Diphylleia Grayi-Inspired Intelligent Temperature-Responsive Transparent Nanofiber Membranes

Nanofiber membranes(NFMs) have become attractive candidates for next-generation flexible transparent materials due to their exceptional flexibility and breathability. However, improving the transmittance of NFMs is a great challenge due to the enormous reflection and incredibly poor transmission generated by the nanofiber-air interface. In this research, we report a general strategy for the preparation of flexible temperature-responsive transparent(TRT) membranes,which achieves a rapid transformation of NFMs from opaque to highly transparent under a narrow temperature window. In this process, the phase change material eicosane is coated on the surface of the polyurethane nanofibers by electrospray technology. When the temperature rises to 37 ℃, eicosane rapidly completes the phase transition and establishes the light transmission path between the nanofibers, preventing light loss from reflection at the nanofiber-air interface. The resulting TRT membrane exhibits high transmittance(> 90%), and fast response(5 s). This study achieves the first TRT transition of NFMs, offering a general strategy for building highly transparent nanofiber materials, shaping the future of next-generation intelligent temperature monitoring, anti-counterfeiting measures, and other high-performance devices.

Embedding Perovskite in Polymer Matrix Achieved Positive Temperature Response with Inversed Temperature Crystallization

Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability.In this study,a novel perovskite-based composite with positive sensitivity to temperature was designed and obtained based on its inverse temperature crystallization,demonstrating good flexibility and solution processability.The supercritical drying method was used to address the limitations of annealing drying in preparing high-performance perovskite.Optimizing the precursor composition proved to be an effective approach for achieving high fluorescence and structural integrity in the perovskite material.This perovskite-based composite exhibited a positive temperature sensitivity of 28.563%℃^(-1)for intensity change and excellent temperature cycling reversibility in the range of 25-40℃in an ambient environment.This made it suitable for use as a smart window with rapid response.Furthermore,the perovskite composite was found to offer temperature-sensing photoluminescence and flexible processability due to its components of perovskite-based compounds and polyethylene oxide.The organic precursor solvent could be a promising candidate for use as ink to print or write on various substrates for optoelectronic devices responding to temperature.

Simulation of alumina dissolution and temperature response under different feeding quantities in aluminum reduction cell

In the feeding process of aluminum electrolytic, feeding quantity of alumina affects eventually dissolved quantity at the end of a feeding cycle. Based on the OpenFOAM platform, dissolution model coupled with heat and mass transfer was established. Applying the Rosin-Rammler function, alumina particle size distribution under different feeding quantities was obtained. The temperature response of electrolyte after feeding was included and calculated, and the dissolution processes of alumina with different feeding quantities (0.6, 0.8, 1.0, 1.2, 1.4, 1.6 kg) after feeding were simulated in 300 kA aluminum reduction cell. The results show that with the increase of feeding quantity, accumulated mass fraction of dissolved alumina decreases, and the time required for the rapid dissolution stage extends. When the feeding quantity is 0.6 kg and 1.2 kg, it takes the shortest time for the electrolyte temperature dropping before rebounding back. With the increase of feeding quantity, the dissolution rate in the rapid dissolution stage increases at first and then decreases gradually. The most suitable feeding quantity is 1.2 kg. The fitting equation of alumina dissolution curve under different feeding quantities is obtained, which can be used to evaluate the alumina dissolution and guide the feeding quantity and feeding cycle.

Using a process-oriented methodology to precisely evaluate temperature suitability for potato growth in China using GIS

A process-oriented methodology to conduct precise evaluation temporally and spatially on temperature suitability for potato growth was applied in China. Arable lands in China were gridded with 1 km×1 km geographic units, and potential potato phenology in each unit was automatically identified in terms of the potato planting initial temperature and effective accu- mulated temperature. A temperature thermal response coefficient model was used to compute a temperature suitability value for each day of potato phenology in each geographic unit. In addition, five temperature suitability ranking methods were applied to define suitable areas： （1） upper fourth quantile, （2） median, （3） expected value＋1/4 standard deviation, （4） expected value＋1/2 standard deviation, （5） expected value＋1 standard deviation. A validation indicator was innovated to test the effectiveness of the five ranking methods. The results showed that from a strict degree point of view, the five methods sequence was as follows： 1=3〉4〉2〉5, with a and c determined as the two best ranking methods. For methods 1 and 3, the suitable potato growing area was 1 of 57.76× 10^4 km2. In addition, the suitable, areas were spatially coincident with the main potato producing counties. The study output technically supports the proposal from China＇s government that there is a large potential area to grow winter-ploughed potato in South China because the potential suitable area for growing potato is approximately 2×10^7 ha. In southeast Heilongjiang and east Jilin, where it is hilly and mountainous, there are still some potentially suitable areas for potato growing accounting for nearly 2.32×10^6 ha. The authors suggest to optimize the agricultural regionalization and layout in China and to adjust the cropping pattern structure.

