CoNi nanoparticles anchored inside carbon nanotube networks by transient heating:Low loading and high activity for oxygen reduction and evolution

Transitional metal alloy and compounds have been developed as the low cost and efficient bifunctional electrocatalysts for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).However,a high mass loading of these catalysts is commonly needed to achieve acceptable catalytic performance,which could cause such problems as battery weight gain,mass transport blocking,and catalyst loss.We report herein the preparation of fine CoNi nanoparticles(5-6 nm)anchored inside a nitrogendoped defective carbon nanotube network(CoNi@N-DCNT)by a transient Joule heating method.When utilized as an electrocatalyst for oxygen reduction and evolution in alkaline media,the CoNi@N-DCNT film catalyst with a very low mass loading of 0.06 mg cm^(-2) showed excellent bifunctional catalytic performance.For ORR,the onset potential(Eonset)and the half-wave potential(E_(1/2))were 0.92 V versus reversible hydrogen electrode(vs.RHE)and 0.83 V(vs.RHE),respectively.For OER,the potential at the current density(J)of 10 mA cm^(-2)(E_(10))was 1.53 V,resulting in an overpotential of 300 mV much lower than that of the commercial RuO_(2) catalyst(320 mV).The potential gap between E_(1/2) and E_(10) was as small as 0.7 V.Considering the low mass loading,the mass activity at E_(10) reached at 123.2 A g^(-1),much larger than that of the RuO_(2) catalyst and literature results of transitional metal-based bifunctional catalysts.Moreover,the CoNi@N-DCNT film catalyst showed very good long-term stability during the ORR and OER test.The excellent bifunctional catalytic performance could be attributed to the synergistic effect of the bimetal alloy.

Thermo-mechanical properties of RTM-made carbon fibre/polyimide composite attaching collar under transient heating

This study focuses on the thermo-mechanical properties of Carbon Fibre/Polyimide Composite(CFPC)attaching collars under transient heating.The CFPC attaching collars were fabricated by a high-temperature resin transfer moulding process,and their thermo-mechanical properties under the conditions of simultaneous transient heating and bending load were investigated.The results show that the attaching collar tends to fail at 118% of the limit load.The failure mode includes the fracture of the connecting screws,local extrusion damage of the hole edges,and slight ablation damage at the outer plies.And there is no observable residual deformation in the composite attaching collar.Furthermore,considering that the material properties vary with temperature,a progressive damage model based on the sequential thermo-mechanical coupling method was established to study the failure mechanism of the attaching collar.Finally,the damage factor of the CFPC was calculated to assess the safety status of the attaching collar.The results show that the primary damage modes of the composite attaching collar are intralaminar failure,which mainly occurs at the heat insulation layer and the hole edges,and these slightly affect the structural bearing capacity.A good correlation between the experiment and FEA is obtained.The test methods and analysis models proposed contribute to the safety assessment of composite structures under transient heating.

Finite Difference-Peridynamic Differential Operator for Solving Transient Heat Conduction Problems

Transient heat conduction problems widely exist in engineering.In previous work on the peridynamic differential operator(PDDO)method for solving such problems,both time and spatial derivatives were discretized using the PDDO method,resulting in increased complexity and programming difficulty.In this work,the forward difference formula,the backward difference formula,and the centered difference formula are used to discretize the time derivative,while the PDDO method is used to discretize the spatial derivative.Three new schemes for solving transient heat conduction equations have been developed,namely,the forward-in-time and PDDO in space(FT-PDDO)scheme,the backward-in-time and PDDO in space(BT-PDDO)scheme,and the central-in-time and PDDO in space(CT-PDDO)scheme.The stability and convergence of these schemes are analyzed using the Fourier method and Taylor’s theorem.Results show that the FT-PDDO scheme is conditionally stable,whereas the BT-PDDO and CT-PDDO schemes are unconditionally stable.The stability conditions for the FT-PDDO scheme are less stringent than those of the explicit finite element method and explicit finite difference method.The convergence rate in space for these three methods is two.These constructed schemes are applied to solve one-dimensional and two-dimensional transient heat conduction problems.The accuracy and validity of the schemes are verified by comparison with analytical solutions.

