Based on the data of core description and sporopollen analysis,the gradual evolution of deltas in vertical direction and transition of channel types in the MPE3 block of the eastern Venezuela Basin have been surveyed ...Based on the data of core description and sporopollen analysis,the gradual evolution of deltas in vertical direction and transition of channel types in the MPE3 block of the eastern Venezuela Basin have been surveyed by seismic phase and well logging facies interpretation.The results show that due to the great sea level rise,the sedimentary system of the Miocene Oficina Formation in the MPE3 block shifted from the distal-source sandy braided river delta to tide-affected delta,and eventually to tide-dominated delta.Vertically,during the early stage of sedimentation of Oficina Formation,the distributary channels of the delta were dominated by braided river channels.While in the later stage,as the tidal effect was gradually intensified,the channel changed from braided channel to meandering channel.On plane,as a result of differential transgression,sedimentary framework and distribution of sand bodies vary across the study area.Compared with the eastern part,the western part has more braided channels,larger channel bars,less developments of distributary bay and higher ratio of sand to mud.Whereas the braided channels in the south are larger than those in the north.It is the first time we pointed out the impact of marine transgression differences on the sedimentary facies distribution and river type transition in the study area.Factors like the structural and paleogeomorphological change,sea level variation,supply of sediments have strong influence on the evolution of sedimentary system and distribution of sandbodies.It is predicted that the major sandbody is more developed in the central south,which can guide the subsequent horizontal well development.展开更多
We study the percolation transition in a one-species cluster aggregation network model, in which the parameter α describes the suppression on the cluster sizes. It is found that the model can exhibit four types of pe...We study the percolation transition in a one-species cluster aggregation network model, in which the parameter α describes the suppression on the cluster sizes. It is found that the model can exhibit four types of percolation transitions, two continuous percolation transitions and two discontinuous ones. Continuous and discontinuous percolation transitions can be distinguished from each other by the largest single jump. Two types of continuous percolation transitions show different behaviors in the time gap. Two types of discontinuous percolation transitions are different in the time evolution of the cluster size distribution. Moreover, we also find that the time gap may also be a measure to distinguish different discontinuous percolations in this model.展开更多
Ferroelastic hybrid perovskite materials have been revealed the significance in the applications of switches,sensors,actuators,etc.However,it remains a challenge to design high-temperature ferroelastic to meet the req...Ferroelastic hybrid perovskite materials have been revealed the significance in the applications of switches,sensors,actuators,etc.However,it remains a challenge to design high-temperature ferroelastic to meet the requirements for the practical applications.Herein,we reported an one-dimensional organicinorganic hybrid perovskites(OIHP)(3-methylpyrazolium)CdCl_(3)(3-MBCC),which possesses a mmmF2/m ferroelastic phase transition at 263 K.Moreover,utilizing crystal engineering,we replace-CH_(3) with-NH_(2) and-H,which increases the intermolecular force between organic cations and inorganic frameworks.The phase transition temperature of(3-aminopyrazolium)CdCl_(3)(3-ABCC),and(pyrazolium)CdCl_(3)(BCC)increased by 73 K and 10 K,respectively.Particularly,BCC undergoes an unconventional inverse temperature symmetry breaking(ISTB)ferroelastic phase transition around 273 K.Differently,it transforms from a high symmetry low-temperature paraelastic phase(point group 2/m)to a low symmetry high-temperature ferroelastic phase(point group ī)originating from the rare mechanism of displacement of organic cations phase transition.It means that crystal BCC retains in ferroelastic phase above 273 K until melting point(446 K).Furthermore,characteristic ferroelastic domain patterns on crystal BCC are confirmed with polarized optical microscopy.Our study enriches the molecular mechanism of ferroelastics in the family of organic-inorganic hybrids and opens up a new avenue for exploring high-temperature ferroic materials.展开更多
