Phase precipitation and mechanical properties of TC21 titanium alloy with two different initial microstructures during heat treatment were determined. Result indicated that compared with coarse microstructure alloy, f...Phase precipitation and mechanical properties of TC21 titanium alloy with two different initial microstructures during heat treatment were determined. Result indicated that compared with coarse microstructure alloy, fine microstructure alloy developed finer microstructure, more unstable <em>ω</em> and <em>α</em><sub>2</sub> precipitates with much smaller size and lower volume fraction, and obtained better mechanical properties during heat treatment.展开更多
The mechanical behaviors and the microstructural characteristics of TC11 alloy with quenched martensite microstructure during hot compressive deformation were investigated. It shows that at various temperatures and st...The mechanical behaviors and the microstructural characteristics of TC11 alloy with quenched martensite microstructure during hot compressive deformation were investigated. It shows that at various temperatures and strain rates, the stress strain curves firstly exhibit strain hardening, then strain softening and finally reach the steady deformation state; in the meanwhile, the initial lamellar microstructure is transformed into the equiaxed and uniform one through dynamic recrystallization. It shows that the present TC11 alloy has different Z D relationships in relatively lower temperature (RLT) range and relatively higher temperature (RHT) range, which is believed to be due to different deformation activation energies. During RHT deformation, dynamic recrystallization occurs in both α phases and β phases, but during RLT deformation, dynamic recrystallization only occurs in α phases and in the meanwhile β phases undergo a process of precipitation and growth.展开更多
TC11 titanium alloy samples with lamellar microstructrue were compressed on a Gleeble 1500D Simulator.Compression tests were carried out at 950 ℃ and a strain rate of 0.1 s-1 with height reduction of 20%,40% and 60%,...TC11 titanium alloy samples with lamellar microstructrue were compressed on a Gleeble 1500D Simulator.Compression tests were carried out at 950 ℃ and a strain rate of 0.1 s-1 with height reduction of 20%,40% and 60%,respectively.Microstruture of the compressed TC11 alloy was obeserved and analyzed by optical microscopy(OM),transmission electron microscope(TEM),electron back-scattered diffraction(EBSD).The lamellar disintegration mechanism of the TC11 titanium alloy was deduced.The results indicated that the compressive deformation promoted the phase transformation in bi-phase area.βphase layers were formed along the gliding planes inα phase,and α slivers were disintegrated into many small flakes through theα/βinterface slipping.展开更多
Na_(2)SiF_(6) was used as surface activating flux for laser welding of TC4 titanium alloy. The effect of Na_(2)SiF_(6) on TC4 titanium alloy laser welding was determined by observing the weld surface. The morphologica...Na_(2)SiF_(6) was used as surface activating flux for laser welding of TC4 titanium alloy. The effect of Na_(2)SiF_(6) on TC4 titanium alloy laser welding was determined by observing the weld surface. The morphological characteristics of the high temperature plasma above the workpiece was observed and analyzed by using high-speed digital camera system. The variation of weld depth,width and microstructure were analyzed by optical microscope. The experimental results show that laser weld of TC4 titanium alloy has good appearance with activating flux of Na_(2)SiF_(6), weld penetration increases by about 0.8%–12%, while weld surface width decrease by about 10%–29%, the depth to width ratio is effectively improved. The inhomogeneity of weld microstructure was improved, and the crystallization direction of β columnar crystals on the upper part of the weld was changed, the grain size and microstructure of the weld were refined by Na_(2)SiF_(6).展开更多
A NiCrAlY coating was deposited on the TC6 titanium substrate by arc ion plating （ALP）. The structure and morphologies of the NiCrAlY coating were characterized by X-ray diffraction （XRD） and scanning electron mic...A NiCrAlY coating was deposited on the TC6 titanium substrate by arc ion plating （ALP）. The structure and morphologies of the NiCrAlY coating were characterized by X-ray diffraction （XRD） and scanning electron microscopy （SEM）, and the influence of vacuum heat treatment on the element diffusion behavior was studied. The results showed that the y＇-Ni3Al phase was precipitated on the NiCrAlY coating after heat treatment. The Ni3（AI,Ti）, TiNi, and Ti2Ni intermetallic layers appeared at the interface from the outside to the inside at 700℃, and the thickness of the intermetallic layers increased with the increase in temperature. At 700℃ Ti and Ni were the major diffusion elements, and the diffusion of Cr was observed when the heat treatment temperature increased up to 870℃. The violent inward diffusion of Ni at 950℃ resulted in the degradation of the NiCrAlY coating.展开更多