Evaluation of ultra-fine grained tungsten under transient high heat flux by high-intensity pulsed ion beam

Pure tungsten, oxide dispersion strengthened tungsten and carbide dispersion strengthened tungsten were fabricated by high-energy ball milling and spark plasma sintering process. In order to evaluate the properties of the tungsten alloys under transient high heat flues, four tungsten samples with different grain sizes were tested by high-intensity pulsed ion beam with a heat flux as high as 160 MW/（m^2·s^-1/2）. Compared with the commercial tungsten, the surface modification of the oxide dispersion strengthened tungsten by high-intensity pulsed ion beam is completely different. The oxide dispersion strengthened tungsten shows inferior thermal shock response due to the low melting point second phase of Ti and Y2O3, which results in the surface melting, boiling bubbles and cracking. While the carbide dispersion strengthened tungsten shows better thermal shock response than the commercial tungsten.

A new complex variable meshless method for transient heat conduction problems

In this paper, based on the improved complex variable moving least-square （ICVMLS） approximation, a new complex variable meshless method （CVMM） for two-dimensional （2D） transient heat conduction problems is presented. The variational method is employed to obtain the discrete equations, and the essential boundary conditions are imposed by the penalty method. As the transient heat conduction problems are related to time, the Crank-Nicolson difference scheme for two-point boundary value problems is selected for the time discretization. Then the corresponding formulae of the CVMM for 2D heat conduction problems are obtained. In order to demonstrate the applicability of the proposed method, numerical examples are given to show the high convergence rate, good accuracy, and high efficiency of the CVMM presented in this paper.

FGOALS-s2 Simulation of Upper-level Jet Streams over East Asia: Mean State Bias and Synoptic-scale Transient Eddy Activity

Upper-level jet streams over East Asia simulated by the LASG/IAP coupled climate system model FGOALS-s2 were assessed, and the mean state bias explained in terms of synoptic-scale transient eddy activ- ity （STEA）. The results showed that the spatial distribution of the seasonal mean jet stream was reproduced well by the model, except that following a weaker meridional temperature gradient （MTG）, the intensity of the jet stream was weaker than in National Centers for Environment Prediction （NCEP）/Department of Energy Atmospheric Model Inter-comparison Project II reanalysis data （NCEP2）. Based on daily mean data, the jet core number was counted to identify the geographical border between the East Asian Sub- tropical Jet （EASJ） and the East Asian Polar-front Jet （EAPJ）. The border is located over the Tibetan Plateau according to NCEP2 data, but was not evident in FGOALS-s2 simulations. The seasonal cycles of the jet streams were found to be reasonably reproduced, except that they shifted northward relative to reanalysis data in boreal summer owing to the northward shift of negative MTGs. To identify the reasons for mean state bias, the dynamical and thermal forcings of STEA on mean flow were examined with a focus on boreal winter. The dynamical and thermal forcings were estimated by extended Eliassen-Palm flux （E） and transient heat flux, respectively. The results showed that the failure to reproduce the tripolar-pattern of the divergence of E over the jet regions led to an unsuccessful separation of the EASJ and EAPJ, while dynamical forcing contributed less to the weaker EASJ. In contrast, the weaker transient heat flux partly explained the weaker EASJ over the ocean.

Thermo-structural analysis on evaluating effects of friction and transient heat transfer on performance of gears in high-precision assemblies

The high precision assemblies with considerable radial interference should be accompanied by heating and cooling processes.However,the mechanical properties of metals are greatly affected by thermal operations.So,for evaluating the stress distribution and distortion of teeth profiles in a gear/shaft assembly,a transient thermal analysis is necessary for finding the change in mechanical properties.The friction on the contact surface is another important parameter in interaction of the gear with the shaft.Evaluating the gear stress and deformation fields for several modes of heat transfer and friction coefficients showed that the maximum radial or tangential stresses on contact surface of the joint may have more than 8%increase by increasing friction coefficient;while the intensity of heat transfer at cooling stage has lower effect on stress distribution.

Theoretical solution of transient heat conduction problem in one-dimensional double-layer composite medium

To make heat conduction equation embody the essence of physical phenomenon under study, dimensionless factors were introduced and the transient heat conduction equation and its boundary conditions were transformed to dimensionless forms. Then, a theoretical solution model of transient heat conduction problem in one-dimensional double-layer composite medium was built utilizing the natural eigenfunction expansion method. In order to verify the validity of the model, the results of the above theoretical solution were compared with those of finite element method. The results by the two methods are in a good agreement. The maximum errors by the two methods appear when τ（τ is nondimensional time） equals 0.1 near the boundaries of ζ =1 （ζ is nondimensional space coordinate） and ζ =4. As τ increases, the error decreases gradually, and when τ =5 the results of both solutions have almost no change with the variation of coordinate 4.

