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Phase-Based Optical Flow Method with Optimized Parameter Settings for Enhancing Displacement Measurement Adaptability
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作者 Zhaoxin Peng Menglian Liu +2 位作者 Zhiliang Wang Wei Liu Xian Wang 《Open Journal of Applied Sciences》 2024年第5期1165-1184,共20页
To enhance the applicability and measurement accuracy of phase-based optical flow method using complex steerable pyramids in structural displacement measurement engineering applications, an improved method of optimizi... To enhance the applicability and measurement accuracy of phase-based optical flow method using complex steerable pyramids in structural displacement measurement engineering applications, an improved method of optimizing parameter settings is proposed. The optimized parameters include the best measurement points of the Region of Interest (ROI) and the levels of pyramid filters. Additionally, to address the issue of updating reference frames in practical applications due to the difficulty in estimating the maximum effective measurement value, a mechanism for dynamically updating reference frames is introduced. Experimental results demonstrate that compared to representative image gradient-based displacement measurement methods, the proposed method exhibits higher measurement accuracy in engineering applications. This provides reliable data support for structural damage identification research based on vibration signals and is expected to broaden the engineering application prospects for structural health monitoring. 展开更多
关键词 Displacement Measurement phase-Based Optical flow Optimized Parameter Setting
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A transient production prediction method for tight condensate gas wells with multiphase flow
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作者 BAI Wenpeng CHENG Shiqing +3 位作者 WANG Yang CAI Dingning GUO Xinyang GUO Qiao 《Petroleum Exploration and Development》 SCIE 2024年第1期172-179,共8页
Considering the phase behaviors in condensate gas reservoirs and the oil-gas two-phase linear flow and boundary-dominated flow in the reservoir,a method for predicting the relationship between oil saturation and press... Considering the phase behaviors in condensate gas reservoirs and the oil-gas two-phase linear flow and boundary-dominated flow in the reservoir,a method for predicting the relationship between oil saturation and pressure in the full-path of tight condensate gas well is proposed,and a model for predicting the transient production from tight condensate gas wells with multiphase flow is established.The research indicates that the relationship curve between condensate oil saturation and pressure is crucial for calculating the pseudo-pressure.In the early stage of production or in areas far from the wellbore with high reservoir pressure,the condensate oil saturation can be calculated using early-stage production dynamic data through material balance models.In the late stage of production or in areas close to the wellbore with low reservoir pressure,the condensate oil saturation can be calculated using the data of constant composition expansion test.In the middle stages of production or when reservoir pressure is at an intermediate level,the data obtained from the previous two stages can be interpolated to form a complete full-path relationship curve between oil saturation and pressure.Through simulation and field application,the new method is verified to be reliable and practical.It can be applied for prediction of middle-stage and late-stage production of tight condensate gas wells and assessment of single-well recoverable reserves. 展开更多
关键词 tight reservoir condensate gas multiphase flow phase behavior transient flow PSEUDO-PRESSURE production prediction
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Effect of droplet characteristics on liquid-phase distribution in spray zone of internal mixing air-mist nozzle
