Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities,...Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities, planning and control of the flow of information and materials in a firm, management of relationships with other organizations and government intervention, However, crude oil theft and pipeline vandalism are established products supply chain disruptors in Nigeria which are rendering the task of running an efficient petroleum supply chain onerous. This paper aims to establish the importance of effective supply chain strategies for companies in the oil and gas industry with special focus on the Nigerian oil and gas sector and the strategies by which the state oil and gas corporation in this sector may mitigate disruptions to its supply chain. This study investigates the enhancement of supply chain strategies towards meeting the challenge of crude oil theft and pipeline vandalism, using the Nigerian National Corporation (NNPC) as a case study. Based on this study, data were collected from two sources: A summary of incident reports obtained from NNPC and an interview with personnel in the PPMC Department. Incident report refers to a report produced when accidents such as equipment failure, injury, loss of life, or fire occur at the work site. Content analysis is utilized to evaluate data obtained from interview responses, CBN financial stability reports, NDIC annual reports, circulars, banking supervision reports and implementation guidelines. The study found out that NNPC should endeavor to sustain its value chain and ward of pipeline vandals and crude oil thieves by engaging in community partnership, detailing security outfits to ensure its pipelines’ right of way and bridging. Concluded that the oil supply chain of the Nigerian National Petroleum Corporation has been plagued by disruptions in the form of crude oil theft and pipeline vandalism which has had debilitating effects on its value.展开更多
Crude oil spillage is a major challenge in Nigeria. It affects the environment, health, life, and livelihood of residents of the Niger Delta region, where oil is explored, processed, and transported via a network of p...Crude oil spillage is a major challenge in Nigeria. It affects the environment, health, life, and livelihood of residents of the Niger Delta region, where oil is explored, processed, and transported via a network of pipelines. Oil spillage is primarily caused by vandalization/sabotage and operational issues such as corrosion, equipment failure, operation, and maintenance errors. Thus, prompt response is required to mitigate the impact of oil spills. In this study, we deployed low-cost Arduino systems, including sensors (vibration and flow), modules (GPS and Wifi) and an IoT platform (ThingSpeak) to detect spillage caused by vandalism and operational inefficiencies proactively. The results demonstrate that low-cost sensors can detect changes in the flow volume between the inflow and outflow attributable to spillage, and vibration shocks caused by vandalism can be detected and linked to the cause of the spillage and communicated in real time to inform response action. Moreover, we proposed a framework for field validation utilizing KoboToolBox (a crowdsourcing/citizen science platform). The prototype system designed and programmed showed promising results, as it could detect spillage for vandalism and operational scenarios in real-time, quantify the volume of spillage, and identify the location and time of spillage occurrence;indicators relevant for response planning to minimize the impact of oil spillage. A video demonstration of the prototype system developed is accessible via: https://youtu.be/wKa9MZvYf1w. .展开更多
The permafrost along the China-Russia Crude Oil Pipeline(CRCOP) is degrading since the pipeline operation in 2011. Heat dissipated from the pipeline, climate warming and anthropogenic activities leads to permafrost wa...The permafrost along the China-Russia Crude Oil Pipeline(CRCOP) is degrading since the pipeline operation in 2011. Heat dissipated from the pipeline, climate warming and anthropogenic activities leads to permafrost warming. The processes of permafrost warming along the CRCOP were studied based on the monitoring of air and soil temperatures, and electrical resistivity tomography(ERT) surveys. Results show that:(1) the mean annual air temperature(MAAT) in permafrost regions along the CRCOP increased with a rate of 0.21°C/10a–0.40°C/10 a during the past five decades;(2) the mean annual ground temperature(MAGT, at-15 m depth) of undisturbed permafrost increased by 0.2°C and the natural permafrost table remained unchanged due to the zero-curtain effect;(3) permafrost surrounding the uninsulated pipeline right-of-way warmed significantly compared with that in a natural site. During 2012–2017, the MAGT and the artificial permafrost table, 2 m away from the pipeline centerline, increased at rates of 0.063°C/a and 1.0 m/a. The thaw bulb developed around the pipe and exhibits a faster lateral expansion;(4) 80-mm-thick insulation could reduce the heat exchange between the pipeline and underlying permafrost and then keep the permafrost and pipe stable. The MAGT and the artificial permafrost table, 4.8 m away from the center line of the pipeline, increased by 0.3°C/a and 0.43 m/a, respectively. Due to the heat disturbance caused by warm oil, the degradation of wetland, controlled burn each autumn and climate warming, the permafrost extent reduced and warmed significantly along the CRCOP route. Field observations provide basic data to clarify the interactions between CRCOP and permafrost degradation and environmental effects in the context of climate change.展开更多
