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光电子能谱和飞行时间二次离子质谱(ESCA—ToFSIMS)联用
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作者 吴正龙 《国外分析仪器技术与应用》 1998年第4期45-48,共4页
关键词 XPS tofsims 表面分析
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三层聚乙烯管道外防腐层剥离事故分析技术 被引量:1
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作者 A Hussain C Pflugbeil 王向农(译) 《防腐保温技术》 2011年第3期56-62,共7页
本文叙述了评价埋地油气输送管道的三层聚乙烯外防腐层(3LPE)特性的各种分析技术,重点分析了熔结环氧粉末(FBE)与钢管底材之间界面上的粘合特性。已经证实,在测定熔结环氧粉末(FBE)涂层的有量纲强度时,傅里叶变换红外光谱(FTI... 本文叙述了评价埋地油气输送管道的三层聚乙烯外防腐层(3LPE)特性的各种分析技术,重点分析了熔结环氧粉末(FBE)与钢管底材之间界面上的粘合特性。已经证实,在测定熔结环氧粉末(FBE)涂层的有量纲强度时,傅里叶变换红外光谱(FTIR)、差示扫描量热法(DSC)、热重分析(TGA)、动态机械分析(DMA)都是非常有用的分析技术。但是,已经证实,在阐述油分、润滑脂、硅胶等污染物对造成熔结环氧粉末(FBE)与钢底材之间界面上涂层剥离的有害影响时,飞行时间二次离子质谱(ToFSIMS)格外有用。根据我们的调查,我们认为,即使这不是最重要的因素,影响三层聚乙烯外防腐层(3LPE)管道使用寿命的最重要因素之一是钢管表面的预处理和降低污染物残余。如果最大程度重视了熔结环氧粉末(FBE)底漆与钢底材之间界面上的粘合,那么管道甚至可以不用实施阴极保护(CP)。 展开更多
关键词 涂层剥离 表面污染 分析技术 阴极保护 FTIR DSC TGA DMA tofsims
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Source Rock Classification and the Basic Structure of Coal and Kerogen
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作者 金奎励 杨陆武 《Journal of China University of Mining and Technology》 2002年第1期1-5,共5页
In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/... In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal. 展开更多
关键词 Source rock classification organic ingredient classification basic structure for coal/kerogen time of flight secondary ion mass spectrometry (tofsims)
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