Near-surface wind field characteristics of the desert-oasis transition zone in Dunhuang,China

The desert-oasis transition zone(DOTZ)serves as a buffer area between the desert and oasis.Understanding its wind field characteristics is of great significance for the prevention and control of aeolian disasters in the oasis.In this study,we used meteorological data during 2013–2019 from the portable meteorological stations at five sites(site A on the edge of the oasis,sites B,C,and D in the DOTZ,and site O in the desert)in Dunhuang,China to analyze the near-surface wind field characteristics and their causes,as well as to reveal the key role of the DOTZ in oasis protection.The results showed that the mean wind speed,frequency of sand-driving wind,and directional variability of wind decreased from west to east within the DOTZ,and wind speed was significantly affected by air temperature.The terrain influenced the prevailing winds in the region,mainly from northeast and southwest.Only some areas adjacent to the oasis were controlled by southeasterly wind.This indicated that the near-surface wind field characteristics of the DOTZ were caused by the combined effects of local terrain and surface hydrothermal difference.At site D,the annual drift potential(DP)was 24.95 vector units(VU),indicating a low wind energy environment,and the resultant drift direction(RDD)showed obvious seasonal differences.Additionally,the DOTZ played an important buffering role between the desert and oasis.Compared with the desert,the mean wind speed in the oasis decreased by 64.98%,and the prevailing wind direction was more concentrated.The results of this study will be useful in interpreting the aeolian activity of the DOTZ in Dunhuang.

Dynamic Identification and Evolution of Urban-suburban-rural Transition Zones Based on the Blender of Natural and Humanistic Factors: A Case Study of Chengdu, China

Urban-suburban-rural(U-S-R)zones exhibit distinctive transitional characteristics in interaction between human and nature.U-S-R transition zones(U-S-RTZ)are also highlighting the function diversity and landscape heterogeneity across territorial spaces.As a super megacity in western China,Chengdu’s rapid urbanization has driven the evolution of U-S-R spaces,resulting in a sequential structure.To promote the high-quality spatial development of urban-rural region in a structured and efficient manner,it is essential to con-duct a scientific examination of the multidimensional interconnection within the U-S-RTZ framework.By proposing a novel identifica-tion method of U-S-RTZ and taking Chengdu,China as a case study,grounded in a blender of natural and humanistic factors,this study quantitatively delineated and explored the spatial evolutions of U-S-RTZ and stated the optimization orientation and sustainable devel-opment strategies of the production-living-ecological spaces along the U-S-R gradients.The results show that:1)it is suitable for the quantitative analysis of U-S-RTZ by established three-dimensional identification system in this study.2)In 1990-2020,the urban-sub-urban transition zones(U-STZ)in Chengdu have continuously undergone a substantial increase,and the scale of the suburban-rural transition zones(S-RTZ)has continued to expand slightly,while the space of rural-ecological transition zones(R-ETZ)has noticeably compressed.3)The landuse dynamics within U-S-RTZ has gradually increased in 1990-2020.The main direction of landuse transition was from farmland to construction land or woodlands,with the expansion of construction land being the most significant.4)R-ETZ primarily focus on ecological functions,and there is a trade-off relationship between the production-ecological function within the S-RTZ,and in the U-STZ,production-living composite functions are prioritized.This study emphasizes the importance of elastic planning and precise governance within the U-S-RTZ in a rapid urbanization region,particularly highlighting the role of suburbs as landscape corridors and service hubs in urban-rural integration.It elucidates to the practical implications for achieving high-quality development of integrated U-S-R territorial spaces.

