Distribution characteristics of soil organic matter（SOM） and total nitrogen（TN） were studied in different plant communities of the Yajiageng vertical belt in Gongga Mountain around the Dadu River banks. The result...Distribution characteristics of soil organic matter（SOM） and total nitrogen（TN） were studied in different plant communities of the Yajiageng vertical belt in Gongga Mountain around the Dadu River banks. The results show： （1） the contents of SOM and TN of the plant communities gradually decreased with the following order： subalpine coniferous forest （3 027 m）, subalpine meadow （3 873 m）, coniferous broadleaved mixed forest（2 737 m）, subalpine shrub（3 565 m） and treeline（3 564 m）. （2） With soil profile depth increasing, the contents of SOM and TN gradually decreased. For different vegetation types, the contents of SOM and TN in sub-alpine coniferous forest were higher than that of other vegetational types. （3）The ratio of the content of carbon to the content of total nitrogen （Cc/CTN）WaS 13.5-27.6, which was relatively lower than the appropriate Cc/CTN of 25-30, and indicated that the soil in favor of the organic matter decomposed and nutrients released. Cc/CTN in the soil had no correlation with sea level altitude. However, its distribution in the soil x, aried with different vegetation types. （4） Nitrogen in SOM existed mainly in the form of organic nitrogen, and Cc/CTN in the soil was not obvious correlated with SOM and TN.展开更多
The problem of effluent total nitrogen(TN)at most of the wastewater treatment plants(WWTPs)in China is important for meeting the related water quality standards,even under the condition of high energy consumption.To a...The problem of effluent total nitrogen(TN)at most of the wastewater treatment plants(WWTPs)in China is important for meeting the related water quality standards,even under the condition of high energy consumption.To achieve better prediction and control of effluent TN concentration,an efficient prediction model,based on controllable operation parameters,was constructed in a sequencing batch reactor process.Compared with previous models,this model has two main characteristics:①Superficial gas velocity and anoxic time are controllable operation parameters and are selected as the main input parameters instead of dissolved oxygen to improve the model controllability,and②the model prediction accuracy is improved on the basis of a feedforward neural network(FFNN)with algorithm optimization.The results demonstrated that the FFNN model was efficiently optimized by scaled conjugate gradient,and the performance was excellent compared with other models in terms of the correlation coefficient(R).The optimized FFNN model could provide an accurate prediction of effluent TN based on influent water parameters and key control parameters.This study revealed the possible application of the optimized FFNN model for the efficient removal of pollutants and lower energy consumption at most of the WWTPs.展开更多
Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)an...Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)and total nitrogen(TN)contents in alpine wetland.A field survey of 180 soilsampling profiles was conducted in an alpine wetland that has been classified into three degradation succession stages.The SOC and TN contents of soil layers from 0 to 200 cm depth were studied,including their distribution characteristics and the relationship between microtopography.The results showed that SOC and TN of different degradation succession gradients followed the ranked order of Non Degradation(ND)>Light Degradation(LD)>Heavy Degradation(HD).SWC was positively correlated with SOC and TN(p<0.05).As the degree of degradation succession worsened,SOC and TN became more sensitive to the SWC.Microtopography was closely related to the degree of wetland degradation succession,SWC,SOC and TN,especially in the topsoil(0-30 cm).This result showed that SWC was an important indicator of SOC/TN in alpine wetland.It is highly recommended to strengthen water injection into the wetland as a means of effective restoration to reverse alpine meadow back to marsh alpine wetland.展开更多
Point and nonpoint sources of phosphorus (P) and nitrogen (N) can cause reductions in water quality, including eutrophication. Nonpoint pollution represents a special challenge because of dispersed not easily identifi...Point and nonpoint sources of phosphorus (P) and nitrogen (N) can cause reductions in water quality, including eutrophication. Nonpoint pollution represents a special challenge because of dispersed not easily identifiable sources such as the runoff from soil, nutrients, and other chemicals from agricultural fields and residential areas. Laguna Cartagena is a tropical freshwater wetland, situated in southwestern Puerto Rico. It is a eutrophic ecosystem, and its eutrophication is caused by both external nutrient loading and internal, mainly by phosphorus. This wetland has been affected by phosphorus loading from inorganic agricultural fertilizer in this historically oligotrophic wetland system