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作者 Wei-li Wu Chang-gui Cheng +2 位作者 Yang Li Shi-fa Wei De-li Chen 《China Foundry》 SCIE EI CAS CSCD 2024年第2期185-196,共12页
In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In ord... In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In order to study the behavior of atomized droplets after reaching the slab surface and to optimize the spray cooling effect,the influence of droplet diameter and droplet velocity on the migration behavior of droplets in the secondary cooling zone was analyzed by FLUENT software.Results show that the droplets in the spray zone and on the slab surface are mainly concentrated in the center,thus,the liquid volume fraction in the center is higher than that of either side.As the droplet diameter increases,the region of high liquid volume fraction on the slab surface becomes wider,and the liquid phase distribution in the slab width direction becomes uneven.Although increasing the droplet velocity at the nozzle exit has little effect on droplet diffusion in the spray zone,the distribution becomes more uneven due to more liquid reaches the slab surface per unit time.A prediction formula of the maximum water flow rate on the slab surface for specific droplet characteristics was proposed based on dimensionless analysis and validated by simulated data.A nozzle spacing of 210 mm was recommended under the working conditions in this study,which ensures effective coverage of the spray water over the slab surface and enhances the distribution uniformity of water flow rate in the transverse direction. 展开更多
关键词 continuous casting secondary cooling zone internal mixing air-mist nozzle droplet characteristics liquid phase distribution water flow rate
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Experimental Investigation of Regular or Wavy Two-Phase Flow in a Manifold
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作者 Xiaowei Nie Lihui Ma +7 位作者 Yiqiu Xu Dong Sun Weibo Zheng Liang Zhou Xiaodong Wang Xiaohan Zhang Weijia Dong Yunfei Li 《Fluid Dynamics & Materials Processing》 EI 2023年第1期37-50,共14页
An experimental study was conducted to investigate the properties of stratified regular or wavy two-phase flow in two parallel separators located after a manifold.A total of 103 experiments with various gas and liquid... An experimental study was conducted to investigate the properties of stratified regular or wavy two-phase flow in two parallel separators located after a manifold.A total of 103 experiments with various gas and liquid velocity combinations in three inlet pipes were conducted,including 77 groups of outlet pipe resistance symmetry and 26 groups of outlet pipe resistance asymmetry trials.The experimental results have revealed that when the gas-liquid flow rate is low,the degree of uneven splitting is high,and“extreme”conditions are attained.When the superficial gas velocity is greater than that established in the extreme case,the direction of the liquid-phase displacement is reversed,while that of the gas remains unchanged.Thus,the degree of gas phase bias tends to be mitigated with an increase in the gas velocity,while the uneven splitting degree of liquid approaches 10%.Finally,varying the gas-phase outlet pipe resistance is shown to effectively change the gas-liquid two-phase flow distribution. 展开更多
关键词 Uneven phase distribution two-phase flow MANIFOLD asymmetric resistance
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Prediction of Flowing Bottomhole Pressures for Two-Phase Coalbed Methane Wells 被引量:5
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作者 LIU Xinfu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第5期1412-1420,共9页