Abstract Transient stress and strain fields of dissimilar titanium alloys （TCll and TC17 ） joint during linear friction welding （ LFW） were investigated by a two-dimensional model with ABAQUS/Explicit. The results...Abstract Transient stress and strain fields of dissimilar titanium alloys （TCll and TC17 ） joint during linear friction welding （ LFW） were investigated by a two-dimensional model with ABAQUS/Explicit. The results showed that in the X-axis, the maximum compressive stress of 850 MPa occurred in the center zone of friction interface , and the maximum tensile stress of 190 MPa distributed at the flash; in the Y-axis, the maximum compressive stress of 1 261 MPa located at the junction region between the welding fixture and edge of the specimen, and the maximum tensile stress of 320 MPa distributed in the connecting portion between the flash and edge of the specimen. In addition, areas of plastic strain increased gradually during welding process. In the X-axis, tensile strain mainly existed at the heads of the specimens; in the Y-axis, compressive strain mainly occurred at the heads of the specimens.展开更多
The formation reason and elimination method of non-uniform microstructure defects in Ti al- loy TC11 bar have been studied.The coagulating and coarsening into block of the part of grain boundary α and secondary α se...The formation reason and elimination method of non-uniform microstructure defects in Ti al- loy TC11 bar have been studied.The coagulating and coarsening into block of the part of grain boundary α and secondary α seem to be caused by the ingot cogging and initial forging temperature in the β region as well as no more enough deformation and uneven distribution. The grain α,elongated α and blocky α may be finally eliminated by adopting the technique of (α+β)thermomechanical processing+β processing,W.Q.+recrystallization annealing,A.C., thus the size of uniform and fine equiaxed α structure is believed to be reduced to 1.9258μm.展开更多
To solve the problem of the poor plasticity and to meet the requirements of high temperature for forming titanium alloy,mechanical properties of TC2 titanium alloy under the compound energy-field(CEF)with temperature ...To solve the problem of the poor plasticity and to meet the requirements of high temperature for forming titanium alloy,mechanical properties of TC2 titanium alloy under the compound energy-field(CEF)with temperature and ultrasonic vibration were studied.The effects of CEF on tensile force,elongation,microstructure and fractography of the TC2 titanium alloy were compared and analyzed.The results show that,under the same thermal conditions,the deformation resistance of TC2 titanium alloy decreases with the increase of ultrasonic vibration energy.The formability is also improved correspondingly due to the input of ultrasonic vibration energy and its influence on the microstructure of the material.However,when the ultrasonic vibration energy is larger,the fatigue fracture will also appear,which reduces its formability.展开更多
In this study, the crack propagation behaviors in the equiaxed and equiaxed-columnar grain regions of a heat-treated laser additive manufacturing(LAM) TC11 alloy with a special bi-modal microstructure are investigated...In this study, the crack propagation behaviors in the equiaxed and equiaxed-columnar grain regions of a heat-treated laser additive manufacturing(LAM) TC11 alloy with a special bi-modal microstructure are investigated. The results indicate that the alloy presents a special bi-modal microstructure that comprises a fork-like primary α(αp) phase surrounded by a secondary α colony(αs) in the α phase matrix after the heat treatment is completed. The samples demonstrate a fast crack growth rate with larger da/d N values through the equiaxed grain sample versus across the equiaxed-columnar grain sample at low K values(<13.8). The differences that are observed between the crack propagation behaviors(in the crack initiation stage) of the samples can be mostly attributed to the different size and morphology of the αp lamellae and αscolony within the grains in the equiaxed and columnar grain regions rather than the grain boundaries. The cracks prefer to grow along the α/β boundary with a smooth propagation route and a fast propagation rate in the equiaxed grain region, where the αpand α clusters have a large size.However, in the columnar grain region, small and randomly distributed αplamellae generate a zigzagshaped propagation path with a reduction in the da/d N value. Additionally, the change in the size of the αp lamellae in the equiaxed grains(heat affected bands, HAB) is also observed to influence the propagation behavior of the crack during the crack initiation stage.展开更多
文摘Phase precipitation and mechanical properties of TC21 titanium alloy with two different initial microstructures during heat treatment were determined. Result indicated that compared with coarse microstructure alloy, fine microstructure alloy developed finer microstructure, more unstable <em>ω</em> and <em>α</em><sub>2</sub> precipitates with much smaller size and lower volume fraction, and obtained better mechanical properties during heat treatment.
