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Three-dimensional coordinates test method with uncertain projectile proximity explosion position based on dynamic seven photoelectric detection screen 被引量:2
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作者 Han-shan Li Xiao-qian Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第9期1643-1652,共10页
To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test ... To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test method, which is made up of six plane detection screens and a flash photoelectric dynamic detection screen. The three-dimensional coordinates calculation model of the projectile proximity explosion position based on seven plane detection screens with dynamic characteristics is established.According to the relation of the dynamic seven photoelectric detection screen planes and the time values,the analytical function of the projectile proximity explosion position parameters under non-linear motion is derived. The projectile signal filtering method based on discrete wavelet transform is explored in this work. Additionally, the projectile signal recognition algorithm using an improved particle swarm is proposed. Based on the characteristics of the time duration and the signal peak error for the projectile passing through the detection screen, the signals attribution of the same projectile passing through six detection screens are analyzed for obtaining precise time values of the same projectile passing through the detection screens. On the basis of the projectile fuze proximity explosion test, the linear motion model and the proposed non-linear motion model are used to calculate and compare the same group of projectiles proximity explosion position parameters. The comparison of test results verifies that the proposed test method and calculation model in this work accurately obtain the actual projectile proximity explosion position parameters. 展开更多
关键词 Dynamic multi-screen array plane Flash photoelectric detection target Projectile signal processing Particle swarm Proximity explosion fuze three-dimensional coordinate
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SARC Model for Three-Dimensional Coordinate Transformation
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作者 YAO Jili WANG Shuguang SUN Yating 《Geo-Spatial Information Science》 2006年第2期84-88,共5页
In this paper, a transformation model named SARC(static-filter adjustment with restricted condition) is presented, which is more practical and more rigorous in theory and fitting any angle of rotation parameter. The t... In this paper, a transformation model named SARC(static-filter adjustment with restricted condition) is presented, which is more practical and more rigorous in theory and fitting any angle of rotation parameter. The transformation procedure is divided into 4 steps: ① the original and object coordinates can be regarded as observations with errors; ② rigorous formula is firstly deduced in order to compute the first approximation of the transformation parameters by use of four common points and the transformation equation is linearized; ③ calculate the most probable values and variances of the seven transformation parameters by SARC model; ④ to demonstrate validity of SARC , an example is given. 展开更多
关键词 SARC 3D coordinate transformation transformation parameters transformation equation
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Three-dimensional models:from cell culture to Patient-Derived Organoid and its application to future liposarcoma research
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作者 SAYUMI TAHARA SYDNEY RENTSCH +4 位作者 FERNANDA COSTAS CASAL DE FARIA PATRICIA SARCHET ROMA KARNA FEDERICA CALORE RAPHAEL E.POLLOCK 《Oncology Research》 SCIE 2025年第1期1-13,共13页
Liposarcoma is one of the most common soft tissue sarcomas,however,its occurrence rate is still rare compared to other cancers.Due to its rarity,in vitro experiments are an essential approach to elucidate liposarcoma ... Liposarcoma is one of the most common soft tissue sarcomas,however,its occurrence rate is still rare compared to other cancers.Due to its rarity,in vitro experiments are an essential approach to elucidate liposarcoma pathobiology.Conventional cell culture-based research(2D cell culture)is still playing a pivotal role,while several shortcomings have been recently under discussion.In vivo,mouse models are usually adopted for pre-clinical analyses with expectations to overcome the issues of 2D cell culture.However,they do not fully recapitulate human dedifferentiated liposarcoma(DDLPS)characteristics.Therefore,three-dimensional(3D)culture systems have been the recent research focus in the cell biology field with the expectation to overcome at the same time the disadvantages of 2D cell culture and in vivo animal models and fill in the gap between them.Given the liposarcoma rarity,we believe that 3D cell culture techniques,including 3D cell cultures/co-cultures,and Patient-Derived tumor Organoids(PDOs),represent a promising approach to facilitate liposarcoma investigation and elucidate its molecular mechanisms and effective therapy development.In this review,we first provide a general overview of 3D cell cultures compared to 2D cell cultures.We then focus on one of the recent 3D cell culture applications,Patient-Derived Organoids(PDOs),summarizing and discussing several PDO methodologies.Finally,we discuss the current and future applications of PDOs to sarcoma,particularly in the field of liposarcoma. 展开更多
