High-temperature titanium alloy for aeroengine compressor applications suffers from high-temperature oxidation and environmental corrosion, which prohibits long-term service of this kind alloy at temperatures above 60...High-temperature titanium alloy for aeroengine compressor applications suffers from high-temperature oxidation and environmental corrosion, which prohibits long-term service of this kind alloy at temperatures above 600℃. In an attempt to tackle this problem, Ti-48Al （at. pct） and Ti-48Al-12Cr （at. pct） protective coatings were plated on the substrate of alloy Ti-60 by arc ion plating （ALP） method. Isothermal and cyclic oxidation tests were performed in static air at elevated temperatures. Phase composition, morphology of the coatings and distribution of elements were investigated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and energy dispersive X-ray analysis （EDX）. The results showed that the Ti-48Al coating exhibited good isothermal oxidation resistance during exposure at 800℃, but poorer resistance against oxidation at 900℃. By contrast Ti-48Al-12Cr coating demonstrated excellent isothermal oxidation resistance at both temperatures. Cyclic oxidation tests performed at 800℃ indicated that resistance and no spallation of coatings was observed. But both coatings demonstrated good cyclic oxidation at 900℃ only Ti-48Al-12Cr coating demonstrated excellent cyclic oxidation resistance.展开更多
The effect of sputtered Ti-50Al-10Cr and Ti-50A1-20Cr coatings on both isothermal and cyclic oxidation resistance at 800-900℃ and hot corrosion resistance at 850℃ of Ti-24Al-14Nb-3V was investigated. Results indicat...The effect of sputtered Ti-50Al-10Cr and Ti-50A1-20Cr coatings on both isothermal and cyclic oxidation resistance at 800-900℃ and hot corrosion resistance at 850℃ of Ti-24Al-14Nb-3V was investigated. Results indicated that Ti-24Al-14Nb-3V alloys exhibited poor oxidation resistance due to the formation of Al2O3+TiO2+AlNbO4 mixed scales in air at 800-900℃ and poor hot corrosion resistance due to the spoliation of scales formed in Na2SO4+K2SO4 melts at 850℃. Both Ti-50Al-10Cr and Ti-50Al-20Cr coatings remarkably improved the oxidation and hot corrosion resistance of Ti-24Al-14Nb-3V alloy.展开更多
A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathemat...A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathematical model of the filling process is established and the forming mechanism of internal gaseous defect is summarized. The results of calculation show that the melt fills the mould with varying cross-section area and inclined angle. The filling speed of the cross-section is a function of filling time. The cross-section area is directly proportional to the filling speed and the inclined angle is inversely proportional to the filling speed at a given rotating speed of the platform. Both of them changes more obvious near the mould entrance. The gaseous defect can be formed in several ways and the centrifugal field has an important influence on the formation of the defect. In addition, the filling process in centrifugal field has been verified by wax experiments and the theoretical analysis are consistent with experimental results.展开更多
The microstructures of the siliconized specimens of Ti-48Al alloy were analyzed by SEM equipped with XEDS. The specimens were pack siliconized with the two different cementations, 15%Si+85% A12O3 and 15%Si+85%ZrO2. Th...The microstructures of the siliconized specimens of Ti-48Al alloy were analyzed by SEM equipped with XEDS. The specimens were pack siliconized with the two different cementations, 15%Si+85% A12O3 and 15%Si+85%ZrO2. The results show that a composite siliconized layer is formed on the surface of the TiAl alloy. The outer layer is the continuous A12O3 where a lot of Si particles adhered; the inner layer is most of Ti5Si3 with amount of ALjOs particles dispersed in. It was deduced that the A12O3 in the cementation layer is formed by the Al atoms in the TiAl substrate react with the residual O in the furnace and in the TiAl substrate.展开更多
The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA)...The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA) was conducted for the characterization of oxidation kinetics. The microstructures of oxide scales were studied by scanning electron microscopy (SEM) and transmission election microscopy (TEM) techniques. Unfavorable effect of the annealing treatment on the oxidation behavior of the coating was also investigated. The results indicate that the oxidation behavior of the alloy is influenced by surface finish and annealing treatment. The oxidation rate of ground sample is lower than that of the polished alloy at 1 000 ℃ in air. The former forms a scale of merely Al2O3, and the latter forms a scale of the mixture of Al2O3 and TiO2. Annealing can improve the formation of TiO2.展开更多
