An expression for energy transfer probability (η) between host (TPD) and guest (Ir(ppy)3) phosphorescent systems is proposed,and the energy transfer process in doped organic electrophosphorescent (EP) devic...An expression for energy transfer probability (η) between host (TPD) and guest (Ir(ppy)3) phosphorescent systems is proposed,and the energy transfer process in doped organic electrophosphorescent (EP) devices is discussed. The results show that (1) The rate of the triplet energy transfer (KHG and KGH) exponentially increases with the host-guest molecular distance (R), and KHG decreases quickly as the intermolecular distance of the guest (RGG) increases. In addition,the KHG/KGH ratio of the dopant system increases when R or RGG is reduced; (2) The energy transfer probability approximately linearly decreases as R increases from 0.8 to 1.2nm,and the variation of RGG can be neglected when R〈1.1nm. For 1. 1nm〈R〈l. 2nm, RGG (〈1.6nm) plays an increasingly important role when 71 drops with the latter' (3) η increases when the Forster energy transfer rate increases or Gibb's energy declines.展开更多
Transmitting quantum states by channels of analogous Bell states is studied in this paper. We analyze the transmitting process. constructed the probabilitic unitary operator, and gain the largest successful transfer q...Transmitting quantum states by channels of analogous Bell states is studied in this paper. We analyze the transmitting process. constructed the probabilitic unitary operator, and gain the largest successful transfer quantum state probability.展开更多
Accurate descriptions of matrix diffusion across the fracture/matrix interface are critical to assessing contaminant migration in fractured media. The classical transfer probability method is only applicable for relat...Accurate descriptions of matrix diffusion across the fracture/matrix interface are critical to assessing contaminant migration in fractured media. The classical transfer probability method is only applicable for relatively large diffusion coefficients and small fracture spacings, due to an intrinsic assumption of an equilibrium concentration profile in the matrix blocks. Motivated and required by practical applications, we propose a direct numerical simulation (DNS) approach without any empirical assumptions. A three-step Lagrangian algorithm was developed and validated to directly track the particle dynamics across the fracture/matrix interface, where particle's diffusive displacement across the discontinuity is controlled by an analytical, one-side reflection probability. Numerical experiments show that the DNS approach is especially efficient for small diffusion coefficients and large fracture spacings, alleviating limitations of the classical modeling approach.展开更多
Based on the charge injection and recombination processes and the triplet-triplet annihilation process, a model to calculate the electroluminescent(EL) efficiency is presented. The influences of the applied electric f...Based on the charge injection and recombination processes and the triplet-triplet annihilation process, a model to calculate the electroluminescent(EL) efficiency is presented. The influences of the applied electric field on the injection efficiency, recombination efficiency and electroluminescent efficiency are discussed. It is found that: (1) The injection efficiency is increasing while the recombination efficiency is decreasing with the applied electric field increasing. (2) The EL efficiency is enhanced at low electric field slowly but is decreasing at high electric field with the increase of applied voltage. (3) The EL efficiency is decreasing with the increase of the host-guest molecular distance (R). So, it is concluded that the EL efficiency in single-layer organic electrophosphorescent devices is dominated by injection efficiency at lower electric field and recombination efficiency at higher electric field.展开更多
In this paper, we explore the process of emotional state transition. And the process is impacted by emotional state of interaction objects. First of all, the cognitive reasoning process and the micro-expressions recog...In this paper, we explore the process of emotional state transition. And the process is impacted by emotional state of interaction objects. First of all, the cognitive reasoning process and the micro-expressions recognition is the basis of affective computing adjustment process. Secondly, the threshold function and attenuation function are proposed to quantify the emotional changes. In the actual environment, the emotional state of the robot and external stimulus are also quantified as the transferring probability. Finally, the Gaussian cloud distribution is introduced to the Gross model to calculate the emotional transitional probabilities. The experimental results show that the model in human-computer interaction can effectively regulate the emotional states, and can significantly improve the humanoid and intelligent ability of the robot. This model is consistent with experimental and emulational significance of the psychology, and allows the robot to get rid of the mechanical emotional transfer process.展开更多
The simulation of solute transport in fractured rock mass has Finite Element Method(FEM) and Finite Analysis Method(FAM), etc. been conducted with the Finite Difference Method(FDM), However, groundwater flow and...The simulation of solute transport in fractured rock mass has Finite Element Method(FEM) and Finite Analysis Method(FAM), etc. been conducted with the Finite Difference Method(FDM), However, groundwater flow and solute transport is very complex in fractured network compared to the rocks matrix because water flow and tracer particles have different selections of pathways when they travel to the fractured intersections. It is difficult for traditional method to simulate the law of solute transport in fractured network. Hence a new simulation method, the probability method, is developed. In the method, transfer probabilities for fractured network are calculated using the flux of input and output from fractured intersection points, and travel times of tracer particles are determined with random numbers, dispersion parameter and velocity. Furthermore, corresponding computing program is developed using the FORTRAN language. The comparison between simulated and experimental results shows that the probability method is of considerable reliability and is an effective method to simulate solute transport in fractured network, and the case study of the Jinping I-Hydropower Station displays its wide application prospect.展开更多
文摘An expression for energy transfer probability (η) between host (TPD) and guest (Ir(ppy)3) phosphorescent systems is proposed,and the energy transfer process in doped organic electrophosphorescent (EP) devices is discussed. The results show that (1) The rate of the triplet energy transfer (KHG and KGH) exponentially increases with the host-guest molecular distance (R), and KHG decreases quickly as the intermolecular distance of the guest (RGG) increases. In addition,the KHG/KGH ratio of the dopant system increases when R or RGG is reduced; (2) The energy transfer probability approximately linearly decreases as R increases from 0.8 to 1.2nm,and the variation of RGG can be neglected when R〈1.1nm. For 1. 1nm〈R〈l. 2nm, RGG (〈1.6nm) plays an increasingly important role when 71 drops with the latter' (3) η increases when the Forster energy transfer rate increases or Gibb's energy declines.
