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Impact of digital economy development on carbon productivity:An empirical analysis based on threshold effect and spatial spillover effect
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作者 XING Huai-zhen YAO Jing 《Ecological Economy》 2024年第2期123-138,共16页
Utilizing provincial panel data from 2014 to 2020,this study employs a fixed effect model,a threshold effect model,and a spatial lag model to empirically examine the correlation between digital economic development an... Utilizing provincial panel data from 2014 to 2020,this study employs a fixed effect model,a threshold effect model,and a spatial lag model to empirically examine the correlation between digital economic development and carbon productivity.The findings indicate that digital economic development significantly contributes to the enhancement of carbon productivity in the long term.Furthermore,through instrumental variable method,replacement of explanatory variables and other methods to test its endogeneity and stability,the results remain robust.In terms of regional heterogeneity,the impact of digital economic development on carbon productivity is less pronounced in the central and western regions compared to the eastern region.Additionally,further investigation reveals that industrial structure upgrading and science and technology investment level exhibit different threshold effects on the influence of digital economy development level on carbon productivity.Moreover,there is a significant spatial spillover effect of digital economy development on carbon productivity with H-H and L-L agglomeration spatial correlation. 展开更多
关键词 digital economy carbon productivity threshold effect spatial spillover effect
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Research on the Threshold Effect of China’s Pharmaceutical Export Trade on Internal and External R&D Investment
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作者 Qiao Jiahui Song Yu +1 位作者 Gong Jingran Chen Yuwen 《Asian Journal of Social Pharmacy》 2024年第2期135-146,共12页
Objective To study the threshold effect of export trade on internal and external R&D investment in China’s pharmaceutical industry,and to provide reference for some pharmaceutical enterprises to improve the inves... Objective To study the threshold effect of export trade on internal and external R&D investment in China’s pharmaceutical industry,and to provide reference for some pharmaceutical enterprises to improve the investment.Methods The panel data of pharmaceutical industry in 25 provinces and cities in China from 2009 to 2019 were selected to conduct empirical analysis by establishing a threshold regression model,and a better export trade interval was obtained.Results and Conclusion There is a threshold value for the effect of new product export on both internal and external R&D expenditures,and the threshold values are 845.2788 million yuan and 318.4198 million yuan,respectively.There is a single threshold effect of export trade on both internal and external R&D investment in China’s pharmaceutical industry,and the effect of export trade on internal and external R&D investment changes from negative to positive as the export trade develops from low to high. 展开更多
关键词 pharmaceutical industry threshold effect export trade R&D investment
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Research on the Impact of China’s Foreign Trade Technology Spillover on Green Total Factor Productivity of Countries Along the“Belt and Road”:Based on the Institutional Quality Threshold Effect
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作者 Li Chai Longnan Ma Lingwei Meng 《Proceedings of Business and Economic Studies》 2024年第2期120-125,共6页
China’s growing trade with countries along the“Belt and Road”Initiative is accompanied by a focus on green development.Based on the panel data from 2007 to 2018,this paper establishes a threshold regression model t... China’s growing trade with countries along the“Belt and Road”Initiative is accompanied by a focus on green development.Based on the panel data from 2007 to 2018,this paper establishes a threshold regression model to empirically analyze the institutional quality threshold effect of China’s foreign trade technology spillover on the GTFP of countries along the“Belt and Road.”The results show that China’s foreign trade technology spillover has a significant institutional quality double threshold effect on the green total factor productivity of the countries along the“Belt and Road.”As the institutional quality of the countries along the“Belt and Road”crosses a specific threshold value,the impact of China’s foreign trade technology spillover on the green total factor productivity of the countries along the“Belt and Road”has a significant positive promoting effect,and corresponding suggestions are put forward. 展开更多
关键词 Technology spillover Green total factor productivity Institutional quality threshold effect
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Productivity Spillovers from FDI in China:Regional Differences and Threshold Effects 被引量:4
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作者 Jianhong Qi Yingmei Zheng +1 位作者 James Laurenceson Hong Li 《China & World Economy》 SCIE 2009年第4期18-35,共18页