Gigantspinosaurus sichuanensis is one of the six Stegosauria genera discovered from the Sichuan basin, which preserves the first skin impressions of stegosaurs around the world and a huge pair of 'comma' -shaped par...Gigantspinosaurus sichuanensis is one of the six Stegosauria genera discovered from the Sichuan basin, which preserves the first skin impressions of stegosaurs around the world and a huge pair of 'comma' -shaped parascapular spines kept in situ, and being named after the latter feature. The holotype was firstly named and reported in an abstract of a lecture by Ouyang, 1992, since when it has never been detailed studied and the taxonomic position of Gigantspinosaurus is also vague. The morphological redescription shows that G. sichuanensis is a medium-sized stegosaur, with external mandibular foramen developed. The ratio of femur to humerus is large, and the intersacral fenestrae are big. According to the wear degree of teeth, the holotype of G. sichuanensis is regarded as an adult individual. On the basis of the recent data matrix of stegosaurs and the characters revisions of G. sichuanensis, its phylogenetic position has been determined again. By our detailed morphological and phylogenetic analysis, G. sichuanensis is considered to inherit some primitive traits, but it is more derived than Huayangosaurus, and located in a transitional position between Huayangosaurus and Tuojiangosaurus, as a kind of evolved stegosaurs. The ancestors of Stegosauria are small and quadruped, with primitive ornithopod-like skull, and grow leaf-shaped teeth, a large number of bone plates.展开更多
We investigated the influence of an inserted bar on the hopper flow experimentally.Three geometrical parameters,size of upper outlet D1,size of lower outlet D0,and the height of bar H,are variables here.With varying H...We investigated the influence of an inserted bar on the hopper flow experimentally.Three geometrical parameters,size of upper outlet D1,size of lower outlet D0,and the height of bar H,are variables here.With varying H we found three regimes:one transition from clogging to a surface flow and another transition from a surface flow to a dense flow.For the dense flow,the flow rate follows Beverloo’s law and there is a saturation of inclination of free surfaceθ.We plotted the velocity field and there is a uniform linear relation between the particle velocity and depth from the free surface.We also found that the required value of D_(1) to guarantee the connectivity of flow is little smaller than D_(0).For the transition from a surface flow to a dense flow,there is a jump of flow rate and the minimumθfor flowing is two degrees larger than the repose angle.展开更多
Interesting classifications of basinogenesis and basins were proposed by many scientists. They classified basinogenesis and basins mainly from a single angle, either from a historical angle or from a dynamic angle . I...Interesting classifications of basinogenesis and basins were proposed by many scientists. They classified basinogenesis and basins mainly from a single angle, either from a historical angle or from a dynamic angle . In order to more comprehensively understand them for more effectively guiding prospecting and exploration, the author integrates the two methods of analysis with each other and proposes an integrative classification .According to the historical - dynamic integrative classification,basinogenesis and basins can be.di-vided into three types :oceanic crust type ,embryo-continental (transitional )crust type and continental crust type .Oceanic crust type can be subdivided into mobile region type (mainly tenskmal )and stable region type . Embryo-continental type includes pre-geosynclinal type (divisible into several mobile region types and stable region types with tensional type predominating among mobile region types ) and ear ly-geosynclinal type (mainly tenskmal ) .Continental crust type includes late- geosynclinal (fold belt)type (compressional or tenskmal ),platform type (mainly sinking and rarely tenskmal subsidence-aulacogen)and geodepression (diwa )type (compressional , tenskmal or compresskmal-tenskmal ).展开更多
Desertification is one of the most serious eco-environmental problems around Qinghai Lake.Based on GIS and RS,GIS analysis was used to obtain the information of spatial-temporal change and different pattern of deserti...Desertification is one of the most serious eco-environmental problems around Qinghai Lake.Based on GIS and RS,GIS analysis was used to obtain the information of spatial-temporal change and different pattern of desertification in each county around Qinghai Lake in four phases of1976,1987,1995 and 2006.Using the function of intersect and overlay supported by ARCGIS,with analyzing attributes of vector RS images,we obtained transition data and established transfer matrix of land-use types in recent 30 years,besides,protracted land-use transition maps of all desertification classes.In further,we analyzed transition quantity and direction of desertification in each county,moreover,reconstructed the process of spatial-temporal evolution of desertification.The results are showed below:(1)it's the transition between desertified land and others but not in the desertified that played the main role in Gangcha and Gonghe County,while the transfer between desertified lands were greater than that with other land-use types in Haiyan County.