Statistics of the Tropopause Inversion Layer over Beijing

High resolution radiosonde data from Beijing, China in 2002 are used to study the strong tropopause inversion layer （TIL） in the extratropical regions in eastern Asia. The analysis, based on the tropopause- based mean （TB-mean） method, shows that the TIL over Beijing has similar features as over other sites in the same latitude in Northern America. The reduced values of buoyancy frequency in 13-17 km altitude in winter-spring are attributed to the higher occurrence frequency of the secondary tropopause in this season. In the monthly mean temperature profile relative to the secondary tropopause, there also exists a TIL with somewhat enhanced static stability directly over the secondary sharp thermal tropopause, and a 4 km thickness layer with reduced values of buoyancy frequency just below the tropopause, which corresponds to the 13-17 km layer in the first TB-mean thermal profile. In the monthly mean temperature profile relative to the secondary tropopause, a TIL also exists but it is not as strong. For individual cases, a modified definition of the TIL, focusing on the super stability and the small distance from the tropopause, is introduced. The analysis shows that the lower boundary of the newly defined TIL is about 0.42 km above the tropopause, and that it is higher in winter and lower in summer; the thickness of the TIL is larger in winter-spring.

Cross-Tropopause Mass Exchange Associated with a Tropopause Fold Event over the Northeastern Tibetan Plateau

A springtime tropopause fold event, found to be related to a cold trough intrusion from the north, was detected in the northeastern Tibetan Plateau （TP） based on various observations. A nested high-resolution mesoscale model was employed to investigate the effect of orography on the stratosphere-troposphere exchange. The model was found to be able to capture plausible tropopause fold properties. The propagation of the tropopause fold changed significantly when the terrain height in the model was altered. However, decreasing the terrain height had no significant effect on the morphology of folds. When a fold passed over an elevated surface, a leeside jet stream and a layer of humid air in the middle troposphere tended to develop. This strong leeside descent of air masses and high mid-level potential instability （PI） could give rise to deep upward motions in the leeside and inject tropospheric air into the lower stratosphere. Besides, when the flow encounters an elevated surface, forced lifting together with mid-level PI can trigger deep convective motions on the windward slope. The troposphere to stratosphere transport was found to be persistent and almost stationary over the windward slope of the TP during the evolution of the fold.

Observation of a Summer Tropopause Fold by Ozonesonde at Changchun,China:Comparison with Reanalysis and Model Simulation

Tropopause folds are one of the key mechanisms of stratosphere-troposphere exchange （STE） in extratropical regions, transporting ozone-rich stratospheric air into the middle and lower troposphere. Although there have been many studies of tropopause folds that have occurred over Europe and North America, a very limited amount of work has been carried out over northeastern Asia. Ozonesondes produced by the Institute of Atmospheric Physics were launched in Changchun （43.9°N, 125.2° E）, Northeast China, in June 2013, and observed an ozone-enriched layer with thickness of 3 km and an ozone peak of 180 ppbv at 6 km in the troposphere. The circulation field from the European Centre for Medium-Range Weather Forecasts Interim Reanalysis （ERA-Interim） dataset shows that this ozone peak was caused by a tropopause fold associated with a jet stream at the eastern flank of the East Asian trough. By analyzing the ozone data from the ozone monitoring instrument and Weather Research and Forecasting model with Chemistry （WRF-Chem） simulations, it was found that a high ozone concentration tongue originating from the lower stratosphere at high latitude （near central Siberia） intruded into the middle troposphere over Changchun between 5 and 8 km on 12 June 2013. The high-resolution WRF-Chem simulation was capable of describing events such as the tropopause fold that occurred on the cyclonic shear side of the jet stream. In addition, the TRAJ3D trajectory model was used to trace the origin of measured secondary ozone peaks in the middle troposphere back, for example, to stratospheric intrusion through the tropopause fold.