关键词 Cell culture LIPOSARCOMA Patient-Derived Organoid(PDO) SPHEROID three-dimensional(3D)cell culture
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Quasi-real time inversion method of three-dimensional epicenter coordinate, trigger time, and magnitude based on CORS 被引量:1
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作者 Xiao Dongsheng Chang Ming +2 位作者 Su Yong Hu Qijun Yu Bing 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2016年第3期425-433,共9页
This study explores the quasi-real time inversion principle and precision estimation of three-dimensional coordinates of the epicenter, trigger time and magnitude of earthquakes with the aim to improve traditional met... This study explores the quasi-real time inversion principle and precision estimation of three-dimensional coordinates of the epicenter, trigger time and magnitude of earthquakes with the aim to improve traditional methods, which are flawed due to missing information or distortion in the seismograph records. The epicenter, trigger time and magnitude from the Lushan earthquake are inverted and analyzed based on high-frequency GNSS data. The inversion results achieved a high precision, which are consistent with the data published by the China Earthquake Administration. Moreover, it has been proven that the inversion method has good theoretical value and excellent application prospects. 展开更多
关键词 continuous operation reference station (CORS) trigger time three dimensional coordinate MAGNITUDE inversion
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THE THREE-DIMENSIONAL FUNDAMENTAL SOLUTION TO STOKES FLOW IN THE OBLATE SPHEROIDAL COORDINATES WITH APPLICATIONS TO MULTIPLES SPHEROID PROBLEMS
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作者 庄宏 严宗毅 吴望一 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2002年第5期514-534,共21页
A new three-dimensional fundamental solution to the Stokes flow was proposed by transforming the solid harmonic functions in Lamb's solution into expressions in terms Of the oblate spheroidal coordinates. These fu... A new three-dimensional fundamental solution to the Stokes flow was proposed by transforming the solid harmonic functions in Lamb's solution into expressions in terms Of the oblate spheroidal coordinates. These fundamental solutions are advantageous in treating flows past an arbitrary number of arbitrarily positioned and oriented oblate spheroids. The least squares technique was adopted herein so that the convergence difficulties often encountered in solving three-dimensional problems were completely avoided. The examples demonstrate that present approach is highly accurate, consistently stable and computationally efficient. The oblate spheroid may be used to model a variety of particle shapes between a circular disk and a sphere. For the first time, the effect of various geometric factors on the forces and torques exerted on two oblate spheroids were systematically studied by using the proposed fundamental solutions. The generality of this approach was illustrated by two problems of three spheroids. 展开更多
关键词 Stokes flow fundamental solution three-dimension oblate spheroid multipole collocation least squares method low Reynolds number multiple particles
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The Establishment of the Projections of Four to Seven-Dimensional Rectangular Coordinate Systems into the Three-Dimensional Space
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作者 Shi Kaida(Zhoushan Teachers’ College, Zhejiang, China) 《浙江海洋学院学报(人文科学版)》 1995年第1期1-8,共8页
Starting from the finite rotation group,the author makes a penetrating study of 4 to 7-dimensional hypercube so that we have acquired the projection models of 4 to 7-dimeneional spatial rectangular coordinate systems ... Starting from the finite rotation group,the author makes a penetrating study of 4 to 7-dimensional hypercube so that we have acquired the projection models of 4 to 7-dimeneional spatial rectangular coordinate systems into the three-dimensional space to have the 4 to 7-dimensional geometric figures demonstrated correctly. 展开更多
关键词 finite ROTATION group rectangular coordinate system hypercube.projection model.