(2)Extremely severe desertified land mainly distributes in Ketu and Sand Islands that belongs to Haiyan County,and moderate desertified land in riversides of Gangcha County,also,the light desertification expanded too rapidly to become the most desertified land-use type in the surrounding of Qinghai Lake since 1976.(3)By using relative change rate of desertified land,the regional variability rank from top to toe was Gangcha,Haiyan and Gonghe.展开更多
In this work, the mesophase properties were tuned via mixing two discotic molecules with structural complementarity. Compared with the liquid crystalline hexakis(n-hexyloxy)triphenylene(H6TP)materials(columnar he...In this work, the mesophase properties were tuned via mixing two discotic molecules with structural complementarity. Compared with the liquid crystalline hexakis(n-hexyloxy)triphenylene(H6TP)materials(columnar hexagonal phase from 53 ℃ to 91 ℃), mesophase types as well as phase transition temperatures varied with the introduction of crystalline hexaazatriphenylene derivative(PBH)molecules. The introduction of less than 33% amount of PBH disrupted the columnar hexagonal phase formed by H6 TP remarkably, followed by the decreased clearing temperatures of liquid crystals. As the PBH amount was further increased, the destroyed columnar hexagonal phase was turned into the columnar rectangular phase, in which H6 TP and PBH molecules together formed the columnar mesophase. The formation of new mesophase contributed to the enlarged mesophase temperature(from44 ℃ to 144 ℃). We speculated that the alkyl chains interaction induced by the PBH component competed with the strong p–p stacking between H6 TP molecules, thus altering the liquid crystalline properties including mesophase types and phase transition temperatures.展开更多
基金supported by the Important National Science Technology Specific Projects (number 2016ZX05031-001)
文摘Based on the data of core description and sporopollen analysis,the gradual evolution of deltas in vertical direction and transition of channel types in the MPE3 block of the eastern Venezuela Basin have been surveyed by seismic phase and well logging facies interpretation.The results show that due to the great sea level rise,the sedimentary system of the Miocene Oficina Formation in the MPE3 block shifted from the distal-source sandy braided river delta to tide-affected delta,and eventually to tide-dominated delta.Vertically,during the early stage of sedimentation of Oficina Formation,the distributary channels of the delta were dominated by braided river channels.While in the later stage,as the tidal effect was gradually intensified,the channel changed from braided channel to meandering channel.On plane,as a result of differential transgression,sedimentary framework and distribution of sand bodies vary across the study area.Compared with the eastern part,the western part has more braided channels,larger channel bars,less developments of distributary bay and higher ratio of sand to mud.Whereas the braided channels in the south are larger than those in the north.It is the first time we pointed out the impact of marine transgression differences on the sedimentary facies distribution and river type transition in the study area.Factors like the structural and paleogeomorphological change,sea level variation,supply of sediments have strong influence on the evolution of sedimentary system and distribution of sandbodies.It is predicted that the major sandbody is more developed in the central south,which can guide the subsequent horizontal well development.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11575036 and 11505016
文摘We study the percolation transition in a one-species cluster aggregation network model, in which the parameter α describes the suppression on the cluster sizes. It is found that the model can exhibit four types of percolation transitions, two continuous percolation transitions and two discontinuous ones. Continuous and discontinuous percolation transitions can be distinguished from each other by the largest single jump. Two types of continuous percolation transitions show different behaviors in the time gap. Two types of discontinuous percolation transitions are different in the time evolution of the cluster size distribution. Moreover, we also find that the time gap may also be a measure to distinguish different discontinuous percolations in this model.