The most economical way to overcome flow assurance problems associated with transportation of heavy crude oil through offshore pipelines is by emulsifying it with water in the presence of a suitable surfactant.In this...The most economical way to overcome flow assurance problems associated with transportation of heavy crude oil through offshore pipelines is by emulsifying it with water in the presence of a suitable surfactant.In this research,a novel surfactant,tri-triethanolamine monosunflower ester,was synthesized in the laboratory by extracting fatty acids present in sunflower(Helianthus annuus)oil.Synthesized surfactant was used to prepare oil-in-water emulsions of a heavy crude oil from the western oil field of India.After emulsification,a dramatic decrease in pour point as well as viscosity was observed.All the prepared emulsions were found to be flowing even at 1°C.The emulsion developed with 60%oil content and 2wt%surfactant showed a decrease in viscosity of 96%.The stability of the emulsion was investigated at different temperatures,and it was found to be highly stable.The effectiveness of surfactant in emulsifying the heavy oil in water was investigated by measuring the equilibrium interfacial tension(IFT)between the crude oil(diluted)and the aqueous phase along with zeta potential of emulsions.2wt%surfactant decreased IFT by almost nine times that of no surfactant.These results suggested that the synthesized surfactant may be used to prepare a stable oil-in-water emulsion for its transportation through offshore pipelines efficiently.展开更多
On-site monitoring is very important for understanding formation mechanisms of frost hazards frequently occurring in pipeline foundation soils and for designing and deploying according mitigative measures in permafros...On-site monitoring is very important for understanding formation mechanisms of frost hazards frequently occurring in pipeline foundation soils and for designing and deploying according mitigative measures in permafrost regions.Significant thaw subsidence of ground surfaces along the ChinaRussia Crude Oil Pipeline(CRCOP) from Mo'he to Daqing,Heilongjiang Province,Northeast China have been observed at some segments underlain by ice-rich warm(>1.0°C) permafrost since the official operation in January 2011.Recent monitoring results of the thermal states of foundation soils at the kilometer post(KP) 304 site along the CRCOP are presented in this paper.The results indicate that during the period from 2012 to 2014,shallow soils(at the depths from0.8 to 4.0 m from ground surface) has warmed by approximately 1.0°C in the lateral range of 1.2 to 2.1 maway from the pipeline axis,and deeper permafrost(such as at the depth of 15 m,or the depth of zero annual amplitude of ground temperatures) by 0.08°C per year 4 m away from the pipe axis,and 0.07°C per year 5 m away from the pipeline axis.The results indicate an all-season talik has developed around and along the CRCOP.The thaw bulb,with a faster lateral expansion(compared with the vertical growth),enlarges in summer and shrinks in winter.This research will provide important references and bases for evaluating thermal influences of warm pipeline on permafrost and for design,construction,operation and maintenance of pipelines in permafrost regions.展开更多
Active layer is a key component for permafrost environment studies as many subsurface biological,biogeochemical,ecological,and pedogenic activities prevail in this layer.This study focuses on active layer temperature ...Active layer is a key component for permafrost environment studies as many subsurface biological,biogeochemical,ecological,and pedogenic activities prevail in this layer.This study focuses on active layer temperature monitoring in an area with sporadic permafrost at two adjacent sites along China-Russia Crude Oil Pipeline(CRCOP),NorthEast China.Site T1 is located in disturbed ground on the right-of-way(on-ROW)2 m away from the center of the oil pipeline.T2 is located in a natural and undisturbed site,around 16.6 m off-ROW.Our objective was to study seasonal variability of the active layer depth and thermal regime from October 2017 to September 2018.The monitoring sites consist of soil temperature probes arranged in a vertical array at different depths at both sites.The following parameters were computed:number of isothermal days(ID),freezing days(FD),thawing days(TD),freezing degree days(FDD),thawing degree days(TDD),number of freeze-thaw days(FTD).The mean air temperature in the monitoring period reached-3.2℃.The temperature profile indicates that the maximum active layer thickness observed during the study period was 10 m at T1 and 2 m at T2.The majority of the soil temperatures were above or close to 0℃,resulting in great values of TDD,especially in the first 4 m depth.TDD for T1 were predominant and ranged between 600-1160℃·days(0-4 m depth)reflecting the influence of oil temperature from the pipeline.In T2 borehole FDD were predominant for all the soil layer depths resulting in less permafrost degradation.This comparison emphasizes the significant influence of vegetation removal and the dispersed heat from the pipeline on the active layer thickness.展开更多
The cold-region eco-environments along the China-Russia Crude Oil Pipeline (CRCOP) in northern Northeast China are in disequilibrium due to the combined influences of pronounced climate warming and intensive anthropog...The cold-region eco-environments along the China-Russia Crude Oil Pipeline (CRCOP) in northern Northeast China are in disequilibrium due to the combined influences of pronounced climate warming and intensive anthropogenic activities.This is evidenced by the sharp areal reduction and northward shifting of the boreal forests,shrinking of wetlands,enhancing of soil erosion,accelerating degradation of permafrost and deteriorating of cold-region eco-environments.The degradation of permafrost plays an important role as an internal drive in the eco-environmental changes.Many components of the cold-region eco-environments,including frozen ground,forests,wetlands and peatlands,forest fires and 'heating island effect' of rapid urbanization,are interdependent,interactive,and integrated in the boreal ecosystems.The construction and long-term operation of the CRCOP system will inevitably disturb the cold-region environments along the pipeline.Therefore,a mandatory and carefully-elaborated environ-mental impact statement is indispensable for the proper mitigation of the ensued adverse impacts.Proper management,effective protection and practical rehabilitation of the damaged cold-region environments are a daunting,costly and long-term commitment.The recommended measures for protection and restoration of permafrost eco-environments along the pipeline route include adequate investigation,assessment and monitoring of permafrost and cold-region environments,compliance of pipeline construction and operation codes for environmental management,proper and timely re-vegetation,returning the cultivated lands to forests and grasslands,and effective mitigation of forest fire hazards.展开更多