Economic theory posits numerous channels through which FDI might create positive spillovers for domestic firms. However, the results of empirical studies that have sought to document these spillovers have been mixed. ... Economic theory posits numerous channels through which FDI might create positive spillovers for domestic firms. However, the results of empirical studies that have sought to document these spillovers have been mixed. One explanation for this variation is that the capacity of domestic firms to absorb spillovers might vary. In the present paper, we explore these issues in the case of China. ,4side from being one of the world's leading hosts offoreign direct investment, China makes for an interesting case study because its provinces vary greatly with respect to those factors most commonly held to influence absorptive capacity, such as the initial level of technology in domestic firms. This paper begins by empirically establishing that the spillovers from foreign direct investment do indeed vary across provinces. Threshold values for varioas factors that influence absorptive capacity factors are then estimated and it is found that conditions in many provinces presently fall short of these values. This provides an obvious focus of attention for China's policy-makers. 展开更多
关键词 Data Envelopment Analysis foreign direct investment productivity spillovers threshold effects
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Development?A Study based on Spatial Effects and Threshold Characteristics
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作者 ZHANG Shengwu GE Yumeng +1 位作者 LI Xiaosheng HUANG Chaoqun 《Journal of Resources and Ecology》 CSCD 2024年第4期1094-1105,共12页
As a pivotal element within the modern service industry,tourism possesses the capacity to reconfigure regional economic dynamics,alter resource flow patterns,and notably influence urban green development.By establishi... As a pivotal element within the modern service industry,tourism possesses the capacity to reconfigure regional economic dynamics,alter resource flow patterns,and notably influence urban green development.By establishing an evaluation index system for urban green development across 60 prefecture-level cities within the Yellow River Basin from 2006 to 2021,this study employs the spatial Durbin model to delve into the nonlinear relationship between the tourism economy and urban green development.Furthermore,it investigates the heterogeneous impact of the tourism economy on green development across varying levels of urbanization.This study reveals several key findings:(1)Both tourism economy and urban green development exhibit significant spatial clustering,with tourism economy showing“midstream>downstream>upstream”and urban green development showing“downstream>midstream>upstream”.(2)The tourism economy exerts a non-linear positive influence on the green development of cities,characterized by a non-linear inverted“S”shape in its direct impact and a nonlinear“S”shape in its indirect impact.(3)As urbanization rate level escalate,the positive influence of the tourism economy on urban green development follows a non-linear trajectory,initially declining before ascending.Specifically,when the urbanization rate level is below the first threshold value,the tourism economy notably promotes urban green development.However,between the first and second threshold values,this positive impact diminishes,only to rebound beyond the second threshold value. 展开更多
关键词 tourism economy urban green development the Yellow River Basin spatial Durbin model threshold effect model
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Impact of coupling coordination development of port and city environments on urban economic competitiveness:Evidence from the coastal port cities in eastern China
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作者 LI Zhen-qiang YI Ying +2 位作者 LI Jia-li YOU Xiao-yue ZHOU Qiu-yang 《Ecological Economy》 2024年第1期53-71,共19页
Promoting the coupling coordination development of port and its hinterland city environments is an important way to improve urban economic competitiveness.Based on relevant data of 13 coastal port cities in eastern Ch... Promoting the coupling coordination development of port and its hinterland city environments is an important way to improve urban economic competitiveness.Based on relevant data of 13 coastal port cities in eastern China from 2000 to 2018,this study explores the coupling coordination development of port and city environments and its impact on urban economic competitiveness by constructing the coupling coordination degree model and the panel threshold model.The research results show that:(1)In terms of the coupling coordination development of port and city environments,most coastal ports and their hinterland cities are in a state of moderate or serious disorder.Overall,the degree of coupling coordination of port and city environments needs to be further improved;(2)The coupling coordination degree of port and city environments has a significant impact on urban economic competitiveness,and this effect gradually increases with the development of the ports and the urban economy.Among the variables that impact the urban economic competitiveness,fixed assets investment and foreign trade are significant factors that can enhance urban economic competitiveness.(3)At present,there is a“U-shaped”relationship between the coupling coordination degree of port-city environments and the urban economic competitiveness.This relationship lies on the right side of the inflection point of the“U-shaped”curve.Therefore,following the concept of assigning priority to ecological development,expanding fixed assets investment and actively developing foreign trade can further enhance the urban economic competitiveness. 展开更多
关键词 coastal ports city environments coupling coordination degree urban economic competitiveness threshold effect
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Does China's digital economy contribute to low-carbon transition?