INFLUENCE OF TEMPERATURE-DEPENDENT PROPERTIES ON TEMPERATURE RESPONSE AND OPTIMUM DESIGN OF C/M FGMS UNDER THERMAL CYCLIC LOADING

The influence of temperature-dependent properties on temperature response and optimum design of newly developed ceramic-metal functionally graded materials under cyclic thermal loading and high temperature gradient environment is studied. The thermal conductivity of the material is considered to be dependent on the temperature. In this paper, the temperature response of the material is calculated using a nonlinear finite element method. Emphasis is placed on the influence of temperatue-dependent properties on the thermal response and insulation property of the material render the different graded compositional distributions and different heat flux magnitudes. Through the analysis, it is suggested that the influence of temperature-dependent properties can not be neglected in the temperature response analysis and the optimum design process of the material must be based on the temperature-dependent temperature analysis theory.

Improvement of a temperature response function for divertor heat flux monitoring in fusion devices

Temperature response functions have been developed to investigate sensor design and divertor heat flux estimation in magnetically confined plasmas. The time-dependent heat flux can be derived by fitting the response function to experimental thermocouple(TC) data. Because the TC signals have a time delay to transit events such as discharge start or confinement transition, the time delay is taken into account in a temperature response function. Such a function accurately describes the signal from each TC channel with time delay in a sensor test using a neutral beam injection. Measurement for commercial TCs shows that the time delay is caused by the finite heat capacity of TC wire and contact heat resistance between TC and target surface.

Response of Sample Temperature during Straight-Line Ion Implantation

A theoretical model for calculation of the sample temperature during straight-line nitrogen ion implantation was established based on the results of experiment in this paper. Taking the pure aluminum as the samples, and from the transformation of electric energy into thermal energy, the calculated values of the temperature were in good agreement with the measured values in the experiment. According to the simulation, this technology can be applied to the control of specimens temperature during the implantation.

Physiological Response to High Temperature and Evaluation of Heat Tolerance of Different Grape Cultivars

[Objectives]This study was conducted to investigate the differences in the physiological responses of different grape cultivars to high temperature.[Methods]The 19 tested cultivars were selected from the grape germplasm resources pool of Turpan Research Institute of Xinjiang Academy of Agricultural Sciences.Twelve physiological indexes including gas exchange parameters,chlorophyll content,antioxidant enzyme activity and proline content were determined in grape leaves under field conditions during the middle period of local natural high temperature period(July,daily maximum air temperature>35℃).The heat tolerance of different cultivars was evaluated by fuzzy membership function analysis and optimum partitioning clustering of ordered samples.[Results](1)Under natural high temperature conditions in Turpan,the 19 tested grape cultivars responded differently to high temperature.‘Red Globe’,‘Fujiminori’,‘Beta’,‘Hetianhuang’had strong heat tolerance,while‘Thompson Seedless’,‘Hongqi Tezaomeigui’,‘Shuijing Wuhe’,‘Victoria’,‘Yatomi Rosa’and‘Crimson Seedless’had weak heat tolerance.(2)Among the 12 physiological indexes,malondialdehyde content and antioxidant enzyme activity were mostly different among various grape cultivars.The grape cultivars with strong heat tolerance,‘Red Globe’and‘Fujiminori’,had relatively lower malondialdehyde contents,while‘Beta’and‘Hetianhuang’had relatively higher malondialdehyde contents.But they had higher activity of antioxidant enzymes.(3)The results of fuzzy membership function analysis showed that the cumulative membership value(AR)of each physiological index was consistent with its apparent heat tolerance performance,suggesting that AR can be a potential index for the evaluation of heat tolerance of grape cultivars.Further cluster analysis classified the tested cultivars as strong,medium and weak.‘Red Globe’,‘Fujiminori’,‘Beta’and‘Hetianhuang’had strong heat tolerance.[Conclusions]This study provides a reference for grape cultivation under high temperature and stress and breeding of heat-tolerant varieties.

