A critical review on solid-state welding of high entropy alloys-processing,microstructural characteristics and mechanical properties of joints

The high entropy alloys(HEAs)are the newly developed high-performance materials that have gained significant importance in defence,nuclear and aerospace sector due to their superior mechanical properties,heat resistance,high temperature strength and corrosion resistance.These alloys are manufactured by the equal mixing or larger proportions of five or more alloying elements.HEAs exhibit superior mechanical performance compared to traditional engineering alloys because of the extensive alloying composition and higher entropy of mixing.Solid state welding(SSW)techniques such as friction stir welding(FSW),rotary friction welding(RFW),diffusion bonding(DB)and explosive welding(EW)have been efficiently deployed for improving the microstructural integrity and mechanical properties of welded HEA joints.The HEA interlayers revealed greater potential in supressing the formation of deleterious intermetallic phases and maximizing the mechanical properties of HEAs joints.The similar and dissimilar joining of HEAs has been manifested to be viable for HEA systems which further expands their industrial applications.Thus,the main objective of this review paper is to present a critical review of current state of research,challenges and opportunities and main directions in SSW of HEAs mainly CoCrFeNiMn and Al_xCoCrFeNi alloys.The state of the art of problems,progress and future outlook in SSW of HEAs are critically reviewed by considering the formation of phases,microstructural evolution and mechanical properties of HEAs joints.

Microstructure and mechanical properties of stationary shoulder friction stir welding joint of 2A14-T62 aluminum alloy

2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.

Improvement of Microstructure and Mechanical Properties of Rapid Cooling Friction Stir-welded A1050 Pure Aluminum

Two-mm thick A1050 pure aluminum plates were successfully joined by conventional and rapid cooling friction stir welding(FSW), respectively. The microstructure and mechanical properties of the welded joints were investigated by electron backscatter diffraction characterization, Vickers hardness measurements, and tensile testing. The results showed that liquid CO_(2) coolant significantly reduced the peak temperature and increased the cooling rate, so the rapidly cooled FSW joint exhibited fine grains with a large number of dislocations. The grain refinement mechanism of the FSW A1050 pure aluminum joint was primarily attributed to the combined effects of continuous dynamic recrystallization, grain subdivision, and geometric dynamic recrystallization. Compared with conventional FSW, the yield strength, ultimate tensile strength, and fracture elongation of rapidly cooled FSW joint were significantly enhanced, and the welding efficiency was increased from 80% to 93%. The enhanced mechanical properties and improved synergy of strength and ductility were obtained due to the increased dislocation density and remarkable grain refinement. The wear of the tool can produce several WC particles retained in the joint, and the contribution of second phase strengthening to the enhanced strength should not be ignored.

Microstructure homogeneity and mechanical properties of laser-arc hybrid welded AZ31B magnesium alloy

Laser-arc hybrid welding of AZ31B magnesium alloy was carried out,the effects of welding parameters on weld formation,microstructure homogeneity and mechanical properties were investigated.The results showed that laser-arc hybrid welding was beneficial to improve the weld formation of magnesium alloy by inhibiting the defect of undercut and pores.The weld microstructure was mainly columnar grains neighboring the fusion line and equiaxed grains at the weld center.It was interesting that the grain size at the upper arc zone was smaller than that at the lower laser zone,with the difference mainly affected by laser power rather than welding current and welding speed.The welding parameters were optimized as laser power of 3.5 kW,welding current of 100 A and welding speed of 1.5 m/min.In this case,the weld was free of undercut and pores,and the tensile strength and elongation rate reached 252 MPa and 11.2%,respectively.Finally,the microstructure homogeneity was illustrated according to the heat distribution,and the evolution law of tensile properties was discussed basing on the weld formation and microstructure characteristics.