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作者 LI Jun-jun HUANG Xin-yu +2 位作者 CHEN Mu ZHANG Meng-jiang ZHANG Zhen 《Ecological Economy》 2024年第2期102-122,共21页
The digital economy,as a new emerging economic form,has become an important power for realizing Chinese-style modernization and promoting green development in China.This paper measures the digital economy and low-carb... The digital economy,as a new emerging economic form,has become an important power for realizing Chinese-style modernization and promoting green development in China.This paper measures the digital economy and low-carbon transition index based on the data of 30 provinces in China from 2013 to 2020 and analyzes the mechanism and path of the digital economy affecting low-carbon transition using the fixed effect panel data model and the threshold effect model.It is found that,(1)The digital economy and low-carbon transition in China are various in different regions,with characteristics of being unbalanced and insufficient.(2)The digital economy significantly promotes low-carbon transition,with the greatest influence in the Central region,followed by the Eastern region and the Western region.Under different dimensions,the development of informatization and digital transactions promote low-carbon transition,but the development of the internet plays an inhibiting role.(3)The higher the degree of urbanization and environmental regulation,the greater the influence of the digital economy on low-carbon transition. 展开更多
关键词 digital economy low-carbon transition threshold effect model instrumental variables quantile regression
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Tourism dependence and poverty alleviation thresholds in Chinese ethnic tourism
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作者 LI Ya-juan OUYANG Chen-xing +2 位作者 ZHOU Sheng-yu YU Hu KNIGHT W David 《Journal of Mountain Science》 SCIE CSCD 2022年第10期3026-3036,共11页
Questions persist on the relationship between tourism dependence and economic growth in ethnic tourism areas.This study addresses such gaps by constructing a threshold regression model based on socio-economic data fro... Questions persist on the relationship between tourism dependence and economic growth in ethnic tourism areas.This study addresses such gaps by constructing a threshold regression model based on socio-economic data from 2006 to 2019 for nine sites in Enshi Prefecture of central China.Arc GIS and other open-source data were also used to visualize changing tourism resources in the region.Findings suggest that tourism dependence(the ratio of tourism-based GDP to overall GDP)significantly promotes economic growth in ethnic minority areas.However,the positive influence of tourism dependence on economic growth appears dynamic and non-linear–rising at first before falling when tourism dependence exceeded a threshold of 34%,with effects varying by site and year.Methods and findings make crucial theoretical contributions to understanding tourism dependence and poverty alleviation linkages.This paper also highlights the importance of political support and balanced investment in diverse industries to minimize decreasing returns beyond tourism dependence thresholds in destinations worldwide. 展开更多
关键词 Ethnic tourism Tourism dependence Economic growth threshold effects Poverty alleviation threshold regression model
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Sustainability of Public Debt and Economic Growth in Cote d’Ivoire:is There a Threshold Effect?
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作者 Koffi Pokou 《Journal of Economic Science Research》 2020年第3期1-12,共12页
The development of Ivorian public debt in recent years has raised concerns.Is its current level capable of boosting the economy or,on the contrary,being at the source of a recession?This paper analyzes the effect of t... The development of Ivorian public debt in recent years has raised concerns.Is its current level capable of boosting the economy or,on the contrary,being at the source of a recession?This paper analyzes the effect of the level of indebtedness on economic growth in Côte d’Ivoire using the Threshold Autoregressive(TAR)model over the period 1970-2018.The results obtained in the short run shed light on the no relationship between public debt and economic growth.In the long run,on the other hand,there is a bi-directional granger causality between public debt and the sustainability of economic growth.The non-linearity between the variables of interest has been studied and the results show the presence of a threshold effect:beyond 48.03 percent of GDP,any increase in public debt by 1%should reduce economic growth by 0.28%.Thus,the study questions the relevance of the criterion set by the WAEMU:public debt<70%of GDP. 展开更多
关键词 Public debt and growth sustainability threshold Autoregressive(TAR) Granger causality threshold effects
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Fiscal Expenditure Structure and Environmental Pollution:Empirical Research Based on the Panel Threshold Model