In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance betwee...In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance between two heating stations on the heating energy consumption.To analyze the transportation economy,the two heated crude oil pipelines laid in one ditch are simulated under four operating conditions based on an unstructured finite volume method.Compared with laying two crude oil pipelines separately in two ditches,the results attest notably higher soil temperature,meaning reduced heat dissipation of each pipeline by laying two pipelines in one ditch.It is inferred that for the same desired oil temperature at the inlet of the next heating station,laying two pipelines in one ditch requires lower oil temperature at the outlet of heating station,indicating decreased energy cost at the heating station and improved transportation economy.Then economy analysis of four configurations of laying two pipelines in one ditch is performed.By comparing the results of four conditions,the interval between two pipelines of 1.2 m is found to save the energy most efficiently,which is as large as 26.6%compared with that of laying two pipelines in two separate ditches.In addition,narrowing the pipeline interval and extending the distance between heating stations is beneficial to save heating energy.This study is expected to provide valuable guidance for operation optimization of heated crude oil pipelines.展开更多
Wax deposits on the wall of a crude oil pipeline are a solid wax network of fine crystals, filled with oil, resin, asphaltene and other impurities. In this paper, a series of experiments on wax deposition in a laborat...Wax deposits on the wall of a crude oil pipeline are a solid wax network of fine crystals, filled with oil, resin, asphaltene and other impurities. In this paper, a series of experiments on wax deposition in a laboratory flow loop were performed under different conditions (flow rate, temperature differential between crude oil and pipeline wall, and dissolved wax concentration gradient), and the wax deposits were analyzed, so quantitative relationships among wax content, wax appearance temperature (WAT), shear stress, and radial concentration gradient of dissolved wax at the solid/liquid interface were obtained. Finally, a model was established to predict WAT and the wax content of the deposit.展开更多
Graphene flakes(GF)have been prepared and assessed as a material for improving flow in oil pipelines under the effect of an electric field.In particular,different amounts of GFs have been considered in order to determ...Graphene flakes(GF)have been prepared and assessed as a material for improving flow in oil pipelines under the effect of an electric field.In particular,different amounts of GFs have been considered in order to determine the optimal flow conditions.The GFs were prepared from graphite foam,derived from the dehydration of sugar with a particle size of 500-600μm,which was dispersed in ethanol and exfoliated in a ball mill under a shear force.After 15 h of exfoliation,sonication,and subsequent high-speed centrifugation at 3000 rpm,irregular-shaped GFs of 50-140 nm were produced and characterized using scanning electron microscopy,X-ray diffractometry,atomic force microscopy,and Raman spectroscopy.The prepared graphene sheets have been found to display excellent morphology and good graphitic structure.Experiments on flow improvement were conducted using the central composite rotatable design method for three parameters:stimulation time(15,30,45,and 60 s),applied voltage(150,170,200,and 220 V),and concentration of the GFs(0,100,200,and 400 mg/L).The optimal conditions for improved crude oil flow were then determined using the STATISTICA and WinQSB software packages.The results have confirmed the effectiveness of the use of the prepared GFs as a flow improver for crude oil,where the flow improvement is essentially a result of a reduction in viscosity and suppression of friction in the crude oil system.展开更多
Conventional pipeline corrosion assessment methods result in failure pressure predictions that are conservative, especially for pipelines that are subjected to internal pressure and axial compressive stress. Alternati...Conventional pipeline corrosion assessment methods result in failure pressure predictions that are conservative, especially for pipelines that are subjected to internal pressure and axial compressive stress. Alternatively, numerical methods may be used. However, they are computationally expensive. This paper proposes an analytical equation based on finite element analysis (FEA) for failure pressure prediction of a high toughness corroded pipeline with a single corrosion defect subjected to internal pressure and axial compressive stress. The equations were developed based on the weights and biases of an Artificial Neural Network (ANN) model trained with failure pressure from finite element analysis (FEA) of a high toughness pipeline for various defect depths, defect lengths, and axial compressive stresses. The proposed model was validated against actual burst test results for high toughness materials and was found to be capable of making accurate predictions with a coefficient of determination (R<sup>2</sup>) of 0.99. An extensive parametric study using the proposed model was subsequently conducted to determine the effects of defect length, defect depth, and axial compressive stress on the failure pressure of a corroded pipe with a single defect. The application of ANN together with FEA has shown promising results in the development of an empirical solution for the failure pressure prediction of pipes with a single corrosion defect subjected to internal pressure and axial compressive stress.展开更多
The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the...The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the variation of yield stress with shear history was explored through simulation experiment of pipelining.It is found that the effect of throughput variation or shear rate on yield stress is not obvious.With the decrease of final dynamic cooling temperature,the yield stress of waxy crude oil decreases,but there exists a little increase at the beginning.The prediction model of yield stress for waxy crude oil under the condition of shutdown is developed and it can be used to predict the yield stress of Daqing crude oil at certain heating temperature,final dynamic cooling temperature and measurement temperature.For the 139 groups of yield stress data of Daqing crude oil from the simulation experiment of pipelining,the result of prediction with this model shows that the average relative deviation between the yield stress measured and predicted is 30.27%,and the coefficient of correlation is 0.962 3.展开更多