Dynamical Tropopause Variability and Potential Vorticity Streamers in the Northern Hemisphere——A Climatological Analysis

This study presents a 44-year climatology of potential vorticity （PV） streamers in the Northern Hemisphere based upon analyses of the ERA-40 reanalysis data set. A comparison to an existing 15-year climatology yields very good agreement in the locations of PV streamer frequency maxima, but some differences are found in the amplitude of frequencies. The climatology is assessed with the focus on links between PV streamer frequencies and the synoptic- and planetary-scale variability of the dynamical tropopause. A comprehensive overview is provided on where （zonally） and when （seasonally） short-term variability throughout the extra-tropical and sub-tropical tropopause is enhanced or reduced. Several key processes that influence this variability are discussed. Baroclinic processes, for example, determine the variability in the storm-track areas in winter, whereas the Asian summer monsoon significantly influences the variability over Asia. The paper also describes links between the frequency of PV streamers in the extra-tropical and subtropical tropopause and three major northern hemisphere teleconnection patterns. The observed changes in the PV streamer frequencies are closely related to concomitant variations of PV and its gradient within the tropopause region. During opposite phases of the North Atlantic Oscillation the location of the streamer frequency maxima shifts significantly in the Atlantic and European region in both the extra-tropics and subtropics. The influence of ENSO on the streamer frequencies is most pronounced in the subtropical Pacific.

A CASE STUDY OF THE UNCORRELATED RELATIONSHIP BETWEEN TROPICAL TROPOPAUSE TEMPERATURE ANOMALIES AND STRATOSPHERIC WATER VAPOR ANOMALIES

Using the measurements from the Halogen Occultation Experiment(HALOE) and the European Centre for Medium-Range Weather Forecasts(ECMWF) Interim reanalysis data for the period 1994-2005, we analyzed the relationship between tropical tropopause temperature anomalies and stratospheric water vapor anomalies. It is found that tropical tropopause temperature is correlated with stratospheric water vapor, i.e., an anomalously high(low) tropical tropopause temperature corresponds to anomalously high(low) stratospheric water vapor during the period 1994-2005,except for 1996. The occurrence frequency and strength of deep convective activity during the‘mismatched'months is less and weaker than that during the‘matched'months in 1996. However, the instantaneous intensity of four short periods of deep convective activity, caused by strong surface cyclones and high sea surface temperatures, are greater during the ‘mismatched'months than during the ‘matched'months. Water vapor is transported from the lower troposphere to the lower stratosphere through a strong tropical upwelling, leading to an increase in stratospheric water vapor. On the other hand, deep convective activity can lift the tropopause and cool its temperature. In short, the key factor responsible for the poor correlation between tropical tropopause temperature and stratospheric water vapor in1996 is the instantaneous strong deep convective activity. In addition, an anomalously strong Brewer-Dobson circulation brings more water vapor into the stratosphere during the‘mismatched'months in 1996, and this exacerbates the poor correlation between tropical tropopause temperature and stratospheric water vapor.

On the Spatio-Temporal Variations of the Tropopause Height over India and Indian Summer Monsoon Activity

The spatio-temporal variation of the tropopause height (TH) over the Indian region (5°N-35°N, 70°E-95°E) has been studied using monthly mean TH data, for 22-year period, 1965 to 1986. The study revealed that the stations south of 20° showed maximum TH in April / May and minimum in September. This variation in TH has been attributed to the corresponding variation of average sea surface temperature (SST) over ± 20° latitudinal belt over Indian Ocean, Arabian Sea and Bay of Bengal. Further the stations north of 20°N showed maximum in June and minimum in October/ November. This maximum in TH has primarily been attributed to the increased insolation and convection. Furthermore it is noticed that the anomaly of TH moved northwards during the period April to July.The interannual variability of the Indian Summer Monsoon Activity (ISMA) has been studied in relation to all India mean TH (at 12 GMT) for six months April through September. The composites of mean TH for good and bad monsoon years showed that all India mean TH is statistically higher in good monsoon years than in bad monsoon years. The relationship between ISMA and all India mean May TH has been studied using the contingency table. The study suggested that the forecast of ISMA could be prepared using mean May TH.

Ten-Year Climatological Features and Air Origin of Midlatitude Double Tropopauses

The 10-year climatological features related to midlatitude double tropopause events （DTs） are examined using ERA- Interim data from 2003 to 2012. The analysis is based on tropopauses defined by lapse rate. Results show that DTs are permanent or semi-permanent in the midlatitudes, and high DT frequency bands move poleward in winter and equatorward in summer, which is consistent with the seasonal movement of the subtropical jet. Based on our statistics, the second tropopause is found at about 100 hPa in the subtropics and at slightly lower altitudes in sub-polar regions. The thickness between the first and second tropopause is smaller in the subtropics and increases with latitude. Next, the origin of air sandwiched between the first and second tropopause of DTs is studied with a revised version of the UK Universities Global Atmospheric Modelling Programme Offline Trajectory Code （Version 3） diabatic trajectory model. The results show that, in the lower or middle troposphere, air is transported into the DTs from lower latitudes, mainly in the tropics. The dominant source regions are mainly areas of deep convection and steep orography, e.g., the western Pacific and Himalayan Mountains, and they show strong seasonality following the seasonal shift of these strong upwelling regions.