until the end of subsidized fertilizer use and sugar cane cultivation in the late 1990s. This study identifies: 1) nonpoint sources of phosphorus (SRP, Soluble Reactive Phosphorus and TP, Total Phosphorus) and nitrogen (nitrate, nitrite, and ammonia) that enter Laguna Cartagena;and 2) the role of precipitation events on the contributions of phosphorus and nitrogen loading to ecosystems. Herein we assess water samples from five channelized external sources of P and N that enter Laguna Cartagena at two-week intervals from October 2013 through November 2014. Rainfall data were obtained weekly from a rain gauge. Standard methods were used for all chemical analyses. Results showed that the channelized waterways that carry water to the lagoon can be classified as hypereutrophic (>100 μg/L) for TP concentrations and oligotrophic (<200 μg/L) for nitrogen concentrations. Currently agriculture (rice and cattle) is the predominant land use at the nearby University of Puerto Rico (UPR) Lajas Agricultural Experiment Substation, the predominant nonpoint source of nutrient pollution (SRP, TP and ammonia) in the principal channelized water sources to the lagoon. Current nutrient loads are likely derived from fertilizers applied to the Substation’s rice fields, and a high density livestock. The second important cause of external surface water degradation (SRP, TP and ammonia) is the discharge from rural households in the drainage basin that discharge greywater directly to the environment, as indicated by the results from Cerro Alto hills immediately to the north of the lagoon. Precipitation also was associated with SRP, TP and ammonia loads.展开更多
The aim of this study was to establish the applicability of near-infrared reflectance spectroscopy(NIRS)as a rapid method for the accurate estimation of nutrient components in agricultural soils.Focusing on the soil o...The aim of this study was to establish the applicability of near-infrared reflectance spectroscopy(NIRS)as a rapid method for the accurate estimation of nutrient components in agricultural soils.Focusing on the soil of the Sanjiang Plain,NIRS was used to predict soil organic matter(SOM),the total nitrogen(TN)and the total phosphorus(TP).A total of 540 samples were collected from the three different depths(180 samples from each depth:0-10,10-20 and 20-30 cm),from 2015 to 2017,from the Sanjiang Plain in Heilongjiang Province,China.From every depth,120 samples were used to construct the calibration set.Other 60 samples were used to check the efficiency of the model.Combining the first-order differentiation with the partial least square(PLS)method,a prediction model was obtained to measure SOM,TN and TP.The correlation coefficient of SOM from 0 to 10 cm was R2=0.9567,from 10 to 20 cm was R2=0.9416,and from 20 to 30 cm was R2=0.9402.The corresponding ratio(standard deviation[SD]/root mean square error of prediction[RMSEP])was>2.96.R2 of TN with the three depths was 0.9154,0.9028 and 0.9024,respectively,all with SD/RMSEP>2.89.Meanwhile,R2 of TP with the three depths was 0.8974,0.8624 and 0.7804,respectively,all with SD/RMSEP>2.50.These results demonstrated that NIRS based on the first-order differentiation and PLS could efficiently predict SOM,TN and TP from different soil depths.展开更多
Using hyperspectral data collected in January and June 2022 from the Sha River,the concentrations of total nitrogen(TN)and total phosphorus(TP)were estimated using the differential method.The results indicate that the...Using hyperspectral data collected in January and June 2022 from the Sha River,the concentrations of total nitrogen(TN)and total phosphorus(TP)were estimated using the differential method.The results indicate that the optimal bands for estimation vary monthly due to temperature fluctuations.In the TN model,the power function model at 586 nm in January exhibited the strongest fit,yielding a fit coefficient(R2)of 0.95 and F-value of 164.57 at a significance level(p)of less than 0.01.Conversely,the exponential model at 477 nm in June provided the best fit,with R2=0.93 and F=80.95 at p<0.01.In the TP model,the exponential model fit of the differential values at 851 nm with TP in January produced the best results,with R2=0.78 and F=20.61.However,the overall fit in June outperformed that in January.Specifically,the quadratic and linear model fits of the differential values at 824 and 863 nm with TP achieved R2=0.96 and F-values of 34.42 and 203.34,respectively.展开更多
In this paper, the bottom of the Dianshan Lake was selected as a test sample. The dynamic release of contaminated sediments into the overlying water column was experimentally investigated in an open water channel unde...In this paper, the bottom of the Dianshan Lake was selected as a test sample. The dynamic release of contaminated sediments into the overlying water column was experimentally investigated in an open water channel under different hydrodynamic conditions. The experimental results indicate that the Total Phosphorus （TP） release process can be divided into three stages： rapid release, slow release and equilibration release. In the initial release stage the measured TP concentration changes along the depth. The TP concentration near the sediment-water interface is higher than that near the water surface, but the TP concentration becomes uniform along the depth after 3 h. The dynamic release of re-suspension sediment pollutants is about 6 times higher than the static release of sediment-water interface. There are three main types of release mechanism： diffusion release, re-suspended pore water mixing release and re-suspended particles desorbing release.展开更多
Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and d...Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and denitrification reactions, was used to assess their possible biodegradation. Because of the negative effects of high salt concentration (3%), heavy metals and toxic organic matter on microorganisms’ activities, some techniques consisting of dilution, coagulation and flocculation, and ozonation pretreatments, were gradually tested to evaluate chemical oxygen demand (COD), ammonia-nitrogen (ammonia-N) and total nitrogen (TN) removal rates. In this process of FCC wastewater, starting with university-domesticated sludge, the ammonia-N and TN removal rates were worst. However, when using domesticated SBR’s sludge and operating with five-fold daily diluted influent (thus reducing salt concentration), the ammonia-N removal reached about 57% while the TN removal rate was less than 37% meaning an amelioration of the nitrification process. However, by reducing the dilution factors, these results were inflected after some days of operation, with ammonia-N removal decreasing and TN barely removed meaning a poor nitrification. Even by reducing heavy metals concentration with coagulation/flocculation process, the results never changed. Thereafter, by using ozonation pre-treatment to degrade the detected organic matter of di-tert-butylphenol and certain isoparaffins, COD, ammonia-N and TN removal rates reached 92%, 62% and 61%, respectively. These results showed that the activities of the microorganisms were increased, thus indicating a net denitrification and nitrification reactions improvement.展开更多
基金the National Basic Research Program of China (973 Program) (2005CB422005)
文摘Distribution characteristics of soil organic matter（SOM） and total nitrogen（TN） were studied in different plant communities of the Yajiageng vertical belt in Gongga Mountain around the Dadu River banks. The results show： （1） the contents of SOM and TN of the plant communities gradually decreased with the following order： subalpine coniferous forest （3 027 m）, subalpine meadow （3 873 m）, coniferous broadleaved mixed forest（2 737 m）, subalpine shrub（3 565 m） and treeline（3 564 m）. （2） With soil profile depth increasing, the contents of SOM and TN gradually decreased. For different vegetation types, the contents of SOM and TN in sub-alpine coniferous forest were higher than that of other vegetational types. （3）The ratio of the content of carbon to the content of total nitrogen （Cc/CTN）WaS 13.5-27.6, which was relatively lower than the appropriate Cc/CTN of 25-30, and indicated that the soil in favor of the organic matter decomposed and nutrients released. Cc/CTN in the soil had no correlation with sea level altitude. However, its distribution in the soil x, aried with different vegetation types. （4） Nitrogen in SOM existed mainly in the form of organic nitrogen, and Cc/CTN in the soil was not obvious correlated with SOM and TN.
基金This work was funded by the Major Science and Technology Program for Water Pollution Control and Treatment(2017ZX07201003)the National Natural Science Foundation of China(51961125101)the Science and Technology Project of Zhejiang Province(2018C03003).
文摘The problem of effluent total nitrogen(TN)at most of the wastewater treatment plants(WWTPs)in China is important for meeting the related water quality standards,even under the condition of high energy consumption.To achieve better prediction and control of effluent TN concentration,an efficient prediction model,based on controllable operation parameters,was constructed in a sequencing batch reactor process.Compared with previous models,this model has two main characteristics:①Superficial gas velocity and anoxic time are controllable operation parameters and are selected as the main input parameters instead of dissolved oxygen to improve the model controllability,and②the model prediction accuracy is improved on the basis of a feedforward neural network(FFNN)with algorithm optimization.The results demonstrated that the FFNN model was efficiently optimized by scaled conjugate gradient,and the performance was excellent compared with other models in terms of the correlation coefficient(R).The optimized FFNN model could provide an accurate prediction of effluent TN based on influent water parameters and key control parameters.This study revealed the possible application of the optimized FFNN model for the efficient removal of pollutants and lower energy consumption at most of the WWTPs.