Biocorrosion, as well as the biodeterioration of crude oil and its derivatives, is one of the major environmental, operational and economic problems in the Venezuelan oil industry. Fungal contaminants are able to prod...Biocorrosion, as well as the biodeterioration of crude oil and its derivatives, is one of the major environmental, operational and economic problems in the Venezuelan oil industry. Fungal contaminants are able to produce large quantities of biomass and synthesize peroxides and organic acids, causing severe damage on metal surfaces and promoting the contamination and biodeterioration of fuels. No evidences regarding fungal strains have been reported to be associated to petroleum naphtha, widely used as a diluent of extra heavy crude oil (EHCO) in the exploitation processes of the Orinoco Oil Belt, the biggest proven reserve of EHCO worldwide. The aims of this paper were to isolate and identify fungal strains from the naphtha storage tank and the naphtha distribution network from an oil field operator in Venezuela. The results showed the isolation of four different fungal strains. The molecular identification by 28S rRNA sequencing and phylogenetic tree analysis allowed us to identify the presence of: 1) a new uncultured Ascomycota fungus species BM-103, with high identity to novel hyphomycetes Noosia banksiae and Sporidesmium tengii, in the naphtha storage tank;2) two yeasts, Rhodotorula mucilaginosa BM-104 (Phylum Basidiomycota) and Wickerhamia sp. BM-105 (Phylum Ascomycota), in a highly damaged naphtha pipeline branch and;3) Cladosporium cladosporioides BM-102 (Phylum Ascomycota) in a cluster oil well. DNA fingerprinting analysis using ERIC-PCR primers pairs also allowed us to detect the presence of R. mucilaginosa BM-104 right in the access of the studied naphtha system. Interestingly, R. mucilaginosa and C. cladosporioides were previously reported as predominant fungal contaminants of diesel and jet fuel and of kerosene and fuel storage systems, respectively. This paper represents the first evidence of fungal strains isolated and identified from the naphtha systems in the Venezuelan oil industry. The results obtained are discussed.展开更多
This paper discusses the influence of valve operations on pressure surge in a pipeline. The valve is a protective type which remains open in a pipeline loading system during normal operation but shut down the system w...This paper discusses the influence of valve operations on pressure surge in a pipeline. The valve is a protective type which remains open in a pipeline loading system during normal operation but shut down the system when there is an emergency such as storm. The data for the study were obtained from measurements at Agbada 1 flow station as well as log sheets. Also, calculations were made using existing and derived formulas to obtain the values of Crude Oil and Pipe parameters that could not be measured directly or derived from data or log sheets. Surge analysis was carried out on the pipeline system to ascertain changes in pressure and flow rates along the pipeline following valve shut down at any time using developed pressure and flow equations. The results of the simulation analysis showed remarkable changes in the fluid pressure and flow rates along the pipe on shut down at any time. The pipeline recorded the highest pressure of 37.4 bar against initial pressure of 25 bar at length 6000 m in 1.5 second valve closure. There is also remarkable pressure drop along the pipe capable of reducing the crude oil pressure below its vapour pressure. The flow is turbulent even before valve operation with Reynolds number as high as 57024.53. The model equations compute changes in pressure and flow rates at different points in a pipeline installed with emergency-relief coupling valve. This enables point of extreme and low pressure to be detected accurately in a pipeline which guides the engineer while positioning surge suppression devices which cushion the effects of pressure surge in any pipeline.展开更多
文摘Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities, planning and control of the flow of information and materials in a firm, management of relationships with other organizations and government intervention, However, crude oil theft and pipeline vandalism are established products supply chain disruptors in Nigeria which are rendering the task of running an efficient petroleum supply chain onerous. This paper aims to establish the importance of effective supply chain strategies for companies in the oil and gas industry with special focus on the Nigerian oil and gas sector and the strategies by which the state oil and gas corporation in this sector may mitigate disruptions to its supply chain. This study investigates the enhancement of supply chain strategies towards meeting the challenge of crude oil theft and pipeline vandalism, using the Nigerian National Corporation (NNPC) as a case study. Based on this study, data were collected from two sources: A summary of incident reports obtained from NNPC and an interview with personnel in the PPMC Department. Incident report refers to a report produced when accidents such as equipment failure, injury, loss of life, or fire occur at the work site. Content analysis is utilized to evaluate data obtained from interview responses, CBN financial stability reports, NDIC annual reports, circulars, banking supervision reports and implementation guidelines. The study found out that NNPC should endeavor to sustain its value chain and ward of pipeline vandals and crude oil thieves by engaging in community partnership, detailing security outfits to ensure its pipelines’ right of way and bridging. Concluded that the oil supply chain of the Nigerian National Petroleum Corporation has been plagued by disruptions in the form of crude oil theft and pipeline vandalism which has had debilitating effects on its value.