A new method to determine the tropopause

The tropopause has a complex structure and some interference information may exist in high-resolution global positioning system （GPS）/low earth-orbiting （LEO） radio occultation （RO） data. The position of the tropopause cannot be accurately determined using traditional cold point tropopause （CPT） and lapse rate tropopause （LRT） algorithms. In this paper, an integrative algorithm is developed to determinate tropopause parameters. The algorithm is applied to GPS/COSMIC RO data to obtain a global distribution of the height and temperature of the tropopause. This algorithm improves the utilization rate of GPS/LEO RO data by 30% compared with that from the traditional CPT method. The rationality and reliability of GPS/LEO RO data in probing the Earth＇s atmosphere are verified by our study of the tropopause using COSMIC data.

Analysis on mechanisms of anomalous variations of tropopause pressure over the Tibetan Plateau during summer in Northern Hemisphere

Using the monthly mean data from NCEP-NCAR reanalysis, through building tropopause pressure index, we investigated the mechanisms of anomalous variations of tropopause pressure over the Tibetan Plateau during summer in Northem Hemisphere. For comparative analysis we selected representative years of 1992 and 1998 to study, and they were respectively the highest and the lowest year oftropopause pressure anomaly over the Tibetan Plateau. The results are summarized as follows： （1） Over the Tibetan Plateau, the variations of tropopause pressure are well correlated respectively with anomalous temperature and geopotential height in both troposphere and stratosphere. Besides, the anomalous tropopause pressure has also close relation with anomalous surface temperature in the Tibetan Plateau. In 1992, the surface temperature was anomalously low, correspondingly, the tropopause pressure over the Tibetan Plateau was anomalously high; but in 1998, the opposite was the case. （2） Over the Tibetan Plateau, the correlation of tropopause pressure and OLR （Outgoing Longwave Radiation） is found to be positive. Furthermore, by further diagnosing the circulation fields between 850 hPa and 200 hPa levels and the whole troposphere vapour field, we found out that the anomalously high tropopause pressure in 1992 corresponded to the anticyclonic divergence of low level wind fields and the cyclonic convergence of high level wind fields, and coupled with divergence of the whole troposphere vapour fields along with the South Asian High weakened at the same time. While in 1998, the case was opposite to that in 1992. These facts indicated that the anomalous convection resulted in the significant difference oftropopause pressure in 1992 and 1998 over the Tibetan Plateau. （3） The vertically integrated heat budget anomalies were responsible for explaining tropopause pressure anomalies in 1992 and 1998 over the Tibetan Plateau.

A Novel Tool for the Determination of Tropopause Heights by Using GNSS Radio Occultation Data

The tropopause is a transitional layer between the troposphere and the stratosphere. The exchange of chemical constituents of the atmosphere (namely masses of air, water vapor, trace gases etc.) and energy between the troposphere and the stratosphere occurs through this layer. We suppose that just exchanges that are taking place at the tropopause heights are strongly influenced by the Global Change forcing. For this reason it is particularly urgent to accumulate temporal data the most accurate possible and with a certain continuity series to understand comprehensively what is happening to our climate. It is well known that Radio Occultation technique applied using Global Navigations Satellite Systems (GNSS-RO) is a powerful tool to detect the tropopause heights. It can be done working on the level 2 data provided by GNSS-RO payload: i.e. atmospheric profiles of pressure and temperature. We propose to measure tropopause using GNSS-RO level 1 data;i.e. the bending angles (BA) of the GNSS signal through the atmosphere. We fit the BA profiles applying in the integral relationship of BA as refractivity profile of background the Hopfield dry model of atmosphere which depends on the fourth degree of the height above the Earth. Through the layers in which tropopause is contained, the residuals between the background model and the observed BA have an anomalous trend. The residuals in this zone form anomalous non-gaussian bumps that we have exploited just to determine the relevant parameters of the tropopause. Such bumps are due to the wrong theoretical assumption made by Hopfield for the re-construction of the dry refractivity that the temperature lapse rate of the atmosphere is constant. But we know that the definition of tropopause according the World Meteorological Organization (WMO) is just the height where a sudden change of the temperature lapse rate usually occurs. Thus in the present work we have determined tropopause heights with new algorithms which exploit the bumps occurring along the BA profiles achieved by GNSS-RO. We have used the huge amount of data provided by several space missions devoted to GNSS-RO (namely COSMIC, METOP, etc.) for tuning the algorithms, performed a validation and provided a robust statistical soundness. The same GNSS-RO observations are helpful also to reconstruct the Mapping Function commonly applied in geodetic applications. Global mapping functions built with GNSS-RO and their evolution in time can be an interesting parameter helpful for climate investigations as well.