NUMERICAL METHOD OF MIXED FINITE VOLUME-MODIFIED UPWIND FRACTIONAL STEP DIFFERENCE FOR THREE-DIMENSIONAL SEMICONDUCTOR DEVICE TRANSIENT BEHAVIOR PROBLEMS

Transient behavior of three-dimensional semiconductor device with heat conduc- tion is described by a coupled mathematical system of four quasi-linear partial differential equations with initial-boundary value conditions. The electric potential is defined by an ellip- tic equation and it appears in the following three equations via the electric field intensity. The electron concentration and the hole concentration are determined by convection-dominated diffusion equations and the temperature is interpreted by a heat conduction equation. A mixed finite volume element approximation, keeping physical conservation law, is used to get numerical values of the electric potential and the accuracy is improved one order. Two con- centrations and the heat conduction are computed by a fractional step method combined with second-order upwind differences. This method can overcome numerical oscillation, dispersion and decreases computational complexity. Then a three-dimensional problem is solved by computing three successive one-dimensional problems where the method of speedup is used and the computational work is greatly shortened. An optimal second-order error estimate in L2 norm is derived by using prior estimate theory and other special techniques of partial differential equations. This type of mass-conservative parallel method is important and is most valuable in numerical analysis and application of semiconductor device.

Combining the complex variable reproducing kernel particle method and the finite element method for solving transient heat conduction problems

In this paper, the complex variable reproducing kernel particle （CVRKP） method and the finite element （FE） method are combined as the CVRKP-FE method to solve transient heat conduction problems. The CVRKP-FE method not only conveniently imposes the essential boundary conditions, but also exploits the advantages of the individual methods while avoiding their disadvantages, then the computational efficiency is higher. A hybrid approximation function is applied to combine the CVRKP method with the FE method, and the traditional difference method for two-point boundary value problems is selected as the time discretization scheme. The corresponding formulations of the CVRKP-FE method are presented in detail. Several selected numerical examples of the transient heat conduction problems are presented to illustrate the performance of the CVRKP-FE method.

Hybrid graded element model for transient heat conduction in functionally graded materials

This paper presents a hybrid graded element model for the transient heat conduction problem in functionally graded materials （FGMs）. First, a Laplace transform approach is used to handle the time variable. Then, a fundamental solution in Laplace space for FGMs is constructed. Next, a hybrid graded element is formulated based on the obtained fundamental solution and a frame field. As a result, the graded properties of FGMs are naturally reflected by using the fundamental solution to interpolate the intra-element field. Further, Stefest＇s algorithm is employed to convert the results in Laplace space back into the time-space domain. Finally, the performance of the proposed method is assessed by several benchmark examples. The results demonstrate well the efficiency and accuracy of the proposed method.

Experimental study on transient behavior of semi-open two-phase thermosyphon

An experimental system was set up to measure the temperature, pressure, heat transfer rate and mass flow rate in a semi-open two-phase thermosyphon. The behaviors of a semi-open two-phase thermosyphon during startup, shutdown and lack of water were studied to get complete understanding of its thermal characteristics. The variation of wall temperature, heat-exchange condition and pressure fluctuations of semi-open two-phase thermosyphons showed that the startup of SOTPT needs about 60-70 min; the startup speed of SOTPT is determined by the startup speed of the condensation section; the average pressure in the heat pipe is equal to the environmental pressure usually; the shutdown of SOTPT needs about 30-50min; a semi-open two-phase thermosyphon has good response to lack of water accident.

A meshless model for transient heat conduction analyses of 3D axisymmetric functionally graded solids

A meshless numerical model is developed for analyzing transient heat conductions in three-dimensional （3D） axisymmetric continuously nonhomogeneous functionally graded materials （FGMs）. Axial symmetry of geometry and boundary conditions reduces the original 3D initial-boundary value problem into a two-dimensional （2D） problem. Local weak forms are derived for small polygonal sub-domains which surround nodal points distributed over the cross section. In order to simplify the treatment of the essential boundary conditions, spatial variations of the temperature and heat flux at discrete time instants are interpolated by the natural neighbor interpolation. Moreover, the using of three-node triangular finite element method （FEM） shape functions as test functions reduces the orders of integrands involved in domain integrals. The semi-discrete heat conduction equation is solved numerically with the traditional two-point difference technique in the time domain. Two numerical examples are investigated and excellent results are obtained, demonstrating the potential application of the proposed approach.