文摘Crude oil spillage is a major challenge in Nigeria. It affects the environment, health, life, and livelihood of residents of the Niger Delta region, where oil is explored, processed, and transported via a network of pipelines. Oil spillage is primarily caused by vandalization/sabotage and operational issues such as corrosion, equipment failure, operation, and maintenance errors. Thus, prompt response is required to mitigate the impact of oil spills. In this study, we deployed low-cost Arduino systems, including sensors (vibration and flow), modules (GPS and Wifi) and an IoT platform (ThingSpeak) to detect spillage caused by vandalism and operational inefficiencies proactively. The results demonstrate that low-cost sensors can detect changes in the flow volume between the inflow and outflow attributable to spillage, and vibration shocks caused by vandalism can be detected and linked to the cause of the spillage and communicated in real time to inform response action. Moreover, we proposed a framework for field validation utilizing KoboToolBox (a crowdsourcing/citizen science platform). The prototype system designed and programmed showed promising results, as it could detect spillage for vandalism and operational scenarios in real-time, quantify the volume of spillage, and identify the location and time of spillage occurrence;indicators relevant for response planning to minimize the impact of oil spillage. A video demonstration of the prototype system developed is accessible via: https://youtu.be/wKa9MZvYf1w. .
基金funded by the National Key Research and Development Program(2016YFC0802103)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA2003020102)+3 种基金National Natural Science Foundation of China(Grants Nos.U1703244,41672310,41630636 and 41702333)the Research Project of the State Key Laboratory of Frozen Soils Engineering(Grant No.SKLFSE-ZY-16)the Major Program of Bureau of International Cooperation of CAS(131B62KYSB20170012)the STS research project of CAS(HHS-TSS-STS-1502)
文摘The permafrost along the China-Russia Crude Oil Pipeline(CRCOP) is degrading since the pipeline operation in 2011. Heat dissipated from the pipeline, climate warming and anthropogenic activities leads to permafrost warming. The processes of permafrost warming along the CRCOP were studied based on the monitoring of air and soil temperatures, and electrical resistivity tomography(ERT) surveys. Results show that:(1) the mean annual air temperature(MAAT) in permafrost regions along the CRCOP increased with a rate of 0.21°C/10a–0.40°C/10 a during the past five decades;(2) the mean annual ground temperature(MAGT, at-15 m depth) of undisturbed permafrost increased by 0.2°C and the natural permafrost table remained unchanged due to the zero-curtain effect;(3) permafrost surrounding the uninsulated pipeline right-of-way warmed significantly compared with that in a natural site. During 2012–2017, the MAGT and the artificial permafrost table, 2 m away from the pipeline centerline, increased at rates of 0.063°C/a and 1.0 m/a. The thaw bulb developed around the pipe and exhibits a faster lateral expansion;(4) 80-mm-thick insulation could reduce the heat exchange between the pipeline and underlying permafrost and then keep the permafrost and pipe stable. The MAGT and the artificial permafrost table, 4.8 m away from the center line of the pipeline, increased by 0.3°C/a and 0.43 m/a, respectively. Due to the heat disturbance caused by warm oil, the degradation of wetland, controlled burn each autumn and climate warming, the permafrost extent reduced and warmed significantly along the CRCOP route. Field observations provide basic data to clarify the interactions between CRCOP and permafrost degradation and environmental effects in the context of climate change.