Unraveling the Stray Current-Induced Interfacial Transition Zone(ITZ)Effect on Sulfate Corrosion in Concrete

The rail transit in sulfate-rich areas faces the combined effects of stray current and salt corrosion;however,the sulfate ion transport and concrete degradation mechanisms under such conditions are still unclear.To address this issue,novel sulfate transport and mesoscale splitting tests were designed,with a focus on considering the differences between the interfacial transition zone(ITZ)and cement matrix.Under the influence of stray current,the ITZ played a pivotal role in regulating the transport and mechanical failure processes of sulfate attack,while the tortuous and blocking effects of aggregates almost disappeared.This phenomenon was termed the“stray current-induced ITZ effect.”The experimental data revealed that the difference in sulfate ion transport attributed to the ITZ ranged from 1.90 to 2.31 times,while the difference in splitting strength ranged from 1.56 to 1.64 times.Through the real-time synchronization of splitting experiments and microsecond-responsive particle image velocimetry(PIV)technology,the mechanical properties were exposed to the consequences of the stray currentinduced ITZ effect.The number of splitting cracks in the concrete increased,rather than along the central axis,which was significantly different from the conditions without stray current and the ideal Brazilian disk test.Furthermore,a sulfate ion mass transfer model that incorporates reactivity and electrodiffusion was meticulously constructed.The embedded finite element calculation exhibited excellent agreement with the experimental results,indicating its reliability and accuracy.Additionally,the stress field was determined utilizing analytical methods,and the mechanism underlying crack propagation was successfully obtained.Compared to the cement matrix,a stray current led to more sulfates,more microstructure degradation,and greater increases in thickness and porosity in the ITZ,which was considered to be the essence of the stray current-induced ITZ effect.

Multiphysics processes in the interfacial transition zone of fiber-reinforced cementitious composites under induced curing pressure and implications for mine backfill materials: A critical review

The mesoscale fiber-matrix interfacial transition zone(FM-ITZ) under induced curing pressure plays a key role in the effectiveness of fiber reinforcement and the engineering application of fiber-reinforced cementitious composites(FRCCs). This critical review establishes the link among induced curing pressure(i.e., external loading condition), multiphysics processes(i.e., internal governing mechanism), and interface behavior(i.e., material behavior) for FRCC materials through analysis of the state-of-the-art research findings on the FM-ITZ of FRCC materials. The following results are obtained. For the mechanical process, the induced curing pressure changes the stress state and enhances multicracking behavior, which can strengthen the FM-ITZ. For the hydraulic process, the strengthened seepage of the FM-ITZ under induced curing pressure weakens the effective stress and exaggerates the deficiency in water retention capacity between the bulk matrix and the FMITZ. For the thermal process, the induced curing pressure causes a steep temperature gradient in the FM-ITZ and thus influences the temperature evolution and thermally-induced microcracks in the FM-ITZ. For the chemical process, the induced curing pressure enhances hydration kinetics and results in the formation of additional hydration products in the FM-ITZ. Moreover, recommendations are proposed on the basis of findings from this review to facilitate the implementation of fiber reinforcement in cemented paste backfill technology.

Influence of Evaporating Under the Clouds on the Precipitation Stable Isotope in the Transition Zone Between Tibetan Plateau and Arid Region of China

Consideration of stable isotopes in precipitation is valuable for investigating hydrological processes.Therefore,correcting the measured isotopic composition of precipitation under below-cloud evaporation is necessary.An accurate description of the underlying processes affecting stable isotopic composition of precipitation could help improve our understanding of the water cycle.The transitivity between monsoonal and arid climates was reflected by the evaporation rate of falling raindrops in precipitation in the Qilian Mountains,a typical transition zone between Tibetan Plateau and arid region of China.Considering 1310 precipitation event-scale samples,based on stable isotope analysis method,the mean below-cloud evaporation rate(f)in the study area was measured as 12.00%during the summer half-year(May-October).The evaporation rate on the northern slopes(12.70%)of the Qilian Mountains in China was significantly higher than that on the southern slopes(9.98%).The transition between monsoonal and arid climates was reflected in the evaporation rate of falling raindrops during precipitation in the Qilian Mountains of China.Below-cloud evaporation contributed to a noticeable enrichment of stable isotopes in the precipitation in the study area.The monthly precipitationδ^(18)O enrichment rate in the Qilian Mountains of China from May to October was 29.18%,23.35%,25.60%,22.99%,31.64%,and 14.72%,respectively.For every 1.00%increase in the evaporation rate of raindrops in Qilian Mountains of China,the changes in the concentration of oxygen isotopes from the bottom of the clouds to the ground increased by 0.92‰;however,with an evaporation rate of<5.00%,for every 1.00%increase in the evaporation rate of raindrops the changes in the concentration of oxygen isotopes from the bottom of the clouds to the ground increased by 1.00‰could also be observed.Furthermore,altitude was an important factor affecting below-cloud evaporation in the study area.