文摘The mechanical behaviors and the microstructural characteristics of TC11 alloy with quenched martensite microstructure during hot compressive deformation were investigated. It shows that at various temperatures and strain rates, the stress strain curves firstly exhibit strain hardening, then strain softening and finally reach the steady deformation state; in the meanwhile, the initial lamellar microstructure is transformed into the equiaxed and uniform one through dynamic recrystallization. It shows that the present TC11 alloy has different Z D relationships in relatively lower temperature (RLT) range and relatively higher temperature (RHT) range, which is believed to be due to different deformation activation energies. During RHT deformation, dynamic recrystallization occurs in both α phases and β phases, but during RLT deformation, dynamic recrystallization only occurs in α phases and in the meanwhile β phases undergo a process of precipitation and growth.
基金Funded by the National Key Natural Science Foundation of China(No.5131903ZT1)
文摘TC11 titanium alloy samples with lamellar microstructrue were compressed on a Gleeble 1500D Simulator.Compression tests were carried out at 950 ℃ and a strain rate of 0.1 s-1 with height reduction of 20%,40% and 60%,respectively.Microstruture of the compressed TC11 alloy was obeserved and analyzed by optical microscopy(OM),transmission electron microscope(TEM),electron back-scattered diffraction(EBSD).The lamellar disintegration mechanism of the TC11 titanium alloy was deduced.The results indicated that the compressive deformation promoted the phase transformation in bi-phase area.βphase layers were formed along the gliding planes inα phase,and α slivers were disintegrated into many small flakes through theα/βinterface slipping.
基金National Natural Science Foundation of China (Grant No. 51165027)Inner Mongolia Natural Science Foundationt(2017MS(LH)0512)。
文摘Na_(2)SiF_(6) was used as surface activating flux for laser welding of TC4 titanium alloy. The effect of Na_(2)SiF_(6) on TC4 titanium alloy laser welding was determined by observing the weld surface. The morphological characteristics of the high temperature plasma above the workpiece was observed and analyzed by using high-speed digital camera system. The variation of weld depth,width and microstructure were analyzed by optical microscope. The experimental results show that laser weld of TC4 titanium alloy has good appearance with activating flux of Na_(2)SiF_(6), weld penetration increases by about 0.8%–12%, while weld surface width decrease by about 10%–29%, the depth to width ratio is effectively improved. The inhomogeneity of weld microstructure was improved, and the crystallization direction of β columnar crystals on the upper part of the weld was changed, the grain size and microstructure of the weld were refined by Na_(2)SiF_(6).
基金This study was supported by the National Key Program of the Tenth Five-Year Plan of China (05-MKP-089).