Circulation Background and Genesis Mechanism of a Cold Vortex over the Tibetan Plateau during Late April 2018

A cold vortex occurred over the northeastern Tibetan Plateau(TP)on 27 April 2018 and subsequently brought excessive rainfall to the spring farming area in southern China when moving eastward.This study investigates the genesis mechanism of the cold TP vortex(TPV)by diagnosing reanalysis data and conducting numerical experiments.Results demonstrate that the cold TPV was generated in a highly baroclinic environment with significant contributions of positive potential vorticity(PV)forcing from the tropopause and diurnal thermodynamic impact from the surface.As a positive PV anomaly in the lower stratosphere moved towards the TP,the PV forcing at the tropopause pushed the tropospheric isentropic surfaces upward,forming isentropic-isplacement ascent and reducing static stability over the TP.The descent of the tropopause over the TP also produced a tropopause folding over the northeastern TP associated with a narrow high-PV column intruding downwards over the TPV genesis site,resulting in ascending air in the free atmosphere.This,in conjunction with the descending air in the valley area during the night,produced air stretching just at the TPV genesis site.Because the surface cooling at night increased the surface static stability,the aforementioned vertical air-stretching thus converted the produced static stability to vertical vorticity.Consequently,the cold TPV was generated over the valley at night.

Meteorological Satellite Remote Sensing of Tropopause Height

The tropopause is the boundary between the troposphere and the stratrosphere, and it is significant in atmospheric environments. Usually there exists a large error of temperature retrieval of satellite remote sensing. In order to improve the accuracy of remote sensing of the tropopause height, a new method of TIROS-N TOVS interpretation has been developed. Its availability has been verified in practical test. The optimum seeking method was used

EFFECTS OF TROPOPAUSE AND POTENTIAL VORTICITY ANOMALY ON FRONTOGENESIS

A two-dimensional,semi-geostrophic numerical model incorporating the tropopause and stratosphere is used to investigate the effects of a positive potential vorticity anomaly and latent heat release on the frontogenetic process and the structure of the resulting frontal zone.It is demonstrated that(1)the inclusion of tropopause and stratosphere significantly changes the frontal structure only in the upper levels;(2)a clearly defined quasi-equivalent barotropic structure and a region of upward motion of finite width appear when a positive potential vorticity anomaly exists on the warm side of the maximum baroclinity in the lower troposphere,especially when it is located on the south edge of the baroclinic zone;(3)the above mentioned structure deteriorates as the frontogenesis proceeds in a dry atmosphere but can be maintained in a moist frontogenetic process with condensational heating;(4)the combination of a positive potential vorticity anomaly and the latent heat release is able to accelerate the frontogenesis significantly with the time needed to form an intense frontal zone reduced to less than 15 h.The results have significant theoretical importance in understanding the complex nature of frontal structure and frontogenesis,especially in understanding the dynamic structure of the subtropical frontal zone observed during early summer over East Asia.