Influence Mechanism of Curing Regimes on Interfacial Transition Zone of Lightweight Ultra-High Performance Concrete

This study aims to clarify the effects of curing regimes and lightweight aggregate(LWA)on the morphology, width and mechanical properties of the interfacial transition zone(ITZ) of ultra-high performance concrete(UHPC), and provide reference for the selection of lightweight ultra-high performance concrete(L-UHPC) curing regimes and the pre-wetting degree LWA. The results show that, under the three curing regimes(standard curing, steam curing and autoclaved curing), LWA is tightly bound to the matrix without obvious boundaries. ITZ width increases with the water absorption of LWA and decreases with increasing curing temperature. The ITZ microhardness is the highest when water absorption is 3%, and the microhardness value is more stable with the distance from LWA. Steam and autoclaved curing increase ITZ microhardness compared to standard curing. As LWA pre-wetting and curing temperatures increase, the degree of hydration at the ITZ increases, generating high-density CSH(HD CSH) and ultra-high-density CSH(UHD CSH), and reducing unhydrated particles in ITZ. ITZ micro-mechanical properties are optimized due to hydration products being denser.

Stem sap flow of Haloxylon ammodendron at different ages and its response to physical factors in the Minqin oasis-desert transition zone, China

Haloxylon ammodendron, with its tolerance of drought, high temperature, and salt alkali conditions, is one of the main sand-fixing plant species in the oasis-desert transition zone in China. This study used the TDP30(where TDP is the thermal dissipation probe) to measure hourly and daily variations in the stem sap flow velocity of H. ammodendron at three age-classes(10, 15, and 20 years old,which were denoted as H10, H15, and H20, respectively) in the Minqin oasis-desert transition zone,China, from May through October 2020. By simultaneously monitoring temperature, relative humidity,photosynthetically active radiation, wind speed, net radiation, rainfall, and soil moisture in this region, we comprehensively investigated the stem sap flow velocity of different-aged H. ammodendron plants(H10,H15, and H20) and revealed its response to physical factors. The results showed that, on sunny days, the hourly variation curves of the stem sap flow velocity of H. ammodendron plants at the three age-classes were mainly unimodal. In addition, the stem sap flow velocity of H. ammodendron plants decreased significantly from September to October, which also delayed its peak time of hourly variation. On rainy days, the stem sap flow velocity of H. ammodendron plants was multimodal and significantly lower than that on sunny days.Average daily water consumption of H. ammodendron plants at H10, H15, and H20 was 1.98, 2.82, and 1.91kg/d, respectively. Temperature was the key factor affecting the stem sap flow velocity of H. ammodendron at all age-classes. Net radiation was the critical factor influencing the stem sap flow velocity of H.ammodendron at H10 and H15;however, for that at H20, it was vapor pressure deficit. The stem sap flow velocity of H. ammodendron was highly significantly correlated with soil moisture at the soil depths of 50and 100 cm, and the correlation was strengthened with increasing stand age. Altogether, our results revealed the dynamic changes of the stem sap flow velocity in different-aged H. ammodendron forest stands and its response mechanism to local physical factors, which provided a theoretical basis for the construction of new protective forests as well as the restoration and protection of existing ones in this region and other similar arid regions in the world.