基金National Natural Science Foundation of China under Grant No.10575017
文摘Transmitting quantum states by channels of analogous Bell states is studied in this paper. We analyze the transmitting process. constructed the probabilitic unitary operator, and gain the largest successful transfer quantum state probability.
基金supported by the United States Department of Energythe Desert Research Institute IR&D Funds
文摘Accurate descriptions of matrix diffusion across the fracture/matrix interface are critical to assessing contaminant migration in fractured media. The classical transfer probability method is only applicable for relatively large diffusion coefficients and small fracture spacings, due to an intrinsic assumption of an equilibrium concentration profile in the matrix blocks. Motivated and required by practical applications, we propose a direct numerical simulation (DNS) approach without any empirical assumptions. A three-step Lagrangian algorithm was developed and validated to directly track the particle dynamics across the fracture/matrix interface, where particle's diffusive displacement across the discontinuity is controlled by an analytical, one-side reflection probability. Numerical experiments show that the DNS approach is especially efficient for small diffusion coefficients and large fracture spacings, alleviating limitations of the classical modeling approach.
基金Excellent Youth Foundation of Hunan Province(03JJY1008) Science Foundation for Post-doctorate of China(2004035083) Science Foundation of Central South University(0601059)
文摘Based on the charge injection and recombination processes and the triplet-triplet annihilation process, a model to calculate the electroluminescent(EL) efficiency is presented. The influences of the applied electric field on the injection efficiency, recombination efficiency and electroluminescent efficiency are discussed. It is found that: (1) The injection efficiency is increasing while the recombination efficiency is decreasing with the applied electric field increasing. (2) The EL efficiency is enhanced at low electric field slowly but is decreasing at high electric field with the increase of applied voltage. (3) The EL efficiency is decreasing with the increase of the host-guest molecular distance (R). So, it is concluded that the EL efficiency in single-layer organic electrophosphorescent devices is dominated by injection efficiency at lower electric field and recombination efficiency at higher electric field.
文摘In this paper, we explore the process of emotional state transition. And the process is impacted by emotional state of interaction objects. First of all, the cognitive reasoning process and the micro-expressions recognition is the basis of affective computing adjustment process. Secondly, the threshold function and attenuation function are proposed to quantify the emotional changes. In the actual environment, the emotional state of the robot and external stimulus are also quantified as the transferring probability. Finally, the Gaussian cloud distribution is introduced to the Gross model to calculate the emotional transitional probabilities. The experimental results show that the model in human-computer interaction can effectively regulate the emotional states, and can significantly improve the humanoid and intelligent ability of the robot. This model is consistent with experimental and emulational significance of the psychology, and allows the robot to get rid of the mechanical emotional transfer process.
基金Supported by the Program for Changjiang Scholars and Innovative Research Team in University (Grant No.IRT0717)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministrysupported by the Natural Science Foundation of Hohai University (Grant No.2008433111)
文摘The simulation of solute transport in fractured rock mass has Finite Element Method(FEM) and Finite Analysis Method(FAM), etc. been conducted with the Finite Difference Method(FDM), However, groundwater flow and solute transport is very complex in fractured network compared to the rocks matrix because water flow and tracer particles have different selections of pathways when they travel to the fractured intersections. It is difficult for traditional method to simulate the law of solute transport in fractured network. Hence a new simulation method, the probability method, is developed. In the method, transfer probabilities for fractured network are calculated using the flux of input and output from fractured intersection points, and travel times of tracer particles are determined with random numbers, dispersion parameter and velocity. Furthermore, corresponding computing program is developed using the FORTRAN language. The comparison between simulated and experimental results shows that the probability method is of considerable reliability and is an effective method to simulate solute transport in fractured network, and the case study of the Jinping I-Hydropower Station displays its wide application prospect.