THE STUDY OF THE NON-STEADY KINETICS OF THE OXYDEHYDROGENATION OF ETHANE TO ETHYLENE OVER THE CATALYST OF Mo-V-Nb/Al_2O_3 BY THE TECHNIQUE OF TEMPERATURE PROGRAMMED TRANSIENT RESPONSE AND ELECTRIC CONDUCTIVITY

In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer(FTIR) a new technique of Temperature Programmed Transient Response(TP-TR) has been used with gas chromatography. Therefore, the TP-TR will be applied more widespreadly than ever before. With the technique of TP-TR and electric conductivity, the study is on the reaction mechanism and the adsorption behavior of the reactants and products to the present catalyst Mo-V-Nb/Al_2O_3 in the reaction from ethane through oxydehydrogenation to ethylene as the product. By Range-Kutta-Gill and Margarat methods, the kinetic parameters of the reaction elementary steps (i.e. rate constants, active energies and frequency factors) have been evaluated. The mathematical treatment coincides with the experimental results.

Manipulating the Phase Transition Behavior of Dual Temperature-Responsive Block Copolymers by Adjusting Composition and Sequence

Temperature-responsive polymers have garnered significant attention due to their ability to respond to external stimuli.In this work,dual temperature-responsive block copolymers are synthesized via reversible addition-fragmentation chain transfer polymerization(RAFT)polymerization utilizing zwitterionic monomer methacryloyl ethyl sulfobetaine(SBMA) and N-isopropyl acrylamide(NIPAAm) as monomers.The thermal responsive behaviors can be easily modulated by incorporating additional hydrophobic monomer benzyl acrylate(BN) or hydrophilic monomer acrylic acid(AA),adjusting concentration or pH,or varying the degree of polymerization of the block chain segments.The cloud points of the copolymers are determined by UV-Vis spectrophotometry,and these copolymers exhibit both controlled upper and lower critical solu bility temperatures(LCST and UCST) in aqueous solution.This study analyzes and summarizes the influencing factors of dual temperature responsive block copolymers by exploring the effects of various conditions on the phase transition temperature of temperature-sensitive polymers to explore the relationship between their properties and environment and structure to make them more selective in terms of temperature application range and regulation laws.It is very interesting that the introduction of poly-acrylic acid(PAA) segments in the middle of di-block copolymer PSBMA_(55)-b-PNIPAAm_(80) to form PSBMA_(55)-b-PAA_(x)-b-PNIPAAm_(80) results in a reversal of temperature-responsive behaviors from 'U'(LCST UCST) type,while the copolymer PSBMA_(55)-b-P(NIPAAm_(80)-co-AA_(x)) not.This work provides a clue for tuning the phase transition behavior of polymers for manufacture of extreme smart materials.

Simple synthesis of sub-nanometer Pd clusters:High catalytic activity of Pd/PEG-PNIPAM in Suzuki reaction

Ultra‐small metal nanoclusters have high surface energy and abundant active sites,and thereforetheir catalytic activities are usually significantly higher than those of larger nanoparticles.A temperature‐responsive copolymer,namely poly(ethylene glycol)‐co‐poly(N‐isopropylacrylamide)(PEG‐PNIPAM)was synthesized as the first step,and then ultra‐small Pd clusters stabilized withinPEG‐PNIPAM copolymer micelles were formed by direct reduction.Pd nanoclusters of size less than2nm showed outstanding catalytic activity in the Suzuki coupling reaction.The reaction betweeniodobenzene and phenylboronic acid was completed in as little as10s(turnover frequency=4.3×104h?1).A yield of64%was achieved in5min in the reaction between chlorobenzene and phenylboronicacid.The catalyst showed significant deactivation during three consecutive runs.However,this composite catalyst consisting of Pd/PEG‐PNIPAM can be easily recycled based on the reversiblephase transition of temperature‐responsive PEG‐PNIPAM.This catalyst therefore has good potentialfor practical applications.

