A lipophilic silica/metatitantic acid（denoted as Si O2/H2 TiO 3） nanocomposite was synthesized by hydrothermal reaction with surface-modified Si O2 as the lipophilic carrier. As-synthesized Si O2/H2 TiO 3nanocomposi...A lipophilic silica/metatitantic acid（denoted as Si O2/H2 TiO 3） nanocomposite was synthesized by hydrothermal reaction with surface-modified Si O2 as the lipophilic carrier. As-synthesized Si O2/H2 TiO 3nanocomposite was used as a catalyst to promote the aquathermolysis reaction of extra-heavy crude oil thereby facilitating the recovering from the deep reservoirs at lowered temperature. The catalytic performance of the as-synthesized Si O2/H2 TiO 3catalyst for the aquathermolysis reaction of the heavy oil at a moderate temperature of 150 °C was evaluated in relation to the structural characterizations by TEM,FTIR,XRD and FESEM as well as the determination of the specific surface area by N2adsorption–desorption method. Findings indicate that as-synthesized Si O2/H2 TiO 3nanocomposite exhibits an average size of about 20 nm as well as good lipophilicity and dispersibility in various organic solvents; and it shows good catalytic performance for the aquathermolysis reaction of the extra-heavy oil extracted from Shengli Oilfield of China. Namely,the assynthesized Si O2/H2 TiO 3catalyst is capable of significantly reducing the viscosity of the tested heavy oil from58,000 c P to 16,000 c P（referring to a viscosity reduction rate of 72.41%） at a mass fraction of 0.5%,a reaction temperature of 150 °C and a reaction time of 36 h,showing potential application in downhole upgrading heavy crude oils.展开更多
Hexagonal NaYF4:Yb3+,Er3+ (β-NaYF4:Yb3+,Er3+) nanoparticles supported on TiO2 nanobelts were prepared using two-step pro- cedures of ion-exchangeable process and hydrothermal treatment: layered titanate nanobelts wer...Hexagonal NaYF4:Yb3+,Er3+ (β-NaYF4:Yb3+,Er3+) nanoparticles supported on TiO2 nanobelts were prepared using two-step pro- cedures of ion-exchangeable process and hydrothermal treatment: layered titanate nanobelts were first ion-exchanged with Y3+, Yb3+ and Er3+ cations to produce titanate nanobelts with these cations, and then, the product nanobelts in NaY solution were treated under hydrothermal con- dition to transform into anatase TiO2 nanobelts supported with β-NaYF4:Yb3+,Er3+ nanoparticles. The final p...展开更多
Cobalt-doped titania(Co-TiO2)nanomaterials were synthesized by the sol–gel method at different calcination temperatures.Using Escherichia coli(a),Staphylococcus aureus(b)and Candida albicans(c)as target strains,the a...Cobalt-doped titania(Co-TiO2)nanomaterials were synthesized by the sol–gel method at different calcination temperatures.Using Escherichia coli(a),Staphylococcus aureus(b)and Candida albicans(c)as target strains,the antibacterial activity in visible light of the nanomaterials were studied.Co-TiO2 nanomaterials were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),UV–Vis diffuse reflectance spectroscopy(DRS),Fourier transform infrared spectrum(FT-IR)and X-ray photoelectron spectroscopy(XPS).The Co ions in the Co-TiO2 nanomaterial exist in the form of CoTiO3 phase.The antibacterial properties of Co-TiO2 nanomaterials on E.coli(a),S.aureus(b)and C.albicans(c)were investigated with the oscillating flask method and the inhibition zone method.The nanomaterials calcined at 600°C exhibit excellent antibacterial activity.The bacteriostatic rates for E.coli,S.aureus and C.albicans reached 99.5%,91.3%and 93.4%respectively.The diameters of the antibacterial rings were up to 36 mm,37 mm,30 mm respectively,and the clarity of the ring was clear.The antibacterial properties of Co-TiO2 nanomaterials were compared with those of traditional silver sol,zinc oxide sol and Zn-doped TiO2 nanomaterials The mechanism of the influences of Co ions doping on the antibacterial activity of TiO2 nanomaterials was also discussed.The doping of Co ions inhibits the particle size of the antibacterial agent and extends the photocatalytic response range,thereby improving the photocatalytic performance of the antibacterial agent.展开更多