Influence of train speed and its mitigation measures in the short-and long-term performance of a ballastless transition zone

The ballastless track is nowadays the most popular railway system due to the required low number of maintenance opera-tions and costs,despite the high investment.The gradual change from ballasted to ballastless tracks has been occurring in Asia,but also in Europe,increasing the number of transition zones.The transition zones are a special area of the railway networks where there is an accelerated process of track degradation,which is a major concern of the railway infrastructure managers.Thus,the accurate prediction of the short-and long-term performance of ballastless tracks in transition zones is an important topic in the current paradigm of building/rehabilitating high-speed lines.This work purposes the development of an advanced 3D model to study the global performance of a ballastless track in an embankment-tunnel transition zone considering the influence of the train speed(220,360,500,and 600 km/h).Moreover,a mitigation measure is also adopted to reduce the stress and displacements levels of the track in the transition.A resilient mat placed in the tunnel and embank-ment aims to soften the transition.The behaviour of the track with the resilient mat is evaluated considering the influence of the train speed,with special attention regarding the critical speed.The used methodology is a novel and hybrid approach that allows including short-term and long-term performance,through the development of a powerful 3D model combined with the implementation of a calibrated empirical permanent deformation model.

Evapotranspiration of an oasis-desert transition zone in the middle stream of Heihe River, Northwest China

As a main component in water balance, evapotranspiration is of great importance for water saving and irrigation-measure making, especially in arid or semiarid regions. Although studies of evapotranspiration have been conducted for a long time, studies concentrated on oasis-desert transition zone are very limited. On the basis of the meteorological data and other parameters（e.g. leaf area index（LAI）） of an oasis-desert transition zone in the middle stream of Heihe River from 2005 to 2011, this paper calculated both reference（ET0） and actual evapotranspiration（ETc） using FAO56 Penman-Monteith and Penman-Monteith models, respectively. In combination with pan evaporation（Ep） measured by E601 pan evaporator, four aspects were analyzed：（1） ET0 was firstly verified by Ep;（2） Characteristics of ET0 and ETc were compared, while the influencing factors were also analyzed;（3） Since meteorological data are often unavailable for estimating ET0 through FAO56 Penman-Monteith model in this region, pan evaporation coefficient（Kp） is very important when using observed Ep to predict ET0. Under this circumstance, an empirical formula of Kp was put forward for this region;（4） Crop coefficient（Kc）, an important index to reflect evapotranspiration, was also analyzed. Results show that mean annual values of ET0 and ETc were 840 and 221 mm, respectively. On the daily bases, ET0 and ETc were 2.3 and 0.6 mm/d, respectively. The annual tendency of ET0 and ETc was very similar, but their amplitude was obviously different. The differences among ET0 and ETc were mainly attributed to the different meteorological variables and leaf area index. The calculated Kc was about 0.25 and showed little variation during the growing season, indicating that available water（e.g. precipitation and irrigation） of about 221 mm/a was required to keep the water balance in this region. The results provide an comprehensive analysis of evapotranspiration for an oasis-desert transition zone in the middle stream of Heihe River, which was seldom reported before.

Effect of the Entrained Air Void on Strength and Interfacial Transition Zone of Air-Entrained Mortar

In order to facilitate the development and application of air entraining agents (AEA) in the high performance concrete, entrained air void structure parameters (air void size range from 10 to 1 600 mu m) of 28 d sifted mortar were measured by image analysis method. The relationship between the air void size distribution and strength of mortar was studied by methods of grey connection analysis and multiple linear regression analysis. The multiple linear regression equation was established with a correlation coefficient of 0.966. The weight of the affection of hierarchical porosity on the compressive strength ratio was also obtained. In addition, the effect of air voids on the paste-aggregate interfacial transition zone (ITZ) was analyzed by microhardness. The results show that the correlation between different pore size range and the compressive strength is negative. The effect of air void size distribution on 28 days compressive strength is different: under the condition of similar total porosity, with the increase of the porosity of the air void size, ranging from 10 to 200 mu m, and the decrease of the porosity, ranging from 200 to 1 600 mu m, the average air void diameter and mean free spacing are decreased; as well as the width of ITZ. On the contrary, the microhardness of the ITZ is increased while the compressive strength loss is decreased.

