Observation of Temperature Induced Plasma Frequency Shift in an Extremely Large Magnetoresistance Compound LaSb

We report an optical spectroscopy study on LaSb, a compound recently identified to exhibit extremely large magnetoresistance. Our optieal measurement indicates that the material has a low carrier density. More inter- estingly, the study reveals that the plasma frequency increases with decreasing temperature. This phenomenon suggests either an increase of the conducting carrier density or/and a decrease of the effective mass of carriers with decreasing temperature. We attribute it primarily to the latter effect. Two possible scenarios on its physical origin are examined and discussed. The study offers new insight into the electronic structure of this compound.

Preparation and Water-Gas Shift Catalytic Activities of the Perovskite Type Complex Oxide La_(1-x) Ce_xFeO_3

The perovskite type rare earth iron complex (REIC) oxide La 1-x Ce xFeO 3 is designed and prepared as water gas shift catalyst. Activity evaluation and heat resisting test show that the perovskite type compounds La 1-x Ce xFeO 3(·K) has a good thermal stability if x is less than or equal to 0.5 . But when x is greater than 0.5 , La 1-x Ce xFeO 3(·K) will turn out to be ceria and magnetite partially or completely at high temperature in the shift reaction atmosphere. In the case of x=0.5, the conversion of carbon monoxide is about 68% at 530 ℃. Potassium can greatly improve the low temperature activity, but slightly lower the high temperature activity, and has little impact on the thermal stability. La 0.5 Ce 0.5 FeO 3 (·K) is a promising chromium free high temperature shift catalyst.

The regime shift in the 1960s and associated atmospheric change over the southern Indian Ocean

The change of sea surface temperature（SST） in the southern Indian Ocean（SIO） during the recent six decades has been analyzed based on oceanic reanalysis and model, as well as atmospheric data. The results show that a thermal regime shift in SIO during the 1960 s, which is not caught enough attentions, has been of equal magnitude to the linear warming since 1970. Empirical Orthogonal Function（EOF） analyses reveal that a thermal shift is combined with atmospheric changes such as the weakening of westerly during the period of 1960–1967. Inner dynamic connections can be defined that when the westerly winds turn weak, the anticyclonic wind circulation between westerly winds and the trade winds decreases, which further reduces the SST to a negative peak in this period. It is noted that the shifts in the 1960 s are also evident for Southern Hemisphere. For example, subtropical high and the entire westerly winds belt at high latitudes both change dramatically in the 1960 s. This large-scaled process maybe link to the change of southern annular mode（SAM）.

Enhancement in Laser Performance of Er^(3+)/Yb^(3+) Co-doped Phosphate Glass Materials

Er3＋/Yb3＋co-doped phosphate are presented, laser glass materials with composition of P2O5-A12O3-Ba CO3-KNO3-Li2O-Zn O-Er2O3-Yb2O3（R-PABKLZ） are presented, in which an optimal molar ratio of 1：4 between Er3＋ and Yb3＋ was observed for achieving peak laser gain. Furthermore, due to adding 4.7 mol% Li1＋ and 4.6 mol% Zn2＋ ions into the glass, an optimum composition structure based laser material was demonstrated. On the other hand, since the high temperature melting method with changeable temperature control was used, the emission cross section of fl uorescence, excited lifetime, and an effective spectral half width reached 9.70 × 10-21 cm2, 8.20 ms, and 53.16 nm, respectively, so that a laser gain（semi× rad） of 103.05 was obtained, which is signifi cantly higher than previously reported results. The manuscript also argued the mechanism of relevant laser gain improvement.

Deuteration triggered downward shift of dielectric phase transition temperature in a hydrogen-bonded molecular crystal

Deuteration of hydrogen-bonded phase transition crystals can increase the transition temperatures due to the isotope effect. But rare examples show the opposite trend that originates from the structural changes of the hydrogen bond, known as the geometric H/D isotope effect. Herein, we report an organic crystal, diethylammonium hydrogen 1,4-terephthalate, exhibits a reversible structural phase transition and dielectric switching. Structural study shows the cations reside in channels formed by one-dimensional hydrogen-bonded anionic chains and undergo an order-disorder transition at around 206 K. The deuterated counterpart shows an elongation of the O…O hydrogen bond by about 0.005 A. This geometric isotope effect releases the internal pressure of the anionic host on the cation guests and results in a downward shift of the phase transition temperature by 10 K.

Thermal Crown Model and Shifting Effect Analysis of Work Roll in Hot Strip Mills

Considering the effect of work roll shifting on roll temperature field,a finite difference method of PR format for roll temperature field was presented,which can meet the requirements of accuracy and speed of online calculation.The step-by-step accumulation method was used to simulate the roll temperature field and thermal crown,and the evolution of roll thermal crown in a rolling campaign was studied.And then,the effects of strip width,rolling rhythm and work roll shifting on roll thermal crown were analyzed.It is found that work roll shifting can disperse the thermal expansion of the roll body especially the edge to make roll thermal contour uniform.The effect of work roll shifting on roll thermal crown is mainly concentrated in regions around twice of roll shifting stroke,and the change range of roll thermal crown is±30μm or so in the same roll body location.

Thermosensitive period for sex determination of the tropical freshwater turtle Malayemys macrocephala

Many egg-laying reptiles possess temperature-dependent sex determination(TSD)in which outcome of gonadogenesis is determined by incubation temperature during a temperature-sensitive period of development.Prior studies on Malayemys macrocephala showed that incubation temperatures influence gonadal development and suggested that M.macrocephala exhibits TSD.However,information on the temperature-sensitivity period in this species was unknown until the current study.Turtle eggs were collected from rice fields in central Thailand from December 2016 to February 2017.In the laboratory,eggs were incubated at male-biased temperature(26°C)and shifted to female-biased temperature(32°C),or vice versa.Single shift experiments were performed systematically during embryonic stages 13–21.After hatching,sex of individual turtles was determined by histological analysis.We found that the sex determination of M.macrocephala is affected by temperature up to stage 16 of embryonic development.