文摘A NiCrAlY coating was deposited on the TC6 titanium substrate by arc ion plating （ALP）. The structure and morphologies of the NiCrAlY coating were characterized by X-ray diffraction （XRD） and scanning electron microscopy （SEM）, and the influence of vacuum heat treatment on the element diffusion behavior was studied. The results showed that the y＇-Ni3Al phase was precipitated on the NiCrAlY coating after heat treatment. The Ni3（AI,Ti）, TiNi, and Ti2Ni intermetallic layers appeared at the interface from the outside to the inside at 700℃, and the thickness of the intermetallic layers increased with the increase in temperature. At 700℃ Ti and Ni were the major diffusion elements, and the diffusion of Cr was observed when the heat treatment temperature increased up to 870℃. The violent inward diffusion of Ni at 950℃ resulted in the degradation of the NiCrAlY coating.
文摘Abstract Transient stress and strain fields of dissimilar titanium alloys （TCll and TC17 ） joint during linear friction welding （ LFW） were investigated by a two-dimensional model with ABAQUS/Explicit. The results showed that in the X-axis, the maximum compressive stress of 850 MPa occurred in the center zone of friction interface , and the maximum tensile stress of 190 MPa distributed at the flash; in the Y-axis, the maximum compressive stress of 1 261 MPa located at the junction region between the welding fixture and edge of the specimen, and the maximum tensile stress of 320 MPa distributed in the connecting portion between the flash and edge of the specimen. In addition, areas of plastic strain increased gradually during welding process. In the X-axis, tensile strain mainly existed at the heads of the specimens; in the Y-axis, compressive strain mainly occurred at the heads of the specimens.
文摘The formation reason and elimination method of non-uniform microstructure defects in Ti al- loy TC11 bar have been studied.The coagulating and coarsening into block of the part of grain boundary α and secondary α seem to be caused by the ingot cogging and initial forging temperature in the β region as well as no more enough deformation and uneven distribution. The grain α,elongated α and blocky α may be finally eliminated by adopting the technique of (α+β)thermomechanical processing+β processing,W.Q.+recrystallization annealing,A.C., thus the size of uniform and fine equiaxed α structure is believed to be reduced to 1.9258μm.
基金Funded by the National Natural Science Foundation of China(Nos.52075347,51575364)
文摘To solve the problem of the poor plasticity and to meet the requirements of high temperature for forming titanium alloy,mechanical properties of TC2 titanium alloy under the compound energy-field(CEF)with temperature and ultrasonic vibration were studied.The effects of CEF on tensile force,elongation,microstructure and fractography of the TC2 titanium alloy were compared and analyzed.The results show that,under the same thermal conditions,the deformation resistance of TC2 titanium alloy decreases with the increase of ultrasonic vibration energy.The formability is also improved correspondingly due to the input of ultrasonic vibration energy and its influence on the microstructure of the material.However,when the ultrasonic vibration energy is larger,the fatigue fracture will also appear,which reduces its formability.
基金supported by the Beijing Municipal Science & Technology Commission (Z171100000817002)the National Postdoctoral Program for Innovative Talents of China (BX201600010)the China Postdoctoral Science Foundation (2017M620014)
文摘In this study, the crack propagation behaviors in the equiaxed and equiaxed-columnar grain regions of a heat-treated laser additive manufacturing(LAM) TC11 alloy with a special bi-modal microstructure are investigated. The results indicate that the alloy presents a special bi-modal microstructure that comprises a fork-like primary α(αp) phase surrounded by a secondary α colony(αs) in the α phase matrix after the heat treatment is completed. The samples demonstrate a fast crack growth rate with larger da/d N values through the equiaxed grain sample versus across the equiaxed-columnar grain sample at low K values(<13.8). The differences that are observed between the crack propagation behaviors(in the crack initiation stage) of the samples can be mostly attributed to the different size and morphology of the αp lamellae and αscolony within the grains in the equiaxed and columnar grain regions rather than the grain boundaries. The cracks prefer to grow along the α/β boundary with a smooth propagation route and a fast propagation rate in the equiaxed grain region, where the αpand α clusters have a large size.However, in the columnar grain region, small and randomly distributed αplamellae generate a zigzagshaped propagation path with a reduction in the da/d N value. Additionally, the change in the size of the αp lamellae in the equiaxed grains(heat affected bands, HAB) is also observed to influence the propagation behavior of the crack during the crack initiation stage.