Dynamical and Chemical Features of a Cutoff Low over Northeast China in July 2007:Results from Satellite Measurements and Reanalysis

The European Centre for Medium-Range Weather orology and measurements from the Microwave Limb Forecasts Re-Analysis Interim （ERA-Interim） meteSounder, High Resolution Dynamics Limb Sounder, and Ozone Monitoring Instrument onboard the Earth Observing System Aura satellite were applied to analyze the dynamical and chemical features of a cutoff low （COL） event over northeast China in early July 2007. The results showed the polar stratospheric origin of an upper-level warm-core cyclone at 100 300 hPa, associated with a funnel-shaped tropopause intruding into the mid-troposphere just above the COL center. The impacts of the stratospheric intrusion on both column ozone and ozone profiles were investigated using satellite measurements. When the intensity of the COL peaked on 10 July 2007, the total column ozone （TCO） increase reached a maximum （40-70 DU）. This could be dynamically attributed to both the descent of the tropopause （~75%） and the downward transport of stratospheric ozone across the tropopause （~25%）. Analysis of the tropospheric ozone profiles provided evidence for irreversible transport/mixing of ozone-rich stratospheric air across the tropopause near the upper-level front region ahead of the COL center. This ozone intrusion underwent downstream transport by the upper tropospheric winds, leading to further increase in TCO by 12 16 DU over broad regions extending from east China toward the northern Japan Sea via South Korea. Meteorological analysis also showed the precedence of the stratospheric intrusion ahead of the development of cyclones in the middle and lower troposphere.

Satellite-based Observational Study of the Tibetan Plateau Vortex:Features of Deep Convective Cloud Tops

In this study, an east-moving Tibetan Plateau vortex(TPV) is analyzed by using the ERA-5 reanalysis and multi-source satellite data, including FengYun-2 E, Aqua/MODIS and CALIPSO. The objective is to demonstrate:(i) the usefulness of multi-spectral satellite observations in understanding the evolution of a TPV and the associated rainfall, and(ii) the potential significance of cloud-top quantitative information in improving Southwest China weather forecasts. Results in this study show that the heavy rainfall is caused by the coupling of an east-moving TPV and some low-level weather systems [a Plateau shear line and a Southwest Vortex(SWV)], wherein the TPV is a key component. During the TPV's life cycle, the rainfall and vortex intensity maintain a significant positive correlation with the convective cloud-top fraction and height within a 2.5?radius away from its center. Moreover, its growth is found to be quite sensitive to the cloud phases and particle sizes. In the mature stage when the TPV is coupled with an SWV, an increase of small ice crystal particles and appearance of ring-and U/V-shaped cold cloud-top structures can be seen as the signature of a stronger convection and rainfall enhancement within the TPV. A tropopause folding caused by ageostrophic flows at the upper level may be a key factor in the formation of ring-shaped and U/V-shaped cloud-top structures. Based on these results, we believe that the supplementary quantitative information of an east-moving TPV cloud top collected by multi-spectral satellite observations could help to improve Southwest China short-range/nowcasting weather forecasts.

Simulation of Tropospheric Ozone with MOZART-2:An Evaluation Study over East Asia

Climate changes induced by human activities have attracted a great amount of attention. With this, a coupling system of an atmospheric chemistry model and a climate model is greatly needed in China for better understanding the interaction between atmospheric chemical components and the climate. As the first step to realize this coupling goal, the three-dimensional global atmospheric chemistry transport model MOZART-2 (the global Model of Ozone and Related Chemical Tracers, version 2) coupled with CAM2 (the Community Atmosphere Model, version 2) is set up and the model results are compared against observations obtained in East Asia in order to evaluate the model performance. Comparison of simulated ozone mixing ratios with ground level observations at Minamitorishima and Ryori and with ozonesonde data at Naha and Tateno in Japan shows that the observed ozone concentrations can be reproduced reasonably well at Minamitorishima but they tend to be slightly overestimated in winter and autumn while underestimated a little in summer at Ryori. The model also captures the general features of surface CO seasonal variations quite well, while it underestimates CO levels at both Minamitorishima and Ryori. The underestimation is primarily associated with the emission inventory adopted in this study. Compared with the ozonesonde data, the simulated vertical gradient and magnitude of ozone can be reasonably well simulated with a little overestimation in winter, especially in the upper troposphere. The model also generally captures the seasonal, latitudinal and altitudinal variations in ozone concentration. Analysis indicates that the underestimation of tropopause height in February contributes to the overestimation of winter ozone in the upper and middle troposphere at Tateno.