文摘High-temperature titanium alloy for aeroengine compressor applications suffers from high-temperature oxidation and environmental corrosion, which prohibits long-term service of this kind alloy at temperatures above 600℃. In an attempt to tackle this problem, Ti-48Al （at. pct） and Ti-48Al-12Cr （at. pct） protective coatings were plated on the substrate of alloy Ti-60 by arc ion plating （ALP） method. Isothermal and cyclic oxidation tests were performed in static air at elevated temperatures. Phase composition, morphology of the coatings and distribution of elements were investigated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and energy dispersive X-ray analysis （EDX）. The results showed that the Ti-48Al coating exhibited good isothermal oxidation resistance during exposure at 800℃, but poorer resistance against oxidation at 900℃. By contrast Ti-48Al-12Cr coating demonstrated excellent isothermal oxidation resistance at both temperatures. Cyclic oxidation tests performed at 800℃ indicated that resistance and no spallation of coatings was observed. But both coatings demonstrated good cyclic oxidation at 900℃ only Ti-48Al-12Cr coating demonstrated excellent cyclic oxidation resistance.
文摘The effect of sputtered Ti-50Al-10Cr and Ti-50A1-20Cr coatings on both isothermal and cyclic oxidation resistance at 800-900℃ and hot corrosion resistance at 850℃ of Ti-24Al-14Nb-3V was investigated. Results indicated that Ti-24Al-14Nb-3V alloys exhibited poor oxidation resistance due to the formation of Al2O3+TiO2+AlNbO4 mixed scales in air at 800-900℃ and poor hot corrosion resistance due to the spoliation of scales formed in Na2SO4+K2SO4 melts at 850℃. Both Ti-50Al-10Cr and Ti-50Al-20Cr coatings remarkably improved the oxidation and hot corrosion resistance of Ti-24Al-14Nb-3V alloy.
文摘A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathematical model of the filling process is established and the forming mechanism of internal gaseous defect is summarized. The results of calculation show that the melt fills the mould with varying cross-section area and inclined angle. The filling speed of the cross-section is a function of filling time. The cross-section area is directly proportional to the filling speed and the inclined angle is inversely proportional to the filling speed at a given rotating speed of the platform. Both of them changes more obvious near the mould entrance. The gaseous defect can be formed in several ways and the centrifugal field has an important influence on the formation of the defect. In addition, the filling process in centrifugal field has been verified by wax experiments and the theoretical analysis are consistent with experimental results.
基金supported by the National Natural Science Foundation of China(No.50171046)the Natural Science Foundation of Shanxi Province,China(No.20021051)
文摘The microstructures of the siliconized specimens of Ti-48Al alloy were analyzed by SEM equipped with XEDS. The specimens were pack siliconized with the two different cementations, 15%Si+85% A12O3 and 15%Si+85%ZrO2. The results show that a composite siliconized layer is formed on the surface of the TiAl alloy. The outer layer is the continuous A12O3 where a lot of Si particles adhered; the inner layer is most of Ti5Si3 with amount of ALjOs particles dispersed in. It was deduced that the A12O3 in the cementation layer is formed by the Al atoms in the TiAl substrate react with the residual O in the furnace and in the TiAl substrate.
基金Project(2007430028) supported by the Science and Technique Foundation of Henan Educational Committee, China
文摘The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA) was conducted for the characterization of oxidation kinetics. The microstructures of oxide scales were studied by scanning electron microscopy (SEM) and transmission election microscopy (TEM) techniques. Unfavorable effect of the annealing treatment on the oxidation behavior of the coating was also investigated. The results indicate that the oxidation behavior of the alloy is influenced by surface finish and annealing treatment. The oxidation rate of ground sample is lower than that of the polished alloy at 1 000 ℃ in air. The former forms a scale of merely Al2O3, and the latter forms a scale of the mixture of Al2O3 and TiO2. Annealing can improve the formation of TiO2.