基金the Indian Institute of Technology (Indian School of Mines), Dhanbad for providing necessary laboratory facilities and financial support
文摘The most economical way to overcome flow assurance problems associated with transportation of heavy crude oil through offshore pipelines is by emulsifying it with water in the presence of a suitable surfactant.In this research,a novel surfactant,tri-triethanolamine monosunflower ester,was synthesized in the laboratory by extracting fatty acids present in sunflower(Helianthus annuus)oil.Synthesized surfactant was used to prepare oil-in-water emulsions of a heavy crude oil from the western oil field of India.After emulsification,a dramatic decrease in pour point as well as viscosity was observed.All the prepared emulsions were found to be flowing even at 1°C.The emulsion developed with 60%oil content and 2wt%surfactant showed a decrease in viscosity of 96%.The stability of the emulsion was investigated at different temperatures,and it was found to be highly stable.The effectiveness of surfactant in emulsifying the heavy oil in water was investigated by measuring the equilibrium interfacial tension(IFT)between the crude oil(diluted)and the aqueous phase along with zeta potential of emulsions.2wt%surfactant decreased IFT by almost nine times that of no surfactant.These results suggested that the synthesized surfactant may be used to prepare a stable oil-in-water emulsion for its transportation through offshore pipelines efficiently.
基金supported by the National Natural Science Foundation Program of China on"Formation mechanisms and mitigative measures for thaw settlement of foundation soils of the China-Russia Crude Oil Pipeline"(Grant No.41171055)the State Key Laboratory of Frozen Soils Engineering Research Projects of China on"Monitoring on thaw settlement of permafrost around the China-Russia Crude Oil Pipeline"(Grant No.SKLFSE-ZY-11)and"Research on isotope tracing and radar detection of permafrost along the China-Russia Crude Oil Pipeline route"(Grant No.SKLFSE-201302)
文摘On-site monitoring is very important for understanding formation mechanisms of frost hazards frequently occurring in pipeline foundation soils and for designing and deploying according mitigative measures in permafrost regions.Significant thaw subsidence of ground surfaces along the ChinaRussia Crude Oil Pipeline(CRCOP) from Mo'he to Daqing,Heilongjiang Province,Northeast China have been observed at some segments underlain by ice-rich warm(>1.0°C) permafrost since the official operation in January 2011.Recent monitoring results of the thermal states of foundation soils at the kilometer post(KP) 304 site along the CRCOP are presented in this paper.The results indicate that during the period from 2012 to 2014,shallow soils(at the depths from0.8 to 4.0 m from ground surface) has warmed by approximately 1.0°C in the lateral range of 1.2 to 2.1 maway from the pipeline axis,and deeper permafrost(such as at the depth of 15 m,or the depth of zero annual amplitude of ground temperatures) by 0.08°C per year 4 m away from the pipe axis,and 0.07°C per year 5 m away from the pipeline axis.The results indicate an all-season talik has developed around and along the CRCOP.The thaw bulb,with a faster lateral expansion(compared with the vertical growth),enlarges in summer and shrinks in winter.This research will provide important references and bases for evaluating thermal influences of warm pipeline on permafrost and for design,construction,operation and maintenance of pipelines in permafrost regions.
基金supported by the National Natural Science Foundation of China(NNSFC)(No.41672310)Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA2003020102)+4 种基金China’s Second Tibetan Plateau Scientific Expedition and Research(2019QZKK0905)the NNSFC(Nos.U1703244 and 41630636)National Key Research and Development Program(2017YFC0405101)the Major Program of Bureau of International Cooperation of the Chinese Academy of Sciences(131B62KYSB20170012)Foundation of the State Key Laboratory of Frozen Soil Engineering(No.SKLFSE-ZY-20)。
文摘Active layer is a key component for permafrost environment studies as many subsurface biological,biogeochemical,ecological,and pedogenic activities prevail in this layer.This study focuses on active layer temperature monitoring in an area with sporadic permafrost at two adjacent sites along China-Russia Crude Oil Pipeline(CRCOP),NorthEast China.Site T1 is located in disturbed ground on the right-of-way(on-ROW)2 m away from the center of the oil pipeline.T2 is located in a natural and undisturbed site,around 16.6 m off-ROW.Our objective was to study seasonal variability of the active layer depth and thermal regime from October 2017 to September 2018.The monitoring sites consist of soil temperature probes arranged in a vertical array at different depths at both sites.The following parameters were computed:number of isothermal days(ID),freezing days(FD),thawing days(TD),freezing degree days(FDD),thawing degree days(TDD),number of freeze-thaw days(FTD).The mean air temperature in the monitoring period reached-3.2℃.The temperature profile indicates that the maximum active layer thickness observed during the study period was 10 m at T1 and 2 m at T2.The majority of the soil temperatures were above or close to 0℃,resulting in great values of TDD,especially in the first 4 m depth.TDD for T1 were predominant and ranged between 600-1160℃·days(0-4 m depth)reflecting the influence of oil temperature from the pipeline.In T2 borehole FDD were predominant for all the soil layer depths resulting in less permafrost degradation.This comparison emphasizes the significant influence of vegetation removal and the dispersed heat from the pipeline on the active layer thickness.