Satellite Measurements of the Madden–Julian Oscillation in Wintertime Stratospheric Ozone over the Tibetan Plateau and East Asia

We investigate the Madden-Julian Oscillation （MJO） signal in wintertime stratospheric ozone over the Tibetan Plateau and East Asia using the harmonized dataset of satellite ozone profiles. Two different MJO indices -- the all-season Real-Time multivariate MJO index （RMM） and outgoing longwave radiation-based MJO index （OMI） -- are used to compare the MJO- related ozone anomalies. The results show that there are pronounced eastward-propagating MJO-related stratospheric ozone anomalies （mainly within 20-200 hPa） over the subtropics, The negative stratospheric ozone anomalies are over the Tibetan Plateau and East Asia in MJO phases 4-7, when MJO-related tropical deep convective anomalies move from the equatorial Indian Ocean towards the western Pacific Ocean. Compared with the results based on RMM, the MJO-related stratospheric column ozone anomalies based on OM1 are stronger and one phase ahead. Further analysis suggests that different sampling errors, observation principles and retrieval algorithms may be responsible for the discrepancies among different satellite measurements. The MJO-related stratospheric ozone anomalies can be attributed to the MJO-related circulation anomalies, i.e., the uplifted tropopanse and the northward shifted westerly jet in the upper troposphere. Compared to the result based on RMM, the upper tropospheric westerly jet may play a less important role in generating the stratospheric column ozone anomalies based on OMI. Our study indicates that the circulation-based MJO index （RMM） can better characterize the MJO- related anomalies in tropopause pressure and thus the MJO influence on atmospheric trace gases in the upper troposphere and lower stratosphere, especially over subtropical East Asia.

Potential Vorticity and the PV Perspective

This paper highlights some theoretical aspects of potential vorticity（PV） and discusses some of the insights the PV perspective has given us. The topics covered include the nature of PV, its controlling role in the symmetric stability of the atmosphere, its inversion to give the flow field, Rossby waves and their coupling to give baroclinic instability, PV and midlatitude weather systems and, finally, insights into tropical motions.

The Impact of Cut-off Lows on Ozone in the Upper Troposphere and Lower Stratosphere over Changchun from Ozonesonde Observations

In situ measurements of the vertical structure of ozone were made in Changchun （43.53°N, 125.13°E）, China, by the Institute of Atmosphere Physics, in the summers of 2010-13. Analysis of the 89 validated ozone profiles shows the vari- ation of ozone concentration in the upper troposphere and lower stratosphere （UTLS） caused by cut-off lows （COLs） over Changchun. During the COL events, an increase of the ozone concentration and a lower height of the tropopause are observed. Backward simulations with a trajectory model show that the ozone-rich airmass brought by the COL is from Siberia. A case study proves that stratosphere-troposphere exchange （STE） occurs in the COL. The ozone-rich air mass transported from the stratosphere to the troposphere first becomes unstable, then loses its high ozone concentration. This process usually happens during the decay stage of COLs. In order to understand the influence of COLs on the ozone in the UTLS, statistical analysis of the ozone profiles within COLs, and other profiles, are employed. The results indicate that the ozone concentrations of the in-COL profiles are significantly higher than those of the other profiles between ±4 km around the tropopause. The COLs induce an increase in UTLS column ozone by 32% on average. Meanwhile, the COLs depress the lapse-rate tropopause （LRT）/dynamical tropopause height by 1.4/1.7 km and cause the atmosphere above the tropopause to be less stable. The influence of COLs is durable because the increased ozone concentration lasts at least one day after the COL has passed over Changchun. Furthermore, the relative coefficient between LRT height and lower stratosphere （LS） column ozone is -0.62, which implies a positive correlation between COL strength and LS ozone concentration.

Vertical characteristics of ozone variation over the Arctic Chukchi Sea region in 1999

In 1999 summer, Chinese Arctic Research Expedition operated the Chukchi Sea. On Chinese icebreaker Xuelong, we made many high resolution ozonesonds measurements. During the period from August 18 to 24, a synoptic scale observation was taken at 75°N, 160°W. Using the above data, together with TOMS total ozone and NCEP circulation data, we showed that atmospheric ozone amount experienced a high low high variation, with low high low tropopause altitude. Correlation analysis showed a close relation between the total ozone and ozone below 13 km, while the variation of the maximum concentration at about 20 km didn't show any relation to the column ozone. In 500 hPa height maps, there was also the weak strong weak southwesterly pattern. Therefore we suggested that the synoptic system might be responsible to a low ozone advection during this ozone variation.