A method is proposed to predict the flowing bottomhole pressures (FBHPs) for two-phase coalbed methane (CBM) wells. The mathematical models for both gas column pressure and two-phase fluid column pressure were dev... A method is proposed to predict the flowing bottomhole pressures (FBHPs) for two-phase coalbed methane (CBM) wells. The mathematical models for both gas column pressure and two-phase fluid column pressure were developed based on the well liquid flow equation. FBHPs during the production were predicted by considering the effect of entrained liquid on gravitational gradients. Comparison of calculated BHPs by Cullender-Smith and proposed method was also studied. The results show that the proposed algorithm gives the desired accuracy of calculating BHPs in the low- productivity and low-pressure CBM wells. FBHP is resulted from the combined action of wellhead pressure, gas column pressure and fluid column pressure. Variation of kinetic energy term, compressibility and friction factors with depth increments and liquid holdup with velocity should be considered to simulate the real BHPs adequately. BHP is a function of depth of each column segment. The small errors of less than 1.5% between the calculated and measured values are obtained with each segment within 25 m. Adjusting BHPs can effectively increase production pressure drop, which is beneficial to CBM desorption and enhances reservoir productivity. The increment of pressure drop from 5.37 MPa2 to 8.66 MPa2 leads to an increase of CBM production from 3270 m3/d to 6700 m3/d and is attributed to a decrease in BHP from 2.25 MPa to 1.33 MPa. 展开更多
关键词 coalbed methane productivity flowing bottomhole pressure gas column pressure two-phase fluid column pressure
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基于CFD-DEM算法的气力输送气固两相流特性分析 被引量:1
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作者 禹言芳 石博文 +2 位作者 孟辉波 丁鹏程 姚云娟 《化工进展》 EI CAS CSCD 北大核心 2024年第3期1133-1144,共12页
超轻粉体颗粒由于质量较小,在运输过程中易受气流扰动而飘散,物料的管道气力输送过程不稳定,易发生堵塞。为了研究超轻粉体颗粒在旋流气力输送中气固两相流流动特性,采用计算流体力学与离散单元法(CFD-DEM),对Komax型静态混合器内气固... 超轻粉体颗粒由于质量较小,在运输过程中易受气流扰动而飘散,物料的管道气力输送过程不稳定,易发生堵塞。为了研究超轻粉体颗粒在旋流气力输送中气固两相流流动特性,采用计算流体力学与离散单元法(CFD-DEM),对Komax型静态混合器内气固两相流动特性进行数值模拟研究。研究发现,带有Komax型元件的水平管道可以改变颗粒的流动情况,改善了水平管道内颗粒堆积和分布不均匀的现象;分别从颗粒相和流体相的流动状态分析得到元件长径比Ar=3时为最优几何结构;通过正交实验极差分析得到影响气固两相流动特性的因素顺序:输送气速>颗粒质量流量>颗粒粒径。当元件Ar=3时,颗粒-颗粒和颗粒-管壁的碰撞次数与碰撞强度呈现负相关,结合出口颗粒流分散状态,优选输送气速为3~4m/s;主要考虑输送气速对管内压降的影响,提出了带有Komax型元件的水平管道气力运输过程中压降与输送气速和轴向位置的经验拟合式。 展开更多
关键词 静态混合器 多相流 稀相旋流气力输送 颗粒流 CFD-DEM耦合法 流动特性
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Effect of solids phase wall boundary condition on simulation of gas-solids flow characteristics in riser 被引量:1
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作者 周新宇 高金森 +1 位作者 徐春明 蓝兴英 《化工学报》 EI CAS CSCD 北大核心 2012年第4期1063-1069,共7页
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基于两步正则化Gauss-Newton迭代算法的ECT图像重建
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作者 张立峰 陈达 刘卫亮 《计量学报》 CSCD 北大核心 2024年第4期546-551,共6页
电容层析成像(ECT)技术求解图像重建问题属于非线性问题,并且存在严重的不适定性。为提高图像重建精度,提出了一种基于两步正则化Gauss-Newton迭代算法的ECT图像重建方法。针对标准正则化Gauss-Newton迭代算法在图像重建中存在的不收敛... 电容层析成像(ECT)技术求解图像重建问题属于非线性问题,并且存在严重的不适定性。为提高图像重建精度,提出了一种基于两步正则化Gauss-Newton迭代算法的ECT图像重建方法。针对标准正则化Gauss-Newton迭代算法在图像重建中存在的不收敛问题,引入了两步迭代方法;改进了正则化矩阵,提高了解估计的精确度;考虑到Gauss-Newton算法对迭代初值的依赖性,加入了同伦算法。最后,进行仿真和静态实验,并与线性反投影(LBP)算法、Landweber算法、Tikhonov正则化算法进行对比。结果表明,该方法可有效提高图像重建精度。 展开更多
关键词 流量测量 电容层析成像 两步正则化 Gauss-Newton迭代算法 正则化矩阵 同伦算法 两相流
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基于IPSO-Elman的气液两相流含气率测量方法
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作者 仝卫国 李茂冉 +1 位作者 石宗锦 寇德龙 《中国测试》 CAS 北大核心 2024年第7期26-32,62,共8页
为安全且非侵入式地测量气液两相流含气率,提出一种电阻层析成像(ERT)陈列电阻与Elman神经网络相结合的含气率测量方法。首先,为加快模型训练速度并避免数据冗余,使用主成分分析(PCA)算法对120维的阵列电阻特征降维。然后,在粒子群(PSO... 为安全且非侵入式地测量气液两相流含气率,提出一种电阻层析成像(ERT)陈列电阻与Elman神经网络相结合的含气率测量方法。首先,为加快模型训练速度并避免数据冗余,使用主成分分析(PCA)算法对120维的阵列电阻特征降维。然后,在粒子群(PSO)算法中引入自适应惯性权重和非线性学习因子,并加入遗传算法(GA)的交叉和变异行为以加快算法收敛速度。最后,通过改进的粒子群(IPSO)算法优化Elman神经网络初始权值和阈值,并建立含气率测量模型。经对比实验发现,PCA-IPSO-Elman含气率测量模型的平均绝对百分比误差为2.92%,且训练时间较IPSO-Elman模型减少68.8%。说明所提方法可以达到预期的测量效果。 展开更多
关键词 气液两相流 截面含气率 改进粒子群 ELMAN神经网络 阵列电阻值
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NUMERICAL SIMULATION OF CHARGED GAS-LIQUID TWO PHASE JET FLOW IN ELECTROSTATIC SPRAYING 被引量:6