基金funded by the Qinghai Science and Technology Department(Grant No.2017-ZJ-799)the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(Grant No.2019QZKK1002)received form Program for the National Natural Sciences Foundation of China(Grant No.41665008,31872999,41565008,41861049)。
文摘Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)and total nitrogen(TN)contents in alpine wetland.A field survey of 180 soilsampling profiles was conducted in an alpine wetland that has been classified into three degradation succession stages.The SOC and TN contents of soil layers from 0 to 200 cm depth were studied,including their distribution characteristics and the relationship between microtopography.The results showed that SOC and TN of different degradation succession gradients followed the ranked order of Non Degradation(ND)>Light Degradation(LD)>Heavy Degradation(HD).SWC was positively correlated with SOC and TN(p<0.05).As the degree of degradation succession worsened,SOC and TN became more sensitive to the SWC.Microtopography was closely related to the degree of wetland degradation succession,SWC,SOC and TN,especially in the topsoil(0-30 cm).This result showed that SWC was an important indicator of SOC/TN in alpine wetland.It is highly recommended to strengthen water injection into the wetland as a means of effective restoration to reverse alpine meadow back to marsh alpine wetland.
文摘Point and nonpoint sources of phosphorus (P) and nitrogen (N) can cause reductions in water quality, including eutrophication. Nonpoint pollution represents a special challenge because of dispersed not easily identifiable sources such as the runoff from soil, nutrients, and other chemicals from agricultural fields and residential areas. Laguna Cartagena is a tropical freshwater wetland, situated in southwestern Puerto Rico. It is a eutrophic ecosystem, and its eutrophication is caused by both external nutrient loading and internal, mainly by phosphorus. This wetland has been affected by phosphorus loading from inorganic agricultural fertilizer in this historically oligotrophic wetland system until the end of subsidized fertilizer use and sugar cane cultivation in the late 1990s. This study identifies: 1) nonpoint sources of phosphorus (SRP, Soluble Reactive Phosphorus and TP, Total Phosphorus) and nitrogen (nitrate, nitrite, and ammonia) that enter Laguna Cartagena;and 2) the role of precipitation events on the contributions of phosphorus and nitrogen loading to ecosystems. Herein we assess water samples from five channelized external sources of P and N that enter Laguna Cartagena at two-week intervals from October 2013 through November 2014. Rainfall data were obtained weekly from a rain gauge. Standard methods were used for all chemical analyses. Results showed that the channelized waterways that carry water to the lagoon can be classified as hypereutrophic (>100 μg/L) for TP concentrations and oligotrophic (<200 μg/L) for nitrogen concentrations. Currently agriculture (rice and cattle) is the predominant land use at the nearby University of Puerto Rico (UPR) Lajas Agricultural Experiment Substation, the predominant nonpoint source of nutrient pollution (SRP, TP and ammonia) in the principal channelized water sources to the lagoon. Current nutrient loads are likely derived from fertilizers applied to the Substation’s rice fields, and a high density livestock. The second important cause of external surface water degradation (SRP, TP and ammonia) is the discharge from rural households in the drainage basin that discharge greywater directly to the environment, as indicated by the results from Cerro Alto hills immediately to the north of the lagoon. Precipitation also was associated with SRP, TP and ammonia loads.
