Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosi...Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosion is a threat to the development and security of marine industry;therefore,evaluating the corrosion resistance of SSs is necessary.In this work,atmospheric corrosion detection probes based on a symmetrical electrode system were used to study the corrosion behaviors of 304 SS and 2205 duplex stainless steel(DSS)in a simulated marine atmosphere.A theoretical model for electrochemical noise(EN)data analysis based on the Thevenin electrochemical equivalent circuit(EEC)model was established.The relationship between the EN characteristic parameters and the corrosion rate was obtained.The Thevenin EEC model analysis showed that the relationship between the noise resistance(Rn),the noise impedance[Rsn(f)],and the impedance modulus(|Z(f)|)was Rn≈Rsn=■.Thus,Rn and Rsn can be used as indicators for quantitative corrosion evaluation.The results of EN detection for the 304 SS and 2205 DSS showed that in a simulated marine atmospheric environment,the passive fi lms on the two SSs were relatively intact at the initial exposure stage,and their dissolution rates were slow.The corrosion resistance of the 2205 DSS was higher than that of the 304 SS.With the deposition of Cl-on the SS surface,pitting was initiated and the dissolution rate increased.The pitting initiation process on the SS surface was random,and part of the active pores could be repassivated.展开更多
The paper presents a new pedagogical method for finding the Thevenin and Norton equivalent circuits of a linear electric circuit (LEC) at the n-different pairs of terminals simultaneously, regardless of the circuit to...The paper presents a new pedagogical method for finding the Thevenin and Norton equivalent circuits of a linear electric circuit (LEC) at the n-different pairs of terminals simultaneously, regardless of the circuit topology and complexity. The proposed method is appropriate for undergraduate electrical and electronic engineering students leading to straightforward solutions, mostly arrived at by inspection, so that it can be regarded as a simple and innovative calculation tool for Thevenin equivalents. Furthermore, the method is easily adapted to computer implementation. Examples illustrating the method’s scientific and pedagogical reliability, as well as real test results and statistically-sound data assessing its functionality are provided.展开更多
基金the National Natural Science Foundation of China(No.51701140)。
文摘Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosion is a threat to the development and security of marine industry;therefore,evaluating the corrosion resistance of SSs is necessary.In this work,atmospheric corrosion detection probes based on a symmetrical electrode system were used to study the corrosion behaviors of 304 SS and 2205 duplex stainless steel(DSS)in a simulated marine atmosphere.A theoretical model for electrochemical noise(EN)data analysis based on the Thevenin electrochemical equivalent circuit(EEC)model was established.The relationship between the EN characteristic parameters and the corrosion rate was obtained.The Thevenin EEC model analysis showed that the relationship between the noise resistance(Rn),the noise impedance[Rsn(f)],and the impedance modulus(|Z(f)|)was Rn≈Rsn=■.Thus,Rn and Rsn can be used as indicators for quantitative corrosion evaluation.The results of EN detection for the 304 SS and 2205 DSS showed that in a simulated marine atmospheric environment,the passive fi lms on the two SSs were relatively intact at the initial exposure stage,and their dissolution rates were slow.The corrosion resistance of the 2205 DSS was higher than that of the 304 SS.With the deposition of Cl-on the SS surface,pitting was initiated and the dissolution rate increased.The pitting initiation process on the SS surface was random,and part of the active pores could be repassivated.
文摘The paper presents a new pedagogical method for finding the Thevenin and Norton equivalent circuits of a linear electric circuit (LEC) at the n-different pairs of terminals simultaneously, regardless of the circuit topology and complexity. The proposed method is appropriate for undergraduate electrical and electronic engineering students leading to straightforward solutions, mostly arrived at by inspection, so that it can be regarded as a simple and innovative calculation tool for Thevenin equivalents. Furthermore, the method is easily adapted to computer implementation. Examples illustrating the method’s scientific and pedagogical reliability, as well as real test results and statistically-sound data assessing its functionality are provided.