A review of linear friction welding of Ni -based superalloys

Ni-based superalloys are one of the most important materials employed in high-temperature applications within the aerospace and nuclear energy industries and in gas turbines due to their excellent corrosion,radiation,fatigue resistance,and high-temperature strength.Linear friction welding(LFW)is a new joining technology with near-net-forming characteristics that can be used for the manu-facture and repair of a wide range of aerospace components.This paper reviews published works on LFW of Ni-based superalloys with the aim of understanding the characteristics of frictional heat generation and extrusion deformation,microstructures,mechanical proper-ties,flash morphology,residual stresses,creep,and fatigue of Ni-based superalloy weldments produced with LFW to enable future optim-um utilization of the LFW process.

A multi-mineral model for predicting petrophysical properties of complex metamorphic reservoirs:Case study of the Bozhong Depression,Bohai Sea

Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future.

Microstructure and mechanical properties of dissimilar Al-Cu joints by friction stir welding

Dissimilar friction stir welding between 1060 aluminum alloy and annealed pure copper sheet with a thickness of 3 mm was investigated. Sound weld was obtained at a rotational speed of 1050 r/min and a welding speed of 30 mm/min. Intercalation structure formed at the crown and Cu/weld nugget （WN） area promotes interracial diffusion and metallurgical bonding of aluminum and copper. However, corrosion morphology reveals the weak bonding mechanism of internal interface, which causes the joint failing across the interface with a brittle-ductile mixed fracture mode. The tensile strength of the joint is 148 MPa, which is higher than that of the aluminum matrix. Crystal defects and grain refinement by severely plastic deformation during friction stir welding facilitate short circuit diffusion and thus accelerate the formation of A14Cu9 and A12Cu intermetallic compounds （IMCs）. XRD results show that A14Cu9 is mainly in Cu/WN transition zone. The high dislocation density and formation of dislocation loops are the major reasons of hardness increase in the WN.

Microstructures and properties of welded joint of aluminum alloy to galvanized steel by Nd:YAG laser + MIG arc hybrid brazing-fusion welding

According to the differences in melting point between aluminum alloy and steel, 6013-T4 aluminum alloy was joined to galvanized steel by large spot Nd：YAG laser ＋ MIG arc hybrid brazing-fusion welding with ER4043（AlSi5） filler wire. The microstructures and mechanical properties of the brazed-fusion welded joint were investigated. The joint is divided into two parts of fusion weld and brazed seam. There is a zinc-rich zone at fusion weld toe, which consists of α（Al）-Zn solid solution and Al-Zn eutectic. The brazed seam is the Fe-Al intermetallic compounds （IMCs） layer of 2-4μm in thickness, and the IMCs include FeAl2, Fe2Al5 and Fe4Al13. FeAl2 and Fe2Al5 are located in the compact reaction layer near the steel side, and Fe4Al13 with tongue shape or sawtooth shape grows towards the fusion weld. The tensile strength of the joint firstly increases and then decreases as the welding current and laser power increase, the highest tensile strength can be up to 247.3 MPa, and the fracture usually occurs at fusion zone of the fusion weld. The hardness is the highest at the brazed seam because of hard Fe-Al IMCs, and gradually decreases along the fusion weld and galvanized steel, respectively.

Effect of hot working on microstructure and mechanical properties of TC11/Ti_2AlNb dual-alloy joint welded by electron beam welding process

The influence of hot working on the microstructures of TC11/Ti2 Al Nb dual-alloy joints welded by electron beam welding(EBW) process was investigated. The tensile tests were performed at room temperature for specimens before and after thermal exposure. The results show that the fusion zone of TC11/Ti2 Al Nb dual-alloy joint welded by EBW is mainly composed of β phase. After deformation and heat treatment, the grain boundaries of the as-cast alloy are broken and the fusion zone mainly consists of β, α2and α phases. The fusion zone performs poor property in the tensile test. Specimens before and after thermal exposure all fail in this area under different deformation conditions. The ultimate tensile strength of specimens after heat treatment is up to 1190 MPa at room temperature. The joints by water quenching after deformation have better plasticity with an elongation up to 4.4%. After thermal exposure at 500 °C for 100 h, the tensile strength of the specimen slightly rises while the ductility changes a little. SEM observation shows that the fracture mechanism is predominantly transgranular under different deformation conditions.