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基于Coordinate Attention和空洞卷积的异物识别 被引量:2
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作者 王春霖 吴春雷 +1 位作者 李灿伟 朱明飞 《计算机系统应用》 2024年第3期178-186,共9页
在我国工厂的工业化生产中,带式运输机占有重要的地位,但是在其运输物料的过程中,常有木板、金属管、大型金属片等混入物料中,从而对带式运输机的传送带造成损毁,引起巨大的经济损失.为了检测出传送带上的不规则异物,设计了一种新的异... 在我国工厂的工业化生产中,带式运输机占有重要的地位,但是在其运输物料的过程中,常有木板、金属管、大型金属片等混入物料中,从而对带式运输机的传送带造成损毁,引起巨大的经济损失.为了检测出传送带上的不规则异物,设计了一种新的异物检测方法.针对传统异物检测方法中存在的对于图像特征提取能力不足以及网络感受野相对较小的问题,我们提出了一种基于coordinate attention和空洞卷积的单阶段异物识别方法.首先,网络利用coordinate attention机制,使网络更加关注图像的空间信息,并对图像中的重要特征进行了增强,增强了网络的性能;其次,在网络提取多尺度特征的部分,将原网络的静态卷积变为空洞卷积,有效减少了常规卷积造成的信息损失;除此之外,我们还使用了新的损失函数,进一步提高了网络的性能.实验结果证明,我们提出的网络能有效识别出传送带上的异物,较好地完成异物检测任务. 展开更多
关键词 coordinate attention 异物检测 空洞卷积 损失函数 目标识别
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Three-dimensional stability calculation method for high and large composite slopes formed by mining stope and inner dump in adjacent open pits 被引量:1
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作者 Zuchao Liang Dong Wang +4 位作者 Guanghe Li Guangyu Sun Mingyu Yu Dong Xia Chunjian Ding 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第4期507-520,共14页
The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of signi... The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis. 展开更多
关键词 Composite slope Destabilization mechanism 3D mechanical effect three-dimensional stability coordinated development distance
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A theory for three-dimensional response of micropolar plates 被引量:1
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作者 Dianwu HUANG Linghui HE 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第8期1403-1414,共12页
Through combined applications of the transfer-matrix method and asymptotic expansion technique,we formulate a theory to predict the three-dimensional response of micropolar plates.No ad hoc assumptions regarding throu... Through combined applications of the transfer-matrix method and asymptotic expansion technique,we formulate a theory to predict the three-dimensional response of micropolar plates.No ad hoc assumptions regarding through-thickness assumptions of the field variables are made,and the governing equations are two-dimensional,with the displacements and microrotations of the mid-plane as the unknowns.Once the deformation of the mid-plane is solved,a three-dimensional micropolar elastic field within the plate is generated,which is exact up to the second order except in the boundary region close to the plate edge.As an illustrative example,the bending of a clamped infinitely long plate caused by a uniformly distributed transverse force is analyzed and discussed in detail. 展开更多
关键词 micropolar plate TRANSFER-MATRIX asymptotic expansion three-dimensional response
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Three-dimensional visualization technology for guiding one-step percutaneous transhepatic cholangioscopic lithotripsy for the treatment of complex hepatolithiasis 被引量:2
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作者 Yong-Qing Ye Ya-Wen Cao +6 位作者 Rong-Qi Li En-Ze Li Lei Yan Zhao-Wei Ding Jin-Ming Fan Ping Wang Yi-Xiang Wu 《World Journal of Gastroenterology》 SCIE CAS 2024年第28期3393-3402,共10页
BACKGROUND Biliary stone disease is a highly prevalent condition and a leading cause of hospitalization worldwide.Hepatolithiasis with associated strictures has high residual and recurrence rates after traditional mul... BACKGROUND Biliary stone disease is a highly prevalent condition and a leading cause of hospitalization worldwide.Hepatolithiasis with associated strictures has high residual and recurrence rates after traditional multisession percutaneous transhepatic cholangioscopic lithotripsy(PTCSL).AIM To study one-step PTCSL using the percutaneous transhepatic one-step biliary fistulation(PTOBF)technique guided by three-dimensional(3D)visualization.METHODS This was a retrospective,single-center study analyzing,140 patients who,between October 2016 and October 2023,underwent one-step PTCSL for hepatolithiasis.The patients were divided into two groups:The 3D-PTOBF group and the PTOBF group.Stone clearance on choledochoscopy,complications,and long-term clearance and recurrence rates were assessed.RESULTS Age,total bilirubin,direct bilirubin,Child-Pugh class,and stone location were similar between the 2 groups,but there was a significant difference in bile duct strictures,with biliary strictures more common in the 3D-PTOBF group(P=0.001).The median follow-up time was 55.0(55.0,512.0)days.The