Quantitative Analysis and Affecting Factors of the Overlapping Degree of Interfacial Transition Zone between Neighboring Aggregates in Concrete

Based on the nearest surface function formula, a quantitative formula to measure the overlapping degree between the interfacial transition zone （ITZ） of neighboring aggregate particles was put forward. The formula was further deduced to quantitatively analyze the influence of the volume fraction of aggregate, ITZ thickness and the maximum aggregate diameter on the overlapping degree between neighboring ITZ. The volume of ITZ was quantitatively calculated in actual concrete by comparing the nearest surface function formula with an approximate method, that is the surface area of the aggregates multiplied by the uniform thickness of the ITZ layers. The results showed that the influencing order of these three factors on the overlapping degree between neighboring ITZ in turn was the interface thickness, aggregate volume fraction and the maximum aggregate diameter; As long as the interface thickness 50 μm and the aggregate volume fraction 50%, the calculated error between two methods mentioned above is about 10 %.

Anal transition zone in the surgical management of ulcerative colitis

Preservation of the anal transition zone has long been a significant source of controversy in the surgical management of ulcerative colitis.The two techniques for restorative proctocolectomy and ileal pouch anal anastomosis(RPC IPAA) in common practice are a stapled anastomosis and a handsewn anastomosis;these techniques differ in the amount of remaining rectal mucosa and therefore the presence of the anal transition zone following surgery.Each technique has advantages and disadvantages in long-term functional outcomes,operative and postoperative complications,and risk of neoplasia.Therefore,we propose a selective approach to performing a stapled RPC IPAA based on the presence of dysplasia in the preoperative endoscopic evaluation.

Iron Isotopic Fractionation and Origin of Chromitites in the Paleo-Moho Transition Zone of the Kop Ophiolite, NE Turkey

The Kop ophiolite in NE Turkey is a fragment of Neo-Tethyan forearc.It can be mainly divided into a paleo-Moho transition zone(MTZ)in the North and a harzburgitic mantle sequence in the South.Dunites are predominant in the MTZ of the Kop ophiolite,and they are locally interlayered with chromitites and enclose minor bodies of harzburgites near the petrological Moho boundary.Large Fe isotopic variations were observed for magnesiochromite(-0.14‰to 0.06‰)and olivine(-0.12‰to 0.14‰)from the MTZ chromitites,dunites and harzburgites.In individual dunite samples,magnesiochromite usually has lighter Fe isotopic compositions than olivine,which was probably caused by subsolidus Mg-Fe exchange between the two mineral phases.Both magnesiochromite and olivine display an increasing trend ofδ56Fe along a profile from chromitite todunite.This trend reflects continuous fractional crystallization in a magma chamber,which resulted in heavier Fe isotopes concentrated in the evolved magmas.In each cumulative cycle of chromitite and dunite,dunite was formed from relatively evolved melts after massive precipitation of magnesiochromite.Mixing of more primitive and evolved melts in the magma chamber was a potential mechanism for triggering the crystallization of magnesiochromite,generating chromitite layers in the cumulate pile.Before mixing happened,the primitive melts had reacted with mantle harzburgites during their ascendance;whereas the evolved melts may lie on the olivine-chromite cotectic near the liquidus field of pyroxene.Variable degrees of magma mixing and differentiation are expected to generate melts with differentδ56Fe values,accounting for the Fe isotopic variations of the Kop MTZ.