Comprehensive study of microstructure and mechanical properties of friction stir welded 5182-O/HC260YD+Z lap joint

The welding of aluminum(Al)and steel has attracted more and more interest due to the weight reduction trend in vehicle and aerospace manufacturing industries.5182-O/HC260YD+Z lap joint was produced by friction stir welding(FSW),and the microstructure and mechanical property of the joint were systemically characterized.The microstructure in horizontal direction of the Al and steel near interface was similar to their corresponding conventional friction stir welded joint.The joint was divided into stir zone of Al(ST-Al),stir zone of interface(ST-I),thermal-mechanically affected zone of steel(TMAZ-Fe)and base material of steel(BM-Fe)according to their distinct microstructure vertically.Three kinds of intermetallic compounds(IMCs)of FeAl_(3),FeAl and Fe_(3)Al were formed at the interface.The horizontal micro hardness distribution exhibited a hat shape and“M”shape in Al and steel,respectively.The hardest region of the joint was located at the ST-I,with a hardness of 175 HV−210 HV.The joint was fractured along the hook structure,with an average shear strength of 73.9 MPa.Fractural morphology of Al and steel indicted a cleavage fracture mode.

Microstructure and mechanical properties of Mg-Li alloy after TIG welding

Tungsten inert gas weld was carried out on super-light magnesium-lithium alloy plates with a thickness of 2 mm, using argon gas as a protecting atmosphere. The microstructure and mechanical properties of the welded joints were investigated. The results indicate that the microstructure in the fusion zone is fine, and the microstructure in the heat-affected zone is coarser than the parent metal. The tensile strength of the welded joint is about 84% that of the parent metal. The fracture occurs in a mixed type of toughness and brittleness in the heat-affected zone. During the welding process, aluminum and cerium are enriched at grain boundaries in the fusion zone.

Mechanical deformation properties of Continuous Welded Rail on kilometer-span suspension bridge for high-speed railway

The complex bridge-track interaction between kilometer-span bridges and continuous Welded Rail(CWR)brings great challenges to CWR designing.Taking a suspension bridge with laying CWR as a case,the mechanical properties of CWR on the bridge are analyzed to reveal the sensitive areas of the track,and the design method of CWR and track structures on the beam ends are proposed.The results show that the unidirectional Rail Expansion Joints(REJ)need to be installed on the beam end of the kilometer-span bridge to reduce rail longitudinal force.Due to the bridge characteristics,there is no CWR fixed area on the kilometer-span bridge,and rail longitudinal force on the main span caused by bending loads needs to be concerned.The deformation of track on the beam end is complex,which is the weak area on the kilometer bridge,the large relative displacement between the stock rail of REJ and the main beam can cause poor stability of ballast bed on beam end,small resistance fasteners need to be laid on the sides of stock rail on the main beam to increase the stability of ballast and fasteners on the beam end.To improve the driving safety and comfort of beam end,the Sleeper-Supporting Apparatus(SSA)should be specially designed to ensure the uniform transition of track on beam ends.Temperature and wind loads have a significant impact on track regularity on the kilometer span bridge,the dynamic response of trains and bridges under those loads needs to be attended to.

Effects of heat treatment on the intermetallic compounds and mechanical properties of the stainless steel 321–aluminum 1230 explosive-welding interface

The effects of heat treatment on the microstructure and mechanical properties of intermetallic compounds in the interface of stainless steel 321 explosively bonded to aluminum 1230 were investigated in this study. Experimental investigations were performed by optical microscopy, scanning electron microscopy, and microhardness and shear tensile strength testing. Prior to heat treatment, increasing the stand-off distance between samples from 1 to 2.5 mm caused their interface to become wavy and the thickness of intermetallic layers to increase from 3.5 to 102.3 μm. The microhardness increased from HV 766 in the sample prepared at a stand-off distance of 1 mm to HV 927 in the sample prepared at a stand-off distance of 2.5 mm; in addition, the sample strength increased from 103.2 to 214.5 MPa. Heat treatment at 450°C for 6 h increased the thickness of intermetallic compound layers to 4.4 and 118.5 μm in the samples prepared at stand-off distances of 1 and 2.5 mm, respectively. These results indicated that increasing the duration and temperature of heat treatment decreased the microhardness and strength of the interface of explosively welded stainless steel 321-Al 1230 and increased the thickness of the intermetallic region.