immediate stone clearance ratio(88.6%vs 27.1%,P=0.000)and stricture resolution ratio(97.1%vs 78.6%,P=0.001)in the 3D-PTOBF group were significantly greater than those in the PTOBF group.Postoperative complication(8.6%vs 41.4%,P=0.000)and stone recurrence rates(7.1%vs 38.6%,P=0.000)were significantly lower in the 3D-PTOBF group.CONCLUSION Three-dimensional visualization helps make one-step PTCSL a safe,effective,and promising treatment for patients with complicated primary hepatolithiasis.The perioperative and long-term outcomes are satisfactory for patients with complicated primary hepatolithiasis.This minimally invasive method has the potential to be used as a substitute for hepatobiliary surgery. 展开更多
关键词 HEPATOLITHIASIS One-step percutaneous transhepatic cholangioscopic lithotripsy Biliary disease three-dimensional visualization Clinical efficacy
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Oxygen tension modulates cell function in an in vitro three-dimensional glioblastoma tumor model 被引量:1
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作者 Sen Wang Siqi Yao +8 位作者 Na Pei Luge Bai Zhiyan Hao Dichen Li Jiankang He J.Miguel Oliveira Xiaoyan Xue Ling Wang Xinggang Mao 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2024年第3期307-319,共13页
Hypoxia is a typical feature of the tumor microenvironment,one of the most critical factors affecting cell behavior and tumor progression.However,the lack of tumor models able to precisely emulate natural brain tumor ... Hypoxia is a typical feature of the tumor microenvironment,one of the most critical factors affecting cell behavior and tumor progression.However,the lack of tumor models able to precisely emulate natural brain tumor tissue has impeded the study of the effects of hypoxia on the progression and growth of tumor cells.This study reports a three-dimensional(3D)brain tumor model obtained by encapsulating U87MG(U87)cells in a hydrogel containing type I collagen.It also documents the effect of various oxygen concentrations(1%,7%,and 21%)in the culture environment on U87 cell morphology,proliferation,viability,cell cycle,apoptosis rate,and migration.Finally,it compares two-dimensional(2D)and 3D cultures.For comparison purposes,cells cultured in flat culture dishes were used as the control(2D model).Cells cultured in the 3D model proliferated more slowly but had a higher apoptosis rate and proportion of cells in the resting phase(G0 phase)/gap I phase(G1 phase)than those cultured in the 2D model.Besides,the two models yielded significantly different cell morphologies.Finally,hypoxia(e.g.,1%O2)affected cell morphology,slowed cell growth,reduced cell viability,and increased the apoptosis rate in the 3D model.These results indicate that the constructed 3D model is effective for investigating the effects of biological and chemical factors on cell morphology and function,and can be more representative of the tumor microenvironment than 2D culture systems.The developed 3D glioblastoma tumor model is equally applicable to other studies in pharmacology and pathology. 展开更多
关键词 HYPOXIA GLIOMA three-dimensional glioma model In vitro
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Three-dimensional cell-based strategies for liver regeneration 被引量:1
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作者 DAN GUO XI XIA JIAN YANG 《BIOCELL》 SCIE 2024年第7期1023-1036,共14页
Liver regeneration and the development of effective therapies for liver failure remain formidable challenges in modern medicine.In recent years,the utilization of 3D cell-based strategies has emerged as a promising ap... Liver regeneration and the development of effective therapies for liver failure remain formidable challenges in modern medicine.In recent years,the utilization of 3D cell-based strategies has emerged as a promising approach for addressing these urgent clinical requirements.This review provides a thorough analysis of the application of 3D cell-based approaches to liver regeneration and their potential impact on patients with end-stage liver failure.Here,we discuss various 3D culture models that incorporate hepatocytes and stem cells to restore liver function and ameliorate the consequences of liver failure.Furthermore,we explored the challenges in transitioning these innovative strategies from preclinical studies to clinical applications.The collective insights presented herein highlight the significance of 3D cell-based strategies as a transformative paradigm for liver regeneration and improved patient care. 展开更多