基金support from the National Natural Science Foundation of China(No.22175079)support from the National Natural Science Foundation of China(No.22205087)+2 种基金the Open Project Program of Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry,Jiangxi University of Science and Technology(No.20212BCD42018)National Natural Science Foundation of China(No.22275075)Natural Science Foundation of Jiangxi Province(Nos.20204BCJ22015 and 20202ACBL203001).
文摘Ferroelastic hybrid perovskite materials have been revealed the significance in the applications of switches,sensors,actuators,etc.However,it remains a challenge to design high-temperature ferroelastic to meet the requirements for the practical applications.Herein,we reported an one-dimensional organicinorganic hybrid perovskites(OIHP)(3-methylpyrazolium)CdCl_(3)(3-MBCC),which possesses a mmmF2/m ferroelastic phase transition at 263 K.Moreover,utilizing crystal engineering,we replace-CH_(3) with-NH_(2) and-H,which increases the intermolecular force between organic cations and inorganic frameworks.The phase transition temperature of(3-aminopyrazolium)CdCl_(3)(3-ABCC),and(pyrazolium)CdCl_(3)(BCC)increased by 73 K and 10 K,respectively.Particularly,BCC undergoes an unconventional inverse temperature symmetry breaking(ISTB)ferroelastic phase transition around 273 K.Differently,it transforms from a high symmetry low-temperature paraelastic phase(point group 2/m)to a low symmetry high-temperature ferroelastic phase(point group ī)originating from the rare mechanism of displacement of organic cations phase transition.It means that crystal BCC retains in ferroelastic phase above 273 K until melting point(446 K).Furthermore,characteristic ferroelastic domain patterns on crystal BCC are confirmed with polarized optical microscopy.Our study enriches the molecular mechanism of ferroelastics in the family of organic-inorganic hybrids and opens up a new avenue for exploring high-temperature ferroic materials.
基金supported by Zigong Dinosaur Museum curator foundation
文摘Gigantspinosaurus sichuanensis is one of the six Stegosauria genera discovered from the Sichuan basin, which preserves the first skin impressions of stegosaurs around the world and a huge pair of 'comma' -shaped parascapular spines kept in situ, and being named after the latter feature. The holotype was firstly named and reported in an abstract of a lecture by Ouyang, 1992, since when it has never been detailed studied and the taxonomic position of Gigantspinosaurus is also vague. The morphological redescription shows that G. sichuanensis is a medium-sized stegosaur, with external mandibular foramen developed. The ratio of femur to humerus is large, and the intersacral fenestrae are big. According to the wear degree of teeth, the holotype of G. sichuanensis is regarded as an adult individual. On the basis of the recent data matrix of stegosaurs and the characters revisions of G. sichuanensis, its phylogenetic position has been determined again. By our detailed morphological and phylogenetic analysis, G. sichuanensis is considered to inherit some primitive traits, but it is more derived than Huayangosaurus, and located in a transitional position between Huayangosaurus and Tuojiangosaurus, as a kind of evolved stegosaurs. The ancestors of Stegosauria are small and quadruped, with primitive ornithopod-like skull, and grow leaf-shaped teeth, a large number of bone plates.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11705256 and 11905272)National Postdoctoral Program for Innovative Talents,China(Grant No.BX201700258)West Light Foundation of the Chinese Academy of Sciences(Grant No.2018-98)。
文摘We investigated the influence of an inserted bar on the hopper flow experimentally.Three geometrical parameters,size of upper outlet D1,size of lower outlet D0,and the height of bar H,are variables here.With varying H we found three regimes:one transition from clogging to a surface flow and another transition from a surface flow to a dense flow.For the dense flow,the flow rate follows Beverloo’s law and there is a saturation of inclination of free surfaceθ.We plotted the velocity field and there is a uniform linear relation between the particle velocity and depth from the free surface.We also found that the required value of D_(1) to guarantee the connectivity of flow is little smaller than D_(0).For the transition from a surface flow to a dense flow,there is a jump of flow rate and the minimumθfor flowing is two degrees larger than the repose angle.