Microstructure and mechanical properties of the joint of 6061 aluminum alloy by plasma-MIG hybrid welding

Plasma-MIG {metal inert gas arc welding） hybrid welding of aluminum alloy with 6 mm thickness using ER5356 welding wire was carried out. The microstructures and mechanical properties of the welded joint were investigated by optical microscopy, X-ray diffraction （XRD） , energy dispersive spectroscopy （EDS） , tensile test, hardness test and scanning electron microscope （ SEM） were used to judge the type of tensile fracture. The results showed that the tensile strength of welded joint was 142 MPa which was 53. 6% o f the strength o f the base metal. The welding seam zone was characterized by dendritic structure. In the fusion zone, the columnar grains existed at one side of the welding seam. The fibrous organization was found in the base metal, and also in the heat affected zone （HAZ） where the recrystallization occurred. The HAZ was the weakest position of the welded joint due to the coarsening of Mg2Si phase. The type of tensile fracture was ductile fracture.

Effect of fusion welding processes on tensile properties of armor grade, high thickness, non-heat treatable aluminium alloy joints

AA5059 is one of the high strength armor grade aluminium alloy that finds its applications in the military vehicles due to the higher resistance against the armor piercing (AP) threats. This study aimed at finding the best suitable process among the fusion welding processes such as gas tungsten arc welding (GTAW) and gas metal arc welding (GMAW) by evaluating the tensile properties of AA5059 aluminium alloy joints. The fracture path was identified by mapping the low hardness distribution profile (LHDP) across the weld cross section under tensile loading. Optical and scanning electron microscopies were used to characterize the microstructural features of the welded joints at various zones. It is evident from the results that GTAW joints showed superior tensile properties compared to GMAW joints and this is primarily owing to the presence of finer grains in the weld metal zone (WMZ) and narrow heat-affected zone (HAZ). The lower heat input associated with the GTAW process effectively reduced the size of the WMZ and HAZ compared to GMAW process. Lower heat input of GTAW process results in faster cooling rate which hinders the grain growth and reduces the evaporation of magnesium in weld metal compared to GMAW joints. The fracture surface of GTAW joint consists of more dimples than GMAW joints which is an indication that the GTAW joint possess improved ductility than GMAW joint.

Mechanical properties of 2024-T4 aluminium alloy joints in ultrasonic vibration enhanced friction stir welding

Ultrasonic vibration enhanced friction stir welding （UVeFSW） is a recent modification of conventional friction stir welding （FSW）, which transmits ultrasonic vibration directly into the localized area of the workpiece near and ahead of the rotating tool. In this study, a high strength aluminium alloy （2024-T4） was welded by this process and conventional FSW, respectively. Then tensile tests, microhardness tests and fracture surface analysis were performed successively on the welding samples. The tests results reveal that ultrasonic vibration can improve the tensile strength and the elongation of welded joints. The microhardness of the stir zone also increases.

Metallographic structure,mechanical properties,and process parameter optimization of 5A06 joints formed by ultrasonic-assisted refill friction stir spot welding

Novel hybrid refill friction stir spot welding （RFSSW） assisted with ultrasonic oscillation was introduced to 5A06 aluminum alloy joints. The metallographic structure and mechanical properties of 5A06 aluminum alloy RFSSW joints formed without ultrasonic assistance and with lateral and longitudinal ultrasonic assistance were compared, and the ultrasonic-assisted RFSSW process parameters were opti- mized. The results show that compared with lateral ultrasonic oscillation, longitudinal ultrasonic oscillation strengthens the horizontal bond- ing ligament in the joint and has a stronger effect on the joint＇s shear strength. By contrast, lateral ultrasonic oscillation strengthens the ver- tical bonding ligament and is more effective in increasing the joint＇s tensile strength. The maximum shear strength of ultrasonic-assisted RFSSW 5A06 aluminum alloy joints is as high as 8761 N, and the maximum tensile strength is 3679 N when the joints are formed at a tool rotating speed of 2000 r/rain, a welding time of 3.5 s, a penetration depth of 0.2 mm, and an axial pressure of 11 kN.

