The intersection point rule for homologues in gas chromatography was discovered many years ago,now more and more application and development are occurring in recent years~[2-6], but there are few systemic theoretical ...The intersection point rule for homologues in gas chromatography was discovered many years ago,now more and more application and development are occurring in recent years~[2-6], but there are few systemic theoretical studies.In this paper,based on the basic equation of reten- tion values in gas chromatography,we prove the intersection point rule of homologues from mathematics,study the factors affecting intersection point position,give the physical meaning of intersection point,and explain the experimental rules in references.展开更多
The NaI and IF product rotational alignment of the reactions of Na,F+CH_3I has been theoretically studied in a LEPS PES.The product alignment versus the relative translational energy of the reactants has been obtained.
文摘The intersection point rule for homologues in gas chromatography was discovered many years ago,now more and more application and development are occurring in recent years~[2-6], but there are few systemic theoretical studies.In this paper,based on the basic equation of reten- tion values in gas chromatography,we prove the intersection point rule of homologues from mathematics,study the factors affecting intersection point position,give the physical meaning of intersection point,and explain the experimental rules in references.
文摘The NaI and IF product rotational alignment of the reactions of Na,F+CH_3I has been theoretically studied in a LEPS PES.The product alignment versus the relative translational energy of the reactants has been obtained.