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作者 Wang Ze,Jin Hanhui,Wang Junfeng,Luo Tiqian (School of Energy and Power,Jiangsu University of Science and Technology) 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2001年第3期266-270,共5页
Multi-fluid k-e-kp, two phase turbulence model is used to simulate charged gas-liquid two phase coaxial jet, which is the transorting flow field in electrostatic spraying. Compared with the results of experiment, cha... Multi-fluid k-e-kp, two phase turbulence model is used to simulate charged gas-liquid two phase coaxial jet, which is the transorting flow field in electrostatic spraying. Compared with the results of experiment, charged gas-liquid two-phase turbulence can be well predicted by this model. 展开更多
关键词 ELECTROSTATICS Two phase flow TURBULENCE Numerical simulation
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Phase transition in evolution of traffic flow with scale-free property 被引量:2
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作者 沈波 高自友 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第9期3284-3288,共5页
This paper investigates the behaviour of traffic flow in traffic systems with a new model based on the NaSch model and cluster approximation of mean-field theory. The proposed model aims at constructing a mapping rela... This paper investigates the behaviour of traffic flow in traffic systems with a new model based on the NaSch model and cluster approximation of mean-field theory. The proposed model aims at constructing a mapping relationship between the microcosmic behaviour and the macroscopic property of traffic flow. Results demonstrate that scale-free phenomenon of the evolution network becomes obvious when the density value of traffic flow reaches at the critical point of phase transition from free flow to traffic congestion, and jamming is limited in this scale-free structure. 展开更多
关键词 phase transition traffic flow scale-free property cellular automata
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From molecular dynamics to lattice Boltzmann:a new approach for pore-scale modeling of multi-phase flow 被引量:4
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作者 Xuan Liu Yong-Feng Zhu +2 位作者 Bin Gong Jia-Peng Yu Shi-Ti Cui 《Petroleum Science》 SCIE CAS CSCD 2015年第2期282-292,共11页
Most current lattice Boltzmann (LBM) models suffer from the deficiency that their parameters have to be obtained by fitting experimental results. In this paper, we propose a new method that integrates the molecular ... Most current lattice Boltzmann (LBM) models suffer from the deficiency that their parameters have to be obtained by fitting experimental results. In this paper, we propose a new method that integrates the molecular dynamics (MD) simulation and LBM to avoid such defect. The basic idea is to first construct a molecular model based on the actual components of the rock-fluid system, then to compute the interaction force between the rock and the fluid of different densities through the MD simulation. This calculated rock-fluid interaction force, combined with the fluid-fluid force determined from the equation of state, is then used in LBM modeling. Without parameter fitting, this study presents a new systematic approach for pore-scale modeling of multi-phase flow. We have validated this ap- proach by simulating a two-phase separation process and gas-liquid-solid three-phase contact angle. Based on an actual X-ray CT image of a reservoir core, we applied our workflow to calculate the absolute permeability of the core, vapor-liquid H20 relative permeability, and capillary pressure curves. 展开更多
关键词 Molecular dynamics - Lattice BoltzmannMulti-phase flow Core simulation
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On the Liquid-Vapor Phase-Change Interface Conditions for Numerical Simulation of Violent Separated Flows 被引量:4
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作者 Matthieu Ancellin Laurent Brosset Jean-Michel Ghidaglia 《Fluid Dynamics & Materials Processing》 EI 2020年第2期359-381,共23页