Thermal behavior of materials in laser-assisted extreme manufacturing:Raman-based novel characterization

Laser-assisted manufacturing(LAM)is a technique that performs machining of materials using a laser heating process.During the process,temperatures can rise above over 2000°C.As a result,it is crucial to explore the thermal behavior of materials under such high temperatures to understand the physics behind LAM and provide feedback for manufacturing optimization.Raman spectroscopy,which is widely used for structure characterization,can provide a novel way to measure temperature during LAM.In this review,we discuss the mechanism of Raman-based temperature probing,its calibration,and sources of uncertainty/error,and how to control them.We critically review the Raman-based temperature measurement considering the spatial resolution under near-field optical heating and surface structure-induced asymmetries.As another critical aspect of Raman-based temperature measurement,temporal resolution is also reviewed to cover various ways of realizing ultrafast thermal probing.We conclude with a detailed outlook on Raman-based temperature probing in LAM and issues that need special attention.

Mixed-Alkali Effect on Thermal Property and Elastic Behavior in Borosilicate Glasses

We investigated the mixed alkali effect on the thermal properties and elastic response to temperature in the borosilicate glasses system with the composition of 70.65Si O_(2)·21.09B_(2)O_(3)·1.88Al_(2)O_(3)·(6.38-x)Li_(2)O·x Na_(2)O glasses,where x=0.00,1.595,3.19,4.785,and 6.38.Except for the expected positive and negative deviations from linearity for the coefficients of thermal expansion,room temperature E and G,we observed a new mixed alkali efiect on the response of elastic moduli to temperature.Fourier transform infrared spectra were obtained to elucidate the possible structural origin of the mixed alkali efiects.This work provides a valuable insight into the structural and mechanical properties of mixed-alkali borosilicate glasses.

The Co-seismic Response of Underground Fluid in Yunnan to the Nepal MS8.1 Earthquake

In this paper,statistics are taken on the co-seismic response of underground fluid in Yunnan to the Nepal M_S8. 1 earthquake,and the co-seismic response characteristics of the water level and water temperature are analyzed and summarized with the digital data. The results show that the Nepal M_S8. 1 earthquake had greater impact on the Yunnan region,and the macro and micro dynamics of fluids showed significant co-seismic response. The earthquake recording capacity of water level and temperature measurement is significantly higher than that of water radon and water quality to this large earthquake; the maximum amplitude and duration of co-seismic response of water level and water temperature vary greatly in different wells. The changing forms are dominated by fluctuation and step rise in water level,and a rising or falling restoration in water temperature. From the records of the main shock and the maximum strong aftershock,we can see that the greater magnitude of earthquake,the higher ratio of the occurrence of co-seismic response,and in the same well,the larger the response amplitude,as well as the longer the duration. The amplitude and duration of co-seismic response recorded by different instruments in a same well are different. Water temperature co-seismic response almost occurred in wells with water level response,indicating that the well water level and water temperature are closely related in co-seismic response,and the well water temperature seismic response was caused mainly by well water level seismic response.

Molecular Regulation of Plant Responses to Environmental Temperatures

Temperature is a key factor governing the growth and development,distribution,and seasonal behavior of plants.The entireplant life cycle is affected by environmental temperatures.Plants grow rapidly and exhibit specific changes in morphology under mild average temperature conditions,a response termed thermomorphogenesis.When exposed to chilling or moist chilling low temperatures,flowering or seed germination is accelerated in some plant species;these processes are known as vernalization and cold stratification,respectively.Interestingly,once many temperate plants are exposed to chilling temperatures for some time,they can acquire the ability to resist freezing stress,a process termed cold acclimation.In the face of global climate change,heat stress has emerged as a frequent challenge,which adversely affects plant growth and development.In this review,we summarize and discuss recent progress in dissecting them olecular mechanism sregulating plant thermomorphogenesis,vernalization,and responses to extreme temperatures.We also discuss the remaining issues that are crucial for understanding the interactions between plants and temperature.

Molecular mechanisms governing plant responses to high temperatures

The increased prevalence of high temperatures （HTs） around the world is a major global concern, as they dramatically affect agronomic productivity. Upon HT exposure, plants sense the temperature change and initiate cellular and metabolic responses that enable them to adapt to their new environmental conditions.Decoding the mechanisms by which plants cope with HT will facilitate the development of molecular markers to enable the production of plants with improved thermotolerance. In recent decades, genetic, physiological, molecular, and biochemical studies have revealed a number of vital cellular components and processes involved in thermoresponsive growth and the acquisition of thermo- tolerance in plants. This review summarizes the major mechanisms involved in plant HT responses, with a special focus on recent discoveries related to plant thermosensing, heat stress signaling, and HT-regulated gene expression networks that promote plant adaptation to elevated environmental temperatures.