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作者 Deng Yanlong 《Meteorological and Environmental Research》 CAS 2018年第1期32-37,共6页
Based on China's provincial panel data from 2004 to 2014,the net effect and threshold characteristics of local governments' fiscal expenditure structure on environmental pollution were tested with the nonlinear pane... Based on China's provincial panel data from 2004 to 2014,the net effect and threshold characteristics of local governments' fiscal expenditure structure on environmental pollution were tested with the nonlinear panel threshold model. The results showed that the net effect of fiscal expenditure structure on regional pollution emission intensity had significant inverted V-shaped single threshold characteristics. Besides,the threshold value of economic density was 6. 039 6 million yuan/km^2,and that of population density was 201 people/km^2. That is,the fiscal expenditure structure inclining to productive expenditure was relatively conducive to the promotion of pollution reduction in the areas with low economic density or low population density. The fiscal expenditure structure inclining to non-productive expenditure was relatively conducive to the promotion of pollution reduction in the areas with high economic density or high population density. 展开更多
关键词 Fiscal expenditure structure Pollution reduction threshold effect
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Research on the Impact of Financial Development on TFP—— DEA-Malmquist Index and Hansen Threshold Model Based on Panel Data of Shandong Province, China
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作者 Fushuai Wang Ruichao Xi Wenxia Cai 《Journal of Finance Research》 2020年第2期71-79,共9页
Shandong’s TFP growth is higher than Chinese average,but the growth rate has slowed in recent years,appearing the phenomenon that the growth momentum of Shandong’s TFP is insufficient.Using DEA-Malmquist Index to me... Shandong’s TFP growth is higher than Chinese average,but the growth rate has slowed in recent years,appearing the phenomenon that the growth momentum of Shandong’s TFP is insufficient.Using DEA-Malmquist Index to measure Shandong’s TFP growth rate,empirical research from the perspective of financial development finds that financial scale,efficiency of financial institutions,fiscal intervention,and scale of foreign capital utilization have significant nonlinear effects on the growth of TFP.Furtherly,through threshold analysis,the efficiency of financial institutions has a significant threshold effect on TFP growth.Financial scale and fiscal intervention are the main core variables that affect the growth of TFP under the threshold effect,and they have the same effect direction on TFP before and after the threshold value.However,the effect intensity of these two core variables on TFP is different. 展开更多
关键词 TFP Financial development Economic growth threshold effect
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Effect of β_3-adrenoceptors on Ventricle Fibrillation Threshold and Effective Refractory Period in Rats With Heart Failure
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作者 Deng Yijun Wu Wei Huang Zhibing Fang Chang 《South China Journal of Cardiology》 CAS 2006年第2期73-77,共5页
Objectives To observe the effect of β3-Adrenoceptor (AR) on ventricle fibrillation threshold (VFT) and effective refractory period (ERP) in rats with heart failure. Methods Rats were randomized into control gro... Objectives To observe the effect of β3-Adrenoceptor (AR) on ventricle fibrillation threshold (VFT) and effective refractory period (ERP) in rats with heart failure. Methods Rats were randomized into control group and heart failure group. The expression of β3-ARmRNA was detected with RTPCR; The VFT, ERP, LVESP,LVEDP, +dp/dtmax and -dp/dtmax was measured at the same time with administration of BRL37344 ( 2 nmol / kg, β3- AR agonist). Results ①Both the expression of β3-AR mRNA and the proportion increased in rats with heart failure in comparison with control rats (0.028 vs. 0.011 and 5.4% vs 1.2%, P 〈 0.05);② ERP was longer in rats with heart failure than control group (70.5±5.5 ms vs 59.5±6.4ms, P 〈 0.05) and there was no difference of ERP in rats with heart failure with administration of BRL37344 (73.0±4.8 ms vs 70.5± 5.5 ms, P 〉0.05); ③VFT was lower in rats with heart failure than control group(10.9±0.8 mv vs 30.5± 1.3 mv, P〈 0.05) and decreased obviously in rats with heart failure with administration of BRL37344 (7.1±0.6 mv vs 10.9±0.8 mv, P 〈 0.05) ; The decrease of VFT correlated with the effect on LVESP, +dp/ dtmax,-dp/dtmax of BRL37344 and the expression of β3-AR mRNA (correlation coefficient: 0.788, 0.708, 0.759, 0.787; P 〈 0.05). Conclusions The expression of β3-AR mRNA of left ventricle was obviously increased in rats with heart failure, and activation of β3-AR had no effect on ERP but could decreased VFT which correlated with the effect of β3-AR on LVESP, +dp/dtmax, -dp/dtmax and the expression of β3-AR mRNA. 展开更多