关键词 three-dimensional Liver regeneration ORGANOIDS Stem cells Cell therapy
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Oxygen‑Coordinated Single Mn Sites for Efficient Electrocatalytic Nitrate Reduction to Ammonia 被引量:2
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作者 Shengbo Zhang Yuankang Zha +8 位作者 Yixing Ye Ke Li Yue Lin Lirong Zheng Guozhong Wang Yunxia Zhang Huajie Yin Tongfei Shi Haimin Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期147-159,共13页
Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites... Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites. 展开更多
关键词 Atomically dispersed Oxygen coordination Nitrate reduction reaction In situ spectroscopic studies Hydrogen evolution reaction
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The combined application of stem cells and three-dimensional bioprinting scaffolds for the repair of spinal cord injury 被引量:3
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作者 Dingyue Ju Chuanming Dong 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第8期1751-1758,共8页
Spinal cord injury is considered one of the most difficult injuries to repair and has one of the worst prognoses for injuries to the nervous system.Following surgery,the poor regenerative capacity of nerve cells and t... Spinal cord injury is considered one of the most difficult injuries to repair and has one of the worst prognoses for injuries to the nervous system.Following surgery,the poor regenerative capacity of nerve cells and the generation of new scars can make it very difficult for the impaired nervous system to restore its neural functionality.Traditional treatments can only alleviate secondary injuries but cannot fundamentally repair the spinal cord.Consequently,there is a critical need to develop new treatments to promote functional repair after spinal cord injury.Over recent years,there have been seve ral developments in the use of stem cell therapy for the treatment of spinal cord injury.Alongside significant developments in the field of tissue engineering,three-dimensional bioprinting technology has become a hot research topic due to its ability to accurately print complex structures.This led to the loading of three-dimensional bioprinting scaffolds which provided precise cell localization.These three-dimensional bioprinting scaffolds co uld repair damaged neural circuits and had the potential to repair the damaged spinal cord.In this review,we discuss the mechanisms underlying simple stem cell therapy,the application of different types of stem cells for the treatment of spinal cord injury,and the different manufa cturing methods for three-dimensional bioprinting scaffolds.In particular,we focus on the development of three-dimensional bioprinting scaffolds for the treatment of spinal cord injury. 展开更多
关键词 BIOMATERIALS embryonic stem cells induced pluripotent stem cells mesenchymal stem cells nerve regeneration spinal cord injury stem cell therapy stem cells three-dimensional bioprinting
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Application of three-dimensional speckle tracking technique in measuring left ventricular myocardial function in patients with diabetes 被引量:1
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作者 Zheng Li Ying Qian +1 位作者 Chun-Yun Fan Yong Huang 《World Journal of Diabetes》 SCIE 2024年第4期783-792,共10页
BACKGROUND Diabetic cardiomyopathy is considered as a chronic complication of diabetes mellitus(DM).Therefore,early detection of left ventricular systolic function(LVSF)damage in DM is essential.AIM To explore the use... BACKGROUND Diabetic cardiomyopathy is considered as a chronic complication of diabetes mellitus(DM).Therefore,early detection of left ventricular systolic function(LVSF)damage in DM is essential.AIM To explore the use of the three-dimensional speckle tracking technique(3D-STI)for measuring LVSF in DM patients via meta-analysis.METHODS The electronic databases were retrieved from the initial accessible time to 29 April 2023.The current study involved 9 studies,including 970 subjects.We carried out this meta-analysis to estimate myocardial function in DM compared with controls according to myocardial strain attained by 3D-STI.RESULTS Night articles including 970 subjects were included.No significant difference was detected in the left ventricular ejection fraction between the control and the diabetic group(P>0.05),while differences in global longitudinal strain,global circumferential strain,global radial strain,and global area strain were markedly different between the controls and DM patients(all P<0.05).CONCLUSION The 3D-STI could be applied to accurately measure early LVSF damage in patients with DM. 展开更多