基金funding from the Chinese Academy of Sciences Knowledge Innovation Program (Grant No. KZCX2-YW-311)the Chinese Academy of Sciences 100-Talents Program (HuiJun Jin)
文摘The cold-region eco-environments along the China-Russia Crude Oil Pipeline (CRCOP) in northern Northeast China are in disequilibrium due to the combined influences of pronounced climate warming and intensive anthropogenic activities.This is evidenced by the sharp areal reduction and northward shifting of the boreal forests,shrinking of wetlands,enhancing of soil erosion,accelerating degradation of permafrost and deteriorating of cold-region eco-environments.The degradation of permafrost plays an important role as an internal drive in the eco-environmental changes.Many components of the cold-region eco-environments,including frozen ground,forests,wetlands and peatlands,forest fires and 'heating island effect' of rapid urbanization,are interdependent,interactive,and integrated in the boreal ecosystems.The construction and long-term operation of the CRCOP system will inevitably disturb the cold-region environments along the pipeline.Therefore,a mandatory and carefully-elaborated environ-mental impact statement is indispensable for the proper mitigation of the ensued adverse impacts.Proper management,effective protection and practical rehabilitation of the damaged cold-region environments are a daunting,costly and long-term commitment.The recommended measures for protection and restoration of permafrost eco-environments along the pipeline route include adequate investigation,assessment and monitoring of permafrost and cold-region environments,compliance of pipeline construction and operation codes for environmental management,proper and timely re-vegetation,returning the cultivated lands to forests and grasslands,and effective mitigation of forest fire hazards.
文摘In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance between two heating stations on the heating energy consumption.To analyze the transportation economy,the two heated crude oil pipelines laid in one ditch are simulated under four operating conditions based on an unstructured finite volume method.Compared with laying two crude oil pipelines separately in two ditches,the results attest notably higher soil temperature,meaning reduced heat dissipation of each pipeline by laying two pipelines in one ditch.It is inferred that for the same desired oil temperature at the inlet of the next heating station,laying two pipelines in one ditch requires lower oil temperature at the outlet of heating station,indicating decreased energy cost at the heating station and improved transportation economy.Then economy analysis of four configurations of laying two pipelines in one ditch is performed.By comparing the results of four conditions,the interval between two pipelines of 1.2 m is found to save the energy most efficiently,which is as large as 26.6%compared with that of laying two pipelines in two separate ditches.In addition,narrowing the pipeline interval and extending the distance between heating stations is beneficial to save heating energy.This study is expected to provide valuable guidance for operation optimization of heated crude oil pipelines.
文摘Wax deposits on the wall of a crude oil pipeline are a solid wax network of fine crystals, filled with oil, resin, asphaltene and other impurities. In this paper, a series of experiments on wax deposition in a laboratory flow loop were performed under different conditions (flow rate, temperature differential between crude oil and pipeline wall, and dissolved wax concentration gradient), and the wax deposits were analyzed, so quantitative relationships among wax content, wax appearance temperature (WAT), shear stress, and radial concentration gradient of dissolved wax at the solid/liquid interface were obtained. Finally, a model was established to predict WAT and the wax content of the deposit.
文摘Graphene flakes(GF)have been prepared and assessed as a material for improving flow in oil pipelines under the effect of an electric field.In particular,different amounts of GFs have been considered in order to determine the optimal flow conditions.The GFs were prepared from graphite foam,derived from the dehydration of sugar with a particle size of 500-600μm,which was dispersed in ethanol and exfoliated in a ball mill under a shear force.After 15 h of exfoliation,sonication,and subsequent high-speed centrifugation at 3000 rpm,irregular-shaped GFs of 50-140 nm were produced and characterized using scanning electron microscopy,X-ray diffractometry,atomic force microscopy,and Raman spectroscopy.The prepared graphene sheets have been found to display excellent morphology and good graphitic structure.Experiments on flow improvement were conducted using the central composite rotatable design method for three parameters:stimulation time(15,30,45,and 60 s),applied voltage(150,170,200,and 220 V),and concentration of the GFs(0,100,200,and 400 mg/L).The optimal conditions for improved crude oil flow were then determined using the STATISTICA and WinQSB software packages.The results have confirmed the effectiveness of the use of the prepared GFs as a flow improver for crude oil,where the flow improvement is essentially a result of a reduction in viscosity and suppression of friction in the crude oil system.
