A facile route is developed to fabricate BiOCI porous cotton-like nanostructure by using Bi203 and hydrochlo- ric acid as raw materials. The BiOCI nanomaterial is actually hierarchically structured by numerous ultrath...A facile route is developed to fabricate BiOCI porous cotton-like nanostructure by using Bi203 and hydrochlo- ric acid as raw materials. The BiOCI nanomaterial is actually hierarchically structured by numerous ultrathin nanosheets. The nanosheets are around 50-500 nm in lateral size and 2-12 nm in thickness. High-resolution trans- mission electron microscopy and selected-area electron diffraction analyses indicate that single-crystalline BiOCl nanosheets have the predominant growth direction along [110], the bottom and top surfaces are {001} facets, and four lateral surfaces are {110} facets. The BiOCl nanosheets are dominantly enclosed by {001} facets. From the diffuse reflectance spectroscopy spectrum, the light absorption edge and band gap energy （Eg） are estimated to be 416 nm and 2.98eV, respectively. The BiOCl photocatalyst possesses superior activity for methyl orange （MO） degradation under visible light irradiation and the photodegradation efficiency is up to 91.5%/180 min. The correlation between morphology and microstructure with enhanced MO-sensitized photodegradation performance under visible light is investigated.展开更多
In this paper, we proposed and experimentally demonstrated a route-asymmetrical light transmission scheme based on the thermal radiative effect, which means that forward and backward propagations of an optical device ...In this paper, we proposed and experimentally demonstrated a route-asymmetrical light transmission scheme based on the thermal radiative effect, which means that forward and backward propagations of an optical device have different transmittances provided they are not present simultaneously. Employing a fiber-chipfiber optomechanical system, our scheme has successfully achieved a broad operation bandwidth of at least 24 nm and an ultra-high route-asymmetrical transmission ratio （RATR） up to 63 dB. The route-asymmetrical device has been demonstrated effectively with not only the continuous-wave （CW） light but also 10 Gbit/s on-off-keying （OOK） digital signals. Above mentioned unique features can be mostly attributed to the significant characteristics of the thermal radiative effect, which could cause a fiber displacement up to tens of microns. The powerful and significant thermal radiative effect opens up a new opportunity and method for route-asymmetrical light transmission. Moreover, this research may have important applications in all-optical systems, such as the optical limiters and ultra-low loss switches.展开更多
基金Supported by the International Science and Technology Cooperation Program of China under Grant No 2014DFA60150the National Natural Science Foundation of China under Grant Nos 51172113 and 51373086the Taishan Scholar Overseas Distinguished Professorship Program from the Shandong Provincial Government
文摘A facile route is developed to fabricate BiOCI porous cotton-like nanostructure by using Bi203 and hydrochlo- ric acid as raw materials. The BiOCI nanomaterial is actually hierarchically structured by numerous ultrathin nanosheets. The nanosheets are around 50-500 nm in lateral size and 2-12 nm in thickness. High-resolution trans- mission electron microscopy and selected-area electron diffraction analyses indicate that single-crystalline BiOCl nanosheets have the predominant growth direction along [110], the bottom and top surfaces are {001} facets, and four lateral surfaces are {110} facets. The BiOCl nanosheets are dominantly enclosed by {001} facets. From the diffuse reflectance spectroscopy spectrum, the light absorption edge and band gap energy （Eg） are estimated to be 416 nm and 2.98eV, respectively. The BiOCl photocatalyst possesses superior activity for methyl orange （MO） degradation under visible light irradiation and the photodegradation efficiency is up to 91.5%/180 min. The correlation between morphology and microstructure with enhanced MO-sensitized photodegradation performance under visible light is investigated.
基金Acknowledgements This work was partially supported by the National Basic Research Program of China （No. 2011CB301704）, the Program for New Century Excellent Talents in Ministry of Education of China （No. NCET-11-0168）, a Foundation for the Author of National Excellent Doctoral Dissertation of China （No. 201139）, the National Natural Science Foundation of China （Grant Nos. 11174096 and 61475052）, and the Opened Fund of the State Key Laboratory on Advanced Optical Communication System and Network （No. 2015GZKF03004）.
文摘In this paper, we proposed and experimentally demonstrated a route-asymmetrical light transmission scheme based on the thermal radiative effect, which means that forward and backward propagations of an optical device have different transmittances provided they are not present simultaneously. Employing a fiber-chipfiber optomechanical system, our scheme has successfully achieved a broad operation bandwidth of at least 24 nm and an ultra-high route-asymmetrical transmission ratio （RATR） up to 63 dB. The route-asymmetrical device has been demonstrated effectively with not only the continuous-wave （CW） light but also 10 Gbit/s on-off-keying （OOK） digital signals. Above mentioned unique features can be mostly attributed to the significant characteristics of the thermal radiative effect, which could cause a fiber displacement up to tens of microns. The powerful and significant thermal radiative effect opens up a new opportunity and method for route-asymmetrical light transmission. Moreover, this research may have important applications in all-optical systems, such as the optical limiters and ultra-low loss switches.