关键词 Diabetes mellitus Left ventricular systolic dysfunction three-dimensional speckle tracking echocardiography Meta analysis
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Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrating Three-dimensional Coordination Polymer,{[Co_3(byip)_2(bix)_3(H_2O)_2]·H_2O}_n 被引量:3
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作者 王子梁 李明雪 +1 位作者 赵俊伟 王敬平 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第5期654-659,共6页
The title coordination polymer including two crystallographically independent Co2+ ions is hydrothermally synthesized, in which the Co(1) 2+ ion is four-coordinated by two carboxylate oxygen atoms from two differe... The title coordination polymer including two crystallographically independent Co2+ ions is hydrothermally synthesized, in which the Co(1) 2+ ion is four-coordinated by two carboxylate oxygen atoms from two different 5-(benzoic acid-4-yldiazenyl)isophthalate (byip3-) anions and two nitrogen atoms from two distinct 1,4-bis(imidazol-1-ylmethyl) benzene (bix) ligands displaying a tetrahedral geometry. The Co(2) 2+ ion is six-coordinated by two water molecules at the apical positions, and two carboxylate oxygen atoms and two nitrogen atoms at the equatorial positions, affording a slightly distorted octahedron. Two Co(1)2+ and two Co(2)2+ ions are linked together by four byip3- anions forming a 44-membered motif and these motifs are further arranged into a three-dimensional framework through bix ligands along the a axis with a larger channel (ca. 22.70×11.01). Each individual network interpenetrates with the other identical network in a parallel fashion to generate a 2-fold interpenetrating array with the {62.84}{63}2{64.82}2 topology. 展开更多
关键词 crystal structure coordination polymer carboxylater INTERPENETRATION TOPOLOGY
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A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid: Synthesis, Crystal Structure,and Luminescence Properties 被引量:3
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作者 姜大雨 隋微 +1 位作者 刘博 王庆伟 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第9期1445-1450,共6页
A novel coordination polymer [Zn2(BTA)2(TDC)]n(HBTA = benzotriazole, H2TDC = thiophene-2,5-dicarboxylic acid) has been synthesized by the reaction of zinc(Ⅱ), H2TDC and HBTA. This compound is fully structural... A novel coordination polymer [Zn2(BTA)2(TDC)]n(HBTA = benzotriazole, H2TDC = thiophene-2,5-dicarboxylic acid) has been synthesized by the reaction of zinc(Ⅱ), H2TDC and HBTA. This compound is fully structurally characterized by elemental analysis, IR, and single-crystal X-ray crystallography. The bulk new materials were further identified by X-ray powder diffraction. Compound 1 crystallizes in the orthorhombic system, space group Pbcn, with a = 9.8825(8), b = 9.4047(8), c = 20.5567(17) , V = 1910.6(3) -3, C(18)H(10)N6O4SZn2, Mr = 537.12, Dc = 1.867 g/cm-3, μ(MoK α) = 2.662 mm-(-1), F(000) = 1072, Z = 4, S = 1.058, the final R = 0.0201 and w R = 0.0530 for 1700 observed reflections(I 2σ(I)). Its compositional stability and photoluminescence properties were further investigated to establish the structure-property relationships. Structural analysis reveals that this compound is a 3D(4, 4)-connected framework with the(6-6)(6-4·8-2) topology. 展开更多
关键词 coordination polymer crystal structure thermal stability analysis fluorescence
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Two Three-dimensional Terbium-1,4-benzenedicarboxylate Coordination Polymers:Syntheses,Structures,and Luminescence 被引量:6
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作者 雷倩 刘庆燕 +2 位作者 王玉玲 陈莉莉 殷顺高 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第4期566-576,共11页
Two coordination polymers with 1,4-benzenedicarboxylic acid(H2BDC) ligand, namely, [Tb3(BDC)(4.5)(H2O)(DMF)2]n (1) and [Tb2(BDC)3(H2O)2(DMF)2]n(2), have been synthesized and characterized. Both com... Two coordination polymers with 1,4-benzenedicarboxylic acid(H2BDC) ligand, namely, [Tb3(BDC)(4.5)(H2O)(DMF)2]n (1) and [Tb2(BDC)3(H2O)2(DMF)2]n(2), have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a = 10.8528(5), b = 12.2516(5), c = 16.9031(7) A, α = 104.462(1), β = 93.659(1), γ = 101.404(1)°, V = 2118.1(2) A^3, Z = 2, C(42)H(34)N2O(21)Tb3, Mr = 1379.47, Dc = 2.163 g/cm^3, μ = 5.045 mm^-1, F(000) = 1326, the final R = 0.0212 and wR = 0.0570 for 8592 observed reflections with I 〉 2σ(I). For