基金Supported by the National Natural Science Foundation(31802120)Research and Demonstration of Large-scale Artificial Grassland Combined Plant and Circular Mode(2017YFD0502106)Academic Backbone Fund Project of Northeast Agricultural University。
文摘The aim of this study was to establish the applicability of near-infrared reflectance spectroscopy(NIRS)as a rapid method for the accurate estimation of nutrient components in agricultural soils.Focusing on the soil of the Sanjiang Plain,NIRS was used to predict soil organic matter(SOM),the total nitrogen(TN)and the total phosphorus(TP).A total of 540 samples were collected from the three different depths(180 samples from each depth:0-10,10-20 and 20-30 cm),from 2015 to 2017,from the Sanjiang Plain in Heilongjiang Province,China.From every depth,120 samples were used to construct the calibration set.Other 60 samples were used to check the efficiency of the model.Combining the first-order differentiation with the partial least square(PLS)method,a prediction model was obtained to measure SOM,TN and TP.The correlation coefficient of SOM from 0 to 10 cm was R2=0.9567,from 10 to 20 cm was R2=0.9416,and from 20 to 30 cm was R2=0.9402.The corresponding ratio(standard deviation[SD]/root mean square error of prediction[RMSEP])was>2.96.R2 of TN with the three depths was 0.9154,0.9028 and 0.9024,respectively,all with SD/RMSEP>2.89.Meanwhile,R2 of TP with the three depths was 0.8974,0.8624 and 0.7804,respectively,all with SD/RMSEP>2.50.These results demonstrated that NIRS based on the first-order differentiation and PLS could efficiently predict SOM,TN and TP from different soil depths.
基金funded by the Gansu Provincial Science and Technology Plan Project,Innovation Base and Talent Project(Project Number:21JR1RA284).
文摘Using hyperspectral data collected in January and June 2022 from the Sha River,the concentrations of total nitrogen(TN)and total phosphorus(TP)were estimated using the differential method.The results indicate that the optimal bands for estimation vary monthly due to temperature fluctuations.In the TN model,the power function model at 586 nm in January exhibited the strongest fit,yielding a fit coefficient(R2)of 0.95 and F-value of 164.57 at a significance level(p)of less than 0.01.Conversely,the exponential model at 477 nm in June provided the best fit,with R2=0.93 and F=80.95 at p<0.01.In the TP model,the exponential model fit of the differential values at 851 nm with TP in January produced the best results,with R2=0.78 and F=20.61.However,the overall fit in June outperformed that in January.Specifically,the quadratic and linear model fits of the differential values at 824 and 863 nm with TP achieved R2=0.96 and F-values of 34.42 and 203.34,respectively.
基金the National Natural Science Foundation of China (Grant Nos. 10972134, 11032007)the Shanghai Program for Innovative Research Team in Universities
文摘In this paper, the bottom of the Dianshan Lake was selected as a test sample. The dynamic release of contaminated sediments into the overlying water column was experimentally investigated in an open water channel under different hydrodynamic conditions. The experimental results indicate that the Total Phosphorus （TP） release process can be divided into three stages： rapid release, slow release and equilibration release. In the initial release stage the measured TP concentration changes along the depth. The TP concentration near the sediment-water interface is higher than that near the water surface, but the TP concentration becomes uniform along the depth after 3 h. The dynamic release of re-suspension sediment pollutants is about 6 times higher than the static release of sediment-water interface. There are three main types of release mechanism： diffusion release, re-suspended pore water mixing release and re-suspended particles desorbing release.
文摘Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and denitrification reactions, was used to assess their possible biodegradation. Because of the negative effects of high salt concentration (3%), heavy metals and toxic organic matter on microorganisms’ activities, some techniques consisting of dilution, coagulation and flocculation, and ozonation pretreatments, were gradually tested to evaluate chemical oxygen demand (COD), ammonia-nitrogen (ammonia-N) and total nitrogen (TN) removal rates. In this process of FCC wastewater, starting with university-domesticated sludge, the ammonia-N and TN removal rates were worst. However, when using domesticated SBR’s sludge and operating with five-fold daily diluted influent (thus reducing salt concentration), the ammonia-N removal reached about 57% while the TN removal rate was less than 37% meaning an amelioration of the nitrification process. However, by reducing the dilution factors, these results were inflected after some days of operation, with ammonia-N removal decreasing and TN barely removed meaning a poor nitrification. Even by reducing heavy metals concentration with coagulation/flocculation process, the results never changed. Thereafter, by using ozonation pre-treatment to degrade the detected organic matter of di-tert-butylphenol and certain isoparaffins, COD, ammonia-N and TN removal rates reached 92%, 62% and 61%, respectively. These results showed that the activities of the microorganisms were increased, thus indicating a net denitrification and nitrification reactions improvement.
