Insight into the Electrochemical Behaviors of NCM811|SiO-Gr Pouch Battery through Thickness Variation

LiNi0.8Co0.1Mn0.1O2(NCM811)|SiOx-graphite(SiO-Gr.)battery chemistry is of intensive attention because its achievable practical energy density is approaching impressively 300 Wh Kg^(-1).However,it still suffers rapid capacity fades during repeated cycles,both chemical,electrochemical and mechanical irreversibility contribute.A comprehensive understanding behind the fading behavior of the cell chemistry is required before fully realize the benefits of this chemistry.Herein,the in-situ thickness variation is introduced as a diagnostic technique and is performed on 5-55 Ah NCM811|SiO-Gr cells.With the help of Li reference electrode and in-situ X-ray diffraction device,the correspondence between thickness variation and the electrode potential is carefully investigated.Firstly,the NCM811|SiO-Gr cell is characterized with the maximum cell thickness at around 80%state-of-charge(SOC)in the discharge process,rather than at 100%SOC.Secondly,the electrochemical behaviors during rate charge/discharge are diagnosed,and a Li platting signal is resolved from thickness variation profile at 2C.This work confirms that the thickness monitoring is a nondestructive and informative complement to conventional diagnostic techniques for failure analysis of pouch cells.

Effect of thickness variations of lithium niobate on insulator waveguide on the frequency spectrum of spontaneous parametric down-conversion

We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum,such as narrowing,broadening,and splitting.We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth.Our study may promote the development of on-chip photon sources in the LNOI platform,as well as opens up a way to engineer photon frequency state.

ON PROBLEMS OF U-SHAPED BELLOWS WITH NONLINEAR DEFORMATION OF LARGE AXISYMMETRICAL DEFLECTION(Ⅱ)——COUNTING VARIATION OF THICKNESS DISTRIBUTION

On the basis of paper [1], assuming the logarithm of thickness at arbitrary point on a U-shaped bellows meridian is linear with the logarithm of distance between that point and axis of symmetry, perturbation solutions of the corresponding problems of large axisymmetrical deflection are given. The effects of thickness distribution variation, which result from technology factors, on stiffness of bellows are discussed.

Comment on “The diurnal variation pattern of choroidal thickness in macular region of young healthy female individuals using spectral domain optical coherence tomography”

Dear Editor,We have read and reviewed the article entitled＂The diurnal variation pattern of choroidal thickness in macular region of young healthy female individuals using spectral domain optical coherence tomography＂by Zhao et al^（[1]）with great interest.

Optical clearing mechanisms characterization in muscle

Optical immersion clearing is a technique that has been widely studied for more than two decades and that is used to originate a temporary transparency effect in biological tissues.If applied in cooperation with clinical methods it provides optimization of diagnosis and treatment procedures.This technique turns biological tissues more transparent through two main mechanisms-tissue dehydration and refractive index(RI)matching between tissue compo-nents.Such matching is obtained by partial replacement of interstit ial water by a biocompat ible agent that presents higher RI and it can be completely rever sible by natural rehydration in vrivo or by assisted rehydration in ex vivo tissues.Experimental data to characterize and discriminate between the two mechanisms and to find new ones are necessary.Using a simple method,based on collimated transmittance and thickness measurements made from muscle samples under treatment,we have estimated the diffusion properties of glucose,ethylene glycol(EG)and water that were used to perform such char acterization and discrimination.Comparing these properties with data from literature that characterize their diffusion in water we have observed that musde cell membrane permeability limits agent and water diffusion in the muscle.The same experi-mental data has allowed to calculate the optical dearing(OC)eficiency and make an inter-pretation of the internal changes that occurred in muscle during the treatments.The same methodology can now be used to perform similar studies with other agents and in other tissues in order to solve engineering problems at design of inexpensive and robust technologies for a consider.able improvement of optical tomogr aphic techmiques with better contrast and in depth imaging.

Effect of Aggregation Structure on Thermal Expansion Behavior of Polyimide Films with Different Thickness

Polyimide films derived from representative PMDA/ODA were prepared with thickness ranging from 5 μm to 25 μm,and the effect of aggregation structure on thermal expansion behavior along different directions was studied.Both in-plane and out-of-plane linear thermal expansion(CTEand CTE) were respectively characterized by thermal mechanical analysis and FT-near-IR interference method.Volumetric and anisotropic behavior of thermal expan sion were also investigated.With increasing film thickness,CTEgradually increased from 32.2 ppm/℃ to46.1 ppm/℃ while CTEdecreased from 149.7 ppm/℃ to 128.2 ppm/℃.Volumetric thermal expansion of polyimide films was less sensitive to the va ried thickness,but anisotropy of thermal expansion was reduced.Polyimide film of 5 μm thickness showed large birefringence,indicating more considerable in-plane chain orientation anisotropy.Besides,molecular chains were more densely packed along in-plane direction when film thickness increased,while became loosely stacked in the out-of-plane direction.In contrast to the enhanced lateral chain packing for thicker film s,higher vertical chain packing order was found in thinner films.The variation of aggregation structure during thermal expansion procedure was analyzed by temperature-dependent WAXD.It is proved that thermal expansion behavior of thinner films could be largely attributed to molecular chain packing,whereas that may be influenced by many factors for thicker films in addition to the effect of chain packing.The results revealed that thermal expansion of films with thickness variation is closely related to molecular chain orientation and packing,which is associated with both chemistry and morphological structure of polyimide.

Determination of continuous constitutive relationship of weld zone of high-strength steel rectangular welded tube

For QSTE700 high-strength steel rectangular welded tube,the mechanical properties of the weld zone vary with the distancefrom the centerline of the weld.Therefore,the accurate description of constitutive relationship of the weld zone is of greatsignificance for the study of formability of QSTE700 rectangular welded tube.Firstly,the mechanical properties of parentand mixed specimens containing weld zone and parent zone were obtained by uniaxial tensile test.And based on the micro-hardness test,the width and the microhardness distribution of the weld zone were determined.Secondly,by subdividingthe weld zone into several small areas,and combining with the rule of mixtures and nanoindentation test,the continuous functional relationships of strength coefficient K,hardening coeffecient n and elastic modulus E were obtained,and then,the continuous constitutive relationship of QSTE700 rectangular welded tube was established.Finally,the validity and reliability of the continuous constitutive relationship of welded tube were verified by nanoindentation fest and rotary drawbending of rectangular welded tubc.Besides,it was found that the finite element model of rotary draw bending of QSTE700 rectangular welded tube established by using the continuous constitutive relationship can well simulate the cross sectiondeformation and wall thickness variation.

Characterization of Automotive Brake Discs with Laser-Machined Surfaces

In the automotive and transport industry,braking noise and vibrations are persisting issues and difficult to control.Automo-tive engineers and researchers are putting considerable effort into overcoming these problems,and significant breakthroughs have been made in this area.In this study,M-shaped grooves were bionically designed and manufactured on the frictional surfaces of four automotive brake discs using a laser machine.Various tests were conducted to characterize the physical and mechanical performance of the modified discs along with their noise and vibration responses.The experimental results demonstrate that discs with laser-machined grooved surfaces have better surface hardness and residual stress reduction than discs with un-grooved surfaces.Significant improvement in the braking performance was observed in terms of disc thickness variation,friction and wear,noise,and vibration reduction.It is concluded that the reduction in braking noise and vibrations is mainly caused by the reduction in the coefficient of friction and wear,increase in damping ratio,and improvement of disc thickness variation of the brake disc by laser surface grooving.