Microstructure and Mechanical Properties of Aer Met 100 Ultra-high Strength Steel Joints by Laser Welding

AerMet100 ultra-high strength steel plates with a thickness of 2 mm were welded using a COz laser welding system. The influences of the welding process parameters on the morphology and microstructure of the welding joints were investigated, and the mechanical property of the welding joints was analyzed. The experimental results showed that the fusion zone of welding joint mainly consisted of columnar grains and a fine dendrite substructure grew epitaxially from the matrix. With the other conditions remaining unchanged, a finer weld microstructure was along with the scanning speed increase. The solidification microstructure gradually transformed from cellular crystal into dendrite crystal and the spaces of dendrite secondary arms rose from the fusion line to the center of the fusion zone. In the fusion zone of the weld, the rapid cooling caused the formation of martensite, which led the microhardness of the fusion zone higher than that of the matrix and the heat affected zone. The tensile strength of the welding joints was tested as 1 700 MPa, which was about 87% of the matrix. However, the tensile strength of the welding joints without defects existed was tested as 1832 MPa, which was about 94% of the matrix.

Effect of ultrasonic assisted friction stir welding on microstructure and mechanical properties of AZ91-C magnesium alloy

The influence of ultrasonic vibrations on microstructure and mechanical properties of the AZ91-C magnesium alloy after ultrasonic assisted friction stir welding(UaFSW)in comparison with conventional friction stir welding(FSW)was investigated.The FSW was applied at the rotational speed of 1400 r/min and welding speed of 40 mm/min and no defects were observed.Using the same welding parameters,the process was carried out with inducing ultrasonic vibrations to the weld line at the amplitude of 15μm.The microstructure of the specimens was observed with optical and scanning electron microscopy.The results indicate that a very fine microstructure is obtained in UaFSW with respect to that of conventional FSW.Moreover,β-Mg17Al12 coarse dendrites are segregated to very fine and partly spherical particles that homogeneously distribute inα-Mg matrix.This remarkably-modified morphology of microstructure attributed to severe plastic deformation comes from ultrasonic vibration and friction stirring effect.Tensile and hardness tests were performed to evaluate the mechanical properties of the welds.According to the results,the vibration greatly improves the mechanical properties of the conventional FSW joint.The tensile strength and hardness are increased from 195 MPa and HV 79 in conventional FSW to 225 MPa and HV 87 in UaFSW,respectively.

Analysis of the Microstructure and Mechanical Properties during Inertia Friction Welding of the Near-α TA19 Titanium Alloy

The current research of titanium alloy on friction welding process in the field of aero-engines mainly focuses on the linear friction welding.Compared to the linear friction welding,inertial friction welding of titanium alloy still has important application position in the welding of aero-engine rotating assembly.However,up to now,few reports on inertial friction welding of titanium alloy are found.In this paper,the near-alpha TA19 titanium alloy welded joint was successfully obtained by inertial friction welding(IFW)process.The microstructures and mechanical properties were investigated systematically.Results showed that the refined grains within 15‒20μm and weak texture were found in the weld zone due to dynamic recrystallization caused by high temperature and plastic deformation.The weld zone consisted of acicularα′martensite phase,αp phase and metastableβphase.Most lath-shapedαs andβphase in base metal were transformed into acicular martensiteα′phase and metastableβphase in thermo-mechanically affected zone and heat affected zone.As a result,the microhardness of welded joint gradually decreased from the weld zone to the base metal.Tensile specimens in room temperature and high temperature of 480℃ were all fractured in base metal illustrating that the inertia friction welded TA19 titanium alloy joint owned higher tensile strength compared to the base metal.