Improved Particle Swarm Optimization for Solving Transient Nonlinear Inverse Heat Conduction Problem in Complex Structure

Accurately solving transient nonlinear inverse heat conduction problems in complex structures is of great importance to provide key parameters for modeling coupled heat transfer process and the structure’s optimization design.The finite element method in ABAQUS is employed to solve the direct transient nonlinear heat conduction problem.Improved particle swarm optimization(PSO)method is developed and used to solve the transient nonlinear inverse problem.To investigate the inverse performances,some numerical tests are provided.Boundary conditions at inaccessible surfaces of a scramjet combustor with the regenerative cooling system are inversely identified.The results show that the new methodology can accurately and efficiently determine the boundary conditions in the scramjet combustor with the regenerative cooling system.By solving the transient nonlinear inverse problem,the improved particle swarm optimization for solving the transient nonlinear inverse heat conduction problem in a complex structure is verified.

Consideration of transient heat conduction in a semi-infinite medium using homotopy analysis method

In the current work, transient heat conduction in a semi-infinite medium is considered for its many applications in various heat fields. Here, the homotopy analysis method （HAM） is applied to solve this problem and analytical results are compared with those of the exact and integral methods results. The results show that the HAM can give much better approximations than the other approximate methods： Changes in heat fluxes and profiles of temperature are obtained at different times and positions for copper, iron and aluminum.

An analytic model for transient heat conduction in bi-layered structures with flexible serpentine heaters

Uniform heating of complex surfaces,especially non-developable surfaces,is a crucial problem that traditional rigid heaters cannot solve.Inspired by flexible electronic devices,a novel design for the stretchable heating film is proposed with the flexible serpentine wire embedded in the soft polymer film,which can be attached to non-developable surfaces conformally.It provides a new way for the stretchable heaters to realize uniform heating of complex surfaces.However,the thermal field of flexible serpentine heaters(FSHs)depends on the configurations of the embedded serpentine heating wire,which requires accurate theoretical prediction of real-time temperature distribution.Therefore,the analytical model for the transient heat conduction in FSHs is solved by the separation of variables method and validated by the finite element analysis(FEA)in this paper.Based on this model,the effects of the geometric parameters,such as the radius and the length of the serpentine heaters,on the thermal uniformity are systematically investigated.This study can help to design and fabricate flexible heaters with uniform heating in the future.

A Novel Meshfree Analysis of Transient Heat Conduction Problems Using RRKPM

By introducing the radial basis functions(RBFs)into the reproducing kernel particle method(RKPM),the calculating accuracy and stability of the RKPM can be improved,and a novel meshfree method of the radial basis RKPM(meshfree RRKPM)is proposed.Meanwhile,the meshfree RRKPM is applied to transient heat conduction problems(THCP),and the corresponding equations of the meshfree RRKPM for the THCP are derived.The twopoint time difference scheme is selected to discretize the time of the THCP.Finally,the numerical results illustrate the effectiveness of the meshfree RRKPM for the THCP.

An improved local radial point interpolation method for transient heat conduction analysis

The smoothing thin plate spline （STPS） interpolation using the penalty function method according to the optimization theory is presented to deal with transient heat conduction problems. The smooth conditions of the shape functions and derivatives can be satisfied so that the distortions hardly occur. Local weak forms are developed using the weighted residual method locally from the partial differential equations of the transient heat conduction. Here the Heaviside step function is used as the test function in each sub-domain to avoid the need for a domain integral. Essential boundary conditions can be implemented like the finite element method （FEM） as the shape functions possess the Kronecker delta property. The traditional two-point difference method is selected for the time discretization scheme. Three selected numerical examples are presented in this paper to demonstrate the availability and accuracy of the present approach comparing with the traditional thin plate spline （TPS） radial basis functions.

EXPERIMENTAL RESEARCH ON TRANSIENT HEAT TRANSFER IN SAND

In order to examine if the heat conduction in porous material behaves like a wave as claimed by other researchers, experiments on transient heat transfer is conducted in casting sand. The results show that the heat propagation can be described neither by wave nor by diffusion model. The CV-wave concept is discussed and challenged according to the experimental results in the entire transient stage, including the transient response of temperature and the response curve of penetration-depth versus penetration-time.

A complex variable meshless local Petrov-Galerkin method for transient heat conduction problems

On the basis of the complex variable moving least-square （CVMLS） approximation, a complex variable meshless local Petrov-Galerkin （CVMLPG） method is presented for transient heat conduction problems. The method is developed based on the CVMLS approximation for constructing shape functions at scattered points, and the Heaviside step function is used as a test function in each sub-domain to avoid the need for a domain integral in symmetric weak form. In the construction of the well-performed shape function, the trial function of a two-dimensional （2D） problem is formed with a one-dimensional （1D） basis function, thus improving computational efficiency. The numerical results are compared with the exact solutions of the problems and the finite element method （FEM）. This comparison illustrates the accuracy as well as the capability of the CVMLPG method.