compound 2, a = 8.547(1), b = 10.170(1), c = 11.192(1)A?, α = 65.531(1), β = 71.886(1), γ = 78.796(1)°, V = 839.2(2) A^3, Z = 1, C(30)H(30)N2O(16)Tb2, Mr = 992.40, Dc = 1.964 g/cm^3, μ = 4.257 mm^-1, F(000) = 482, the final R = 0.0220 and wR = 0.0649 for 3626 observed reflections with I 〉 2σ(I). The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional(3D) framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb3 units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb2 secondary building units. Photoluminescence studies show both compounds exhibit typical Tb(Ⅲ) luminescence emissions. An efficient ligand-to-Tb(Ⅲ) energy transfer is observed in the emission spectra for both compounds. 展开更多
关键词 terbium coordination compounds luminescence templates 1 4-benzenedicarboxylate
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Synthesis, Crystal Structure and Photoluminescent Property of a Three-dimensional Zinc(Ⅱ) Coordination Polymer: [Zn_1.5(PDB)(bix)_0.5(μ_2-OH)]_(2n) 被引量:3
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作者 王庆伟 芦廷峰 +3 位作者 国佳 李秀梅 纪建业 刘博 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第1期137-141,共5页
A new metal-organic coordination polymer [Zn1.5(PDB)(bix)0.5(μ2-OH)]2n 1 (H2PDB = pyridine-3,4-dicarboxylic acid, bix = 1,4-bis(imidazol-1-ylmethyl)-benzene) has been hydrothermally synthesized and structur... A new metal-organic coordination polymer [Zn1.5(PDB)(bix)0.5(μ2-OH)]2n 1 (H2PDB = pyridine-3,4-dicarboxylic acid, bix = 1,4-bis(imidazol-1-ylmethyl)-benzene) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P2/c with a = 7.411(2), b = 7.848(3), c = 25.048(8), V = 1451.8(8)3, C28H22N6O10Zn3, Mr = 798.63, Dc = 1.827 g/cm3, μ(MoKα) = 2.529 mm-1, F(000) = 804, Z = 2, the final R = 0.0440 and wR = 0.1035 for 1952 observed reflections (I 2σ(I)). It exhibits a three-dimensional framework structure. Moreover, its luminescent property has been investigated in the solid state. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Virtual and augmented reality systems and three-dimensional printing of the renal model—novel trends to guide preoperative planning for renal cancer
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作者 Claudia-Gabriela Moldovanu 《Asian Journal of Urology》 CSCD 2024年第4期521-529,共9页
Objective:This study aimed to explore the applications of three-dimensional (3D) technology, including virtual reality, augmented reality (AR), and 3D printing system, in the field of medicine, particularly in renal i... Objective:This study aimed to explore the applications of three-dimensional (3D) technology, including virtual reality, augmented reality (AR), and 3D printing system, in the field of medicine, particularly in renal interventions for cancer treatment.Methods:A specialized software transforms 2D medical images into precise 3D digital models, facilitating improved anatomical understanding and surgical planning. Patient-specific 3D printed anatomical models are utilized for preoperative planning, intraoperative guidance, and surgical education. AR technology enables the overlay of digital perceptions onto real-world surgical environments.Results:Patient-specific 3D printed anatomical models have multiple applications, such as preoperative planning, intraoperative guidance, trainee education, and patient counseling. Virtual reality involves substituting the real world with a computer-generated 3D environment, while AR overlays digitally created perceptions onto the existing reality. The advances in 3D modeling technology have sparked considerable interest in their application to partial nephrectomy in the realm of renal cancer. 3D printing, also known as additive manufacturing, constructs 3D objects based on computer-aided design or digital 3D models. Utilizing 3D-printed preoperative renal models provides benefits for surgical planning, offering a more reliable assessment of the tumor's relationship with vital anatomical structures and enabling better preparation for procedures. AR technology allows surgeons to visualize patient-specific renal anatomical structures and their spatial relationships with surrounding organs by projecting CT/MRI images onto a live laparoscopic video. Incorporating patient-specific 3D digital models into healthcare enhances best practice, resulting in improved patient care, increased patient satisfaction, and cost saving for the healthcare system. 展开更多
关键词 three-dimensional model three-dimensional printing Augmented reality Virtual reality
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