Iron-rich compounds with the tetragonal ThMn12-type structure have the potential to meet current demands for rare-earth-lean permanent magnets with high energy density and operating temperatures of 150-200℃.However,w...Iron-rich compounds with the tetragonal ThMn12-type structure have the potential to meet current demands for rare-earth-lean permanent magnets with high energy density and operating temperatures of 150-200℃.However,while it is normal for magnet technology to lag behind the development of underlying magnetic material,this gap has always been unusually large for ThMn12-type magnets.The gap has widened further in recent years,as excellent combinations of intrinsic magnetic properties have been obtained in compounds synthesized with a smaller amount of structure-stabilizing elements(e.g.,SmFe11V or Sm0.8Zr0.2Fe9.2Co2.3Ti0.5)or with no such elements(i.e.,SmFe9.6Co2.4 thin films).The search for promising compounds continues-with increasing help coming from theoretical calculations.Unfortunately,progress in the development of magnets beyond polymer-bonded interstitially modified powders remains marginal.The introduction of lanthanum(La)was found to stabilize low-meltingtemperature minority phases in Sm(Fe,Ti)12 alloys,thus allowing for liquid-phase sintering for the first time.The high reactivity of La,however,has apparently undermined the development of coercivity(Hc).A controlled crystallization of the initially suppressed ThMn12-type phase makes"bulk"magnetic hardening possible,not only in Sm-Fe-V alloys(in which it has been known since the 1990s),but also is in La-added(Ce,Sm)(Fe,Ti)12 alloys.The properties of the bulk-hardened alloys,however,remain unsatisfactory.Mechanochemically synthesized(Sm,Zr)(Fe,Si)12 and(Sm,Zr)(Fe,Co,Ti)12 powders may become suitable for sintering into powerful fully dense magnets,although not before a higher degree of anisotropy in both alloys and a higher Hc in the latter alloy have been developed.展开更多
The effect of substitution of Mn on the structure and magnetic properties of HoFe 12- x Mn x (x =2 0, 3 0, 4 0 and 5 0) compounds was investigated. All the HoFe 12x Mn x compounds studied cry...The effect of substitution of Mn on the structure and magnetic properties of HoFe 12- x Mn x (x =2 0, 3 0, 4 0 and 5 0) compounds was investigated. All the HoFe 12x Mn x compounds studied crystallize in ThMn 12 type of structure. The lattice constants and unit cell volume increase monotonously with increasing Mn concentration. The Curie temperature and the moments of the transition metal sublattice of HoFe 12- x Mn x compounds decrease monotonously with increasing Mn content. A minimum appears at x =3 0 in the Mn concentration dependence of the saturation magnetization of HoFe 12- x Mn x compounds. A compensation point appears in the M(t) curve of the compound with x =4 0. The mean field constant n RT of HoFe 9Mn 3 was calculated.展开更多
The structure and magnetic properties of the intermetallic compounds Y(Fe 1- x Co x ) 11.3 Nb 0.7 ( x =0, 0 05, 0 1, 0 2) were studied by X ray diffraction and magnetic property measurements. ...The structure and magnetic properties of the intermetallic compounds Y(Fe 1- x Co x ) 11.3 Nb 0.7 ( x =0, 0 05, 0 1, 0 2) were studied by X ray diffraction and magnetic property measurements. X ray diffraction patterns and thermomagnetic curves show that all compounds almost exhibit single phase. All Y(Fe 1- x Co x ) 11.3 Nb 0.7 compounds ( x =0, 0 05, 0 1, 0 2) crystallize in ThMn 12 type structure. Substitution of Co for Fe leads to a clear increasing of Curie temperature and a monotonic decreasing of lattice constants. At room temperature the composition dependence of saturation magnetization exhibits a maximum at about x =0 1～0 2. The magnetocrystalline anisotropy field at room temperature at first increases and then decreases with the increasing of Co content.展开更多
A systematical investigation was carried out on structure and magnetic properties in SmFe_(9-x)V_(x)(x=0.4,0.8,1.2)compounds prepared by a single-roller quenching method.The high cool-down rate leads to metastable TbC...A systematical investigation was carried out on structure and magnetic properties in SmFe_(9-x)V_(x)(x=0.4,0.8,1.2)compounds prepared by a single-roller quenching method.The high cool-down rate leads to metastable TbCu_(7) phase in the parent compound,which gradually transforms into equilibrium ThMn_(12) structure with V-doping content increasing.The Curie temperature increases from 470 to 590 K with V doping,which is consistent with the phase transformation.Surprisingly,simultaneous increase in both coercivity and remanence is resulted by V doping,reaching the highest value of 685 kA·m^(-1)and 44.8×10^(-3)A·m^(2)·g^(-1)in x=1.2 compound,respectively.This phenomenon can be explained by the combination of phase transformation and intergranular exchange coupling throughδM-H plots.展开更多
基金supported by the US Department of Energy,United States(DE-FG02-90ER45413)EU Horizon 2020 Program(686056–NOVAMAG)Ford Motor Company,United States.