Temperature Modulates Tissue-Specification Program to Control Fruit Dehiscence in Brassicaceae

Plants respond to diurnal and seasonal changes in temperature by reprogramming vital developmental pathways. Understanding the molecular mechanisms that define environmental modulation of plant growth and reproduction is critical in the context of climate change that threatens crop yield worldwide. Here, we report that elevated temperature accelerates fruit dehiscence in members of the Brassicaceae family including the model plant Arabidopsis thaliana and important crop species. Arabidopsis fruit development is controlled by a network of interacting regulatory genes. Among them, the INDEHISCENT （IND） gene is a key regulator of the valve-margin tissue that mediates fruit opening, hence facilitating fruit dehiscence. We demonstrated that the valve-margin development is accelerated at higher temperature and that IND is tar- geted for thermosensory control. Our results reveal that IND upregulation is facilitated via temperature- induced chromatin dynamics leading to accelerated valve-margin specification and dispersal of the seed. Specifically, we show that temperature-induced changes in IND expression are associated with ther- mosensory H2A.Z nucleosome dynamics. These findings establish a molecular framework connecting tis- sue identity with thermal sensing and set out directions for the production of temperature-resilient crops.

Temperature and structural responses of a single-section utility tunnel throughout fire exposure

In this study,fire tests of four single-section scaled-down utility tunnels were conducted.By analyzing temperature and structural responses of the utility tunnel throughout the fire exposure,the effects on the fire behavior of two different construction methods,cast-in-situ and prefabricated,and of two different materials,ordinary concrete and full lightweight concrete,were explored.The results of the study showed that the shear failure of the cast-in-situ utility tunnel occurred at the end of the top or bottom plate,and the failure of the prefabricated utility tunnel occurred at the junction of the prefabricated member and post-cast concrete.As the temperature increased,the temperature gradient along the thickness direction of the tunnel became apparent.The maximum temperature difference between the inner and outer wall surfaces was 531.7°C.The highest temperature occurred in the cooling stage after stopping the heating,which provided a reference for the fire protection design and rescue of the utility tunnel.The displacement of the top plate of the prefabricated utility tunnel was 16.8 mm,which was 41.8%larger than that of the cast-in-situ utility tunnel.The bearing capacities of the ordinary concrete utility tunnel and full lightweight concrete utility tunnel after the fire loss were 27%and 16.8%,respectively.The full lightweight concrete utility tunnel exhibited good ductility and fire resistance and high collapse resistance.

Temperature Responses to External Heat Fluxes of the Power Distribution System on Alpha Magnetic Spectrometer

High-temperature warnings frequently occurred at the Power Distribution System(PDS)of the Alpha Magnetic Spectrometer(AMS).To investigate the fundamental reasons,a theoretical model for the AMS PDS was established under the International Space Station(ISS)normal and special operating conditions.With the model,the study investigated the external heat fluxes and the temperature responses of the PDS.The effects of ISS special operations on the PDS’s thermal environment were also investigated.Results reveal that the total external heat flux at the PDS reaches its maximum value when the angleβis around–25°,where high-temperature warning frequently occurs.Under the ISS normal operating condition,the temperature response hysteresis at the PDS varies from 116 s to 230 s.When the ISS performed special operations,locking the ISS solar arrays had the greatest influence on the PDS’s external heat fluxes,and the average temperature at the PDS fell by 1.7°C.When the ISS performed multiple special operations,simultaneously locking the ISS solar arrays and adjusting the ISS flight attitude were the most frequent operations,of which the influences on the PDS temperature were the largest,i.e.,the changes in peak temperature reached up to+2.5°C.

Temperature-mediated regulation of flowering time in Arabidopsis thaliana

Throughout a plant's life cyde,temperature plays a major role in development.Regulatory modules use temperature cues to control gene expression,facilitating physiological change from germination to flowering.These regulatory modules control morphological and molecular responses to temperature changes caused by seasonal changes or by temporary fluctuations,providing a versatile plasticity of plants.In this review,we outline how temperature changes affect the regu latory modules that induce and repress flowering,in addition to general temperature regulation.Recent studies have identified several regulatory modules by which floral transition and growth responses are controlled in a tem-perature-dependent manner.This review will report on recent studies related to floral transition and ambient temperature response.