Numerous models have been proposed in the literature to include phase change into numerical simulations of two-phase flows.This review paper presents the modeling options that have been taken in order to obtain a mode... Numerous models have been proposed in the literature to include phase change into numerical simulations of two-phase flows.This review paper presents the modeling options that have been taken in order to obtain a model for violent separated flows with application to sloshing wave impacts.A relaxation model based on linear non-equilibrium thermodynamics has been chosen to compute the rate of phase change.The integration in the system of partial differential equations is done through a non-conservative advection term.For each of these modelling choices,some alternative models from the literature are presented and discussed.The theoretical framework for all phase change model(conservation equations and entropy growth)is also summarized. 展开更多
关键词 phase change modeling two-phase flow non-equilibrium thermodynamics compressible flow hyperbolic system of conservation laws
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Effects of internals on phase holdup and backmixing in a slightly-expanded-bed reactor with gas–liquid concurrent upflow 被引量:1
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作者 Kang Yu WeijieWang +2 位作者 Tao Zhang Yumei Yong Chao Yang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第10期2273-2283,共11页
Five different internals were designed,and their effects on phase holdup and backmixing were investigated in a gas–liquid concurrent upflow reactor where the spherical alumina packing particles of three diameters(3.0... Five different internals were designed,and their effects on phase holdup and backmixing were investigated in a gas–liquid concurrent upflow reactor where the spherical alumina packing particles of three diameters(3.0,4.5 and6.0 mm)were slightly expanded under the conditions of varied superficial gas velocities(6.77×10-2-3.61×10-1 m·s-1)and superficial liquid velocities(9.47×10-4-2.17×10-3 m·s-1).The experimental results show that the gas holdup increases with the superficial gas velocity and particle size,opposite to the variational trend of liquid holdup.When an internal component is installed amid the upflow reactor,a higher gas holdup,a less liquid holdup and a larger Peclet number characterizing the weaker backmixing are obtained compared to those in the bed without internals under the same operating conditions.Additionally,the minimal backmixing is observed in the reactor equipped with the internals with a novel multi-step design.Finally,empirical correlations were proposed for estimating gas holdup,liquid holdup and Peclet number with the relative deviations within 11%,12%and 25%,respectively. 展开更多
关键词 INTERNALS phase HOLDUP BACKMIXING Slightly-expanded-bed REACTOR Multiphase flow Hydrodynamics
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Flow Characteristics Analysis of TC18 Titanium Alloy during Hot Deformation Based on Phase Transformation
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作者 SUN Tao TENG Haihao +2 位作者 JIANG Xiaojuan TENG Shuman ZHOU Jie 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第6期1418-1425,共8页
An accurate flow stress model was established by considering the parameters of strain rate,strain and temperature as well asβ→a+βphase transformation in order to develop the plastic forming theory of TC18 titanium ... An accurate flow stress model was established by considering the parameters of strain rate,strain and temperature as well asβ→a+βphase transformation in order to develop the plastic forming theory of TC18 titanium alloy.Firstly,the phase transition kinetics of TC18 titanium alloy during isothermal and continuous cooling at 1073 and 1273 K was studied by thermodynamic calculation,meanwhile,the relationship of volume fraction of phase transition with temperature and time was obtained.Constitutive models were calculated by investigating flow behaviors under hot compression tests with the strain rates of 0.001-1s^(-1) and temperatures of 973-1223 K in the singleβand a+βregions in TC18 titanium alloy,respectively.By combining the phase transformation dynamic kinetics with constitutive models,an accurate flow stress model was established,providing theoretical basis and data support for the hot forging of TC18 titanium alloy. 展开更多