文摘Iron-rich compounds with the tetragonal ThMn12-type structure have the potential to meet current demands for rare-earth-lean permanent magnets with high energy density and operating temperatures of 150-200℃.However,while it is normal for magnet technology to lag behind the development of underlying magnetic material,this gap has always been unusually large for ThMn12-type magnets.The gap has widened further in recent years,as excellent combinations of intrinsic magnetic properties have been obtained in compounds synthesized with a smaller amount of structure-stabilizing elements(e.g.,SmFe11V or Sm0.8Zr0.2Fe9.2Co2.3Ti0.5)or with no such elements(i.e.,SmFe9.6Co2.4 thin films).The search for promising compounds continues-with increasing help coming from theoretical calculations.Unfortunately,progress in the development of magnets beyond polymer-bonded interstitially modified powders remains marginal.The introduction of lanthanum(La)was found to stabilize low-meltingtemperature minority phases in Sm(Fe,Ti)12 alloys,thus allowing for liquid-phase sintering for the first time.The high reactivity of La,however,has apparently undermined the development of coercivity(Hc).A controlled crystallization of the initially suppressed ThMn12-type phase makes"bulk"magnetic hardening possible,not only in Sm-Fe-V alloys(in which it has been known since the 1990s),but also is in La-added(Ce,Sm)(Fe,Ti)12 alloys.The properties of the bulk-hardened alloys,however,remain unsatisfactory.Mechanochemically synthesized(Sm,Zr)(Fe,Si)12 and(Sm,Zr)(Fe,Co,Ti)12 powders may become suitable for sintering into powerful fully dense magnets,although not before a higher degree of anisotropy in both alloys and a higher Hc in the latter alloy have been developed.
文摘The effect of substitution of Mn on the structure and magnetic properties of HoFe 12- x Mn x (x =2 0, 3 0, 4 0 and 5 0) compounds was investigated. All the HoFe 12x Mn x compounds studied crystallize in ThMn 12 type of structure. The lattice constants and unit cell volume increase monotonously with increasing Mn concentration. The Curie temperature and the moments of the transition metal sublattice of HoFe 12- x Mn x compounds decrease monotonously with increasing Mn content. A minimum appears at x =3 0 in the Mn concentration dependence of the saturation magnetization of HoFe 12- x Mn x compounds. A compensation point appears in the M(t) curve of the compound with x =4 0. The mean field constant n RT of HoFe 9Mn 3 was calculated.
文摘The structure and magnetic properties of the intermetallic compounds Y(Fe 1- x Co x ) 11.3 Nb 0.7 ( x =0, 0 05, 0 1, 0 2) were studied by X ray diffraction and magnetic property measurements. X ray diffraction patterns and thermomagnetic curves show that all compounds almost exhibit single phase. All Y(Fe 1- x Co x ) 11.3 Nb 0.7 compounds ( x =0, 0 05, 0 1, 0 2) crystallize in ThMn 12 type structure. Substitution of Co for Fe leads to a clear increasing of Curie temperature and a monotonic decreasing of lattice constants. At room temperature the composition dependence of saturation magnetization exhibits a maximum at about x =0 1～0 2. The magnetocrystalline anisotropy field at room temperature at first increases and then decreases with the increasing of Co content.
基金financially supported by the National High Technology Research and Development Program of China (No. 2011AA03A402)
文摘A systematical investigation was carried out on structure and magnetic properties in SmFe_(9-x)V_(x)(x=0.4,0.8,1.2)compounds prepared by a single-roller quenching method.The high cool-down rate leads to metastable TbCu_(7) phase in the parent compound,which gradually transforms into equilibrium ThMn_(12) structure with V-doping content increasing.The Curie temperature increases from 470 to 590 K with V doping,which is consistent with the phase transformation.Surprisingly,simultaneous increase in both coercivity and remanence is resulted by V doping,reaching the highest value of 685 kA·m^(-1)and 44.8×10^(-3)A·m^(2)·g^(-1)in x=1.2 compound,respectively.This phenomenon can be explained by the combination of phase transformation and intergranular exchange coupling throughδM-H plots.