文摘Conventional pipeline corrosion assessment methods result in failure pressure predictions that are conservative, especially for pipelines that are subjected to internal pressure and axial compressive stress. Alternatively, numerical methods may be used. However, they are computationally expensive. This paper proposes an analytical equation based on finite element analysis (FEA) for failure pressure prediction of a high toughness corroded pipeline with a single corrosion defect subjected to internal pressure and axial compressive stress. The equations were developed based on the weights and biases of an Artificial Neural Network (ANN) model trained with failure pressure from finite element analysis (FEA) of a high toughness pipeline for various defect depths, defect lengths, and axial compressive stresses. The proposed model was validated against actual burst test results for high toughness materials and was found to be capable of making accurate predictions with a coefficient of determination (R<sup>2</sup>) of 0.99. An extensive parametric study using the proposed model was subsequently conducted to determine the effects of defect length, defect depth, and axial compressive stress on the failure pressure of a corroded pipe with a single defect. The application of ANN together with FEA has shown promising results in the development of an empirical solution for the failure pressure prediction of pipes with a single corrosion defect subjected to internal pressure and axial compressive stress.
基金Project(07E1007) supported by the Youth Innovation Foundation for Petroleum Science and Technology of China National Petroleum CorportationProject(2006AA09Z357) supported by the National High Technology Research and Development of China
文摘The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the variation of yield stress with shear history was explored through simulation experiment of pipelining.It is found that the effect of throughput variation or shear rate on yield stress is not obvious.With the decrease of final dynamic cooling temperature,the yield stress of waxy crude oil decreases,but there exists a little increase at the beginning.The prediction model of yield stress for waxy crude oil under the condition of shutdown is developed and it can be used to predict the yield stress of Daqing crude oil at certain heating temperature,final dynamic cooling temperature and measurement temperature.For the 139 groups of yield stress data of Daqing crude oil from the simulation experiment of pipelining,the result of prediction with this model shows that the average relative deviation between the yield stress measured and predicted is 30.27%,and the coefficient of correlation is 0.962 3.
文摘Biocorrosion, as well as the biodeterioration of crude oil and its derivatives, is one of the major environmental, operational and economic problems in the Venezuelan oil industry. Fungal contaminants are able to produce large quantities of biomass and synthesize peroxides and organic acids, causing severe damage on metal surfaces and promoting the contamination and biodeterioration of fuels. No evidences regarding fungal strains have been reported to be associated to petroleum naphtha, widely used as a diluent of extra heavy crude oil (EHCO) in the exploitation processes of the Orinoco Oil Belt, the biggest proven reserve of EHCO worldwide. The aims of this paper were to isolate and identify fungal strains from the naphtha storage tank and the naphtha distribution network from an oil field operator in Venezuela. The results showed the isolation of four different fungal strains. The molecular identification by 28S rRNA sequencing and phylogenetic tree analysis allowed us to identify the presence of: 1) a new uncultured Ascomycota fungus species BM-103, with high identity to novel hyphomycetes Noosia banksiae and Sporidesmium tengii, in the naphtha storage tank;2) two yeasts, Rhodotorula mucilaginosa BM-104 (Phylum Basidiomycota) and Wickerhamia sp. BM-105 (Phylum Ascomycota), in a highly damaged naphtha pipeline branch and;3) Cladosporium cladosporioides BM-102 (Phylum Ascomycota) in a cluster oil well. DNA fingerprinting analysis using ERIC-PCR primers pairs also allowed us to detect the presence of R. mucilaginosa BM-104 right in the access of the studied naphtha system. Interestingly, R. mucilaginosa and C. cladosporioides were previously reported as predominant fungal contaminants of diesel and jet fuel and of kerosene and fuel storage systems, respectively. This paper represents the first evidence of fungal strains isolated and identified from the naphtha systems in the Venezuelan oil industry. The results obtained are discussed.
文摘This paper discusses the influence of valve operations on pressure surge in a pipeline. The valve is a protective type which remains open in a pipeline loading system during normal operation but shut down the system when there is an emergency such as storm. The data for the study were obtained from measurements at Agbada 1 flow station as well as log sheets. Also, calculations were made using existing and derived formulas to obtain the values of Crude Oil and Pipe parameters that could not be measured directly or derived from data or log sheets. Surge analysis was carried out on the pipeline system to ascertain changes in pressure and flow rates along the pipeline following valve shut down at any time using developed pressure and flow equations. The results of the simulation analysis showed remarkable changes in the fluid pressure and flow rates along the pipe on shut down at any time. The pipeline recorded the highest pressure of 37.4 bar against initial pressure of 25 bar at length 6000 m in 1.5 second valve closure. There is also remarkable pressure drop along the pipe capable of reducing the crude oil pressure below its vapour pressure. The flow is turbulent even before valve operation with Reynolds number as high as 57024.53. The model equations compute changes in pressure and flow rates at different points in a pipeline installed with emergency-relief coupling valve. This enables point of extreme and low pressure to be detected accurately in a pipeline which guides the engineer while positioning surge suppression devices which cushion the effects of pressure surge in any pipeline.