关键词 β3-adrenoceptors Ventricle fibrill-ation threshold Effective refractory period
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A 0.6 μm CMOS bandgap voltage reference circuit
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作者 梁帮立 王志功 +5 位作者 田俊 冯军 夏春晓 胡艳 张丽 熊明珍 《Journal of Southeast University(English Edition)》 EI CAS 2003年第3期221-224,共4页
On the basis of mutual compensation of mobility and threshold voltage temperature effects, a stable CMOS band-gap voltage reference circuit was designed and fabricated in CSMC-HJ 0.6 μm CMOS technology. Operating fro... On the basis of mutual compensation of mobility and threshold voltage temperature effects, a stable CMOS band-gap voltage reference circuit was designed and fabricated in CSMC-HJ 0.6 μm CMOS technology. Operating from 0 to 85 ℃ under a supply voltage ranging from 4.5 to 5.5 V, the voltage reference circuit offers an output reference voltage ranging from 1.122 to 1.176 V and a voltage variation less than ±3.70%. The chip size including bonding pads is only 0.4 mm×0.4 mm and the power dissipation falls inside the scope of 28.3 to 48.8 mW operating at a supply voltage of 4.5 to 5.5 V. 展开更多
关键词 CMOS mutual compensation mobility and threshold voltage temperature effects
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The Effects of Tourism Industry Agglomeration on Tourism Environmental Carrying Capacity: Evidence from a Panel Threshold Model 被引量:3
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作者 LIU Jia LI Jing AN Keke 《Journal of Resources and Ecology》 CSCD 2022年第6期1037-1047,共11页
By utilizing the panel data of 26 cities in the Yangtze River Delta urban agglomeration of China from 2000 to 2018, this study constructs a panel threshold model to examine the nonlinear relationship between Tourism E... By utilizing the panel data of 26 cities in the Yangtze River Delta urban agglomeration of China from 2000 to 2018, this study constructs a panel threshold model to examine the nonlinear relationship between Tourism Environmental Carrying Capacity(TECC) and Tourism Industry Agglomeration(TIA). TECC is evaluated based on the Driver-Pressure-State-Impact-Response(DPSIR) model, and TIA is estimated by the location quotient index.The analysis reveals that TIA and TECC both show growth trends and significant regional differences among the 26cities, but the latter fluctuates at certain stages. Moreover, TIA has a significant double threshold effect on TECC,which shows that the positive impact of TIA is enhanced initially but then weakens afterwards. Theoretically, this study contributes to enriching the current literature on TECC from the perspective of TIA. Practically, it could help local governments effectively arrange agglomerations to promote the sustainable development of the tourism industry in China. 展开更多
关键词 tourism environmental carrying capacity tourism industry agglomeration panel threshold effect Yangtze River Delta urban agglomeration of China
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THE ROLE OF CONNEXIN 43 GENE IN ACUPUNCTURE ANALGESIA
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作者 余炜昶 黄光英 +1 位作者 张明敏 王伟 《World Journal of Acupuncture-Moxibustion》 2007年第3期17-23,共7页
Objective To and connexin 43. Methods investigate the possible relationship between the analgesic effect of acupuncture Connexin 43 gene knock-out mice were randomly divided into 4 groups: a wide type (WT) control ... Objective To and connexin 43. Methods investigate the possible relationship between the analgesic effect of acupuncture Connexin 43 gene knock-out mice were randomly divided into 4 groups: a wide type (WT) control group, a WT acupuncture group, a heterozygous (HT) control group and HT acupuncture group. Hot-plate test and writhing response induced by acetic acid were used for investigating the different analgesic effect of acupuncture on HT and WT mice. Results There was no significant difference in the basic pain threshold value between HT and WT mice (P 〉0.05). Acupuncture could significantly increase the pain threshold value, prolong the latency period of writhing body and decrease the number of writhing body as compared with pre-acupuncture in WT and HT mice (P 〈 0.01 or P 〈 0.05). The pain threshold, latency period of writhing and number of writhing body in HT mice were less than WT mice post-acupuncture (P〈0.05). Conclusion Connexin 43 gene knock-out might partially inhibit the analgesic effect of acupuncture, suggesting that connexin 43 is possibly related with meridians and the effect of acupuncture. 展开更多
关键词 Connexin 43/acupuncture effect Pain threshold/acupuncture effect Acupuncture Analgesia
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Capital Account Openness,Exchange Rate Volatility and Economic Growth:International Experiences and Implications 被引量:1
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作者 李丽玲 王曦 《China Economist》 2017年第6期69-85,共17页
