Template Polymerization Based on Stober Method:an Improved Method for Fabrication of Hollow Polysiloxane Spheres

A modified Stober method has been developed which permits the controlled growth of spherical hollow spheres with diameters between 197 and 208 nanometers by consecutively cocondensed methyltrimethoxysilane and dimethyldimethoxysilane monomers onto microemulsion of polydimethylsiloxane and subsequently removing the templated polydimethylsiloxane by exposure to solvents. Ammonia was used as a morphological catalyst. The morphology of the polymer spheres was demonstrated by transmission electron micrographs （TEM） and atomic force microscopy （AFM）.

CONTROLLED FABRICATION OF ONE-DIMENSIONAL POLYMER NANOSTRUCTURES via METALLOGEL TEMPLATE POLYMERIZATION

A facile method is reported to controllably fabricate one dimensional （1D） polymer nan,astructures via metallogel template polymerization. The metallogel was prepared through coordination interactions between silver ions and a ligand （L） bearing three pyridyl groups in tetrahydrofuran （THF）. The diameters of the metallogel nanofibers could be tuned by the gel concentration （GC）. Due to its high thermal stability and facility of removal, the metallogel was used as the template for radical polymerization of diacryolyl-2,6-diaminopyridine （DADAP） to form poly-diacryolyl-2,6-diaminopyridine （PDADAP） nanostructures. The gradually eroding of the templates by PDADAP provided us an effective way to fabricate various nanostructures of the polymer. We have demonstrated that different 1D nanostructures, including n^noribbons, nanotubes and nanowires, could be selectively fabricated by adjusting polymerization time, monomer concentration and GC. The rheological properties of the gel samples were tested by a rheometer. As prolonging the reaction time, more and more polymers were formed and the strength of the resulting polymer gels became higher and higher. The simple preparation process, easy controlled microstructures and adequate gel strength would make it a facile synthetic method for different 1D polymer nanosturctures.

Facile synthesis of metal-organic frameworks embedded in interconnected macroporous polymer as a dual acid-base bifunctional catalyst for efficient conversion of cellulose to 5-hydroxymethylfurfural

5-Hydroxymethylfurfural(5-HMF),as a key platform compound for the conversion of biomass to various biomass-derived chemicals and biofuels,has been attracted extensive attention.In this research,using Pickering high internal phase emulsions(Pickering HIPEs)as template and functional metal-organic frameworks(MOFs,UiO-66-SO;H and UiO-66-NH;)/Tween 85 as co-stabilizers to synthesis the dual acid-base bifunctional macroporous polymer catalyst by one-pot process,which has excellent catalytic activity in the cascade reaction of converting cellulose to 5-HMF.The effects of the emulsion parameters including the amount of surfactant(ranging from 0.5%to 2.0%(mass)),the internal phase volume fraction(ranging from 75%to 90%)and the acid/base Pickering particles mass ratio(ranging from 0:6 to 6:0)on the morphology and catalytic performance of solid catalyst were systematically researched.The results of catalytic experiments suggested that the connected large pore size of catalyst can effectively improve the cellulose conversion,and the synergistic effect of acid and base active sites can effectively improve the 5-HMF yield.The highest 5-HMF yield,about 40.5%,can be obtained by using polymer/MOFs composite as catalyst(Poly-P12,the pore size of(53.3±11.3)μm,the acid density of 1.99 mmol·g^(-1)and the base density of 1.13 mol·g^(-1))under the optimal reaction conditions(130℃,3 h).Herein,the polymer/MOFs composite with open-cell structure was prepared by the Pickering HIPEs templating method,which provided a favorable experimental basis and theoretical reference for achieving efficient production of high addedvalue product from abundant biomass.