关键词 constitutive modeling TC18 titanium alloy phase transformation flow stress
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Pore-scale study of the pressure-sensitive effect of sandstone and its influence on multiphase flows 被引量:4
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作者 Jun-Jian Li Yang Liu +2 位作者 Ya-Jun Gao Bao-Yang Cheng Han-Qiao Jiang 《Petroleum Science》 SCIE CAS CSCD 2019年第2期382-395,共14页
The pressure-sensitive effect on the pore structure of sandstone was investigated using X-ray computed micro-tomography and QEMSCAN quantitative mineral analysis. In a physical simulation study, we extracted the pore ... The pressure-sensitive effect on the pore structure of sandstone was investigated using X-ray computed micro-tomography and QEMSCAN quantitative mineral analysis. In a physical simulation study, we extracted the pore network model from digital cores at different confining pressures and evaluated the effect of pressure sensitivity on the multiphase displacement process. In both the pore network model and QEMSCAN scanning, the pore structure was observed to be damaged under a high confining pressure. Due to their different scales, the pores and throats exhibited inhomogeneous changes; further, the throats exhibited a significant variation compared to that exhibited by the pores. Meanwhile, the heterogeneity of the pore structure under the two aforementioned activities was aggravated by the elastic-plastic deformation of the pore structure.The pressure-sensitive effect increased the proportion of mineral particles, such as quartz(the main component of the core skeleton), and reduced the proportion of clay minerals. The clay minerals were originally attached to the pore walls or interspersed in the pores; however, as the pressure increased, the clay minerals accumulated in the pores resulting in blockage of the pores. While simulating the multiphase displacement process, increasing the confining pressure was observed to severely restrict the flowability of oil and water. This study promises to improve the efficiency of reservoir development in terms of oil and gas exploitation. 展开更多
关键词 PRESSURE SENSITIVE - QEMSCAN MICRO-CT PORE network model MULTIphase flow
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Phase transition model of water flow irradiated by high-energy laser in a chamber 被引量:1
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作者 魏继锋 孙利群 +1 位作者 张凯 胡晓阳 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第7期459-464,共6页
In the absorption chamber of a high-energy laser energy meter, water is directly used as an absorbing medium and the interaction of the high-power laser and the water flow can produce a variety of physical phenomena s... In the absorption chamber of a high-energy laser energy meter, water is directly used as an absorbing medium and the interaction of the high-power laser and the water flow can produce a variety of physical phenomena such as phase transitions. The unit difference method is adopted to deduce the phase transition model for water flow irradiated by a high-energy laser. In addition, the model is simulated and verified through experiments. Among them, the experimental verification uses the photographic method, shooting the distribution and the form of the air mass of water flow in different operating conditions, which are compared with the simulation results. The research shows that it is achievable to reduce the intensity of the phase transition by increasing the water flow, reducing the power intensity of the beam, shortening the distance the beam covers, reducing the initial water temperature or adopting a shorter wavelength laser. The study's results will provide the reference for the design of a water-direct-absorption-type high-energy laser energy meter as well as an analysis of the interaction processes of other similar high-power lasers and water flow. 展开更多