Based on the Barro classical growth model, this paper introduces capital account openness and exchange rate volatility to conduct an empirical analysis using the panel data of 182 countries(regions) during 1970-2013 t... Based on the Barro classical growth model, this paper introduces capital account openness and exchange rate volatility to conduct an empirical analysis using the panel data of 182 countries(regions) during 1970-2013 to examine the combined effects of capital account openness and exchange rate risks on economic growth. Our findings are as follows:(1) Without considering exchange rate volatility, capital account openness is subject to a threshold effect, i.e. capital account openness significantly promotes the economic growth of middle-and high-income countries but exerts the opposite effect on low-income countries; and(2) after exchange rate volatility is taken into account, the growth effect of capital account openness is reduced and the greater the exchange rate volatility is, the smaller the marginal effect of capital account openness will be; sample-specific results also proved the existence of the threshold effect. This paper offers the following implications:(1) The effect of capital account openness can be better examined based on risk factors;(2) moderately controlling exchange rate volatility is conducive to acquiring greater benefits from capital account openness; and(3) the threshold effect of capital account openness cannot be overlooked. 展开更多
关键词 capital account openness exchange rate volatility threshold effect economicgrowth
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Soil microbial communities regulate the threshold effect of salinity stress on SOM decomposition in coastal salt marshes 被引量:2
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作者 Guangliang Zhang Junhong Bai +5 位作者 Jia Jia Wei Wang Dawei Wang Qingqing Zhao Chen Wang Guozhu Chen 《Fundamental Research》 CSCD 2023年第6期868-879,共12页
Salinity stress is one of the critical environmental drivers of soil organic matter(SOM)decomposition in coastal ecosystems.Although the temperature sensitivity(Q_(10))of SOM decomposition has been widely applied in E... Salinity stress is one of the critical environmental drivers of soil organic matter(SOM)decomposition in coastal ecosystems.Although the temperature sensitivity(Q_(10))of SOM decomposition has been widely applied in Earth system models to forecast carbon processes,the impact of salinity on SOM decomposition by restructuring microbial communities remains uncovered.Here,we conducted a microcosm experiment with soils collected from the coastal salt marsh in the Yellow River Estuary,which is subjected to strong dynamics of salinity due to both tidal flooding and drainage.By setting a gradient of salt solutions,soil salinity was adjusted to simulate salinity stress and soil carbon emission(CO_(2))rate was measured over the period.Results showed that as salinity increased,the estimated decomposition constants based on first-order kinetics gradually decreased at different temperatures.Below the 20‰salinity treatments,which doubled the soil salinity,Q_(10)increased with increasing salinity;but higher salinity constrained the temperature-related response of SOM decomposition by inhibiting microbial growth and carbon metabolisms.Soil bacteria were more sensitive to salinity stress than fungi,which can be inferred from the response of microbial beta-diversity to changing salinity.Among them,the phylotypes assigned to Gammaproteobacteria and Bacilli showed higher salt tolerance,whereas taxa affiliated with Alphaproteobacteria and Bacteroidota were more easily inhibited by the salinity stress.Several fungal taxa belonging to Ascomycota had higher adaptability to the stress.As the substrate was consumed with the incubation,bacterial competition intensified,but the fungal co-occurrence pattern changed weakly during decomposition.Collectively,these findings revealed the threshold effect of salinity on SOM decomposition in coastal salt marshes and emphasized that salt stress plays a key role in carbon sequestration by regulating microbial keystone taxa,metabolisms,and interactions. 展开更多
关键词 Salt marshes Salinity stress Soil organic matter decomposition Temperature sensitivity threshold effect Microbial community
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Tuning SnO_2 surface with CuO for soot particulate combustion: The effect of monolayer dispersion capacity on reaction performance
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作者 Jiating Shen Xiaohui Feng +7 位作者 Rui Liu Xianglan Xu Cheng Rao Jianjun Liu Xiuzhong Fang Chao Tan Youchang Xie Xiang Wang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第6期905-916,共12页
