The dihydrated potassium yttrium diphosphate, KYP2O7·2H2O, has been synthesized for the first time. Single-crystal XRD study has allowed the determination of its structure and correct formula. It crystallizes in ...The dihydrated potassium yttrium diphosphate, KYP2O7·2H2O, has been synthesized for the first time. Single-crystal XRD study has allowed the determination of its structure and correct formula. It crystallizes in the monoclinic system, space group P21/c, with the cell parameters a = 7.7069（3）, b = 10.5801（4）, c = 10.0204（5）A,β = 93.24（3）A, V= 815.76（6）A^3, Z= 4, Mr = 337.98, F（000） = 656, Dc = 2.752 g/cm^3 and/t = 8.073 mm^-1. The single-crystal structure was solved from 1856 unique reflections with the final R = 0.0365 and wR = 0.0772, refined with 119 parameters. The atomic arrangement of KYP2O7·2H2O is built by the P2O7 groups, the YO7 and the KO10 polyhedrons which are connected by corner and edge-sharing to form a three-dimensional framework. Water molecules are directly bonded to the Y and K atoms, and they are located in channels running along the a direction.展开更多
The damping performance evaluation for electromechanical oscillations in power systems is crucial for the stable operation of modern power systems.In this paper,the connection between two commonly-used damping perform...The damping performance evaluation for electromechanical oscillations in power systems is crucial for the stable operation of modern power systems.In this paper,the connection between two commonly-used damping performance evaluation methods,i.e.,the damping torque analysis(DTA)and energy flow analysis(EFA),are systematically examined and revealed for the better understanding of the oscillatory damping mechanism.First,a concept of the aggregated damping torque coefficient is proposed and derived based on DTA of multi-machine power systems,which can characterize the integration effect of the damping contribution from the whole power system.Then,the pre-processing of measurements at the terminal of a local generator is conducted for EFA,and a concept of the frequency-decomposed energy attenuation coefficient is defined to screen the damping contribution with respect to the interested frequency.On this basis,the frequency spectrum analysis of the energy attenuation coefficient is employed to rigorously prove that the results of DTA and EFA are essentially equivalent,which is valid for arbitrary types of synchronous generator models in multi-machine power systems.Additionally,the consistency between the aggregated damping torque coefficient and frequency-decomposed energy attenuation coefficient is further verified by the numerical calculation in case studies.The relationship between the proposed coefficients and the eigenvalue(or damping ratio)is finally revealed,which consolidates the application of the proposed concepts in the damping performance evaluation.展开更多
文摘The dihydrated potassium yttrium diphosphate, KYP2O7·2H2O, has been synthesized for the first time. Single-crystal XRD study has allowed the determination of its structure and correct formula. It crystallizes in the monoclinic system, space group P21/c, with the cell parameters a = 7.7069（3）, b = 10.5801（4）, c = 10.0204（5）A,β = 93.24（3）A, V= 815.76（6）A^3, Z= 4, Mr = 337.98, F（000） = 656, Dc = 2.752 g/cm^3 and/t = 8.073 mm^-1. The single-crystal structure was solved from 1856 unique reflections with the final R = 0.0365 and wR = 0.0772, refined with 119 parameters. The atomic arrangement of KYP2O7·2H2O is built by the P2O7 groups, the YO7 and the KO10 polyhedrons which are connected by corner and edge-sharing to form a three-dimensional framework. Water molecules are directly bonded to the Y and K atoms, and they are located in channels running along the a direction.
基金This work was supported in part by the National Natural Science Foundation of China(No.51807171)the Guangdong Science and Technology Department(No.2019A1515011226)+1 种基金the Hong Kong Research Grant Council(No.15200418)the Department of Electrical Engineering,The Hong Kong Polytechnic University for the Start-up Fund(No.1-ZE68).
文摘The damping performance evaluation for electromechanical oscillations in power systems is crucial for the stable operation of modern power systems.In this paper,the connection between two commonly-used damping performance evaluation methods,i.e.,the damping torque analysis(DTA)and energy flow analysis(EFA),are systematically examined and revealed for the better understanding of the oscillatory damping mechanism.First,a concept of the aggregated damping torque coefficient is proposed and derived based on DTA of multi-machine power systems,which can characterize the integration effect of the damping contribution from the whole power system.Then,the pre-processing of measurements at the terminal of a local generator is conducted for EFA,and a concept of the frequency-decomposed energy attenuation coefficient is defined to screen the damping contribution with respect to the interested frequency.On this basis,the frequency spectrum analysis of the energy attenuation coefficient is employed to rigorously prove that the results of DTA and EFA are essentially equivalent,which is valid for arbitrary types of synchronous generator models in multi-machine power systems.Additionally,the consistency between the aggregated damping torque coefficient and frequency-decomposed energy attenuation coefficient is further verified by the numerical calculation in case studies.The relationship between the proposed coefficients and the eigenvalue(or damping ratio)is finally revealed,which consolidates the application of the proposed concepts in the damping performance evaluation.
