ammonia and nitrate) by live rock(LR), a key component in the "Berlin system" coral aquarium. The expression levels of bacterial functional genes, AOA3,amo A and nos Z, were measured on the exterior and interior of LR. The nitrifying and denitrifying bacterial abundance on LR was quantified and the nitrogen nutrient regulatory effects of LR were evaluated. The results demonstrated that LR mainly removed ammonium(NH_4~+) from the water with a mean efficiency of 0.141 mg/(kg·h), while the removal of nitrate(NO_3~–) was not significant. Bacterial diversity analysis showed that ammonia-oxidizing bacteria(AOB) were the most common bacteria on LR, which accounted for 0.5%–1.4% of the total bacterial population, followed by denitrifying bacteria, which accounted for 0.2% of the total population, and the ammonia-oxidizing archaea(AOA) were the least common type(〈0.01%). The low abundance of denitrifying bacteria may be responsible for the poor nitrate(NO_3~–) removal of LR. Thus, other biological filtration methods are needed in coral aquaria to control nitrates generated from nitrification or biological metabolism.
文摘This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust particle size was smaller than 180 mesh. The effects of the electrode width, the electrode spacing, voltage, frequency, waveform, and the duty ratio on the dust removal efficiency were studied. The obtained optimum conditions of dust removal were as follows: voltage was 1500 V, frequency was 15 Hz, square wave, 10% duty ratio, the electrode width was 0.5 mm, electrodes spacing was 1.3 mm. Our previous experimental results show that the dust removal efficiency would be up to 95%. But in this experiment, under the optimum conditions, the dust removal efficiency could be up to 99%.