Northeast India has a good deposit of sub-bituminous tertiary coal. The northeast Indian coals have unusual physico-chemical characteristics such as high sulfur, volatile matter and vitrinite content, and low ash cont...Northeast India has a good deposit of sub-bituminous tertiary coal. The northeast Indian coals have unusual physico-chemical characteristics such as high sulfur, volatile matter and vitrinite content, and low ash content. In addition, many environmental sensitive organic and mineral bound elements such as Fe, Mg, Bi, AI, V, Cu, Cd, Ni, Pb, and Mn etc. remain enriched in these coals. Such characteristics are associated with more severe environmental impacts due to mining and its utilization in coal based industries. Environmental challenges include large scale landscape damage, soil erosion, loss of forest ecosystem and wildlife habitat, air, water and soil pollution. Several physical and chemical methods are reported in literature for the removal of mineral matter, total sulfur and different forms of sulfur from high sulfur coal in northeast India. This paper may help different researchers and stakeholders to understand current state of research in the field. Initiatives may be taken towards sustainable use of coal resources by adopting innovative clean technologies and by implementing effective control measures and regulatory policies.展开更多
The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm wa...The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm was achieved. The crushing strength of the agglomerates was determined for good handling of fine （coal-liquid mixture） to improve fugitive dust control, decrease in transportation losses, reduce risk of coal freezing, lower risk of spontaneous combustion, etc. in iron and steel industries, railway corporations and coal corporations. Kerosene （paraffin oil） was used as a binder and the agglomerated coal oil mixture was pelletized using balling technique （disc）. Mechanical and physical tests like compressive strength test, etc. were carried out. The relationship between the bridging liquid surface tension and specific surface area on strength factor of coal agglomerates showed that there is considerable variation in these parameters in the coal powder systems.展开更多
ReaxFF molecular dynamic simulation combined with experimental verification was performed to understand the overall reaction mechanism,especially the primary and secondary reactions involving in tar formation of sub-b...ReaxFF molecular dynamic simulation combined with experimental verification was performed to understand the overall reaction mechanism,especially the primary and secondary reactions involving in tar formation of sub-bituminous coal pyrolysis.Quantitative relationship at atomic level is clarified between bond breakage of functional groups and products generation,revealing that the amount and order in forming each product are subject to the number of corresponding functional groups and their bond energies respectively.The primary breakage of-C-O-and-C-C-bridge-bonds present in initial coal macromolecular generates molecular of heavy tar,whereas heavy tar can be converted into light tar through cracking side chain of aromatic rings and cyclic hydrocarbons at increased pyrolysis temperatures.At very high temperatures the cracking of short-chain hydrocarbons and residual atoms connecting to aromatic rings further occurs to generate light tar and gas.The remaining aromatic-ring fragments of heavy tar are likely cross-linked to form char.Furthermore,the simultaneous evolution tendency of tar yield and tar quality under different pyrolysis temperatures and heating rates is obtained at molecular level.For obtaining high yield and quality of tar,appropriately high temperature as well as suitable heating rate are needed to compromise the high yield of primary tar and high quality of secondarily upgraded products.展开更多
文摘Northeast India has a good deposit of sub-bituminous tertiary coal. The northeast Indian coals have unusual physico-chemical characteristics such as high sulfur, volatile matter and vitrinite content, and low ash content. In addition, many environmental sensitive organic and mineral bound elements such as Fe, Mg, Bi, AI, V, Cu, Cd, Ni, Pb, and Mn etc. remain enriched in these coals. Such characteristics are associated with more severe environmental impacts due to mining and its utilization in coal based industries. Environmental challenges include large scale landscape damage, soil erosion, loss of forest ecosystem and wildlife habitat, air, water and soil pollution. Several physical and chemical methods are reported in literature for the removal of mineral matter, total sulfur and different forms of sulfur from high sulfur coal in northeast India. This paper may help different researchers and stakeholders to understand current state of research in the field. Initiatives may be taken towards sustainable use of coal resources by adopting innovative clean technologies and by implementing effective control measures and regulatory policies.
文摘The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm was achieved. The crushing strength of the agglomerates was determined for good handling of fine （coal-liquid mixture） to improve fugitive dust control, decrease in transportation losses, reduce risk of coal freezing, lower risk of spontaneous combustion, etc. in iron and steel industries, railway corporations and coal corporations. Kerosene （paraffin oil） was used as a binder and the agglomerated coal oil mixture was pelletized using balling technique （disc）. Mechanical and physical tests like compressive strength test, etc. were carried out. The relationship between the bridging liquid surface tension and specific surface area on strength factor of coal agglomerates showed that there is considerable variation in these parameters in the coal powder systems.
基金financially supported by the National Natural Science Foundation of China(Grant No.U1908201)the National Key Research and Development Program of China(Grant No.2018YFC0808500).
文摘ReaxFF molecular dynamic simulation combined with experimental verification was performed to understand the overall reaction mechanism,especially the primary and secondary reactions involving in tar formation of sub-bituminous coal pyrolysis.Quantitative relationship at atomic level is clarified between bond breakage of functional groups and products generation,revealing that the amount and order in forming each product are subject to the number of corresponding functional groups and their bond energies respectively.The primary breakage of-C-O-and-C-C-bridge-bonds present in initial coal macromolecular generates molecular of heavy tar,whereas heavy tar can be converted into light tar through cracking side chain of aromatic rings and cyclic hydrocarbons at increased pyrolysis temperatures.At very high temperatures the cracking of short-chain hydrocarbons and residual atoms connecting to aromatic rings further occurs to generate light tar and gas.The remaining aromatic-ring fragments of heavy tar are likely cross-linked to form char.Furthermore,the simultaneous evolution tendency of tar yield and tar quality under different pyrolysis temperatures and heating rates is obtained at molecular level.For obtaining high yield and quality of tar,appropriately high temperature as well as suitable heating rate are needed to compromise the high yield of primary tar and high quality of secondarily upgraded products.