文摘Interesting classifications of basinogenesis and basins were proposed by many scientists. They classified basinogenesis and basins mainly from a single angle, either from a historical angle or from a dynamic angle . In order to more comprehensively understand them for more effectively guiding prospecting and exploration, the author integrates the two methods of analysis with each other and proposes an integrative classification .According to the historical - dynamic integrative classification,basinogenesis and basins can be.di-vided into three types :oceanic crust type ,embryo-continental (transitional )crust type and continental crust type .Oceanic crust type can be subdivided into mobile region type (mainly tenskmal )and stable region type . Embryo-continental type includes pre-geosynclinal type (divisible into several mobile region types and stable region types with tensional type predominating among mobile region types ) and ear ly-geosynclinal type (mainly tenskmal ) .Continental crust type includes late- geosynclinal (fold belt)type (compressional or tenskmal ),platform type (mainly sinking and rarely tenskmal subsidence-aulacogen)and geodepression (diwa )type (compressional , tenskmal or compresskmal-tenskmal ).
基金National Key Technology R&D Program of China(2007BAC30B03)"The Fundamental Research Funds for the Central Universities"and"Forestry Industry Research Special Funds for Public Welfare"(201004025)
文摘Desertification is one of the most serious eco-environmental problems around Qinghai Lake.Based on GIS and RS,GIS analysis was used to obtain the information of spatial-temporal change and different pattern of desertification in each county around Qinghai Lake in four phases of1976,1987,1995 and 2006.Using the function of intersect and overlay supported by ARCGIS,with analyzing attributes of vector RS images,we obtained transition data and established transfer matrix of land-use types in recent 30 years,besides,protracted land-use transition maps of all desertification classes.In further,we analyzed transition quantity and direction of desertification in each county,moreover,reconstructed the process of spatial-temporal evolution of desertification.The results are showed below:(1)it's the transition between desertified land and others but not in the desertified that played the main role in Gangcha and Gonghe County,while the transfer between desertified lands were greater than that with other land-use types in Haiyan County.(2)Extremely severe desertified land mainly distributes in Ketu and Sand Islands that belongs to Haiyan County,and moderate desertified land in riversides of Gangcha County,also,the light desertification expanded too rapidly to become the most desertified land-use type in the surrounding of Qinghai Lake since 1976.(3)By using relative change rate of desertified land,the regional variability rank from top to toe was Gangcha,Haiyan and Gonghe.
基金supported by the National Natural Science Foundation of China(No.51303177)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB12020300)
文摘In this work, the mesophase properties were tuned via mixing two discotic molecules with structural complementarity. Compared with the liquid crystalline hexakis(n-hexyloxy)triphenylene(H6TP)materials(columnar hexagonal phase from 53 ℃ to 91 ℃), mesophase types as well as phase transition temperatures varied with the introduction of crystalline hexaazatriphenylene derivative(PBH)molecules. The introduction of less than 33% amount of PBH disrupted the columnar hexagonal phase formed by H6 TP remarkably, followed by the decreased clearing temperatures of liquid crystals. As the PBH amount was further increased, the destroyed columnar hexagonal phase was turned into the columnar rectangular phase, in which H6 TP and PBH molecules together formed the columnar mesophase. The formation of new mesophase contributed to the enlarged mesophase temperature(from44 ℃ to 144 ℃). We speculated that the alkyl chains interaction induced by the PBH component competed with the strong p–p stacking between H6 TP molecules, thus altering the liquid crystalline properties including mesophase types and phase transition temperatures.