Imaging mantle transition zone discontinuities in southwest China from dense array ambient noise interferometry

Body waves retrieved from ambient noise cross-correlation functions（NCFs） have been reported by more and more recent studies in addition to the dominant recovered surface waves. And one of important applications of these recovered body waves is to investigate the structure of discontinuities within the mantle transition zone（MTZ）. In this study, clear body wave phases reflected from the MTZ discontinuities at 410 km and 660 km have been observed on the NCFs in the frequency band of 0.1–0.2 Hz from a dense regional seismic array in southwest China. The original timedomain reflected signals in the NCFs were first converted to the depth-domain NCFs based on a velocity model before they were further stacked spatially within different bins. Then the depth-domain NCFs were stacked to investigate the lateral variations of the MTZ discontinuities, that is, the 410-km and 660-km discontinuities. Our results exhibit a simple and lateral coherent P;P phase and a much more complicated P;P phase along two profiles, which are in good agreement with mineralogical prediction and recent receiver function studies in the same area. This interferometric method can provide stable reflected body wave phases mainly in the frequency band 0.1–0.2 Hz due to the secondary microseism noise, which can be potentially used for high-resolution mantle interface imaging. This approach is also a good complement to traditional imaging methods, such as receiver function imaging.

Sandstone-concrete interface transition zone (ITZ) damage and debonding micromechanisms under freeze-thaw

The sufficient bond between concrete and rock is an important prerequisite to ensure the effect of shotcrete support. However, in cold regions engineering protection system, the bond condition of rock and concrete surface is easily affected by freeze-thaw cycles, resulting in interface damage, debonding and even supporting failure. Understanding the micromechanisms of the damage and debonding of the rock-concrete interface is essential for improving the interface protection.Therefore, the micromorphology, micromechanical properties, and microdebonding evolution of the sandstone-concrete interface transition zone(ITZ) under varying freeze-thaw cycles(0, 5, 10, 15, 20) were studied using scanning electron microscope, stereoscopic microscope, and nano-indentation. Furthermore, the distribution range and evolution process of ITZ affected by freeze-thaw cycles were defined. Major findings of this study are as follows:(1) The microdamage evolution law of the ITZ under increasing freeze-thaw cycles is clarified, and the relationship between the number of cracks in the ITZ and freeze-thaw cycles is established;(2) As the number of freeze-thaw cycles increases, the ITZ's micromechanical strength decreases, and its development width tends to increase;(3) The damage and debonding evolution mechanisms of sandstone-concrete ITZ under freeze-thaw cycles is revealed, and its micromechanical evolution model induced by freeze-thaw cycles is proposed.

Geochemistry and Petrogenesis of Volcanic Rocks from the Continent-Ocean Transition Zone in Northern South China Sea and Their Tectonic Implications

Miocene–Pliocene(22–5 Myr) volcanism and associated seamounts are abundant in the continent-ocean transition(COT) zone in the margin of the north South China Sea(SCS). The petrogenesis of volcanic rocks from these seamounts and regional tectonic evolution of COT zone are poorly known. In this paper, we obtained whole-rock major and trace element compositions and Sr-Nd-Pb isotopic data for these volcanic rocks from the Puyuan and Beipo seamounts within COT zone, in northeastern SCS. Based on the geochemical analyses, the volcanic rocks are classified as alkaline ocean island basalts(OIB) and enriched mid-ocean ridge basalts(E-MORB). The OIBs from the Puyuan seamount are alkaline trachybasalts and tephrites that show enrichment of the light rare earth elements(LREE) relative to heavy rare earth elements(HREE) and more radiogenic Sr-Nd isotopic compositions, and have significant ‘Dupal isotopic anomaly'. In contrast, the E-MORBs from the Beipo seamount are tholeiitic basalts that have less enrichment in LREE and less radiogenic Sr-Nd isotopic compositions than the counterparts from the Puyuan seamount. Petrological and geochemical differences between the OIBs and MORBs from these two seamounts can be explained by different mantle sources and tectonic evolution stages of the COT zone. Syn-spreading OIB type basalts from the Puyuan seamount were derived from an isotopically ‘enriched', and garnet facies-dominated pyroxenitic mantle transferred by the Hainan mantle plume. In contrast, post-spreading E-MORB type basalts from the Beipo seamount are considered to be derived from the melting of isotopically ‘depleted' pyroxenite mantle triggered by lithosphere bending and subsequent post-rifting at the lower continental slope of the northern margin.