With the objective to investigate the structure-reactivity relationship of CuO/SnO2 and eventually design more applicable catalysts for soot combustion,catalysts with different CuO loadings have been prepared by impre... With the objective to investigate the structure-reactivity relationship of CuO/SnO2 and eventually design more applicable catalysts for soot combustion,catalysts with different CuO loadings have been prepared by impregnation method.By using X-ray diffraction and X-ray photoelectron spectroscopy extrapolation methods,it is disclosed that CuO disperses finely on the SnO2 support to form a monolayer with a capacity of 2.09 mmol 100 m^-2,which equals 4.8 wt%CuO loading.When the CuO loading is below the capacity,it is in a sub-monolayer state.However,when the loading is above the capacity,CuO micro-crystallites will be formed that coexist with the CuO monolayer.The soot combustion activity of the catalyst increases with the CuO loading until it reaches the monolayer dispersion capacity.A further increase in the CuO loading has no evident influence on the activity.Raman results have testified that with the addition of CuO onto the SnO2 support,a surface-active oxygen species can be formed,the amount of which also increases significantly with the increase in the CuO loading until it reaches the monolayer dispersion capacity.Increasing the CuO loading further has no evident impact on the amount of surface oxygen.Therefore,an apparent monolayer dispersion threshold effect is observed for soot combustion over CuO/SnO2 catalysts.It is concluded that the amount of surface-active oxygen sites is the major factor determining the activity of the catalyst. 展开更多
关键词 CuO supported on SnO2 Soot particulate combustion Monolayer dispersion X-ray diffraction and X-ray photoelectron spectroscopy extrapolation threshold effect
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Investigation of lattice capacity effect on Cu2+-doped SnO2 solid solution catalysts to promote reaction performance toward NOx-SCR with NH3
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作者 Xianglan Xu Yunyan Tong +7 位作者 Jingyan Zhang Xiuzhong Fang Junwei Xu Fuyan Liu Jianjun Liu Wei Zhong Olga ELebedeva Xiang Wang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2020年第5期877-888,共12页
To understand the effect of the doping amount of Cu^2+ on the structure and reactivity of SnO2 in NOx-SCR with NH3, a series of Sn-Cu-O binary oxide catalysts with different Sn/Cu ratios have been prepared and thoroug... To understand the effect of the doping amount of Cu^2+ on the structure and reactivity of SnO2 in NOx-SCR with NH3, a series of Sn-Cu-O binary oxide catalysts with different Sn/Cu ratios have been prepared and thoroughly characterized. Using the XRD extrapolation method, the SnO2 lattice capacity for Cu^2+ cations is determined at 0.10 g Cu O per g of SnO2, equaling a Sn/Cu molar ratio of 84/16. Therefore, in a tetragonal rutile SnO2 lattice, only a maximum of 16% of the Sn4+ cations can be replaced by Cu^2+ to form a stable solid solution structure. If the Cu content is higher, Cu O will form on the catalyst surface, which has a negative effect on the reaction performance. For samples in a pure solid solution phase, the number of surface defects increase with increasing Cu content until it reaches the lattice capacity, as confirmed by Raman spectroscopy. As a result, the amounts of both active oxygen species and acidic sites on the surface, which critically determine the reaction performance, also increase and reach the maximum level for the catalyst with a Cu content close to the lattice capacity. A distinct lattice capacity threshold effect on the structure and reactivity of Sn-Cu binary oxide catalysts has been observed. A Sn-Cu catalyst with the best reaction performance can be obtained by doping the SnO2 matrix with the lattice capacity amount of Cu^2+. 展开更多
关键词 SnO2-based solid solution Lattice capacity of Cu^2+ XRD extrapolation method NOx-SCR with NH3 threshold effect
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A Monte Carlo Simulation of Radiation Damage of SiC and Nb Using JA-IPU Code 被引量:1
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作者 Nagendra Singh Raghaw Vinod Kumar +2 位作者 Ambika Tundwal Yury Korovin Jindrich Adam 《Journal of Energy and Power Engineering》 2015年第11期967-975,共9页
MC (Monte Carlo) simulation code, JA-IPU is used to study radiation damage of SiC irradiated to spallation neutron and AmBe neutron spectra. The code is based on the major physical processes of radiation damage on i... MC (Monte Carlo) simulation code, JA-IPU is used to study radiation damage of SiC irradiated to spallation neutron and AmBe neutron spectra. The code is based on the major physical processes of radiation damage on incorporation of atomic collision cascade and limited to 10 MeV neutron energy. A phenomenological relation for radiation swelling is also derived. Based on the calculation of swelling, DPA (displacement per atom), defect production efficiency and effective threshold energy, Efff from the data of MC simulation, SiC is inferred to be a highly radiation resistant material when compared with Nb and Ni metals which are used in composition of several reactor steels. Experimental results of hill-hock density measured using AFM (atomic force microscopy), also confirm radiation resistant behavior of SiC. 展开更多
关键词 Monte-Carlo simulation radiation resistant material DPA effective damage threshold energy.
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