ATRP-Template Dispersion Polymerization of Methacrylic Acid/PVP

ATRP-template dispersion polymerization of methacrylic acid （MAA） on the template of polyvinyl pyrrolidone （PVP K-30） was carried out in the aqueous solution by using methyl 2-bromopropionate （MBP）/CuC1/2,2＇-bipyridine （bpy） as the initiation system. The scanning electron microscopy （SEM）, dynamic light scattering （DLS） and gel permeation chromatography （GPC） were employed for evaluating the results of polymerization. As a result, the minimonomer droplets formed due to the H-bond interaction of PVP-MAA. The stability of droplets was dependent on pH and the concentrations of both PVP and MAA. When pH 〈 2, the coagulum of PVP-MAA formed, whereas when pH 〉 4.5, the droplets were not observable by DLS. In order to prepare the stable latex, the concentration of PVP should be lower than 9 wt%, whilst the concentration of MAA should be lower than 5.5 wt%. The optimum condition was pH 2.4, PVP 4.76 wt% and MAA 5 wt%, by which the stable latex of ca. 50 nm nanoparticles of PMAA/PVP was prepared by ATRP polymerization and simultaneously the molar mass of PVP was duplicated by PMAA according to GPC diagrams. In contrast, by using AIBN, KPS and KPS-Na2SO3 redox initiation system, the coagulum accompanying with the larger molar mass of PMAA was obtained, irrespective of pH and concentrations of PVP and MAA.

Screening the Insecticidal Efficacy of Nano ZnO Synthesized via in-situ Polymerization of Crosslinked Polyacrylic Acid as a Template

Nano zinc oxide （ZnO） is a very useful and important material in many industrial and biological applications. In the present work, ZnO was synthesized by post thermal degradation of the precursor ＂zinc acetate di-hydrate＂ templated in crosslinked polyacrylic acid （PAA）. The crosslinked PAA template was prepared through an in-situ polymerization process adopted in presence of ammonium per sulphate, as an initiator, and N, Nt- methylene bis-acrylamide as the crosslinker. Variation of preparation parameters and their impact on the oxide stoichiometry, crystal structure, crystallite size and surface texture of the oxide were investigated. Energy dispersive X-ray technique （EDX）, X-ray diffraction （XRD） and scanning electron microscopy （SEM） were convincingly used to reveal the oxide structural features and characteristics. The performed bioassay tests indicated the efficacy of this method of preparation to produce nano ZnO with novel insecticidal activity against the greater wax moth, Galleria rnellonella.

Coordinated organogel templated fabrication of silver/polypyrrole composite nanowires

A new method to fabricate metal/conducting polymer composite nanowires is presented by taking silver/polypyrrole composite nanowires as an example. A silver （D-coordinated organogel as template was prepared firstly, and redox-polymerization of pyrrole took place on the gel fiber, giving product of silver/polypyrrole nanowires. The silver/polypyrrole nanowires were characterized by multiple techniques. This strategy could be carried out in one-step procedure at room temperature, and it proves the utility of coordinated organogels in template synthesis of polymer nanostructures.

Efficient and Generic Preparation of Diverse Polyelectrolyte Nanogels by Electrostatic Assembly Directed Polymerization

Nanogels hold promise as soft and functional carriers and nanoreactors,but whether they will ever reach the stage of large-scale application depends crucially on efficient production methods,and on what interesting properties and functionalities they can have.In particular,nanogels consisting of highly charged polyelectrolyte have not yet been very much explored.Here,the authors present a novel and generic strategy for controlled and efficient synthesis of a large diversity of polyelectrolyte nanogels.The method is based on polymerizing an ionic monomer in the presence of an oppositely charged polyion-neutral diblock copolymer as template,while adding a cross-linker.The growing polymer chains assemble with the template,forming polyion complex micelles,which dissociate upon increasing salt concentration.Subsequent separation yields nanogels with well-controlled size and properties,and free template polymers that can be used again.Our design can be applied generally to a wide range of both cationic and anionic monomers,as well as various cross-linkers.Scaled-up production presents no problems as increasing monomer concentration(hundreds of mM)and reaction volume(up to 1 L)hardly compromise product quality.Moreover,the obtained nanogels with their well-controlled size,morphology,chemistry,and cross-linking degree perform well as soft nanocarriers and catalytic nanoreactors.