基金supported by the National Natural Science Foundation of China (grant Nos.21371047 and 21471047)
文摘A lipophilic silica/metatitantic acid（denoted as Si O2/H2 TiO 3） nanocomposite was synthesized by hydrothermal reaction with surface-modified Si O2 as the lipophilic carrier. As-synthesized Si O2/H2 TiO 3nanocomposite was used as a catalyst to promote the aquathermolysis reaction of extra-heavy crude oil thereby facilitating the recovering from the deep reservoirs at lowered temperature. The catalytic performance of the as-synthesized Si O2/H2 TiO 3catalyst for the aquathermolysis reaction of the heavy oil at a moderate temperature of 150 °C was evaluated in relation to the structural characterizations by TEM,FTIR,XRD and FESEM as well as the determination of the specific surface area by N2adsorption–desorption method. Findings indicate that as-synthesized Si O2/H2 TiO 3nanocomposite exhibits an average size of about 20 nm as well as good lipophilicity and dispersibility in various organic solvents; and it shows good catalytic performance for the aquathermolysis reaction of the extra-heavy oil extracted from Shengli Oilfield of China. Namely,the assynthesized Si O2/H2 TiO 3catalyst is capable of significantly reducing the viscosity of the tested heavy oil from58,000 c P to 16,000 c P（referring to a viscosity reduction rate of 72.41%） at a mass fraction of 0.5%,a reaction temperature of 150 °C and a reaction time of 36 h,showing potential application in downhole upgrading heavy crude oils.
基金Project supported by the "973" Basic Research Foundation of China (2006CB932605)the National Natural Science Foundation of China (20976002)
文摘Hexagonal NaYF4:Yb3+,Er3+ (β-NaYF4:Yb3+,Er3+) nanoparticles supported on TiO2 nanobelts were prepared using two-step pro- cedures of ion-exchangeable process and hydrothermal treatment: layered titanate nanobelts were first ion-exchanged with Y3+, Yb3+ and Er3+ cations to produce titanate nanobelts with these cations, and then, the product nanobelts in NaY solution were treated under hydrothermal con- dition to transform into anatase TiO2 nanobelts supported with β-NaYF4:Yb3+,Er3+ nanoparticles. The final p...
基金the support from the National Natural Science Foundation of China(No.51474056)。
文摘Cobalt-doped titania(Co-TiO2)nanomaterials were synthesized by the sol–gel method at different calcination temperatures.Using Escherichia coli(a),Staphylococcus aureus(b)and Candida albicans(c)as target strains,the antibacterial activity in visible light of the nanomaterials were studied.Co-TiO2 nanomaterials were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),UV–Vis diffuse reflectance spectroscopy(DRS),Fourier transform infrared spectrum(FT-IR)and X-ray photoelectron spectroscopy(XPS).The Co ions in the Co-TiO2 nanomaterial exist in the form of CoTiO3 phase.The antibacterial properties of Co-TiO2 nanomaterials on E.coli(a),S.aureus(b)and C.albicans(c)were investigated with the oscillating flask method and the inhibition zone method.The nanomaterials calcined at 600°C exhibit excellent antibacterial activity.The bacteriostatic rates for E.coli,S.aureus and C.albicans reached 99.5%,91.3%and 93.4%respectively.The diameters of the antibacterial rings were up to 36 mm,37 mm,30 mm respectively,and the clarity of the ring was clear.The antibacterial properties of Co-TiO2 nanomaterials were compared with those of traditional silver sol,zinc oxide sol and Zn-doped TiO2 nanomaterials The mechanism of the influences of Co ions doping on the antibacterial activity of TiO2 nanomaterials was also discussed.The doping of Co ions inhibits the particle size of the antibacterial agent and extends the photocatalytic response range,thereby improving the photocatalytic performance of the antibacterial agent.