Numerical Experiments for the influence of the Transition Zone Migration on Summer Climate in North China

As the position of the transition zone changes obviously, that is, as the transition zone migrates to the north or the south from present position, it affects water or heat balance between the land and the atmosphere in a considerable degree and has a profound influence on climate in North China. The experiment results in this paper indicate whether in the dry case or in the wet case of the large-scale climatological background field, the surface air temperature in a wide range of the transition zone migration and its surrounding decreases as the transition zone migrates northward. Moreover, the net upward fluxes of the surface long wave radiation and the sensible heat decrease, and the evaporation to the atmosphere increases. As the transition zone migrates southward, the results are opposite. This kind of significant thermal forcing between the land and the atmosphere can excite secondary circulation or circulation cells, which interact with the large-scale circulation systems, changing the atmospheric motion, affecting the water vapor transportation and consequently having an effect on the precipitation.

Quantitative Characterization and Elastic Properties of Interfacial Transition Zone around Coarse Aggregate in Concrete

Backscattered electron images（BSE） obtained by scanning electron microscope was used to quantitatively characterize the microstructure of interfacial transition zone（ITZ） in concrete. Influences of aggregate size（5, 10, 20, and 30 mm）, water to cement ratio（0.23, 0.35 and 0.53） and curing time（from 3d to 90d） on the microstructure of interfacial transition zone between coarse aggregate and bulk cement matrix were investigated. The volume percentage of detectable porosity and unhydrated cement in ITZ was quantitatively analyzed and compared with that in the matrix of various concretes. Nanoindentation technology was applied to obtain the elastic properties of ITZ and matrix, and the elastic modulus of concrete was then calculated based on the Lu ＆ Torquato model and self-consistence scheme by using the ITZ thickness and elastic modulus obtained from this investigation. The experimental results demonstrated that the microstructure and thickness of ITZ in concrete vary with a variety of factors, like aggregate size, water to cement ratio and curing time. The relative low elastic properties of ITZ should be paid attention to, especially for early age concrete.

Nanoindentation Characteristics of Cement Paste and Interfacial Transition Zone in Mortar with Rice Husk Ash

The nanostructure of cementitious materials has important effects on concrete properties. The effects of rice husk ash（RHA） on cement hydration product phases and interfacial transition zone（ITZ） in mortar were investigated from the nano-scale structure perspective. The experimental results indicate that, with the increase of RHA dosages of samples, the volume fraction of high-density calcium-silicate-hydrate（HD C-S-H） in porosity and hydration product phases increases. The volume fractions of HD C-S-H in C-S-H of samples show an increasing trend with the increase of RHA dosages. RHA decreases the thickness of ITZ and increases the matrix elastic moduli of samples, however, the RHA dosoges hardly affect the thickness and elastic moduli.

Nanomechanical Characteristics of Interfacial Transition Zone in Nano-Engineered Concrete

This study investigates the effects of nanofillers on the interfacial transition zone(ITZ)between aggregate and cement paste by using nanoindentation and statistical nanoindentation techniques.Moreover,the underlying mechanisms are revealed through micromechanical modeling.The nanoindentation results indicate that incorporating nanofillers increases the degree of hydration in the ITZ,reduces the content of micropores and low-density calcium silicate hydrate(LD C-S-H),and increases the content of highdensity C-S-H(HD C-S-H)and ultra high-density C-S-H(UHD C-S-H).In particular,a new phase,namely nano-core-induced low-density C-S-H(NCILD C-S-H),with a superior hardness of 2.50 GPa and an indentation modulus similar to those of HD C-S-H or UHD C-S-H was identified in this study.The modeling results revealed that the presence of nanofillers increased the packing density of LD CS-H and significantly enhanced the interaction(adhesion and friction)among the basic building blocks of C-S-H gels owing to the formation of nano-core-shell elements,thereby facilitating the formation of NCILD C-S-H and further improving the performance of the ITZ.This study provides insight into the effects of nano fillers on the ITZ in concrete at the nanoscale.