关键词 phase transition high-energy laser water flow photographic method
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天然气储层裂隙中气-液两相流的流态转变条件数学模型
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作者 闫晋 倪小明 +3 位作者 郭盛强 何庆宏 赵彦伟 宋金星 《煤炭科学技术》 EI CAS CSCD 北大核心 2024年第6期155-164,共10页
气-液两相在储层裂隙中流动时可能存在气泡流、段塞流、环雾流等流态,查明流动时流态转变条件能为气-液两相流流态形成机理研究提供依据,有助于天然气井的生产管控。根据气-液两相流不同流态的流动特点,结合连续介质控制理论和动量守恒... 气-液两相在储层裂隙中流动时可能存在气泡流、段塞流、环雾流等流态,查明流动时流态转变条件能为气-液两相流流态形成机理研究提供依据,有助于天然气井的生产管控。根据气-液两相流不同流态的流动特点,结合连续介质控制理论和动量守恒原理,构建了气泡流-段塞流-环雾状流等流态之间转变的数学模型,确定了各流态间变化的临界条件和主控因素,通过气-液运移产出微观流动物理模拟试验验证了所建数学模型的准确性。结果表明:气-液两相在裂隙中的流态转变是气/液相的物理性质、注气通道孔径、裂隙流动通道孔径、气相流体流速、液相流体流速等因素耦合作用的结果。气泡流与段塞流能否转变主要取决于初生气泡大小、流动通道空间、液相界面波高度;段塞流与环雾流间能否转变取决于气相流体能否击碎液相流体并使之悬浮。不同流态间转变的主要控制因素不同:气泡流与段塞流相互转变的主控因素为裂隙系统的孔径,注气通道孔径越大、流动通道孔径越小,越容易发生段塞流;段塞流与环雾流相互转化的主控制因素为流体流速、气/液相流体的物理性质,气/液相对速度越大、气/液密度差越小、液相表面张力越小,越容易发生环雾流。研究成果能够为天然气储层裂隙中气-液两相流态形成机理和天然气运移产出研究提供理论依据。 展开更多
关键词 储层裂隙 -液两相流 流态转化 流体流速 气泡流 段塞流 环雾流
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Soft Template-Induced Porous Polyvinylidene Fluoride Membrane for Vanadium Flow Batteries
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作者 Dingqin Shi Chunyang Li +1 位作者 Zhizhang Yuan Guojun Li 《Transactions of Tianjin University》 EI CAS 2023年第4期284-292,共9页
Vanadium flow batteries(VFBs)are considered ideal for grid-sc ale,long-duration energy storage applications owing to their decoupled output power and storage capacity,high safety,efficiency,and long cycle life.However... Vanadium flow batteries(VFBs)are considered ideal for grid-sc ale,long-duration energy storage applications owing to their decoupled output power and storage capacity,high safety,efficiency,and long cycle life.However,the widespread adoption of VFB s is hindered by the use of expensive Nafion membranes.Herein,we report a soft template-induced method to develop a porous polyvinylidene fluoride(PVDF)membrane for VFB applications.By incorporating water-soluble and flexible polyethylene glycol(PEG 400)as a soft template,we induced the aggregation of hydrophilic sulfonated poly(ether ether ketone),resulting in phase separation from the hydrophobic PVDF polymer during membrane formation.This process led to the creation of a porous PVDF membrane with controllable morphologies determined by the polyethylene glycol content in the cast solution.The optimized porous PVDF membrane enabled a stable VFB performance for 200 cycles at a current density of 80 mA/cm^(2),and the VFB exhibited a Coulombic efficiency of 95.2%and a voltage efficiency of 87.8%.These findings provide valuable insights for the development of highly stable membranes for VFB applications. 展开更多
关键词 Energy storage Vanadium flow battery Porous polyvinylidene fluoride membrane Soft template-induced phase separation
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基于相场方法的铀枝晶生长电化学-流场耦合研究
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作者 赵干 许晓锐 +2 位作者 周文涛 王亚飞 王德忠 《无机盐工业》 CAS CSCD 北大核心 2024年第4期64-71,共8页
铀枝晶生长是导致乏燃料后处理电解精炼装置发生意外短路的潜在威胁因素,同时会使铀产物夹杂大量熔盐,影响产物纯度。为了更好地理解铀枝晶生长的微观机理,掌握阴极沉积形貌的控制方法,基于相场方法建立了铀在阴极的电沉积模型,研究了... 铀枝晶生长是导致乏燃料后处理电解精炼装置发生意外短路的潜在威胁因素,同时会使铀产物夹杂大量熔盐,影响产物纯度。为了更好地理解铀枝晶生长的微观机理,掌握阴极沉积形貌的控制方法,基于相场方法建立了铀在阴极的电沉积模型,研究了铀枝晶的底部沉积宽度、主枝晶干高度和总沉积面积等形貌参数对流场速度变化的依赖规律。发现外加流场的引入会使铀枝晶的底部沉积宽度降低37.18%,主枝晶干高度降低30.5%,总沉积面积降低49.3%。说明外加流场可以抑制铀枝晶生长,改善铀沉积形貌,但同时也会使破碎的枝晶须重新溶解到熔盐体系中,降低铀电解精炼效率。另外,通过对流场与电解电压、初始浓度等沉积条件耦合影响下铀枝晶形貌特征相图的分析可知,在实际电解精炼过程中,应在保证电解精炼效率的基础上尽量选择高初始浓度和高电解电压的沉积条件,同时设置合理的流场速度以获得理想的铀枝晶沉积形貌。 展开更多
关键词 铀枝晶生长 相场方法 流场
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